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Map Series No. 133 MINERAL RESOURCES OF CLAY COUNTY, FLORIDA By Steven M. Spencer, P.G. #319, J. William Yon, Jr., Ronald W. Hoenstine and Ed Lane FLORIDA GEOLOGICAL SURVEY WALTER SCHMIDT, STATE GEOLOGIST AND CHIEF DIVISION OF RESOURCE MANAGEMENT DEPARTMENT OF NATURAL RESOURCES TALLAHASSEE, FLORIDA 1991 ISSN 0085-0624 CLAY COUNTY INTRODUCTION in recent years considerable attention has been focused on Florida's rapid development, the accompanying population increase, and their effects on the state's important mineral resources. Frequently, this development occurred in areas underlain by known mineral deposits, precluding extraction of the minerals. These mineral resources provide substantial employment and income to the private sector as well as taxes to county and state governments. One response to this growing conflict between rapid growth and development of the state's mineral resources was in the form of legislation enacted by the Florida Legislature in 1985 requiring each county to establish a comprehensive land use plan. Additional guidelines and due dates were established by the 1986 Florida Legislature. In response to this act and at the request of the Northeast Florida Regional Planning Council, the Florida Geological Survey initiated a study of Clay County's mineral resources. The objective of this report is to interpret and summarize geologic data (i.e., core and well cutting descriptions, geophysical logs, and data derived from field reconnaissance) in a format appropriate for use by city and county planners. A knowledge of Clay County's mineral resources is basic and integral to the process of initiating, developing and implementing an effective comprehensive land use plan. This information is essential to planners and officials in their analyses of urban and rural development in such areas as zoning, road construction and the establishment of waste disposal sites. Factors used in evaluating the economic value of the county's known and potential mineral resources are varied, changing and in many instances interrelated, thus complicating an accurate assessment. The evaluation process is inherently dependant on an extensive exploration program to determine reserves, content and extent of specific mineral resources. In addition, such factors as operating expenses, transportation, beneficiation, reclamation and capital costs of mining must be included in the overall calculations. Resource evaluation for this report is based on a number of sources including Florida Geological Survey reports and unpublished data, field reconnaissance, state and federal statistical data, company reports, questionnaires, and numerous discussions with mining company personnel and state and federal officials. Although detailed information on company statistics is confidential, information of a more general nature is readily available or can be reasonably extrapolated from existing data. The diversity of sources as well as their close association to the various aspects of resource evaluation lends substantial confidence to the general assessment and inferences of this report. tMeTRIC CONVERSION FACTORS To prevent the duplication of English and metric units in this report, the following conversion factors are provided. MULTIPLY feet miles fahrenheit GEOMOR Located in northeast Florida, (1970) Northern (Proximal) Zone This zone is characterized by a extends across the northern Florid Western Highlands of Florida's p divided into a number of geomori are present in Clay County. Thes Trail Ridge, Duval Upland, Peoria 1). The Northern Highlands cove County (Figure 1). The topograpl numerous lakes and elevations tha mean sea level (MSL). The ea Highlands in Clay County is marl which approximates the 100 feet al (1970) describes this break as the the Atlantic Coastal Plain. Trail Ridge is located along th border of Clay County. This dist Northern Highlands. Elevations northeastern Florida, averaging ove mineral deposits present in the BY TO OBTAIN 0.3048 meters 1.609 kilometers 5/9 F-32) centigrade PHOLOGY Clay County falls within White's which traverses northern Florida. continuous broad upland which a peninsula and westward into the )anhandle. The Northern Zone is phic subdivisions, several of which e include the Northern Highlands, Hill and the Eastern Valley (Figure rs the western one-third of Clay hy of this area is characterized by at