<%BANNER%>

FGS





xml record header identifier oai:www.uflib.ufl.edu.ufdc:UF0000127600001datestamp 2008-12-01setSpec [UFDC_OAI_SET]metadata oai_dc:dc xmlns:oai_dc http:www.openarchives.orgOAI2.0oai_dc xmlns:dc http:purl.orgdcelements1.1 xmlns:xsi http:www.w3.org2001XMLSchema-instance xsi:schemaLocation http:www.openarchives.orgOAI2.0oai_dc.xsd dc:title Florida Geological Survey: Report of Investigation: Stratigraphy and oil potential of the Lower Cretaceous Sunniland Formation in south FloridaFGS: Report of investigation 89dc:creator Applegate, Albert V.Pontigo, Felipe A. Jr.dc:publisher U. S. Geological SurveyBureau of Geology, Florida Department of Natural Resourcesdc:date 1984dc:type Bookdc:identifier http://www.uflib.ufl.edu/ufdc/?b=UF00001276&v=00001000460824 (aleph)AAA0714 (ltqf)ACM3857 (ltuf)dc:source University of Florida


xml version 1.0 encoding UTF-8
REPORT xmlns http:www.fcla.edudlsmddaitss xmlns:xsi http:www.w3.org2001XMLSchema-instance xsi:schemaLocation http:www.fcla.edudlsmddaitssdaitssReport.xsd
INGEST IEID E20090509_AAAANF INGEST_TIME 2009-05-10T03:52:16Z PACKAGE UF00001276_00001
AGREEMENT_INFO ACCOUNT UF PROJECT UFDC
FILES
FILE SIZE 19067 DFID F20090509_AABQAG ORIGIN DEPOSITOR PATH 00036thm.jpg GLOBAL FALSE PRESERVATION BIT MESSAGE_DIGEST ALGORITHM MD5 44d815b338ad086440bdefd705492a11SHA-1 243e63407d8c6f9f3847ff5374d4d7d78ab075c8
136064 F20090509_AABPTI 00010.QC.jpg 08d500118a7f1421e352eb09e8db53700d108487cb309b11f2e989527ebf7aba3da50915
349816 F20090509_AABPYG 00029.jpg c980f66f3435acc34f0fceca91d2bea760f6cb4a60a1cba89de753d9064dac76e7c7a6f4
137 F20090509_AABQAH 00037.jp2 31e1d290bcbbed591dc6c531fb256c97163dc1cd6be2a750601a9d4ea6388ec27b3a84d8WARNING CODE A_JPEG2K_BAD_JP2CBOX Malformed codestream
60945 F20090509_AABPTJ 00010.tif ab3d4b4e74167f35b2a8cb80c6405dd453006cddac2816f7a22580b9c1e35e60f94b19a6
52022 F20090509_AABPYH 00029.pro 676cc8fc290c62c050cb1c935299af2d44970ea4acbc43a41c8e21254c674a207797300bM_MIME_TYPE_MISMATCH conflict in mime type metadata
189175 F20090509_AABQAI 00037.jpg 085ec1b4c1fb4a8d51944893e1c8265533fb60482d5971da4cee2b6c60f0c60cdc595348
2422 F20090509_AABPTK 00010.txt f695bf962a17550391abb3b627bd2eda45d2267a68e56c80b754f5b3bafd32926814c389
111617 F20090509_AABPYI 00029.QC.jpg 5d983a7e62524792101d8a43221f6491481ac337e0a0b6428f106cc8d06f9bba3a708359
31841 F20090509_AABQAJ 00037.pro 1c0b98c47f1059a43f98ae1eeea870ed6061b1e05f6518286d1c5e864e18963f964157deconflict in mime type metadata
35317 F20090509_AABPTL 00010thm.jpg 4c7726617ba85d4184ca58085de4f655f303bf4c83c44fe17dcf27f129545654b9bc48a8
54131 F20090509_AABPYJ 00029.tif 987c7c9cbbd57c6d48ac800c37c5e22f350556a048790dc70cec1ab60c9bf586b7be77d3
60822 F20090509_AABQAK 00037.QC.jpg 6dd5049c836748b42cec691808cd876ac16f3593f82d0e762afb8450ff6e9a3daf35074f
F20090509_AABPTM 00011.jp2 c741bff19a09b9b7266143260b710ef6986ae1fc370762ef463cf908da8a143d91d4ddc9Malformed codestream
1995 F20090509_AABPYK 00029.txt f745e6e6a2def30d812c99072261995560b779a2604cb327b9c309f34e2eab418bdbbc86
28587 F20090509_AABQAL 00037.tif b3906b80a16d798b23918fb80f265014cc28fb2bfe74b9ab58464970cb69d75867f260c3
301612 F20090509_AABPTN 00011.jpg b853e6d75b35714bac68518468e759c0e6d080de5806d596ed8a54b91e94ffe812dce3ca
30622 F20090509_AABPYL 00029thm.jpg 42ca02551f169535deaf002deba4087149484eae127ca92f9c71c008b23203b09765bc7c
1502 F20090509_AABQAM 00037.txt de39f2891887aa9509dcca1d30e8a3347baff77f88463e7bbcad13d6dad6e459f376cc40
22733 F20090509_AABPTO 00011.pro 1a94c1a1e3ae0850ec41362be830e1abc1a8a1333ef9fcfd373a71e7b612b1ba2f2d0144conflict in mime type metadata
F20090509_AABPYM 00030.jp2 3b9d24f170cea45b499ddee7cce89faacaa5f247768f5f62d1ff12de84cb42b9504b5481Malformed codestream
101549 F20090509_AABPTP 00011.QC.jpg f4b11292867539f8aabd99b2125528bc8ecb81bc18fe106d37a2eedd08f1b764607c390b
27003 F20090509_AABPYN 00030.jpg 3419dcd7ad2ee230b1f89a67f3f0aac74a1a205a9c1df3e0cf0042f76962da4c22560709
19571 F20090509_AABQAN 00037thm.jpg cb6a357d0ca726c6f00ecf7762e7d31efcd506f4664b90c3ae6fb5b4c8bf867e78644383
45776 F20090509_AABPTQ 00011.tif c37f5aa63d93275d36f06e3c1bdeb52ebadc7d3cc199d27f329f292573139578e6d5274d
2147 F20090509_AABPYO 00030.pro db2e636a26f5d83a0ffc0f599b7cf9b2699e067c0b9a71f99d4013b2549e971fd14a9781conflict in mime type metadata
F20090509_AABQAO 00038.jp2 6d1857f0f4654d23a0b20915824b325937febe7dcc85ae0706598baeb7bec098a49b6ad8Malformed codestream
856 F20090509_AABPTR 00011.txt d0333386b351a5773459335335352e9f0062460677592d3032d88b09a1d6b0d25e917951
8488 F20090509_AABPYP 00030.QC.jpg 7d6caf2d8e8fe681110a892dab980bb6e1823e611aa1da4729ef5f68e5aeefbbbf75583a
129510 F20090509_AABQAP 00038.jpg f69043f801ee0a040f4af8a40d7c81513ae804dd4208e301236b387388eb4811004905e3
29350 F20090509_AABPTS 00011thm.jpg bb7d8966abdde8180583f007859be359e7c9d13ef284150ef55b38c24ae7d2109bef3d7a
3233 F20090509_AABPYQ 00030.tif caa25282058449bad23746f48dd62fb3b12b93e98013a3923cb1c3dce80796f5ae8a0183
18424 F20090509_AABQAQ 00038.pro 7be2f76c0490db2d91aacdb1500d6f1e2ce0f68607eb4b5fad57fc539808389979ee4c7econflict in mime type metadata
F20090509_AABPTT 00012.jp2 643a6f67525d36b1290233b86e14e7462ec47fd0339b0ed8a1734bcf01c5bed3751df27fMalformed codestream
87 F20090509_AABPYR 00030.txt c8e3bbaea716a083d9063f342806d4963cad6178c23fcdf823fec011ddd244d559481270
43061 F20090509_AABQAR 00038.QC.jpg 13480c145aec93b6af4f6a1ae7924cf97cf4fdd79cc2cc00a61535b28f713decc5a45680
505148 F20090509_AABPTU 00012.jpg dd7c99438e18ef5f27dc49d84503f195581d62098012edc34e0a4d3e094d5e326f4f0ea0
4241 F20090509_AABPYS 00030thm.jpg d1a60a30f2e6ed5ef2fe42ce1c40c83295007495efbc7775d6aa1e942b333ef7e65d66c6
17033 F20090509_AABQAS 00038.tif 1f611fd8085ed414f466a824e8799af877ff71daf29006a53f8ad94af54dbd01415b32ea
73048 F20090509_AABPTV 00012.pro 66b2e53f88d2dfda3c58487c73889de4092364d1ad3bcb87f3f411868715b69e11639892conflict in mime type metadata
F20090509_AABPYT 00031.jp2 264c67c0e22417149fcbf4a57fdfd3b5d48fc58667e63a9385aa112312a102efd49fa7dbMalformed codestream
871 F20090509_AABQAT 00038.txt 9c80ebb1ea7d760de571b71115658c8d99a1cdddadbb0985b35b7f9cd266e9ae6bdb64ea
153103 F20090509_AABPTW 00012.QC.jpg 90606ff66846d4a2eeae2622da5afd9554c84345aadba991d69747bb8561b3d6969fcd23
303193 F20090509_AABPYU 00031.jpg b8e0d957a15d91afeb7dd8d39b6c35aeb436f094e9283bec5eadad97cf1b8c670d2cb33d
14545 F20090509_AABQAU 00038thm.jpg 344a8a693bc338399b96382b86f99df2a1ffc6bc58498d2e446130a2b0cf858effb2fb9b
72264 F20090509_AABPTX 00012.tif 55591ac430c8d9c0db28ec52ce892ebe58a380df3b8727c7ceb33960e7d7383ee7aa36a0
44014 F20090509_AABPYV 00031.pro 5d708e7c9ba92ed76a37cf2a5b8a6c34f3ca9dbae5a7fd6f9f534ba94a7a445955a23ae9conflict in mime type metadata
F20090509_AABQAV 00039.jp2 5e43130839a52e4c4f1eedac7ce3cde70f2b982da960bc238d22b0de99fd152c68d5ebfdMalformed codestream
2874 F20090509_AABPTY 00012.txt 4b09d944b670d1689f780105c342cb7b907760422268a2533b6846c401259a4fe7d62d2a
94530 F20090509_AABPYW 00031.QC.jpg c356d1cb8ab93e2cef9b03b50fcb59dc4ff04afa1426af5aeb459ac6d4e829039453e9c0
114519 F20090509_AABQAW 00039.jpg 10309d173b46e09f4ef73bd14ddaf1834926a42d49e978df71191673538f5ee2b81aa2ed
1649 F20090509_AABPRA 00001thm.jpg 06418cc59d416a518c5fb9d85190d6adc2817633d3425ccf9089c758f3d76112074d44c5
39114 F20090509_AABPTZ 00012thm.jpg 5856c21eea7761e946cb35b4119a4eda032fc9f8de419a0dc3574537d5f1e388d5311107
44773 F20090509_AABPYX 00031.tif d0fe1ac649d445fd66f8d57bff151e6efc38b3c46335d8da5188ad891d7598268c451d70
40964 F20090509_AABQAX 00039.pro 5c014271fc391cb0e0cec657dd04a1607ca089c356c647aee2011f3ddf49f0addb674788conflict in mime type metadata
F20090509_AABPRB 00002.jp2 1e95db3bf98df1198b2c4e637bc0a82db3187a0c2614bafece8935dace7a97d3939bab83Malformed codestream
1711 F20090509_AABPYY 00031.txt d425a6ecb9fb5e50232a675d3dd417e34e22723fa45e97e148b415271c39a68f5bd16c82
39491 F20090509_AABQAY 00039.QC.jpg 1c3a07f861175ce3bb019b087834e4f1e44eedba087010a73ce4c7f96e7db20a46eeea8d
144760 F20090509_AABPRC 00002.jpg 9a514a1b0c749a5e73913aca0b1d1699acacc680748b269b4d7003f71a45f973138ef379
51731 F20090509_AABPWA 00020.tif d94a4480402b26956c9d78d6e45f9633c6a90065bcc00d798ae66cd6cbf903d3bd7ceb4b
24606 F20090509_AABPYZ 00031thm.jpg aec3b1ce96b2046857fdc3e6eb9f43ed9acac2f1c98dcb76807e583cbd3a432fb3c455ab
