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MAP SERIES NO. 129 MINERAL RESOURCES OF JEFFERSON COUNTY, FLORIDA BY PAULETTE BOND, P.G.#182, RONALD W. HOENSTINE AND ED LANE FLORIDA GEOLOGICAL SURVEY DIVISION OF RESOURCE MANAGEMENT DEPARTMENT OF NATURAL RESOURCES TALLAHASSEE, FLORIDA 1989 ISSN 0085-0624 JEFFERSON COUNTY INTRODUCTION In recent years, Florida's population has increased dramatically. This population growth has been accompanied by extensive douelopmnt. Development, by its very nature, may render important mineral resources inaccessible to mining even though those resources are essential to the various activities that accompany growth. The industries associated with the utilization of mineral resources have a positive impact on Florida's economy. Extraction, transportation and distribution of mineral resources generate employment for the state's citizens and are a source of revenue for state and local government. Utilization and conservation of mineral resources may be in conflict with the goals and projects that arise from rapid population growth. In 1985 and 1986, the Florida Legislature enacted legislation which requires each county to establish a comprehensive land use plan with certain deadlines. These land use plans should serve to reconcile the pressures of population growth with wise utilization of essential mineral resources. The information provided here may also be applied to problems involving zoning, road construction and waste disposal site location. As a response to this act and at the request of the Apalachee Planning Council, the Florida Geological Survey initiated a study of the mineral resources of Jefferson County. The results of the study are presented as a map with an accompanying text written for use by state and local planners. At present there is no commercial production of mineral commodities In Jefferson County. The general assessment of mineral resource potential presented here is not site specific. Resource evaluation for this report is based on a number of sources including Florida Geological Survey reports and unpublished data, field reconnaissance, state and federal statistical data, and state and federal officials. The diversity of sources as well as their close association with the various aspects of resource evaluation lend substantial confidence to the general assessments and inferences of this report. METRIC CONVERSION FACTORS in order to prevent the awkward duplication of English and metric units in this report the following conversion factors are provided. MULTIPLY BY TO OBTAIN feet 0.3048 meters mies 1.609 kilometers GEOMORPHOLOGY White, Vernon and Purl (in Purl and Vernon, 1964) divided the state into a number of general regions. Jefferson County includes three of these regions: the Northern Highlands, the Gulf Coastal Lowlands and the Coastal Swamps. Calico Hill, a minor feature superimposed on the Gulf Coastal Lowlands of Jefferson County is mapped by White, Vernon and Purl (in Puri and Vernon, 1964) but is not discussed In their work. Yon (1966) completed a detailed study of Jefferson County in which he described landforms which are locally superimposed on the regionally extensive features proposed by White, Purl and Vernon. The Cody Escarpment separates the Northern Highlands from the Gulf Coastal Lowlands in Jefferson County (Figure 1). The Northern Highlands is a series of gently sloping, well drained plateaus which have been dissected by dendritic streams. This geomorphic region extends north into Georgia and Alabama. The Cody Escarpment, which is considered to be one of the most persistent topographic breaks in Florida, extends east from the Apalachicola River Valley to central Putnam County and is locally breached by the valleys of major streams. The Northern Highlands have been locally subdivided; in the region that includes Jefferson County they are represented by the Tallahassee Hills. The Tallahassee Hills have been extensively dissected by stream erosion and subsurface dissolution of underlying limestone (Yon, 1966). They are characterized by relief ranging from less than 50 feet to approximately 100 feet with elevations locally of approximately 160 feet above mean sea level (MSL). In Jefferson County, the Tallahassee Hills are characteristically interspersed with lakes, ponds and numerous small streams. The Tallahassee Hills of eastern Jefferson County in the vicinity of the Aucila River are characterized by numerous wetland areas. Hills in this area are isolated and relief is somewhat lower than relief noted in westem Jefferson County (Yon, 1966). The area of Jefferson County, which is characterized by the Tallahassee Hills, is underlain mainly by the Pliocene Series (COSUNA chart, Gulf Coast Section, Braunstein et al., 1988), Miccosukee Formation (Hendry and Yon, 1967). The Gulf Coastal Lowlands are bounded to the north in Jefferson County by the Cody Escarpment. They are low in elevation, poorly drained and extend south to the Gulf of Mexico. In Jefferson County, this geomorphic region is occupied by the extension of the Woodville Karat Plain from Leon and Wakulla Counties (Yon, 1966) (Figure 1). The Woodvile Karst Plain (Hendry and Sproul, 1966) is a low, gently sloping plain characterized by dune sands lying on a limestone surface. The porous dune sands have allowed water to percolate downward, causing dissolution in underlying limestones. Collapse of these limestones has resulted In the development of shallow sinkholes (Yon, 1966). The coastline is marshy and Irregular without sand beaches or barrier slelands. It is placed Into the Coastal Swamps region by White, Puri and Vernon (Puri and Vernon, 1964). The absence of beaches and barriers is due to the shallow offshore slope which results in a lack of wave actMty and an Insufficlent sand supply. Virtually all of the valleys in Jefferson County are associated with rivers which flow through the county and may be classified as river valley lowlands (Yon, 1966). Although a number of streams originate in Jefferson County or (low through it the three major ones are the Auclla. Waciesa and St Marks Rivers (Mineral Resources Map). Healy (1975) mapped four marine terraces In the Tallahassee Hils of Jefferson County (Figure 2). These terraces Include the Haziehurst Terrace (215-320 feet MSL), the Coharie Terrace (170-215 feet MSL), the Sundedand Terrace (100-170 feet MSL), and the Wicomico Tenace (70-100 feet MSL) (Figure 2). Healy mapped these four terraces in Jefferson County on theastes of contour elevations and topographic expression of land forms. A morede- taled study (Yon. 19),. which considered bedrock and cowering sediments in addition to topographic elevaons and rlxpreselon, did not recognize marine terraces In the Tallahassee His of Jefferson County. Thus, the Hazlehurat, Cohade, and Sunderland Terraces probably represent elevation zones, as opposed to true marine terraces and will not be discussed further In this report. The three marine terraces superimposed on the Gulf Coastal Lowlands of Jefferson County are discussed by Yon (1966) and Healy (1975), who also provide summaries of the historical development of the terrace nomenclature pertinent to Jefferson County. Reference should be made to those publications for additional Information. The Wicomico Terrace (70-100 feet MSL) in Jefferson County (Yon, 1966) is bounded to the north by the Cody Scarp and includes the area between the northern bounding scarp of the Pamlico Terrace and the Cody Scarp. Healy (1975) extends this terrace Into the Northern Highlands based on elevation. Sediments associated with the Wicomico Terrace. include sand and clayey sand which are deposited almost entirely on Suwennee Limestone (Yon, 1968). The Pamlico Terrace in Jefferson County extends from the 10-foot contour (the elevation of the base of the small scarp which marks the landward limit of the Silver Bluff Terrace) inland approximately eight miles (Yon, 1966). The northern boundary of the Pamlico Terrace in Jefferson County is marked by a scarp, which has Its toe at an elevation ranging from 26 to 30 feet, and exhibits eight to ten feet of relief. The Pamlico Terrace in Jefferson County is a limestone plain which is covered by varying thicknesses of sand and clay. The surface is well drained in eastern Jefferson County but is poorly drained with swamp development to the west (Yon, 1966). Calico Hill is described by Yon (1966) as a sand ridge with approximately 12 feet of relief oriented parallel to the Wacissa River and may represent a Pamnlico dune. The Silver Bluff Terrace, the youngest and lowest coastal terrace, extends from the coast to the 10-foot contour line which marks the base of the small scarp (Yon, 1966). Adjacent to the present coastline the Silver Bluff Terrace is characterized by coastal marshlands developed on the underlying Suwannee Limestone. GEOLOGY The rocks and sediments that underlie Jefferson County range in age from Mesozoic to Recent. To date, the deepest penetration of subsurface sediments in the county occurred at a depth of 7,909 feet (MSL). These sediments, obtained from an oil well (W-1854, section 1, Township 