frequently exceed 200 feet above stern boundary of the Northern ked by the Cody Scarp, the toe of bove MSL elevation contour. White best known relict marine scarp of he northwestern and west-central inctive feature is a subunit of the s here are among the highest in er 200 feet above MSL. The heavy- area represent one of the largest concentrationsl inUtl I|| |11 a zUI[ t a a ar ie U O I l o nii, s heavy-mineral industry. The Duval Upland is located to the east of Trail Ridge and the Northern Highlands. This north-south approximately linear geomorphic feature is characterized by elevations much lower than those of Trail Ridge, averaging 100 feet above MSL. The gently sloping topography of the Duval Uplands includes much of the central one-third of Clay County. The Eastern Valley occupies the eastern portion of Clay County. Although placed by White (1970) in the Central Highlands, this feature extends into the Northern (Proximal) Zone and lies contiguous to the eastern boundary of the Duval Upland in Clay County. A number of swampy areas are present in the Eastern Valley. In general, this area has the lowest elevations in the county, ranging from a low of approximately six feet above MSL along the St. Johns River to 30 feet above MSL near the eastern edge of the Duval Upland (Figure 1). White (1970) interpreted the Eastern Valley as representing an ancient beach-ridge plain with relict beach ridges throughout that are coast- parallel. Peoria Hill is a small, irregular shaped feature identified by White (1970) as being present in the northeastern part of Clay County along the St. Johns River. Its elevations are distinctly higher than the surrounding Eastern Valley. In addition to the above geomorphic features a number of relict terraces formed by ancient seas are present in the county. Healy (1975) identified seven terraces in Clay County based on land surface elevations (Figure 2). In order of descending elevation, they are: Hazelhurst Terrace (215-320 feet above MSL), Coharie Terrace (170- 215 feet above MSL), Sunderland Terrace (100-170 feet above MSL), Wicomico Terrace (70-100 feet above MSL), Penholoway Terrace (42- 70 feet above MSL), Talbot Terrace (25-42 feet above MSL) and Pamlico Terrace (10-25 feet above MSL). GEOLOGY The geology of Clay County is characterized by surface and near- surface occurrences of siliciclastic sediments (quartz sand, silt, clayey sand and clay) underlain by thick sequences of carbonates (limestone and dolomite). In turn, these sediments overlie Paleozoic Era base- ment rocks at depths of more than 3,000 feet below land surface. A deep oil test well (W-1590, section 4, Township 6S, Range 25E) drilled by Humble Oil and Refining Company encountered a Paleozoic age quartzitic sandstone at a depth of approximately 3,600 feet below MSL (Applin, 1951). Figure 3a is a map showing the location of geologic cross sections used in this report. Figures 3b, 3c and 3d are the geologic cross sections of sedimentary rocks of Late Eocene and younger age. The Ocala Group limestone is an important and productive part of the Roridan aquifer system in Clay County. Deposited during the Eocene Epoch, 57 to 36 million years before the present (BP), these rocks generally consist of a soft, white, chalky, relatively pure limestone containing abundant fossils foraminiferaa, mollusks, bryozoans and echinoids). The top of the Ocala Group is typical of a karst surface with numerous sinkholes and depressions. Present throughout Clay County, the Ocala Group occurs at varying depths ranging from 80 to 300 feet below MSL (Florida Geological Survey well data). A maximum observed thickness of 254 feet was encountered in W- 10633 (section 4, Township 4S, Range 26E) in northeastern Clay County near Orange Park. Hawthorn Group lithologies, which were deposited during the Early to Middle Miocene (23 to 15 million years BP) overlie the Ocala Group limestone throughout the county. The lithology of these sediments is diverse, consisting of interbedded phosphatic clay, silt, clayey quartz sand and dolomite. Three formations comprise this group in Clay County (Scott, 1988a). They are, from oldest to youngest, the Penney Farms Formation, the Marks Head Formation and the Coosawhatchie Formation. The highly variable nature of the Hawthorn lithologies in this area makes identification of the individual units difficult. Therefore, these rocks are referred Ito as Hawthorn Group undifferentiated