31548 F20090509_AABQAZ 00039.tif c2b93ed11ba1a1d0368303ffcf88cfe60472a7647b48a83aa8f20f2733071f42721c3c47
14721 F20090509_AABPRD 00002.pro ced765d2bf00e93c1b828fd81a2a5a75f84914e4bdae43b231e0f76c68b5b1f498583170conflict in mime type metadata
1000 F20090509_AABPWB 00020.txt e9f98bbdec52875417bd0af15b59e9a744ababfeaf109a5931b8f415fe3a331c07176fb8
51542 F20090509_AABPRE 00002.QC.jpg 2498d223a7be5c96928a3dbc0f3982ec7b006317c9c338b880d912dce25bb58b527b39a1
35625 F20090509_AABPWC 00020thm.jpg 1273d309909eb63d2b9be0a3b78045c9d654e795f8cb66f3298e199f1e420d7290fb4d7c
21542 F20090509_AABPRF 00002.tif c6361299d12c9d3beed9c187dd4e7efbb0b741521a0270a2707686226d38c97913d90e7e
25268 F20090509_AABQDA 00047.pro 4e75a7d122f125db6f7f41fe2b435ee1ca3b12aea2b7fa1e3af823b231fc5d4405b30634conflict in mime type metadata
331137 F20090509_AABPWD 00021.jpg 7b379d2d9a6675f634611b6733665ed8f467f0c7a2b363e5e95ef86158b90d785f7ca17c
713 F20090509_AABPRG 00002.txt a3f174e4f5d6b58d8b3e6bfad34d18cc7a947bfb3816345cfdcadeabc02ee7e49cee4aa1
60785 F20090509_AABQDB 00047.QC.jpg c03781aebe2cb6a9cafe613a84c1734e8adb379d8785d0dc4adfb478441a06e7b2921557
14247 F20090509_AABPRH 00002thm.jpg d878efb5f233b7a18a6dac8cd21c5539ec45de7180c9074cc9caa68d2652ad2ed92f5c36
26484 F20090509_AABQDC 00047.tif 5cde7597c15e2af8994889623a20a405ff92f3d2f1b80629e8d06dfdd533feac7f335988
20805 F20090509_AABPWE 00021.pro 6c134ad86bb0ddafd1081206829a072e4887d61cf4eea321b64389811c69e6ee933f1215conflict in mime type metadata
F20090509_AABPRI 00003.jp2 ec2351c01846422c861e0c36607867cea0535447f30111e40cfa7b978aa061e12c6a4d85Malformed codestream
1359 F20090509_AABQDD 00047.txt 1b8e1aba167f42c082c8d3ce0732b6643b5b7269852c5ffc0bb70511f69d9d9ae247e69d
111473 F20090509_AABPWF 00021.QC.jpg e5466cd3933880e142ef5f34c1c6d05f444300a1c76d90a81797172dfd7ebc1eb5ab5484
82859 F20090509_AABPRJ 00003.jpg a80b871eb3b94072225c2e968ac53b8fad0b5c20b645d0a9f5e4b3f4c3be3dd402f6a793
19542 F20090509_AABQDE 00047thm.jpg f00b36796f88b05ad614c7226d5482fb5f045ce8f1efe35173b3aa21624102f18d88dc02
48291 F20090509_AABPWG 00021.tif 64f551f396a97ce3ea2d8041b4fd008e833d3d33d50a09e374b12c2d129c756a44a8d5e2
8866 F20090509_AABPRK 00003.pro f094cc3b1bf2b53e4421676a80eb44fb155a8eb961cef91c3f254059043c64bfd372c546conflict in mime type metadata
F20090509_AABQDF 00048.jp2 7cd4a37b7a3b26aa22d95bf02f332c7fe7c0948aa8fc1150446c9c4b7ee4d1e901d72c36Malformed codestream
798 F20090509_AABPWH 00021.txt 1e79722845cfaa5a2dca9f032dec28b1be2734d100d1740beb2066f67abf0c835e4abaa2
28918 F20090509_AABPRL 00003.QC.jpg 4db01018a94492e56a4640b82d50bc07bdd9ae8907302a01b440d6483a9c3f7f35c16059
179665 F20090509_AABQDG 00048.jpg a73cee5d6f5fbbf39aff40a79a8818d9e19db73dea3d1d76baee7ec61b10f850b05fdebf
32376 F20090509_AABPWI 00021thm.jpg ebfa2dbf3b99c3f2790d2991b9469a3bdbc14423460503eb8e9651eddeec577b8236e862
11363 F20090509_AABPRM 00003.tif 2edca312fdead719b12a835ca8786a5728ac91b4e83b4a23c33cd5d917cc82f3c186f6e0
29055 F20090509_AABQDH 00048.pro 86fe80e3c14ea7af07ef622179319d0fc08707370ef313f668f3cbf7b2e6cc5545f515b2conflict in mime type metadata
F20090509_AABPWJ 00022.jp2 4728020f50f7787220e283c4956ec41f4d9161449d987ecbfd369f09fd19f680f4009067Malformed codestream
433 F20090509_AABPRN 00003.txt cba5209923addffbcf694a758c090e74dd9eef9eda7deb491d0dfe62a120e4d0695c401d
64928 F20090509_AABQDI 00048.QC.jpg 1b0c8ded7bebb6bcaf49a55862bc9bea8da54babf9bdf01a8d428513f465bea2b4d65f06
425919 F20090509_AABPWK 00022.jpg 7f16140c6b7e0bde00c47febcc1638a47f2e1c6c355d7680adb750d855ed174d33cb6d4c
10240 F20090509_AABPRO 00003thm.jpg 6fbd51f1a70e2f825859a0b782243dd7b13ffd903ea09a9d5c5c51392b8cf53b92d5c12c
26811 F20090509_AABQDJ 00048.tif 5d1aa9c41b032f57f1a556e316ee3831efc057e5b0c97d2f50e41c7c168dd0df6b7a4d18
24355 F20090509_AABPWL 00022.pro fc0c48d8c3cf24329a594c96f6ed25ba0ea29a916f7560c7bc948a4c2e9cd6ef002cb8fcconflict in mime type metadata
F20090509_AABPRP 00004.jp2 e736d175790d04ed84ad4f920203477c822fe9df179d9a41320a1d36790210dfb389497aMalformed codestream
1469 F20090509_AABQDK 00048.txt 415eaeb62408d393c2b6ee9b3e9c97f3960f729be72d8aafe46ec152be6e77df364e2d09
140224 F20090509_AABPWM 00022.QC.jpg 2561e987f700efb5d00398748b5204220f4a6376747d608824bfc067e1532d93f03c4fbc
179003 F20090509_AABPRQ 00004.jpg 7323bfee85965a2f8fa7184edb11a81ff45fd4af3cc1d2cebb9d41c2096a31f22dd0427a
20246 F20090509_AABQDL 00048thm.jpg b5416770b3d42c31f26e2eac57974180389f402258de72ad3295af8da4dd48dabc419579
62781 F20090509_AABPWN 00022.tif 2dfe38ecca3678fc94a15fa38b757053900cdcfe07c9a284261dabe5abc89254535ac06e
21594 F20090509_AABPRR 00004.pro 387ce204cd4441bde224a96af392469ec72fe64580e609ff4342a722d5ba8edbdeabe960conflict in mime type metadata
F20090509_AABQDM 00049.jp2 8db95f00715b024ddeee010dcd43ab81212414e88477c858e82a3a7cafd3ef5791508538Malformed codestream
891 F20090509_AABPWO 00022.txt 524e4bb5546192da6ada5c0871d3fe594fdd0721337a2ed0ec06e9fe589a65b958372fe1
176252 F20090509_AABQDN 00049.jpg 339b798ae4de357580e6758e739f09bafdb8fa579f81bf2f80ee978e05bb06e7b0b001b5
38527 F20090509_AABPWP 00022thm.jpg a65acaadf598feb0b4b4357aee7fb5b718f7b205fbae59cbfaf2771ae1ed869627f6e4ba
59141 F20090509_AABPRS 00004.QC.jpg d865b8a333b9310720dadc4f65fa692f5ad8fb22b9e7aa268c0b7c67c8504cc13cadb690
21850 F20090509_AABQDO 00049.pro c8a0b07472987d78b22d70ff739d0f7c946836784f3cfa989cd008dacc3b67ebaed6f44dconflict in mime type metadata
F20090509_AABPWQ 00023.jp2 6f31406ba26db9a4b745f90cf31a2ef3ef18e643a7ffd3b22a98d50253c85ea210528017Malformed codestream
25299 F20090509_AABPRT 00004.tif 228c33c29d85e9d1f74df1a26d8f4f1f6e7c996ddadcf3c63cd703a29d4b3b0adfc57c04
64043 F20090509_AABQDP 00049.QC.jpg 8c5b0336dc6c97a810737c3ad55b80476b4374fe14f666d375f8a80f71c7348dc4d13bb5
549160 F20090509_AABPWR 00023.jpg 03e95b6a167afed1099b4df398f3155477d0c7506bbc43cf523bc3035a6be435c15a8bda
986 F20090509_AABPRU 00004.txt 94a619813768ede78e979870262d0a256b99dc774a9abb23ed3ec8767d6007bba2647e92
81877 F20090509_AABPWS 00023.pro 25cae18aed2837754053ae846e8d1ac2fc4e10e4183caf957fd8381e542dd573a3ef0359conflict in mime type metadata
17558 F20090509_AABPRV 00004thm.jpg af1225fbf829d083280e83a8761540bcfe04fd1e95b8b92fd9bac7d36650fa4e09dcb7af
27375 F20090509_AABQDQ 00049.tif de86f3029162e01b050a0502c2dbab477b03047eed336a142c38433b81b18c8fc9730fab
163156 F20090509_AABPWT 00023.QC.jpg 4cc3f279f7d40b0bdd774d7c5ae32ba6aa2cb7a81f0c6c176002843dab466136fad68a72
F20090509_AABPRW 00005.jp2 0c249eb620f9c6c7a02ff54c76e6a6040d9676a7245d308287f16b5cbf27e83ac7e30539Malformed codestream
1133 F20090509_AABQDR 00049.txt f592833663220df4b3ca4af03b28febada05705b5d5f5049d49e7f55d0c99736f05736cb
83398 F20090509_AABPWU 00023.tif 290f9ab20e37fbda2e9e0dbf83072e00c9f3e62e4e60d25c9dd5b32083b8f6444fb69548
27597 F20090509_AABPRX 00005.jpg d7ce146174e7d804159cf460bad31d986ae22b25ee4ccb3fc7b008b2421e070ac213f001
17600 F20090509_AABQDS 00049thm.jpg 546433889afcbaff16eaecb2117767ac6d6379eff43986efd8d8d4b7739c2a3a9c6239f9
3075 F20090509_AABPWV 00023.txt e6d646d0684737df1c1898dd22f69766ab62a89fd65be1e9e9932d403ee18eb71b843999
3738 F20090509_AABPRY 00005.pro 29145d12dc5f6edb81802d617850eb8061b436aef832af76351f6983d9626c2870c5ac05conflict in mime type metadata
F20090509_AABQDT 00050.jp2 aaa5e4898f752e7c12a7883fb08a87080e91a69bacd23db2c9479fdce00a2bf0982389e7Malformed codestream
41085 F20090509_AABPWW 00023thm.jpg 505a9d62b77413e03611cfd23798262a47e8084f09955b3f09366183a8c70130e1938647
9184 F20090509_AABPRZ 00005.QC.jpg db9b17ba9dfc36368b0d7bf6b535477e5d2b3e76f7850672d66efc772506a9415ffd21f0
16624 F20090509_AABQDU 00050.jpg 6b243e6da3b2a1084db2a56b2e94c405ca25a32f30241dd94f912c88650d7072b8bce18b
302208 F20090509_AABPWX 00024.jpg a054b0afbd85cd1231d2c31e2ce28e200af202cb690f93f369b9ad9c93df3ca7e7e73f68
225 F20090509_AABQDV 00050.pro 8d613b764561619be3eff82269b7ecc5279952615f8e789f6174ab11b73f862ab526d5c1conflict in mime type metadata
F20090509_AABPUA 00013.jp2 25288412115b8e71ec67c9a7649e018f340fd85bcf08be1acfe77aef20270c6a72212049Malformed codestream
24395 F20090509_AABPWY 00024.pro b61184dca32d331e53dc5e549e5ad01e25dcb3d7d32e3a8321234f8c611b86569a832b0cconflict in mime type metadata
5404 F20090509_AABQDW 00050.QC.jpg 083e1a70812282e061c89d1e9e5064f42ee22f32e135466c4936a1f554faa91ac0b52d4e
262622 F20090509_AABPUB 00013.jpg 364c46cb28bda7a7c196d16d41f10fc23ffa82f564622f44005a6259949e0dbf8c8e35b1