2S, Range 3E), were identified as Triassic (?) diabase and related igneous rocks deposited approximately 210 million years ago (Applin, 1951; Arthur, 1988). Thousands of feet of Mesozoic Era siliciclastics and carbonates limestones and dolomites) are overlain by carbonates and near-surface sillciclastic sediments Including sand, silt, and clay that were deposited during the Cenozoic Era. Figure 3a shows the location of shallow geologic cross sections used In this report. The oldest exposed unit In Jefferson County is the Suwennee ULimestone, deposited 24 to 37 million years before present (B.P.), during the Ollgocene Epoch. It crops out extensively (although locally covered by a veneer of Pleistocene sands) south of Wacissa in southern Jefferson County (Yon, 1966) and limited data suggests its thickness ranges from 150 180 feet (Figure 3b). Uthologically It is a pale orange, finely crystalline, fossliferous limestone. Locally, the Suwannee Umestone may be silicifled or dolomitized (Yon, 1966). The Miocene age St Marks Formation lies above the Suwannee Limestone in much of Jefferson County, although locally it is absent (Yon, 1966). In Jefferson County, it is a white to very pale orange, finely crystalline, sandy, slty, clayey limestone. Its major outcrop areas occur in southern Jefferson County. The St. Marks Formation may be silicified or dolomitized in outcrop as well as in the subsurface (Yon, 1966). It ranges in thickness from approximately 20-110 feet (Figure 3c). In Jefferson County, the Miocene age, 15 to 23 million years B.P., Hawthorn Group overlies the St.Marks Formation and, locally, the Suwannee Umestone where the St. Marks is absent. Lithologically, the sediments of the Hawthorn Group in Jefferson County consists of pale olive, light greenish-gray, yellowish-gray, light gray, and moderate yellow, sandy, waxey, phosphatic clay. The clay is Interbedded with very fine to medium, clayey quartz sands that contain phosphate. The clays and sands are frequently cherty and often associated with stringers of sandy calcilutites. The Hawthorn Group usually ranges in thickness from approximately 50 to 70 feet, although, In eastern Jefferson County Yon (1966) noted that this unit locally attains thicknesses of approximately 240 feet. The Miccosukee Formation, which lies above the Hawthorn Group In Jefferson County, was considered by Hendry and Yon (1966) to be Late Miocene In age. As more data has become available, recent workers have assigned the Miccosukee Formation to the Pliocene (COSUNA Chart, Gulf Coast Section, Braunstein et al., 1988). Locally, the Miccosukee lies above the St. Marks Formation or the Hawthorn Group. Lithologically the Miccosukee Formation Is an assemblage of lenticular clayey sands and clay beds which are laterally discontinuous (Yon, 1966). Generally, the Miccosukee Formation is a moderately to poorly sorted, coarse to fine grained, variably colored, clayey quartz sand. The thickness of the Miccosukee Formation in Jefferson County is Irregular but ranges up to 160 feet in thickness (Yon, 1966). These distinctive sediments can be observed along numerous road cuts throughout the northern half of the county. Variable thicknesses of Pleistocene, 2.8 million to 0.1 million years B.P., clayey quartz sand overle the St. Marks Formation and the Suwannee Umestone in southern Jefferson County and the MIccosukee Formation northwest of Waclssa. Younger Holocene, 0.1 million years B.P., deposits consisting of reworked Pleistocene sand and quartz sand derived from the Miccosukee Formation occur along stream valleys (Yon, 1966). MINERAL RESOURCES The intent of this discussion is to provide Information on the distribution of various mineral resources in Jefferson County. It will also present the results of tests applied to specific samples from the county. These tests were carried out to define properties of a sample related to its potential industrial uses. The data presented here are from scattered locations and are Intended, where favorable, to provide a basis for further investigation. The mineral commodities, which are discussed here, include limestone, dolomite, clay, clayey sand and peat. It is essential to note that many factors must be considered before a commodity is actually mined. These include the quality or purity of a mineral deposit, the amount of material ultimately available for mining and the thickness of overlying but unusable material (overburden) as well as transportation costs and distance to market. Occasional variations between the geologic cross-sections and the mineral