in the cross sections of this report (Figures 3b and 3c). The top of the Hawthorn Group is variable in depth averaging approximately 25 to 50 feet above MSL. The thickness varies from less than 225 feet in the northwestern part of the county to as much as 370 feet in north-central Clay County (W-14219, section 27, Township 4S, Range 24E). Approximately 15 feet of Hawthorn Group sediments (that are overlain by 7 to 10 feet of undifferentiated sands and clays) can be observed at the Florida Solite Mine (section 39, Township 5S, Range 25E). Poorly indurated, clayey, silty quartz sands overlie the Hawthorn Group in western Clay County. These Pleistocene age siliciclastics, formerly included in the Citronelle Formation by Cooke (1945), have recently been placed in the Cypresshead Formation (Scott, 1988b). The Nashua Formation overlies the Hawthorn Group in the northeastern part of Clay County. The lithologies of this unit range from an unconsolidated calcareous shelly sand to a sandy shell bed. Huddlestun (1988) dates this formation as Late Pliocene in age based on planktonic foraminifera. The lower surface of this unit occurs at elevations which range from approximately 8 to 6 feet below MSL, while its thickness varies from 10 to 55 feet in W-14193 (section 13, Township 4S, Range 25E) and W-14476 (section 17, Township 6S, Range 26E), respectively (Figure 3d). Undifferentiated sand, clay and shell with maximum thicknesses of over 100 feet cover Clay County (Figure 3c). These Pleistocene and Holocene age deposits are composed of a clayey sand with occurrences of shell material. An exception is northeastern Clay County where the surface sediments are predominantly a sandy clay. MINERAL RESOURCES INTRODUCTION The mineral resources map and following discussion of the economic geology of Clay County is not intended to be a complete investigation leading to immediate industrial development because, in many cases, the data represents information on a single outcrop, pit or mine. Favorable data, however, may indicate that certain areas warrant further investigation. The Mineral Resources Map is designed to present an overview of the major mineral commodities in an area. Factors such as thickness of overburden, quality, and quantity or volume of the deposit, all have an effect on mining of a mineral commodity at any one specific site. Geologic cross sections (Figures 3b, 3c and 3d) were generated from core and well cuttings to show the general distribution and thickness of surface and near-surface stratigraphic units. The following is a discussion of the clay, heavy minerals, peat, phosphate, sand and the undifferentiated resources of Clay County. Clay Clay minerals (smectite and kaolinite) are common to abundant in various regions of Clay County. Miocene age Hawthorn Group clays and Pleistocene to Holocene age undifferentiated alluvial deposits dominate the surface and near-surface sediments in the northeastern portion of the county. Sediments in the southwestern corner are kaolin-bearing sands associated with the Pleistocene age Cypresshead Formation. Kaolinite, a hydrous aluminosilicate, is used in the manufacture of such items as china ware, paper coating, tile, glaze, and pottery. The clay, which comprises a matrix material of the Cypresshead, was analyzed by Calver (1949). The samples were taken from an old, abandoned kaolin mine (Chalk Hole) located in section 6, Township 8S, Range 23E. Results of the tests indicated the kaolin to be of high quality similar to the finest produced in Florida at the time. There are no active kaolin mines in Clay County at the present time. Ball (1924) conducted a study of the clay resources in a number of Florida counties. He analyzed samples of common clay and kaolin for their physical properties. In Clay County, Bell (1924) analyzed samples from what were then established common clay production areas such as Doctors Inlet, Middleburg and Green Cove Springs. Bell also tested the kaolinitic quartz sands near White Sand Lake north of Keystone Heights. Results of Bell's numerous tests indicate that the clay from Doctors Inlet was satisfactory for a good grade of common brick, drain tile, and hollow block. The potential uses for the Middleburg clay included face brick, common brick, drain tile and hollow ware. Green Cove Springs clays were suitable for common brick and drain tile manufacturing. The clay sample (kaolin) from near White Sand Lake was