100987 F20090509_AABPWZ 00024.QC.jpg 9548b8d5fd619119882427e8b6b143e38d4d887306c73b6e8f6c3c3b0eeb58a652296fed
1437 F20090509_AABQDX 00050.tif 7ab11d176d445554d6dcb6dcc1f73c37a3b081ee827dba20c9c6fc856473c6aa6615c8c7
2321 F20090509_AABQDY 00050thm.jpg b7ab11e9421f4ee09ab5430e6fafc8f28cf0b95dc9c2ab6375907154b1178bbe89a2fe20
25055 F20090509_AABPUC 00013.pro b873c78ad5723d34c53c7a256cc72f22d39eba093bb1ded6475be1bf7301f75e50c848c2conflict in mime type metadata
F20090509_AABPZA 00032.jp2 c22567451891041875ed6814fc5388d3576a45bfa7bf0b47b1acbbdfabf027bb7b5ab557Malformed codestream
1919 F20090509_AABQBA 00039.txt ea1f80d51e80c17f872af56902ea1a450df04de900ee69bd5b7078643c543302130cefc2
153168 F20090509_AABQDZ copyright.jp2 083152b6cea5abb0dad19f97f7800844fd73be20ff77d88d0b5e87d6e8b23ec06dfa153f
88742 F20090509_AABPUD 00013.QC.jpg 5bf2f6c9cc48ebfc377c7d2a605e3102454a277ca77c7931caa4c6cd080a3de6cb01ce6d
491945 F20090509_AABPZB 00032.jpg c07ae597b87e0d514b5fc41c90c2630c27c94c0397476c78ec6164ca7e142c7712825120
11696 F20090509_AABQBB 00039thm.jpg e9f90915561f702f63119c84fc9236053a6a09e7e54ad95a02443191863a941a6b22b970
37960 F20090509_AABPUE 00013.tif 78e27f9b402750dad80e4755744f32f07fe879a3c07d577a9848b1bf0b7cc6572517f1c5
70728 F20090509_AABPZC 00032.pro 24242b56aa26f631aa2878ca9c4cfa048cab9daeb8386919b48f0ce296a9dc17e5b56d13conflict in mime type metadata
90446 F20090509_AABQBC 00040.jpg adc40c71d02cb09a371e06e902cecd88b27b45140b846ae3245c455fb05b4288856b46c8
943 F20090509_AABPUF 00013.txt 39f9bb6670b6b90c9befbcfbabc052a44390e481c25f1b7208d0061b0884e3261820f553
148405 F20090509_AABPZD 00032.QC.jpg fe0c05d649a0c2ce83af5fc16f1fddcf57d280b74a6c4fc19ac46e3e80da99658ee79dc8
32428 F20090509_AABQBD 00040.pro b2f63aa873590bbb010877dcceb070ff68b63e99bc795dbaac84442f97c4702ace76cf21conflict in mime type metadata
26416 F20090509_AABPUG 00013thm.jpg 30d30f7271d7e00f50fcbe34ba23847363c2623eb75a6efbbdd2f7c50ae67e470925fcac
71894 F20090509_AABPZE 00032.tif d6efcb179698ce3ab610de9b9a9e0d564496cd3c471def94d1996eb0083f305762f2afec
31645 F20090509_AABQBE 00040.QC.jpg 1b075be879241ded58524a21e484e5128cb01484c736451c726008832a8d05b9437df977
F20090509_AABPUH 00014.jp2 27ba417a5520598a397981ccdadd5536f32e6591f0e919fb887f71ba01a69792804cd39eMalformed codestream
2709 F20090509_AABPZF 00032.txt 0a89d3dfa0117ca9f9b447f5311f157592c109df19dfcd326399df3718b9f4a5e3646c9b
23864 F20090509_AABQBF 00040.tif eea771ebd2616b44679f02b96c869857a4955188493554d109dd75ad4b062a87907aaba1
462336 F20090509_AABPUI 00014.jpg 30551c43cb31f34d7c9c7304005406ae0f214ecd510bb5b4779c654e7e51e030f13e2476
37909 F20090509_AABPZG 00032thm.jpg 60aeae266d8e43c715690f14310447f82888c783b31104cb50894054b6b721bc81f61d06
1694 F20090509_AABQBG 00040.txt 656072a5e775eea149927e61a9a0825c42ecd11a1fcf94491f33333052576945a12e5b83
53704 F20090509_AABPUJ 00014.pro fbc0354b78f680dd45d4bc6037ce888bf82a0056c05b0b1b2f441dbe7d4415148cfe665cconflict in mime type metadata
11176 F20090509_AABQBH 00040thm.jpg 19d49b94547c436d6893c82dbdd4b783ea7cd45db079d686e5269041f37db2617607e554
147496 F20090509_AABPUK 00014.QC.jpg d458f236d0e18bf53ff87413c73b4df9fae3e80f6c3c470b94ea77093e9ef1475e072ce8
F20090509_AABPZH 00033.jp2 40621a4ae19c3d77b9223c62aafdc8026d7be50577ea1361269bd1f15eabc5e343730b16Malformed codestream
F20090509_AABQBI 00041.jp2 6930f9f829a33665a651d2299bc2e8ca4bc60319da2c99f3a16801d8dc6a3a46e07f60edMalformed codestream
59634 F20090509_AABPUL 00014.tif 9889725ca743f0cfca993e9970a9306dbe2530e1735818a1d1eb6cc6fd588d48f8500dc8
518284 F20090509_AABPZI 00033.jpg cbb17feb9e3183fdcea6490f47bd7965ccc2ee5bf69a135e16ac5e3826d57ad9ff64f8c5
83295 F20090509_AABQBJ 00041.jpg 6f0cc2c610414f11461ba2274e72354021e1f8b593ac944f83babe0fc97907e5c819fd83
2203 F20090509_AABPUM 00014.txt 16b9ec8d64ed7d3dbb9432f3485880002bae5a0010eef8a93fb32e6f02c0ac75204d3ed9
79056 F20090509_AABPZJ 00033.pro 8d43294b764bb4591c5b7763f3caa070c4da7a03282370cd983fa76c257e2b19cf01c627conflict in mime type metadata
33242 F20090509_AABQBK 00041.pro 25bbd1625278f1fb350bb036ecc52682549e95733738440b7f52c34d5acf9a6d58b43e2fconflict in mime type metadata
39094 F20090509_AABPUN 00014thm.jpg a42f6f3299373f1b3185ecbe33d6b89aac6756c7e429d2be15da5ba2bca17474465dc430
159144 F20090509_AABPZK 00033.QC.jpg 810e6d55756804735756ccfdf8803792f2b2c8c7c2780f5aa82c01966ab4bb9cf8dcd6a0
30783 F20090509_AABQBL 00041.QC.jpg 4ce7d44715db1a812e10ab09f391da9262c40acd5bde3e3e51a4c13f99d611268c1a555f
79263 F20090509_AABPZL 00033.tif 295e2783b66a1bd15cf538abf7a6ce93e7b2122c8627a703a6f1ca600576b1e82f7f0ab3
21961 F20090509_AABQBM 00041.tif 2bc3c16848ad10538ff975e9831f6afa95d10a3157a2cc00afd28136ac15149960188ed9
F20090509_AABPUO 00015.jp2 58c9b7889d7665f86da7279cc631fd09070a650cc6d2cc346d73adf4936cab6bbf9be7c1Malformed codestream
2946 F20090509_AABPZM 00033.txt dfc3b59d5ecdcb9c5cd4a90746904fda84bbc4e54d0293a34040bcb541a105b1b266f95d
1698 F20090509_AABQBN 00041.txt 1af2117f9f52662171212704c60af16aa45ab37770a646e8944e2ab83cad96b3600dd456
397766 F20090509_AABPUP 00015.jpg e76eef9b4beb48ede30fdc612b8b8eccd1559626c53a441dc45905223a4ab3205d348cc9
39099 F20090509_AABPZN 00033thm.jpg bd0452c01ab97cb0af5f56cc8668ee605f6ae9b0e0813d26a17ad1d79a017e3f7193cbc2
32320 F20090509_AABPUQ 00015.pro 614b532557998b446bfed845f4a2937809f8bbde88cdb2845a4ceeb03368840629353a1econflict in mime type metadata
F20090509_AABPZO 00034.jp2 6de0ea95fd7b9bda41901d87ba9eb293a8d141951839ccdc14118eaea57cac4fa06b09edMalformed codestream
9701 F20090509_AABQBO 00041thm.jpg 02071ac3f63bbe3baace6aca40b3e39375ccbbe27eaa95f7d027c4fb846baa56ca9a4d69
118958 F20090509_AABPUR 00015.QC.jpg 72ecf33483f5435efddd513d56b54e460925a8dc32bdca03acda11b90f259d70bab2ce73
530823 F20090509_AABPZP 00034.jpg 9872643b6ad65d461d5c70a06d69300706cdc8db4240bd45ac0421c41b9a998a3dcade69
F20090509_AABQBP 00042.jp2 3d18316318a6e9d41cecaa3b3a5391ed8b99d6447c7d6a047810f6f2549159a7aef0456fMalformed codestream
89360 F20090509_AABPUS 00015.tif 6c654e7f66756bea6fbf04676b41cfb09c0f73d08f43fad28c58f2805a99c54cfdea00b7
72572 F20090509_AABPZQ 00034.pro da65846e4310751451fddbe5acccadd6ab5913bec5a1aabbcb63fe266c95e52cb5ce2a16conflict in mime type metadata
70163 F20090509_AABQBQ 00042.jpg f7ec79db5c567188fea66eef2feae6d889b49589837ae4d0538ce842bd0366b2225ff75d
1456 F20090509_AABPUT 00015.txt 17e002ae95208f47da5dae8b936819f241d74712e8fafc07551e29e32fc9fc68b1a54e54
161436 F20090509_AABPZR 00034.QC.jpg 06bbcd41d0e3f62c9edd0570e3a4b3b83aa8393e1636406bbed728c75555650c54a10780
23747 F20090509_AABQBR 00042.pro 2d3755c36bfa77fc84f3b89445961ae3d1c58e1f8f49f16f524767c6406896f25d3667c4conflict in mime type metadata
33229 F20090509_AABPUU 00015thm.jpg ae6d787d3a8d4b5e3864bb88ecdda15ec2dfd78e704bf2c2a60991df997a7eadb49ad818
73442 F20090509_AABPZS 00034.tif be7c9afcac9c3bc46427338572b972b599998ed039de20e08376126553c1d0eb6d9af479
26562 F20090509_AABQBS 00042.QC.jpg 2909d5df303c74baace8102b7de2b37661e16cc4c095fad3f51f265404847b9965e49042
F20090509_AABPUV 00016.jp2 30d5e430f5f0ec6fa35439f1b1f3627bc965c48695b46f292bcfac8b63e729f42a1f5846Malformed codestream
2745 F20090509_AABPZT 00034.txt 468aa8c8c39ff514751af1050ae65176868e5ed57f4b3bc986b9528f63394da768b89423
17097 F20090509_AABQBT 00042.tif ab673f91947a59a9b5b861a842c48055ed0bc6610d596cc20796db24da8e51b7d3c5f503
204466 F20090509_AABPUW 00016.jpg 0b91a0f7d287972cfd2f72296b345861f75ff791f18d1c6812b8b6c364aad42d88edcac4
42940 F20090509_AABPZU 00034thm.jpg 6820cfc201d455a424c66453668e809a63375ca81af5070635b5da12ac8e02e07d8ea202
1166 F20090509_AABQBU 00042.txt 2bae41afa9e682c79ec6090716acf5a786e84200c0814e582eab7e28049db16adab4b3c7
17308 F20090509_AABPUX 00016.pro 1436f7eaa1f374d8ad3ac444896774139dff4e60f831489c71800da4fe55cc0495dc5284conflict in mime type metadata
487301 F20090509_AABPZV 00035.jpg 66d12cb903aa42cfec36b782a248caa23ad1f084750ad0be56d62e9a1eb73eafb25c50bf
9061 F20090509_AABQBV 00042thm.jpg bc8410dcb64ff622a976dff98e82d2db720bdfe7e574cf4c5fe60e76c5a77c16a7e4fb51
60419 F20090509_AABPUY 00016.QC.jpg 80b82e9f4d150d2fa8af1fbc4c5bfe4957eaa52797972333919f535139138872b52b8019
73303 F20090509_AABPZW 00035.pro 0be6518e9735af7eccce044063f0fc8735008588672016535f8402c2290f784a324d2cc7conflict in mime type metadata