resources map may occur. The mineral resources map Is designed as an overview of mineral resources In Jefferson County. The geologic cross-sections are Included to provide information on the distribution of llthologies from the surface to depths for which data Is generally available. This report is Intended to document the general distribution of potential mineral resources. Utmestone Limestone is a sedimentary rock composed mainly of the mineral calcite (calcium car- bonate) with the chemical formula CaCO3. Yon (1966) noted that the Suwannee Limestone of Ollgocene age is the most important potential source of limestone in Jefferson County. The limestone shown on the mineral resources map accompanying this report is almost entirely Suwannee Umestone, which contains in excess of 95 percent calcium carbonate. The thickness of overburden should not inhibit mining in most areas as the Suwannee Umestone lies within approximately 20 feet of the surface from just south of the town of Wacissa to the coast and, In most areas, Is covered by 10 feet or less of overburden as shown on the geologic map of Jefferson County (Yon, 1966). There is no current commercial production of limestone In Jefferson County and the limestone of the county were rated in a statewide report on mineral resources as having low potential for development (Schmidt, et al., 1979). This rating was based on the fact that even though limestone is present in southern Jefferson County (Knapp, 1978; Schmidt, 1979), it has not been proven economic. Yon (1966), however, noted that in 1964 limestone was mined by the county road department and Buckeye Cellulose Company for roadbase In the southern part of the county. Yon (1966) suggested that the Suwannee Limestone might potentially be used as roadbase course material, agricultural limestone, or quick and hydrated lime. Dolomite Dolomite is a sedimentary rock containing more than 50 percent of the mineral calcite and dolomite, in which dolomite is the most abundant (Schmidt, et al., 1979). Although not currently being mined, the distribution of dolomite in Jefferson County is shown on the Mineral Resources Map. Yon (1966) noted that the dolomite in Jefferson County Is primarily located along the Aucilla River. The thickness of the dolomite has not been determined. Schmidt et al. (1979) classify an area In southernmost Jefferson County as having low potential for the development of dolomite. "Low potential" In this report Indicates that although some dolomite is present it has not been proven economic. Clay Clay has not been mined in Jefferson County to date. In Jefferson County, Yon (1906) reported that montmorlonites and kaolinites are associated with the Hawthorn Group, the Miccosukee Formation and the undiferentiated sediments of Pleistocene age. It is noted that some of the clays from the Miccosukee Formation have a very low sand content, which is favorable for commercial use. However, It Ia also noted that these delays generally occur In discontinuous lenticular deposits Terrace deposits of southern Jefferson County contain sandy mrnonrllonitcc days. Calver (1949) sampled day sediments from a 9-1/2 foot test boring located one and one- half mie east of Waciasa (Jf-1, section 14, Township IS, Range 3E). Tests Indicated that it may be suitable for porous common brick (Table 1, Mineral Resources Map). Yon (1966) arranged for seven clay samples from Jefferson County to be tested for various physical properties. Of seven samples tested, two samples were found to be suitablefor malng brick and one sample with the addition of alkali was poesibly suitable or pottery or decorative tie (Jf-2, section 33ac, Township 18, Range 4E, Table 2 and Jf-3, section 19bb, Township 18, Range SE, Table 3, Mineral Resources Map). Clayey Sand Sand deposits In Jefferson County are mainly associated with the Miccosukee Formation. The sand ranges in size from very fine to very coarse grained and is predominantly fine to medium grained. The Florida General Soils Atlas for Regional Planning Districts I and II assigns the Lakeland-Troup soil association to much of the area mapped as clayey sand on the Mineral Resources Map. The Lakeland-Troup association is further noted to be a good source of sand and Is described as sandy throughout with "very thick sandy layers over loamy subsoils" (Florida Division of State Planning, 1974). This rating of "good" Indicates that the soil generally contains a layer of sand at least three-feet thick which has its top within at least six-feet of the surface. It is noted, however, that the ratings do