suitable, if washed, for some grades of white ware. Calver (1949) tested clays from the Green Cove Springs area, Russell and Middleburg. The results from the Green Cove Springs deposit indicated the clay would be unsuitable for common brick. The Russell deposit was found to be usable for face brick, drain tile, and common brick. The Middleburg clay was found to be suitable for hollow ware in addition to the Russell deposit usages. Hickman and Hamlin (1964) conducted a study on clay sediments from several northeastern Rorida counties. Within Clay County their study centered on 59 test holes in the Doctors Inlet to Middleburg region along State Highway 21 and County Highway 220. Their findings were similar to previous investigations indicating that the clays could be used in the manufacture of common brick. Additionally, due to positive results during bloating tests, potential uses included lightweight aggregate in hole 36 (section 34, Township 4S, Range 25E) Table 1, hole 42 (section 6, Township 5S, Range 25E) Table 2, and hole 53 (section 14, Township 5S, Range 25E) Table 3. Florida Solite Corporation, located near Russell in section 39, Township 5S, Range 25E, is the only company actively mining clay in the county. They extract the commodity from a deep, massive, northwest trending deposit at a depth of approximately 30 feet (John Kuiken, personal communication, 1989). Up to 10 feet of sand overlies the clay deposit. The clay is naturally bloating and comprised of smectite and minor amounts of kaolinite (Campbell, 1986). These bloating properties are essential for the successful production of lightweight aggregate, the company's primary product. Heavy Minerals Heavy-mineral sands occur as a small fraction in nearly all of Rorida's sand deposits. The source region for peninsular Florida's heavy minerals is the Piedmont and Blue Ridge region of the Appalachian Mountains. The weathering products of the Appalachians were transported by streams which deposited.them in alluvial, deltaic, and longshore environments (Pirkle et al., 1974). The first commercial production of heavy-mineral sands began in 1916 at Mineral City, now called Ponte Vedra, St. Johns County. Mr. H. Buckman and Mr. G. Pritchard began a mining and milling operation at the site for the manufacture of titanium tetrachloride, used for war purposes. The United States Bureau of Mines (Thoenen and Warne, 1949) conducted a study and drilled over 700 test. holes in 1947 to 1948 in northeastern Florida. Much of that investigation was centered around the Trail Ridge region. The U.S. Bureau of Mines (USBM) drilled holes along State Highway 100 neai Keystone Heights, along State Highway 21 near the Mike Roess Gold Head Branch State Park, near the Clay- Bradford county line, and in northwestern Clay County near Highland. Thoenen and Warne (1949) indicated that the Gold Head Branch State Park contains sediments with over 6 percent heavy minerals. Partially, as a result of the USBM study of that area, the E.I. duPont de Nemours Company ultimately began mining heavy-mineral sands in the Camp Blanding Military Reservation. There are three ore deposits in Clay county: the Trail Ridge and the Highland ore deposit along the western boundary of Clay County, and the Green Cove Springs ore deposit in the southeastern part of the county. E.I. duPont de Nemours has mined large tracts of land in western Clay County. RGC (USA) Minerals, Inc., formerly Associated Minerials, mines the Green Cove Springs deposit. Heavy minerals present in the Trail Ridge area characteristically include the titanium minerals ilmenite, rutile and leucoxene which comprise approximately half of the total volume of recovered heavy minerals (RHM) (Reeves, 1962). Zircon is next in abundance at 10-15 percent RHM; the other minerals include monazite, staurolite, kyanite, sillimanite, tourmaline, andalusite, pyroxene, spinel and corundum, all of which comprise about 40 percent of the remainder RHM (Reeves, 1962). The Highland Ore body averages about three percent heavy minerals with the titanium minerals accounting for about 45 percent of the RHM ore minerals (Pirkle et al., 1977). The average TiO content of the titanium minerals is 69 percent. Other minerals present in the deposit include staurolite, zircon, kyanite, slllimanite and tourmaline (Pirkle et al., 1977). The Green Cove Springs deposit has, in addition to those minerals found in the other two deposits, lesser