F20090509_AABQBW 00043.jp2 bd2b1f1cbe70b3c59f2876a48974a718b7a6bb6bcd3dd2cef12b1cd52972b2e3ab112c98Malformed codestream
3922 F20090509_AABPSA 00005.tif 0911eb505e7388fb2e77876b666efc4b31999ae3b84105051a22abd0a51422d1caab5e01
115477 F20090509_AABPUZ 00016.tif 5524dedd3dfdedaa8f4eace2d17de5e0de935e01e6d366aa52e8b727b2d1b2255bd3d853
147408 F20090509_AABPZX 00035.QC.jpg 0914a57402dd4fba273b77325649cdd1d27826d88b338d5896bbd7f7c69f4db7bb391636
115880 F20090509_AABQBX 00043.jpg f822cd4cd4f4432e74c69ea479b16c86b85f79af96fde22a5a557e06b575306847af76d6
312 F20090509_AABPSB 00005.txt 2dfe329bd25ee013d9f00039b3f434871fbebb8d3f6a259e605dc568c20a3eb26fb1aa0b
43074 F20090509_AABPXA 00024.tif 215db01b219aabd93659b47d52ba827aceba1d23df485023000905882379e3656519f582
75279 F20090509_AABPZY 00035.tif 8879d00274710db1b0f0832018640f9e961e50c7b55f836c5a265f3d9789aa6db6c96717
41989 F20090509_AABQBY 00043.pro 055f965a425f60ccb9fe84ca90c651e6705156482b433e578a004d6a12b159859426ba51conflict in mime type metadata
3493 F20090509_AABPSC 00005thm.jpg d20afdc398e5fe1f01975167990789b8192d7294cbca228867b6d2ecfd284ac5da3c4b52
1443 F20090509_AABPXB 00024.txt 12b706a835aa492d7e276035c100bc274bd38215b68b6c0447ff79082d302bff3cc931a6
2797 F20090509_AABPZZ 00035.txt 8243cfd6804a6cf05856cedd014d1e43107d7336f3f4d95fde58a80a3770a8e39436d6ae
34176 F20090509_AABQBZ 00043.QC.jpg 7e21b2ff972ba8c3d4ec09565c79ffc899407fb53fbf1a6613358bcb60bafef2c99774c1
F20090509_AABPSD 00006.jp2 a65d0e9cef94a6e90c053b245ea5d174c6211b669fa57e86c366304f05a4c2727da1b57eMalformed codestream
31189 F20090509_AABPXC 00024thm.jpg 9a9140bc8d5dd35b46534dab5f8687451707173c66a2c36c6dca32d337cd27965c6ef70b
256684 F20090509_AABPSE 00006.jpg 7583e52d6b568f3a8622e8edd43b4283723baa6757b06ceb76cf087c2b3c14cde38fbf87
F20090509_AABPXD 00025.jp2 cdd9ff75d8a56682d7572848007821a2457cb0df6cf9525c6624cc4573d68ca51bb98721Malformed codestream
59648 F20090509_AABPSF 00006.pro d3918ab0a2bf45d4cac1375d1eb01b42b9e031055ab82d307f85dbd0f6a1d1eeb20f279bconflict in mime type metadata
319377 F20090509_AABQEA copyright.jpg 240d93ea502d8e8d812b30031bcb0e2538484e48ee07cedb11353800926c3d33e59b37e9
304680 F20090509_AABPXE 00025.jpg 00bac6adaacd5436cd0469a60c489d98800da2257385113b136455d61007ee945d2352ed
83687 F20090509_AABPSG 00006.QC.jpg 0d718d3b9463ae0b619f88958766e6f4ad7ba47dc83ed2f27abbe193ab7466a301fd6240
35680 F20090509_AABQEB copyright.pro d4ebe75aca19f2601c53637232383091be2800fe1b6d6a108661809b082f35391c0ddf33conflict in mime type metadata
30871 F20090509_AABPSH 00006.tif 0dfaba5ad88a90894bf5a0be4c5fa05cadb16dfe1c324da9f9554a946ad714ffce279c1f
125124 F20090509_AABQEC copyright.QC.jpg 39be1331a62476001b55152c55f89346c81fc12f86333de191c93f0aabece1cb2a08619c
22417 F20090509_AABPXF 00025.pro 88d2e7794c470963d681d67a465ca143294784dac0be7bbada5da380daab6129b880f8ccconflict in mime type metadata
2574 F20090509_AABPSI 00006.txt a111fce9c021295ad9c0bc9027629eab8bf5ff910ad65f42f99b0a9951d7b19d27d62943
1069796 F20090509_AABQED copyright.tif 7ffd82ae129e3d2fa9f2ff0d75e3ec113031c5ff582a35b6547e951950f9d3e6507001d1
101936 F20090509_AABPXG 00025.QC.jpg 907570e75b54a358d2cb0a133d26a182452cd0def0e0e8eaa169401dbb5d4eb656eca144
21566 F20090509_AABPSJ 00006thm.jpg a94b3a9a88a11d040bec1c066942f80123d739f39e5b6d11385d939ce5fd104a8d7a0570
1329 F20090509_AABQEE copyright.txt 15f2bbd34b776d39b92ffb1c4f760b27b0251f2ed30996bc7ed3d8efa687abc9a6800fa9
43019 F20090509_AABPXH 00025.tif e52327550643d8d8d0c45ba280457cb1e62d5a5ed33fb2d4b61b1a0998bd89e13648adce
F20090509_AABPSK 00007.jp2 4a7295f833a6331690a756350f4128cc368b15dcd61b9ec2b1b99c2119da3846f3c85163Malformed codestream
57392 F20090509_AABQEF copyrightthm.jpg 88e6dbf09eace79daa5dec1650108cb13138cf56f6cce1912c219fb7a0be66e042721bef
1311 F20090509_AABPXI 00025.txt eddc8c45dcf3d9d2c492e46e6d039997f251a8bf35695366ee35b7f1b61b27071b50bf21
226736 F20090509_AABPSL 00007.jpg ce69f173f23c9c81284f98996b37a65237a69b0395f729557230f02cd338623b69cd1717
78764 F20090509_AABQEG UF00001276_00001.mets FULL 266568b7b97232b58596b40976ef227ecfebdbf583ef9e98d3bda910cd008bc480d1f797
30263 F20090509_AABPXJ 00025thm.jpg bdca2e6a846d7bd9860593611707b86b0156e1c109362d9c681be7820af17a64ac2006c9
50245 F20090509_AABPSM 00007.pro 2f2b12f2242db8018f7ba397df2f4789153869f248f908ba5be857badf3c33127aaac2bbconflict in mime type metadata
70247 F20090509_AABPSN 00007.QC.jpg f802e8abb1c7d06068789009c7ac56c0abb6884f60ac90d0ec6b439ece00a7215ffcd520
F20090509_AABPXK 00026.jp2 b075da89f14e2e12dc94a09271ece93e41825a2ffbcff950affd1588bf09e98892346518Malformed codestream
32404 F20090509_AABPSO 00007.tif 665203e85a7641e9f896d6bb8ae8262492deaa9ec3c4b9521004386ab6bbc621281d1b2d
99162 F20090509_AABQEJ UF00001276_00001.xml da57c3c3c853ed43ba50910273643b5c771f519d61269d7e91a24f1fdfbab133dc8acbdf
304369 F20090509_AABPXL 00026.jpg c0e84a78308c46ed1b375954b9210bf93ebd5754d34ae9ffbb458c5a70c6399419176458
2072 F20090509_AABPSP 00007.txt 615e402c1cd4ffc9ba2e865dcc94c83655151b98c8f3c1db2b2fd6c2c8e2f975222fb360
22062 F20090509_AABPXM 00026.pro 0ceb7a352eff45f86a13fb96a36aa44f2571db2594434f678f91305bb1c49c1cdf3567dfconflict in mime type metadata
18447 F20090509_AABPSQ 00007thm.jpg b49aabe0dcad8f95132be31a42d98dfa49bc4c55e946751819bfa5855239a422868066c9
103727 F20090509_AABPXN 00026.QC.jpg c870e0324b2bb276a7205112a008d93aa116e8b0149ca15a3bb44520f3b918c675e111a6
F20090509_AABPSR 00008.jp2 8b21eaf78712a238340d961cf6dacf1db2b0bde8e57fa71a4761cce1299b1602edbf9f01Malformed codestream
43046 F20090509_AABPXO 00026.tif ad1fd4d08ccf9f8f7c738ddd07092e8af018b8f62067b3ebbe57889a817c4c75ad90d6b8
46858 F20090509_AABPSS 00008.jpg 2806d9bf5a3dcb7ac4a4f1d93c414e9af496e4025c72c3a97b1669de80845b53690cf4d1
1422 F20090509_AABPXP 00026.txt 5af8882a30aa6fdbfdbd69a4f5729fda9d8d4e60e0aca39e8ac6976a3132da92b211ecf6
7933 F20090509_AABPST 00008.pro 47bd86e80915e144d45be39ef9ebf53557ed6cb1d23fcced7a7e6a0795352b26ab24e716conflict in mime type metadata
29430 F20090509_AABPXQ 00026thm.jpg 64d3b2ff6da07f4785f0b7534ea1705c0b371c4f010be74297a909b1c8eb4c6517a17a5c
16581 F20090509_AABPSU 00008.QC.jpg 155c0dc5139fe9c431c60edb77a7c4dbd52a424ae4fb8365c73b0a3f7f0bb4d950ef617f
F20090509_AABPXR 00027.jp2 20904d9d6a5c3198d9f493a1857a8de99406dee0ce0409cb9f636c09189ae4e32a039867Malformed codestream
6582 F20090509_AABPSV 00008.tif aa9b4dc30681e6f8ed89473031ae7fc2f9c1319bdc43ca2991683e6b8c3af30780b4f52b
426666 F20090509_AABPXS 00027.jpg f19c995ca688e9e936e3be688fe2ed3da9e64ac72189ac4f2d57cf7a9c01dd44bf899460
398 F20090509_AABPSW 00008.txt 66b07e486bab965a5869edca84b54e16b9422f226015b8ab2a94c72c6fa0ed404f2534e5
41442 F20090509_AABPXT 00027.pro 14c76cfdf097683a13e87456770e22f1d82e7ad9a4bb2285cc42811961f61486ad1d0483conflict in mime type metadata
6128 F20090509_AABPSX 00008thm.jpg 8b3cabfdf06266cd8f7bb89dbda46eb03ab2365b72460c1c4e23484cc560a9e121a00304
135322 F20090509_AABPXU 00027.QC.jpg 129ecd494b4268988037a33e497f648ad5da90aeb5325b5e39e9a187e76c926a53764153
F20090509_AABPSY 00009.jp2 425e28ef354c5eb43a056e1b2422f76ea2b669e7b28877b7c5fe70f815cf42f504e9ab83Malformed codestream
63667 F20090509_AABPXV 00027.tif 80f1d5991e276a282e9ebb34365177ed26c0af67e2a0c908a3e816171e93be96a9f15273
102128 F20090509_AABPSZ 00009.jpg 300bd26d50a8994c0c963eeebb6aaf73efeb1024ace8f5ce8cb3d573c51c91f615d4e72a
1561 F20090509_AABPXW 00027.txt b6e70081febd8cdb0bc9f79c3116c3d36aaa97fd53349f9a88e5d770c108d2faa528f060
36681 F20090509_AABPXX 00027thm.jpg 7b06e2871fd3d7c0de6f1faca12647e4c6763222c30686135bc68af6e1b4cf60672250a0
F20090509_AABPVA 00016.txt bf840b5094ba38949d4aa018237ffbd3da680650e74eb6e667e31d3a3ad34c82f14d0d24
F20090509_AABPXY 00028.jp2 4be82eb077b0ca73a1d885d418829020c1aa85e224e367b5459edf50ba0f590de56b5c04Malformed codestream
16595 F20090509_AABPVB 00016thm.jpg 66e456119cc5bd65707faf556b5f43cdbf6564e2aeb165209e47337070c1515b1ff54a4f
368067 F20090509_AABPXZ 00028.jpg 603182682caee36975202a3c278dec493d4ca2c98bf93c110e36803e498e06bf569e4e45
F20090509_AABPVC 00017.jp2 0eae332c847c9fbfb5f623d2c3581555dd2bd863480171434d7e14ec9ddf366062ea7225Malformed codestream
28499 F20090509_AABQCA 00043.tif f7834576bb496dac9225ffcd4dd561ed4fe4ff9a43b28f8d2ee4fb33036e0420f8370753
1704 F20090509_AABQCB 00043.txt 93cd9b98edeb60f7830c22a779f72e283b0cb890652a356c5dd4318858a7f7f25bde9e4a