not consider location of the water table, quality or quantity of the deposit or other factors affecting mining. Yon (1966) had divided the sands in Jefferson County Into primary clayey quartz sands and secondary clayey quartz sands based on the relative purity of the sands. It must be noted, however, that sands examined in this area are generally mixed with clay and are iron stained so that the outlook for their commercial development is not good. Sand Is not currently mined in Jefferson County. Past Peat accumulates when plant material Is deposited In a wet environment in which the action of decomposing organisms Is inhibited (Bond, at al., 1986). Although peat Is not currently mined in Jefferson County, the county has extensive wetlands. Davis (1949) in his comprehensive survey of Florida peatiands noted that there are a few small marshes which contain peat as well as some tyty and bay swamps which are characterized by peat accumulation. Jones at al., (1907) also noted the presence of organic underlying several small marshes. Peat is used extensively in a variety of horticultural and agricultural applications in Florida. Undifferentiated Resources Large areas of the county have surface and near-surface sediments comprised of sands, sandy clays, clay, mad, and organic muck. These undifferentiated resources are present throughout much of the northeastern and southwestern parts of Jefferson County. The heterogeneous nature of these sediments would tend to preclude their large scale economic marketability. Two sites in this area were sampled for grain size analysis (JF-4 and JF-5, Mineral Resources Map). Results of these analyses are shown in Table 4. The values obtained Indicate that the sands have no economic potential at this time. Locally, however, where costs are not prohibitive and the need is present for uses such as top soil or road fill, extraction Is feasible. The possibility does exist that a future comprehensive Investigation of these undifferentiated sediments may lead to economic or industrial applications. REFERENCES Applin, P. L, 1951, Preliminary report on buried pre-Mesozoic rocks in Florida and adjacent states: U.S. Geological Survey Clrcular 91, 28 p. Arthur, J. D., 1988, Petrogenesis of Early Mesozoic tholelitein the Florida basement and overview of Florida basement geology: Florida Geological Survey Report of investigation 97,39 p. Bates, R. L, and Jackson, J. A., eds. 1980, Glossary of geology (2nd edition): American Geological Institute, Falls Church, Virginia, 751 p. Bell, 0.G., 1924, A preliminary report on the clays of Florida (exclusive of fuller's earth): in Florida State Geological Survey, Fifteenth Annual Report 1922 1923, 266 p. Bond, P., Campbell, K. M., and Scott, T. M., 1986, An overview of peat in Florida and related issues: Florida Geological Survey Special Publication 27,151 p. Braunstein, J., Huddlestun, P., Blel, R., 1988, Gulf Coast Region: Correlation of stratigraphic units of North America (COSUNA) Project, The n Association of Petroleum Geologists. Calver, J. L, 1949, Florida kaolins and days: Florida Geological Survey Information Circular 2, 59 p. Davis, J. H., Jr., 1949, The peat deposits of Florida, their occurence, development, and uses: Florida Geological Survey Bulletin 30,247 p. Florida Department of Transportation, 1984, Manual of Florida sampling and testing methods, sieve analysis of fine and coarse aggregates: FDOT, designation FM 1-T 027, 6 p. Florida Division of State Planning, 1974, The Florida general soils atlas with interpretations for regional planning districts I and II: Florida Department of Administration, Division of State Planning, Bureau of Comprehensive Planning, 35 p. Healy, H. G., 1975, Terraces and shorelines of Florida: Florida Geological Survey Map Series 71, scale 1:2,000,000. Hendry, C. W., Jr., and Sproul, C. R., 1966, Geology and ground-water resources of Leon County, Florida: Florida Geological Bulletin 47, 178 p. and Yon, J. W., Jr., 1967, Stratigraphy of Upper Miocene Miceoeukee Formation, Jefferson and Leon Counties. Florida: American Association of Petroleum Geologists Bulletin, v. 51, p. 250-256. Jones, G. B., Tharp, W. E., and Belden, H. L, 1907, Soils survey of Jefferson County, Florida: U.S. Department of Agriculture, Bureau of Sols, 34 p. Knapp, M. S., 1978, Environmental Geology Series Valdosta Sheet: Florida Bureau of Geology Map Series 88, scale 1:250,000. Purl, H. S., and Vernon, R. 0., 1964, Summary of the geology of Florida and a guidebook of the classic exposures: Florida Geological Survey Special Publication 5 (revised), 312 p. Schmidt, W., 1979, Environmental Geology Series Tallahassee Sheet: Florida Bureau of Geology Map Series 90, scale 1:250,000. Hoenstine, R. W., Knapp, M. S., Lane, E., Ogden, G. M., Jr., and Scott, T. M., 1979, The limestone, dolomite and coquina resources of Florida: Florida Bureau of Geology Report of Investigation 88, 54 p. Yon, J. W., Jr., 1966, Geology of Jefferson County, Florida: Florida Bureau of Geology Bulletin 48, 119 p. Table 1 Physical Properties of Wacissa Clay JF-1, Mineral Resources Map (From Calver, 1949) SPlasticity, judged by feel............................................... Good W ater of plasticity......................................................... 31.01% Linear air shrinkage....................................................... 8.6% Modulus of rupture, average.. 210.0 pounds per square Inch. Slaking tst..........................................................................Fast Color ............................................................................ Brown Fire Tests: Temp. Near Sheer Absorption OF Percent Percent Porosity or Par cat 1742 1.0 14.9 34.8 Reddish Orange 1922 2.5 14.8 35.0 Reddish Orange 2102 2.0 14.1 34.0 Brick Red 2174 2.5 14.4 34.0 Brick Red 2246 2.5 13.6 32.5 Brick Red 2390 2.5 13.8 33.3 Brick Red Table 2 Table 2 Physical Properties for Clay JF-2, Mineral Resources Map (From Yon, 1966) Working characteristcs................... short working, stick, plastic Water of plasticity..................................................... 25.0 Drying shrinkage............................ .......... Dry strength.............................................................Fair, warping Slow Firing Test: Temp. near Shrinkage Absorption OF Per coa Per cent Hardness Color Fair Hard Fair Hard Hard Hard Very Hard Very Hard ULight Brown Light Brown Brown Chocolate Chocolate Chocolate Table 3 Physical Properties for Clay JF-3, Mineral Resources Map (From Yon, 1966) Working characteristics............... long working, smooth, plastic W after of plasticity................................................. ............ 2 .0% Drying shrinkage................................................... ......... .. 5% ry strength...........................................................Fair, warping Slow Firing Test: Temp. Unear Shrinkage OF Per cent Absorption Par cent arridnew Fair Hard Fair Hard Hard Hard Very Hard Steel Hard cnlnr Tan Tan Tan Tan Buff Tan OUve Tan Potential use: light color, some cracking, shrinkage a little high, addition of alkali might make a pottery or decorative tie. Table* Screen aoyse of sand In Jefferson county, Florida. Labortory Tet hte eponelts sron Iinylsis iteem no. and Crauitatie weiht Percent Retained Section Nsthod Finenssu slipte N. Trmhp, SRen of Satin 4 8 16 30 0s 100 Noduts* sec 3bs Jf-4 m, MN Spot 6.73 8.12 10.81 19.21 43.35 100.0 1.M ms ltbb Jft- TIN. RMa pot 0 0.27 0.85 6.94 .09 t0.o 1.41 *Finenss Nodulus: A mew of evaluating and and s ort deposits tthlh consists of sieving sempls through stant rd set of steves, sdlirn the ctmultatiln eight percentes of the Individual screens, dividing by 100, and comparin the resultant finienss modulus uber to various specflcetloen roqulrson ts(tese and Jackluen, 19M). The finr e modulus is an Indt of the finens or coarMeM u of an aggregate., but gives no Idea of grading. The higher the finenesso moduus the coMer the greete (ASM, 197). The method of leve analysis presented here folious that outlined In AST 107., v. 4.02, section C 136-11. The redr I s ao referred to the Floride DOT Manual of Forid suptingn ad testing asthodi for susgnltes, FDOT, dsinttion FN I-T 027. The well and quarry system used in this report uses the rectangular system of section. township and rang tfor identification. The weal or outcrop number consilsts of six parts: W lotr well or L for quarry. county abreviation, the Township, Range. and Section, and the quarter/quarter location within the section. FIGURE 1 GEOMORPHOLOGY (modified from White, 1970) -N- 11 SCALE FOR FIGURES 1,2 AND 3a FIGURE 3a CROSS SECTION LOCATIONS P55TfaTSR ":0I.. r, VTiTIMCL IAEXAMdATIOS I APIUATKLY 1M W TiNG FIGURE 3b CROSS SECTION A-A' P5519657565 EXPLANATION 215'-320' HAZLEHURST TERRACE 170"-215' COHARIE TERRACE 100'-170' SUNOERLAND TERRACE 70'-100' WICOMICO TERRACE 42"-70' PENHOLOWAY TERRACE 25'-42' TALBOT TERRACE 10'-25' PAMLICO TERRACE 0-10' SILVER BLUFF TERRACE FIGURE 2 TERRACES AND SHORELINES (modified from Healy, 1975) FIGURE 3c CROSS SECTION B-B' SCALE FOR FIGURES 3b AND 3c ~___ _~ |
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