amounts of epidote and garnet (Pirkle et al., 1974). This deposit of heavy minerals occurs at the top of a scarp whose toe is at an approximate elevation of 40 feet above MSL (Pirkle et al., 1974). Although company statistics are confidential as to the amount of material produced and the value of those minerals, the USBM reports that Florida is the leading producer of heavy minerals in the United States. Geologists continue to explore areas for new deposits to add to their reserves as old deposits are mined out. The heavy mineral sands of Clay County continue to hold promise for future operations. Peat Peat is the accumulation of decomposed organic material, which collects in perennially wet areas (Davis 1946; Bond et al., 1986). Other factors of importance for the accumulation of peat include climate and topography. Specific areas in Clay County are suited for the accumulation of this commodity and, in fact, peat is presently mined in southwestern Clay County by Stricklin Peat Inc. (section 16, Township 8S, Range 24E) (Mineral Resources Map). The areal extent of the Stricklin mine is approximately 100 acres with a maximum depth of 28 feet. Griffin et al. (1982) mapped several peat deposits in Clay County. However, detailed information on the deposits are not available. The United States Soil Conservation Service (1989) interim report on the soils of Clay County shows numerous locations of highly organic soils. It is the organic-rich Maurepas Muck that is mined as peat in southern Clay County. Pamlico Muck, another soil type, is also a potential source for peat. The Mineral Resources Map shows the location of the previously mentioned soils which are associated with peat or peaty muck as well as areas where peat has been or is now mined. In addition to deposits scattered throughout the county, many highly organic (peaty) soils are located in the swampy lowlying areas along the St. Johns River, and Black Creek and its tributaries. Mining procedures generally used by peat operators include removal of surface vegetation followed by site dewatering and subsequent removal of the peat by dragline or bulldozer. The material is shredded and stockpiled for future use. Currently, all Florida peats are used for horticultural purposes. Phosphate Economic deposits of phosphate are known to exist in several counties throughout Florida. Clay County is situated in the Northeastern Phosphate District (Scott, 1988a). Phosphate sediments in this district are of the pebble and sand-sized variety and are from the Hawthorn Group. Characteristics of the phosphatic sediments are as follows: NORTHERN PHOSPHATE DISTRICT Overburden thickness in Feet 50-150 Ore zone thickness in Feet 5-50 Bone Phosphate of Lime (BPL) in precent 62-65 (Source: Zellars and Williams, 1978). The low economic value of the Clay County phosphatic sediments probably precludes mining in the near future. Sand Quartz sand occurs over most of Clay County. It is a primary component of the Cypresshead Formation and the Pleistocene- Holocene deposits occurring in the county. The known deposits of commercial quartz sand found in the county come from the Northern Highlands area In the southwestern part of Clay County. Martens (1928) collected and analyzed a number of sand samples from the following locations in Clay County: LOCALITY PERCENT PASSING EACH SIEVE 1/4 inch 10 20 50 80 100 200 One mile west of Green Cove Springs 100.0 -- 96.80 55.80 -- 12.70 3.80 Green Cove Springs 100.0 -- 100.00 97.30 -- 8.80 0.60 Kingsley Lake 100.0 -- 99.90 52.90 -- 0.90 0.02 Two ond one-half 100.0 -- 99.00 71.20 -- 13.60 1.70 miles southwest of Lake Geneva In his analyses of the above samples Martens (1928) determined that the sample from two and one-half miles southeast of Lake Geneva was satisfactory for use in the manufacture of concrete. RFlorida Rock Products currently mines sand from similar deposits at their Goldhead Mine located in section 2, Township 8S, Range 23E. Sand is mined at the Goldhead Mine by suction dredge from an open water-filled pit. From the pit, the sand is pumped in a slurry to screen shakers where the sand is separated into several size fractions. These sands are utilized for manufacturing concrete and as a masonry sand. A number of borrow pits are used by local operators and the Clay County Road Department for road construction and fill (Mineral Resources Map). Samples were collected for testing from two borrow pits (Mineral