180185 F20090509_AABPVD 00017.jpg a78238ebd636e7a382b65ceaeefbccc004c1257094633318dc07f5a33008ad25d409dfaa
9817 F20090509_AABQCC 00043thm.jpg 5f89baa5249d3272989e6ba6ab01049d2fc39298e3dc746acfc2fb4bf22923378549f0a8
4145 F20090509_AABPVE 00017.pro 096d8941a73e9858aa561c4f8856ea26999e3d7ee573841ac330e3b4939590fc7924a00econflict in mime type metadata
F20090509_AABQCD 00044.jp2 8f45b07fc4455d5ebda3c4adb16445481dd2bbf29ea7a0f54489dc2ad5a70288340ff337Malformed codestream
53153 F20090509_AABPVF 00017.QC.jpg 9872029b7312f012a781ba9cc8b6d4c596d2ff6366c3243a926e0e309d691e66d4220684
176805 F20090509_AABQCE 00044.jpg 70f12508956c2f2b66db2b936e747421bfef518c08b6529af3cd4252496f2b554ff809c8
99223 F20090509_AABPVG 00017.tif 3137a3a7f7b2b9f048ffb7387bf92956ff1a3ce8926de76957f225b761be83664c399b2b
26909 F20090509_AABQCF 00044.pro 36d5154475bba065ac82d66684ad2024f923735e4eb7ecd7fd5e2a943937caa794d86cf0conflict in mime type metadata
268 F20090509_AABPVH 00017.txt 2d0fb7d00f7aa120912dbda83a1c9c68683f1843d3d438e66d9021110f331ad144227274
59172 F20090509_AABQCG 00044.QC.jpg 63979a8959a78b17f20f0bb723a0b431c898a8e0c69e3c6339a720852a8b8a110ae057bf
15611 F20090509_AABPVI 00017thm.jpg 173aa2349452c876407081691c7cfa4745870ed9df10900875d3ddca8b65f942228cc9c0
26361 F20090509_AABQCH 00044.tif eaafc8d3784a0c93ed3317124be12a6f591485f11a855ca616f79f2bb8e3c8bcc327c934
648173 F20090509_AABPVJ 00018.jpg a56d370f99d4bbe7e40b9ab7b99d93507453bd477b59a11fa37a8766857c40a5fde3ee9f
1489 F20090509_AABQCI 00044.txt cd329c80880f911c294775fb7ec239df1c6f6b31d8757d1ce29ae11929972d11240fcf5b
93996 F20090509_AABPVK 00018.pro c56fdf26ab284efdfbb482b8c5a7d7a29298ec4ea5f6e7182151f98c7a778cc94b01d614conflict in mime type metadata
20754 F20090509_AABQCJ 00044thm.jpg a7d8d725edec64c5b3fc1872f0db0f2ed20fd1cc1ea7f0e666670468f78874d729e9ece5
194313 F20090509_AABPVL 00018.QC.jpg b0f41398ee89fb74712b1004a499171af4454ce9db9ce965aab06c3db8e157b21f808eec
F20090509_AABQCK 00045.jp2 66813b7050405393d1149ce163025cc525d8a0a892f87d1d080601c63ab8614e4563326dMalformed codestream
89006 F20090509_AABPVM 00018.tif ea7b0592adf5117946f6e3d016a8dda1b5406e4c0c26fedd1822279032f3884fda58d262
171594 F20090509_AABQCL 00045.jpg 2b7c67f3a4fb57fe0f9c17709ad5fa29cce9b881f542c618061507d38e879a654a60bd2e
3417 F20090509_AABPVN 00018.txt 994c3050f489e923808b62f3e305654f9d45ab9324e870f7cc26c89a0e116f33fb5a4aed
26742 F20090509_AABQCM 00045.pro 8ea72b9fadc3bdb2ad5571c0396b7f30020dde8e6de0dad7e53a3289e605f14dc7337c39conflict in mime type metadata
48030 F20090509_AABPVO 00018thm.jpg f5c712ed38c7316da3d7a6483233c59935878a4cefbaf8469789d5e47b7cd2458ec64650
61220 F20090509_AABQCN 00045.QC.jpg b8edca1d06535280a3cde2e7ff2bd4b02f71ccf58f1517ced8abe9c2e168f584e8240326
F20090509_AABPVP 00019.jp2 5e85ec742adc156bda5cdb43c1bf48d199ac9199697149de7afbdd6dda2432722e3b783bMalformed codestream
370240 F20090509_AABPVQ 00019.jpg 47da83e8e4d1e7aaed208ea5073950e4d30339819e28a74a0a9b4485ea52acdd6f76b33d
25247 F20090509_AABQCO 00045.tif 8268552b2825257c5ad5e92177fde57d617e6a57add10b6bc0eb1deb175a0a18317c5721
23964 F20090509_AABPVR 00019.pro 46addab023b7a6aef4aa3d1659eec72b3e4bb41f6270aff698e4695d36e143bcd9ddce15conflict in mime type metadata
F20090509_AABPQU 00001.jp2 b3635512649b7e274861d0acd5de2e82526d77d2228308e632e5a31a7f74f1bef235af42Malformed codestream
122724 F20090509_AABPVS 00019.QC.jpg a940f670e0550b06fcf37e46cfa2237629c5f4df220f3464e36600db9d746703be07ad98
10887 F20090509_AABPQV 00001.jpg 5bb1e26a398aacd696258d481b197681299e2a57ed8e1e44320c62a4772da2cc12b4af2f
F20090509_AABQCP 00045.txt c7f3a78d3b117a4f942ff7aa805d4d369d8f581d53f3f4478b07b7d64142db3d15322266
52560 F20090509_AABPVT 00019.tif 94129107dd4944f0f2b5357be777e01d0e51e5a299ab09cdb4381e7781413ef01cef4503
227 F20090509_AABPQW 00001.pro 559d4d3bf77c348c44b11268dacbe6677fbc782949908479875369eccd248d211f17c38bconflict in mime type metadata
18605 F20090509_AABQCQ 00045thm.jpg 40650a54bea41354be38a378c18ac1f678cac7df6b9438d4a34266f802a593b57516e9bf
893 F20090509_AABPVU 00019.txt 106c45b4052bce5065716078a5219869b2ae95c83987416c7cc3a4e76d1d8210efc93345
3567 F20090509_AABPQX 00001.QC.jpg 5378f2f90d04e8d59985ffd1b5589dc204eea5b5e51de65973b5d3e675550c8adbabc9f9
F20090509_AABQCR 00046.jp2 b1c9eea529e3bfc05fe6dd588a5c1b51eaa9979361847a7c2a9c40953e1b384420a5646bMalformed codestream
35964 F20090509_AABPVV 00019thm.jpg 39d78596cc42f9a6f200ca86edad823efafd02755192a0ebe705ea5103c040420845ac13
956 F20090509_AABPQY 00001.tif ac14c7c95c8aafd346d392ba74e913ed5a348e5c96973f758ebfafe439e8ce7dfcfd957c
177837 F20090509_AABQCS 00046.jpg cd5896a3e3688e4af0a5ee1c0050c9227d4b26354ac8a458bb0d89088075b3e828fae08b
F20090509_AABPVW 00020.jp2 2ed3f0b1c14c7dbcb3c90f89cc0bca925d101881289e35b70833528b0f4a20f9aa091860Malformed codestream
3 F20090509_AABPQZ 00001.txt bc949ea893a9384070c31f083ccefd26cbb8391cb65c20e2c05a2f29211e55c49939c3db
24983 F20090509_AABQCT 00046.pro 6aae55dc2f988bedc322e57bfb99b43a122fb1bfb365aebaa57f83a1cd0587cbfae113c8conflict in mime type metadata
349674 F20090509_AABPVX 00020.jpg 6664d0659191d35bddf86e0029bd225c0d50663dc760ccf1f2fb5cb4b70e761142706ac6
61874 F20090509_AABQCU 00046.QC.jpg 005fdf631271b6c92b80bbf49502824fd05079af849dd2e77491f31076bffb2b75f2287b
27313 F20090509_AABPVY 00020.pro 430644292af508f3f0a93f28c58d27f6d832b277cc0718fe92af638a704bcfd8e027e319conflict in mime type metadata
26033 F20090509_AABQCV 00046.tif ca5e876a22fa3853f7880e26fc41c985c0206fb94fa4e986af75a20fb273b1b957fc1c34
14000 F20090509_AABPTA 00009.pro e639dda7982bd7019c3b7917ce36439864baaf5bab80b1325a46ae7b5afdbeab65c87785conflict in mime type metadata
115194 F20090509_AABPVZ 00020.QC.jpg e0ef20826f0314f977e4f8d6e03f2b9917563db4e2629f4af9c75a60179241575c748816
1189 F20090509_AABQCW 00046.txt 73cf3811ddd881d8c5b256f0970dc4ba65d7f8255f901cf1b75179f1124e2810f93b08ff
19760 F20090509_AABQCX 00046thm.jpg 337a5934ab53089d1304234737be5af8e980e2e77446118b376f65293fab31bcbfdf960e
30204 F20090509_AABPTB 00009.QC.jpg 827a53fcb3fb316e8866ef57c68ed3925aff7767b8d4269f68a70a3485c03caeda81e869
51234 F20090509_AABPYA 00028.pro 747c0cf14b60becf1f03a92181ff766bbe01c7d11ccc30b680969effb3530f068343c85econflict in mime type metadata
36974 F20090509_AABQAA 00035thm.jpg 88b29baa3ca6e6d105b1456f888891c2975305a66cb3fae54b8e9d32b08efb563608a408
F20090509_AABQCY 00047.jp2 66a770403df7e232e3a7f7a251fa3575cc0572aa10d542358db11e08602dc6389e647377Malformed codestream
15113 F20090509_AABPTC 00009.tif 8240fc37ea9d46f3c15f7258a04bca94525c8ea29a95346dfc21da5dfc7102edb5f359aa
108816 F20090509_AABPYB 00028.QC.jpg 0a4aa6f0bfc175e2aff90fa6c8b9d1ec314a37291caa3d233db3fa64bd272045d048ef36
194751 F20090509_AABQAB 00036.jpg 0e7f184314a6d765848b951c4955688038faedd44ae8aa941dae5cd9d1d3127a2912812e
173976 F20090509_AABQCZ 00047.jpg 5b64119ee46ab68c8fb4ac502e7f55974b8787ecc2a9225f0889f8c10829c08fa4acc483
566 F20090509_AABPTD 00009.txt d8cb42b78f5254248769d55ba539b8f8af2bb7d40c09f0d7ecea2255edff9c7eb7b8ce3d
52409 F20090509_AABPYC 00028.tif ac47a67de035ead2089fc94d6bd1471cf8447125944e023b09c2d34a8f5804335a7d69d3
36336 F20090509_AABQAC 00036.pro 7d14c15e2f8ed22a6c6a2ce780737e7aa65271a3d2546db802ab3c5ac8d8e34742e558ddconflict in mime type metadata
9140 F20090509_AABPTE 00009thm.jpg 5e78594d4e63f39e814a9de0b9fcfcb8fba8abd160816c864bc20b770b40c6321695abfa
1899 F20090509_AABPYD 00028.txt 37274e0f66c9e0f6b560e78bc743b8798323bca7e16e2812060b3b70d2cb4cab1db87a6f
68905 F20090509_AABQAD 00036.QC.jpg 5621265fe327777f0949bc2ce390d4f4f825f79709e71560f664f57b34115ae7d9c3efcd
F20090509_AABPTF 00010.jp2 a30e93260767251712c6abe452ba6d7516da053c88c8e8a2b19b2069f07d343a48a91a49Malformed codestream
28493 F20090509_AABPYE 00028thm.jpg 3c5bc893bdaab6d2636ae290df6c08e1caf025912177c5fedb7cc668df97e718e5fcb51c
24896 F20090509_AABQAE 00036.tif 1a6ffbb1349127290eb60add8bd068fd4936432d4697fa8cac282a9c2cb11cca48f1c048
443035 F20090509_AABPTG 00010.jpg e206310d8022df6f906e34fcbd34650790866090952ed7404cf03d7b2658f984ad807e8a
F20090509_AABPYF 00029.jp2 755fc3dafd7c347234e690b2d8901d871bf061ac74e3fc1909bedb8093a87786ce7a50dcMalformed codestream
1633 F20090509_AABQAF 00036.txt 1a1709d06ec0044401f11b754be33f65972acfaa61ffdc641708c8fbdedd28c405855053
61449 F20090509_AABPTH 00010.pro 661293927bdda3299167d731857a9e2e8641b9e5b8da4b4122bcb3425ea8ba27d7649748conflict in mime type metadata


Stratigraphy and oil potential of the Lower Cretaceous Sunniland Formation in south Florida ( FGS: Report of investigati...
CITATION SEARCH PDF VIEWER PAGE IMAGE ZOOMABLE
Full Citation
STANDARD VIEW MARC VIEW
Permanent Link: http://ufdc.ufl.edu/UF00001276/00001
 Material Information
Title: Stratigraphy and oil potential of the Lower Cretaceous Sunniland Formation in south Florida ( FGS: Report of investigation 89 )
Series Title: ( FGS: Report of investigation 89 )
Physical Description: viii, 40 p. : ill., maps ; 23 cm.
Language: English
Creator: Applegate, Albert V
Pontigo, Felipe A
Publisher: Florida Dept. of Natural Resources, Bureau of Geology
Place of Publication: Tallahassee Fla
Publication Date: 1984
 Subjects
Subjects / Keywords: Petroleum -- Geology -- Florida   ( lcsh )
Geochemical prospecting -- Florida   ( lcsh )
Geology, Stratigraphic -- Cretaceous   ( lcsh )
Genre: government publication (state, provincial, terriorial, dependent)   ( marcgt )
non-fiction   ( marcgt )
 Notes
Bibliography: Bibliography: p. 20.
Statement of Responsibility: by Albert V. Applegate and Felipe A. Pontigo, Jr.
 Record Information
Source Institution: University of Florida
Rights Management:
The author dedicated the work to the public domain by waiving all of his or her rights to the work worldwide under copyright law and all related or neighboring legal rights he or she had in the work, to the extent allowable by law.
Resource Identifier: aleph - 000460824
oclc - 11409168
notis - ACM3857
System ID: UF00001276:00001