Resources Map). Laboratory procedures involved in analyzing the above samples consisted of drying then quartering using a riffle type splitter. One quarter was then weighed and screened using a U. S. Standard Sieve Series. Information from the analysis of this sample is presented in Table 4. In the Rorida General Soils Atlas (Kolb, 1974), soils information is presented which is useful in determining an area's suitability for various land uses. The soil survey indicates that the Tavares-Myakka- Bassinger soil association is a good source for sand. The good rating for this soil association means that the sand is at least three-feet thick and its top is within six feet of the land surface. Mining factors such as thickness of overburden, quality of the material and depth to the water table are not considered in the sand rating. The Tavares-Myakka-Bassinger soil association occurs along the southern border of Clay County in the Northern Highlands and the Duval Upland (Kolb, 1974). The abundance of potential construction sand in the Northern Highlands in southwestern Clay County makes the possibility for developing this area for sand mining relatively high. As indicated by the number of borrow pits, the sand areas in other parts of the county have a good potential for use as fill material (Mineral Resources Map). Undifferentiated Resources A large percentage of Clay County's surface and near-surface sediments are comprised of undifferentiated clayey sands, marl, and organic muck. The heterogeneous nature of these sediments would tend to preclude any large scale economic marketability. Locally, however, where costs are not prohibitive and the need is present for uses such as fill or top soil, extraction on a small scale may be feasible. If, in the future, a comprehensive investigation of these undifferentiated sediments is undertaken, those data may lead to economic or industrial applications. REFERENCES American Society of Testing Materials, 1987, Annual book of ASTM standards, section 4, v. 4.02 Concrete and Mineral Aggregates: ASTM, Philadelphia, PA, 997 p. Applin, P. L., 1951, Preliminary report on buried pre-Mesozoic rocks in Rorida and adjacent states: U. S. Geological Survey Circular 91, 28 p. Bates, R. L., and Jackson, J.A., eds., 1980, Glossary of geology (2nd edition): Falls Church, Virginia, American Geological Institute, 751 p. Bell, 0. G., 1924, A preliminary report on the clays of Rorida (exclusive of Fuller's Earth): Florida Geological Survey RFifteenth Annual Report, pp. 53-260. Bond, P. A., Campbell, K. M., and Scott, T. M., 1986, An overview of peat in RFlorida and related issues, report to the Rorida Legislature: Rorida Geological Survey Special Publication 27, 151 p. Calver, J. L., 1949, Rorida kaolins and clays: RFlorida Geological Survey Information Circular 2, 59 p. Campbell, K. M., 1986, The industrial minerals of RFlorida: Rorida Geological Survey Information Circular 102, 94 p. Cooke, C. W., 1939, Scenery of RFlorida interpreted by a geologist: RFlorida Geological Survey Bulletin 17, 118 p. 1945, Geology of Rorida: Rorida Geological Survey Bulletin 28, 339 p. Davis, J. H., 1946, The peat deposits of Rorida, their occurrence, development and uses: Rorida Geological Survey Bulletin 30, 250 p. RFlorida Department of Transportation, 1984, Manual of RFlorida sampling and testing methods, sieve analysis of fine and coarse aggregates: FDOT, designation FM 1-T 027, 6 p. Griffin, G. M., Weiland, L.Q.H., Goode, R. W., Sawyer, R. K., and McNeil, 0. F., 1982, Assessment of the peat resources of RFlorida, with a detailed study of the northern Everglades: State of Florida, Governor's Energy Office, Tallahassee, RFlorida, 190 p. Healy, H. G., 1975, Terraces and shorelines of Florida: RFlorida Bureau of Geology Map Series 71, scale 1:2,000,000. Hickman, R. C., and Hamlin, H. P., 1964, Ceramic clay investigations in Alachua, Clay, and Putnam Counties, RFlorida: Florida Geological Survey Information Circular 102, 94 p. Huddlestun, P. F., 1988, A revision of the lithostratigraphic units of the coastal plain of Georgia the Miocene through Holocene: Georgia Geologic Survey Bulletin 104, 162 p. Kolb, W. 0., 1974, The Florida general soil atlas with interpretation for regional planning districts III & IV: Rorida Department of Administration, Division of State Planning, Bureau of Comprehensive Planning, 44 p. MacNeil, F. S., 1950, Pleistocene shorelines in Florida and Georgia: United States Geological Survey Professional Paper 221-F, p. 95-107. Martens, J. H. C., 1928, Sand and gravel deposits of Florida: Florida Geological Survey Annual Report no. 19, p. 33-123. Pirkle, E. C., Pirkle, W. A., and Yoho, W. H., 1974, The Green Cove Springs and Boulougne heavy-mineral sand deposits of Florida: Economic Geology, v. 6, no. 7, pp. 1129-1137. ______ Pirkle, W. A., and Yoho, W. H., 1977, The Highland heavy-mineral sand deposit on the Trail Ridge in northern peninsular Florida: Florida Bureau of Geology Report of investigation 84, 50 p. Reeves, W. D., 1962, Mineral resources adjacent to the proposed Trans-Florida Barge Canal: Rorida Geological Survey unpublished report, 44 p. Scott, T. M., 1978, Environmental geology series Jacksonville Sheet: Rorida Bureau of Geology Map Series 89, scale 1:250,000. 1988a, The lithostratigraphy of the Hawthorn Group (Miocene) of RFlorida: RFlorida Geological Survey Bulletin 59, 148 p. 1988b, The Cypresshead Formation in northern peninsular Rorida: in Pirkle, F.L., and Reynolds, J.G. (eds.), Southeastern Geological Society Annual Fieldtrip Guidebook, February 19 & 20,1988, 76 p. Thoenen, J. R., and Warne, J. D., 1949, Titanium minerals in central and northeastern RFlorida: U. S. Bureau of Mines Report of Investigation 4515, 23 p. United States Department of Agriculture Soil Conservation Service, 1989, Interim soil survey report Clay County, Florida: U. S. Department of Agriculture Soil Conservation Service in cooperation with the University of RFlorida, Institute of Food and Agricultural Services, 92 p. Vernon, R. 0., 1942, Geology of Holmes and Washington Counties, Rorida: Rorida Geological Survey Bulletin 21, 90 p. White, W. A., 1970, The geomorphology of the Florida Peninsula: Rorida Geological Survey Bulletin 51,164 p. Zellars and Williams, Inc., 1978, Evaluation of the phosphate deposits of Rorida using the Minerals Availability System: Final report prepared for the U. S. Bureau of Mines, 196 p. Table 1. Hole No. 36 (from Hickman and Hamlin, 1964) Type Unfired color Clay Medium red groy Raw properties Longworklng, plastic, smooth, requiring 36% water for plasticity, 9.0% drying shrinkage, with no drying defects. Fired properties Slow Fire Percent Percent App. Temp. 'F Color Hordness shrinkage absorption Sp.Gr. 1800 Salmon Hard 13.5 11.0 2.52 2000 Lt. red Very hard 13.5 5.4 2.41 2100 Med. red Very hard 16.0 3.4 2.42 2200 Very dk. red Very hard 16.0 3.5 2.36 Brown 2300 Expanded & Glozed -.. . 2400 Expanded & Glazed -- -- -- Quick Fire Percent Temp. F Bulk density Ilb. cu. ft. absorpion Remarks 1800 1.48 92.2 17.1 No bloating 1900 1.29 80.4 17.1 No bloating 2000 1.08 67.3 20.5 Poor bloating 2100 1.06 66.0 16.9 Fair bloating 2200 0.72 44.9 20.2 Good bloating 2300 0.70 43.6 08.3 Good bloating Bloating Test Positive Potential use Ughtweight aggregate Table 2. Hole No. 42 (from Hickman and Hamlin, 1964) Type Unfired color loay Dark Brown Row properties Longworking. plastic, smooth, requiring 29% water for plasticity. 10V drying shrinkage, with no drying defects. Fired properties Slow Fire Temp. 'F Color Hordnes sl Lt. Salmon Lt. red Mod. red Ok. red brown Ok. brown Bloating Tet Slight Hard Very hard Very hard Very hard Expanded Percent Percent App. hrinkage absorption Sp.Gr. Potential uee Brick & ULghtweight aggregate (slntered) Table 3. Hole No. 53 (from Hickman and Hamlin. 1964) Type Unfired color Sandy cloy Gray-block Raw properties Longworking, plastic, requiring 31X water for plasticity, 10.0X drying shrinkage, with no drying defects. Fired properties Slow Fire Percent Percent App. Temp. "F Color Hardness shrinkage absorption Sp.Gr. 1800 Cocoa brown Hard 10.5 13.4 2.52 2000 Cocoa brown Very hard 13.5 9.0 2.46 2100 Dark brown Steel hard 14.5 4.3 2.16 2200 Expanded -- -- - 2300 Expanded 2400 Expanded .. . Quick Fire Percent Temp.'F Bulk density lb. cu. ft. absorplon Remarks Blootin Teat Poitve Table 3. (cont.) Remarks Preliminary tests indicate that this clay could be used as decorative brick if fired around 2000 F. The shrinkage is rather high, but it does not eliminate the material entirely as a source of brick. If fired to 2100 F, the material might be used in the manufacture of sewer pipe provided the shrinkage can be reduced by additions of sand. The material seems to be more favorable for the manufacture of lightweight aggregate. The bloating range is fairly long and the mate- rials sees to be fairly strong when