Downloads

This item has the following downloads:

UF00001276_00001 ( PDF )


Full Text






FLRD GEOLOSk ( IC SUfRiW


COPYRIGHT NOTICE
[year of publication as printed] Florida Geological Survey [source text]


The Florida Geological Survey holds all rights to the source text of
this electronic resource on behalf of the State of Florida. The
Florida Geological Survey shall be considered the copyright holder
for the text of this publication.

Under the Statutes of the State of Florida (FS 257.05; 257.105, and
377.075), the Florida Geologic Survey (Tallahassee, FL), publisher of
the Florida Geologic Survey, as a division of state government,
makes its documents public (i.e., published) and extends to the
state's official agencies and libraries, including the University of
Florida's Smathers Libraries, rights of reproduction.

The Florida Geological Survey has made its publications available to
the University of Florida, on behalf of the State University System of
Florida, for the purpose of digitization and Internet distribution.

The Florida Geological Survey reserves all rights to its publications.
All uses, excluding those made under "fair use" provisions of U.S.
copyright legislation (U.S. Code, Title 17, Section 107), are
restricted. Contact the Florida Geological Survey for additional
information and permissions.














STATE OF FLORIDA
DEPARTMENT OF NATURAL RESOURCES
Elton J. Gissendanner, Executive Director


DIVISION OF RESOURCE MANAGEMENT
Charles W. Hendry, Jr., Division Director


BUREAU OF GEOLOGY
Steve R. Windham, Chief


Report of Investigation No. 89


STRATIGRAPHY AND OIL POTENTIAL OF THE
CRETACEOUS SUNNILAND FORMATION
SOUTH FLORIDA


LOWER
IN


Albert V. Applegate
and
Felipe A. Pontigo, Jr.



Published for the
BUREAU OF GEOLOGY
DIVISION OF RESOURCE MANAGEMENT
FLORIDA DEPARTMENT OF NATURAL RESOURCES


TALLAHASSEE
1984
















LIBRAM
DEPARTMENT
OF
NATURAL RESOURCES



BOB GRAHAM
Governor


GEORGE FIRESTONE
Secretary of State


BILL GUNTER
Treasurer


RALPH D. TURLINGTON
Commissioner of Education


DOYLE CONNER
Commissioner of Agriculture


ELTON J. GISSENDANNER
Executive Director


JIM SMITH
Attorney General


GERALD LEWIS
Comptroller




LETTER OF TRANSMITTAL


Bureau of Geology
Tallahassee

March 1984


Governor Bob Graham, Chairman
Florida Department of Natural Resources
Tallahassee, Florida 32301

Dear Governor Graham:

The Bureau of Geology, Division of Resource Management, Florida
Department of Natural Resources, is publishing as its Report of Inves-
tigation No. 89, "Stratigraphy and Oil Potential of the Lower Cretaceous
Sunniland Formation in South Florida."

This report discusses the occurrence of hydrocarbons in the South
Florida Basin, the present producing trend, and the future potential of
this hydrocarbon-producing formation. This information will aid in the
development and use of this valuable natural resource.

Respectfully yours,

Steve R. Windham, Chief
Bureau of Geology



















































Printed for the
Florida Department of Natural Resources
Division of Resource Management
Bureau of Geology

Tallahassee
1984



Iv



















CONTENTS
Page
Acknowledgements ............................................. viii
Abstract ............................................................. 1
Introduction ......... ................................................ 2
Metric Conversion Factors ......................................... 3
Exploration Summary ................................................. 3
Stratigraphy ............................................ .... ...... 4
Punta Gorda Formation ................................ ............ 5
Sunnland Formation .... ... ........ ..................... ... ...... 6
Lake Trafford Formation ....................... ..................... 12
Gravity .................................... ..................... 14
Geochemical Analyses ................................................ 14
Sunnlland Formation ............................................... 14
Fredericksburg Stage .................... ...... ... ............ 18
Conclusions ........................................................ 19
Selected References ................................................... 20
Appendices-Methods of Investigations ............................... 21
Appendix A. Geological ................ ........ ................. 22
Appendix B. Geochemical............................................ 23
C1-CY Hydrocarbon Analysis .................................... 23
Sample Preparation ...................... ... ............ 24
Detailed C4-Cr Hydrocarbon Analysis ................. ........... 24
Organic Carbon Analysis ..... ............................... 24
Ci1+ Soxhlet Extraction, Deasphaltening and
Chromatographic Separation ....................... .. ...... 25
Gas Chromatography Analysis of Cis+ Paraffin-
Napthene (P-N) Hydrocarbons ............................ 25
Visual Kerogen Analysis ................. .................... 26
Vitrinite Reflectance Analysis .. .................................. 26
Fluorescence Spectrophotometric Analysis ...................... 26
Appendix C. Results of Analysis .................................... 27
Summary of Total Organic Carbon and Visual Kerogen Analyses ....... 28
Summary of Individual Well Organic Analyses ...................... 35





















ILLUSTRATIONS
Figure
1 Location Mapof South FloridaBasin ..................... .......... 2
2 Location Map of South Florida Oil Fields ........................ 4
3 Stratigraphic Column ........................................... 5
4 Stratigraphic Cross-section A-A' ................................. 6
5 Stratigraphic Cross-section B-B'...... ......... ..... ... ......... 7
6 Stratigraphic Cross-section C-C'................................... 8
7 Sunniland Formation Dark Carbonate Map ....... .................... 10
8 Equivalent Good Porosity Map of the Sunniland Formation .... ......... 11
9 Dolomite Isolith Map of South Florida Basin .......................... 12
10 BouguerAnomaly Map of South Florida .................. ........ 13
11 Total Organic Carbon Cross-section ....................... ........ 15
t2 Total C,+ Extractable Bitumen Cross-section ....................... 16
13 Total Ct,+ Hydrocarbon Cross-section ................ ........... 17
14 Correlation Chart Used to Determine Hydrocarbon Source Quality ........ 18
15 Summary of organic analyses for Humble Oil No. 1, Tuscon Corp.
(Permit 47) ......................................... .. 35
16 Summary of organic analyses for Oleum Corp., Ted Welner Unit 12-4
(Permit 662) ..... ............... ...... ...... .... .. ..... .. 36
17 Summary of organic analyses for Tribal-Exxon, Gulf Coast Realty Unit 2-4
(Permit 563) ................................................ 37
18 Summary of organic analyses for Humble Oil No. 1, J. A. Curry
(Permit 222) ................... ... ..................... 38
19 Summary of organic analyses for Tribal Oil Co., Collier Corp. Unit 26.4
(Permit 775) ....................................... ..39
20 Summary of organic analyses for Humble Oil No. 1, Collier Corp.
(Permit 130) ........................ ......... ........... 40






























TABLES
Table
1 Summary of total organic carbon and visual kerogen analyses ............ 28
2 Summary of Cis+ Soxhlet extraction, deasphaltening and
liquid chromatography ...................................... 30
3 Saturate hydrocarbon analyses ..................................... 33
























ACKNOWLEDGEMENTS
Geochemical data, graphs and geochemical cross-sections were pre-
pared by personnel of Geochem Laboratories of Houston, Texas, under
the supervision of Stephen Brown. The age determination for rhyolite in
the Bass Enterprises well in Collier County was under the supervision of
Marshall Carothers of Shell Oil Corporation. Statistical data concerning
reserves, wells drilled, and productive acreage, were supplied by Dr.
Charles H. Tootle of the Florida Bureau of Geology.





REPORT OF INVESTIGATION NO. 89


STRATIGRAPHY AND
OIL POTENTIAL OF THE LOWER CRETACEOUS SUNNILAND
FORMATION IN SOUTH FLORIDA

by
Albert V. Applegate and Felipe A. Pontigo, Jr.

ABSTRACT
The length of the present productive trend in the South Florida Basin,
which extends from the Lehigh Park Field in Lee County to the Forty-
Mile Bend Field in Dade County, is about 145 miles. The width for this
trend is estimated to be 12 miles. Productive acreage in the 11 fields so
far discovered is 19,180 acres out of an estimated 1,100,000 acres on the
trend, or about 1.74 percent.
Three Sunniland maps, prepared principally from core studies, are
significant in delineating the areas where future wildcatting has the
best chance for success. These maps are: (1) effective porosity, (2) dark
carbonate percentage of total carbonate, and (3) dolomite isolith.
A study of these maps reveals the following:
1. Almost all of the effective porosity is located along the northwest-
southeast hingeline where organic mound build-up in the Sunni-
land has led to commercial oil accumulation.
2. The presence of dark carbonates in the Sunniland is believed to be
necessary for the production of oil. Short range horizontal migra-
tion to a low relief organic mound area is postulated. All of the oil
fields discovered to date lie in areas where dark carbonates make
up from 30 to 60 percent of the total Sunniland section. It is
believed that if the dark carbonate percentage is appreciably lower
or absent, the free oil generating capacity is not present. In the
downdip areas where only dark carbonates are present, oil is pres-
ent but is trapped in the micritic limestones.
3. A study of an isolith map of dolomite in the Sunniland reveals that
dolomite thickness decreases rapidly to the southwest from the
productive trend. To the northeast of the productive trend the dolo-
mite decreases to a minimum thickness of about 20 feet and then
increases in eastern Hendry and Palm Beach counties.
Analyses made by Geochem Laboratories, Inc. show that the hydro-
carbon-generating capacity is poor in the updip area of the South
Florida Basin and excellent in the downdip area in Collier County.