bloated. When fired around 2000 to 2100 F, the aggregate weight compares favorably with commercial aggregates. *33% of entire Sample 1 was retained in Pan. **86% of entire Sample 2 was retained in Pan. Fineness Modulus: A means of evaluating sand and gravel deposits which consist of sieving samples through a standard set of sieves, adding the cumulative weight percentages of the individual screens, dividing by 100, and comparing the resultant fineness modulus to various specification requirements (Bates and Jackson, 1980). The fineness modulus is an index of the fineness or coarseness of an aggregate, but gives no idea of grading. The higher the fineness modulus the coarser the aggregate (ATSM 1987). The method of sieve analysis presented here follows that outlined in ATSM 1987, v. 4.02, section C136-84a. The reader is also referred to the Rorida DOT Manual of Florida sampling and testing methods for aggregates, FDOT, designation FM 1-T 027. FEET METERS 200.-60 t0 20 -20 -40 -2 --0 FEET METERS 200- 60 -2ooa.-so 2.2 No bloating 9.7 Poor bloating 2.3 Fair bloating 6.4 Fair bloating 2.7 Good bloating 3.5 Good bloating. sticky Potential uee Decorative brick, sewer pipe. and lightweight aggregate METERS 60 40 20 -20 -40 -eO The well and quarry system used in this report uses the rectangular system of section, township and range for Identification. The well or outcrop number consists of six parts: W for well or L for quarry, county abbreviation, the Township, Range, and Section, and the quarter/quarter location within the section. EXPLANATION r NORTHERN HIGHLANDS ms Trail Ridge S DUVAL UPLAND PEORIA HILL 'N r CODY SCARP S NORTHERN HIGHLANDS Figure 1. Geomorphology (modified from White, 1970) Figure 2. Terraces and Shorelines (modified from Healy, 1975) W- 24E-27dd \V- 14219 HAWTHORN GROUP UNDIFFERENTIATED HAWTHORN GROUP UNDIFFERENTIATED T 320' TO 492' TO 357' TO 708' Figure 3b. Geologic Cross section A-A' B' WCy-4S-24E-27dd W-14219 UNDIFFERENTIATED HAWTHORN 2 TD 492' WCy-7S-24E-20bc WCy-6S-25E-7cd W- 14301 SAND CLAY AND-13769SHELL SAND, CLAY AND SHELL GROUP UNDIFFERENTIATED TO TD 252' T 319 TO 319- Figure 3c. Geologic Cross section B-B' EXPLANATION 215-320' INCLUDES HAZELHURST TERRACE (formerly Brandywine) (Cooke, 1939). COASTWISE DELTA PLAIN (Vernon. 1942) PART OF HIGH PULIOCENE TERRACE (MocNell. 1950). 170'-215' COHARIE TERRACE 100'-170' SUNDERLAND TERRACE (COOKE. 1939) OKEFENOKEE TERRACE (MACNEIL. 1950) 70'-100' WICOMICO TERRACE 42'-70' PENHOLOWAY TERRACE 25'-42' TALBOT TERRACE 10'-25' PAMLICO TERRACE -N- 0'-10' SILVER BLUFF TERRACE SCALE S0 2 4 MILES 0 2 4 6 KILOMETERS -4S-26E-6 For Figures 1, 2, 3o Figure 35a. Geologic Cross section locations SCALE 0 2 4 MESs C I I I Y ~0 3 6 KLOMCTBB -36CC VERTICAL. OwEOiNsPoIMAe 6 O ELM Y 211 TIMES -"1 For Figure 3b. 3c, 3d Figure 3d. Geologic Cross section C-C' Table 4. Screen analyses of sand in Clay County, Florida Laboratory Test Data/Screen Analysis/ Deposits Sieve No. and Cumulative Weight Percent Retained Sample Location Method of 4 8 16 30 50 100 Fineness No. (T.R.Sec.) Sampling Modulus A *Cloy-1 T5S, R24E Channel .006 .057 .936 1.06 sec 24d **Clay-2 T6S, R26E Channel .012 .988 1.01 sec 08b m" I -j |
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| MILLISECOND | CLASS.METHOD | MESSAGE |
|---|---|---|
| 0 | sobekcm_page_globals.constructor | |
| 0 | sobekcm_page_globals.constructor | Application State validated or built |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.constructor | Navigation Object created from URI query string |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.display_item | Retrieving item or group information |
| 0 | sobekcm_page_globals.get_entire_collection_hierarchy | Retrieving hierarchy information |
| 0 | sobekcm_assistant.get_entire_collection_hierarchy | |
| 0 | cached_data_manager.retrieve_item_aggregation | |
| 0 | cached_data_manager.retrieve_item_aggregation | Found item aggregation on local cache |
| 0 | item_aggregation_builder.get_item_aggregation | Found 'all' item aggregation in cache |
| 0 | system.web.ui.page.page_load (ufdc.page_load) | |
| 0 | sobekcm_page_globals.constructor.on_page_load | |
| 0 | html_echo_mainwriter.add_style_references | Adding style references to HTML |
| 0 | html_echo_mainwriter.add_text_to_page | Reading the text from the file and echoing back to the output stream |
| 26 | html_echo_mainwriter.add_text_to_page | Finished reading and writing the file |