BUREAU OF GEOLOGY


INTRODUCTION
This regional geologic study of the onshore portion of the Sunniland
Formation was made to delineate the best areas for further exploration
effort. A geochemical study of selected wells in the South Florida Basin
corroborates the overall conclusions arrived at in this study. Geochem-
ical analyses of the Dollar Bay Formation (Fredericksburg Stage of
Comanchean Series) from one well were also made.
The South Florida Basin extends over approximately 77,000 square
miles (figure 1). The onshore part represents about half of the basin, with
the remaining area extending west to the edge of the Continental Shelf
(Oglesby, 1966).


Figure 1. Location map of South Florida Basin, showing location of
stratigraphic and geochemical cross-sections discussed in this report.






REPORT OF INVESTIGATION NO. 89


The productive trend extends from the Lehigh Park Field in Lee
County to the Forty-Mile Bend Field (abandoned) in Dade County, a
distance of approximately 145 miles. The average width of this trend is
12 miles. Core data and porosity calculations made from sonic, density
and neutron logs indicate that the more porous units are in this trend.
These productive carbonates are rudistid deposits, with quantities of
algal plates, bioclastic debris, and pellets, which were probably win-
nowed by wave action, thereby creating favorable porosity and perme-
ability. In some areas porosity has been enhanced by dolomitization.
Geochemical analyses indicate that the hydrocarbon-generating
capability of the Sunniland Formation increases downdip, grading from
poor in the updip wells in Palm Beach County, to very good to excellent
in the downdip wells in Collier County.
METRIC CONVERSION FACTORS
The Florida Bureau of Geology, in order to prevent duplication of
parenthetical units, inserts a tabular listing of conversion factors to
obtain metric units.

Multiply by to obtain
feet 0.3048 meters
inches 2.5400 centimeters
inches 0.0254 meters
miles 1.6090 kilometers
acres 0.4047 hectares

EXPLORATION SUMMARY
From 1943 through 1980,184 wildcat wells were drilled to the Sunni-
land Formation in the onshore portion of the South Florida Basin. This
drilling has resulted in the discovery of 11 oil fields (figure 2) with
260,642,000 barrels of original oil-in-place and 98,280,000 barrels of
estimated recoverable oil, for a recovery factor of 38 percent (C. Tootle,
personal communication). The discovery well for the South Florida
Basin was the Humble Oil Company Gulf Coast Realties Well No. 1
(W-820, Florida Bureau of Geology accession number), at Sunniland
Siding, Collier County, Florida (now Sunniland Field). This field had
original oil-in-place of 37,685,000 barrels and total recoverable oil of
18,842,000 barrels, for a recovery factor of 50 percent. Productive acre-
age is 2,080 acres.
The most productive field discovered in the South Florida Basin is the
West Sunoco Felda Field (figure 2), which had estimated oil-in-place of
142,857,000 barrels and recoverable reserves of 50,000,000 barrels. Pro-
ductive acreage is 7,660 acres.
Total wildcat footage drilled to the Sunniland Formation or below
between 1943 and the end of 1980 was 2,209,000 feet for a discovery rate
of 45 barrels of recoverable oil for each foot drilled. Total oil production
through 1980 was 66,869,000 barrels. In 1981 and 1982 an additional 17





BUREAU OF GEOLOGY


Figure 2. Location map of south Florida oil fields.


wildcat wells were drilled with total footage of 202,464. This resulted in
the discovery of the Townsend Canal Field. No reserve calculations for
this field have yet been made. Additional oil production during 1981 and
1982 was 7,082,000 barrels.
Depth of production from the Sunniland Formation is between 11,322
feet and 11,892 feet. The average API (American Petroleum Institute
Standard) gravity of this oil is between 25 and 26 degrees. The average
gas-oil ratio is approximately 100:1. The moderately low gravity and low
gas-oil ratio is believed to be due to the fact that the oil has been gener-
ated near the low temperature limits for oil formation. This observation
is supported by geochemical analyses (see Appendix B).
STRATIGRAPHY
The strata from the onshore portion of the South Florida Basin are





REPORT OF INVESTIGATION NO. 89 5

predominantly carbonates and evaporites, and range in age from Late
Jurassic or earliest Cretaceous to Pleistocene.
The emphasis of this report is on the Sunniland Formation. Only two
other formations will be discussed; the Punta Gorda Formation, which
underlies the Sunniland, and the Lake Trafford Formation, which over-
lies the Sunniland (figure 3). The changes in the thickness and the
lithology of the Sunniland Formation are shown on figures 4, 5, 6.


w W U.


..-... .. ..... ..... ...........
P unt FORMrATION




l z o"'"'.*''.,iLAKE TRAFFORD::-::-",

and "n C' L ." .." .." .. .." W ." .. .( .p .
o -
I-
z .. ..: ..:' *,:: SUNNILAND.,.. ,
w I-

PUNTA GORDA.:*%.,%



Figure 3. Stratigraphic column of formations discussed in this report.


Punta Gorda Formation
The type section for the Punta Gorda Formation is in the Humble Oil
and Refining Company Lowndes Treadwell Well No. 1A (no permit
number) in Sec. 17, T42S, R23E, Charlotte County (Applin and Applin,
1965, p. 39). The Punta Gorda Formation was cored and found to be
467-feet thick. Core recovery was 81 percent and a study of the core
showed about 80 percent anhydrite, 11 percent micritic limestone, 6
percent gray, non-porous dolomite, and 3 percent calcareous shale. A
thin bed of salt was also present in the core. The thickness of the Punta
Gorda increases downdip in the basin and is about 600-feet thick in
many wells in the Sunniland trend. The thickest section encountered to
date onshore was 820 feet found in P-778 (Bass Enterprises Barron
Collier Jr., Sec. 12, T52S, R27E, Collier County). Seven wells in the South
Florida Basin were drilled to igneous or basal clastics. A study of den-
sity logs in the respective wells showed 83 percent anhydrite.
Salt beds within this formation have been recorded from wells in the





BUREAU OF GEOLOGY


? 232 I


TRAFFORD FM.


-12,524 12,173
-10,985
PUNTA GORDA FM.
LEGEND
5, 16 DOLOMITE
o '0 I ED LIGHT LIMESTONE
S-s 25- 1 DARK LIMESTONE
SAMi-IvYnITr


MILES
SCALE


ANHYDRITIC LIMESTONE
SALT


Figure 4. Stratigraphic cross-section A-A'. See Figure 1 for location.


Florida Keys. The Gulf FSL-826-G well in Florida Bay (offshore Monroe
County) was partially cored in the Punta Gorda Formation and 17 feet,
10 feet, and 1 foot of salt were encountered at 12,150 feet, 12,517 feet,
and 12,625 feet, respectively.

Sunniland Formation
The Sunniland Limestone was described by Applin and Applin (1965).
The type section of the Sunniland Limestone is in the Humble Oil and
Refining Company, Gulf Coast Realties Corporation Well No. 2, W-961
(no permit number), Sec. 30, T48S, R30E, Collier County, in the Sunni-
land Field.
The authors of this paper propose that the name of this rock unit be
changed from Sunniland Limestone to Sunniland Formation. The rock
unit has widely varying percentages of limestone, dolomite, and


LAKE


I





B # B '
775 563 662 265 47


-11767 LAKE TR A AFFORD FM.
-IIS22 -11359 -liii7
11587




O



"-,
0








zz
.. z
mW9
LEGEND
gE3 DOLOMITE WELL SvYMOLS
SLIGHT UMESTONE DRY HOLE
PRODUCER
IsIM DARK LIMESTONE ABANDONED
50 PRODUCER
M' ANHYDRITE


MILES a
SCALE


Figure 5. Stratigraphic cross-section B-B'. See Figure 1 for location.














3c



0.(D
Mo 0

+ C



0







C)
=r








^-9o
CD









CO(D
370
/ 3


Figure 6. Stratigraphic cross-section C-C'. See Figure 1 for location.


- 6



MILES
SCALE





REPORT OF INVESTIGATION NO. 89


In the type well and the wells which are not undip, the lowermost unit
of about 50 feet is very consistent. It is a dark gray or dark brown, indu-
rated, conchoidally fracturing, occasionally argillaceous, micritic lime-
stone. It normally has a petroliferous odor on a fresh surface and often
has stylolites developed in it. The stylolites are filled with bituminous or
argillaceous residue and indicate post-depositional alteration of the
carbonates. These pressure solution features are probably a result of
compaction coupled with loss of volume (Bathurst, 1976, p. 471).
Mobil Oil Corporation, Barron Collier Jr., No. 1 (P-401), Sec. 9, T47S,
R28E, Collier County, the discovery well and only well in the Lake Traf-
ford Field, was completed in the 11,870-11,892 foot interval of the lower
Sunniland Formation for 118 barrels of oil per day. It is the only well that
has been capable of sustained production in the lower part of the Sunni-
land Formation. Production is believed due to fracture porosity. This
interval has been called the "Rubble Zone" due to its propensity to frac-
ture when cored. This interval is also "Unit 5" in a study by John A.
Means (1977) of the Sunoco Felda and West Sunoco Felda fields.
Lying directly above the limestone unit previously described is the
"Black Shale" This is not a shale but a dense argillaceous limestone
about 40-feet thick. The top of this unit is usually marked by a swing to
the right of the self potential and resistivity log. This unit and the under-
lying "Rubble Zone" are sometimes called the "Cape Sable Member"
(Oglesby, unpublished cross sections) of the Sunniland Formation.
The two units described above are believed by some geologists to be
essential for the generation of oil in the Sunniland Formation. Geo-
chemical analyses of these micritic limestones indicate that they are
organically rich and a potential source rock for oil. All of the oil fields
discovered to date lie on a northwest-southwest trend where these dark
carbonates are present (figure 7).
Lying directly above the "Black Shale" is a light brown to cream col-
ored, non-porous, non-permeable limestone which is occasionally dolo-
mitic. This limestone is approximately 50-feet thick. It is miliolid-rich
and has at its base a bed 10 to 15-feet thick containing large numbers of
foraminifera, including Orbitolina texana and Dictyoconus floridanus.
Applin and Applin (1965, p. 3) state that this faunal association is a
unique and characteristic feature of the Sunniland Formation. The
Sunniland Formation is considered to be late Trinity in age (Applin and
Applin, 1965, p. 53). There are other occurrences of these fossils in the
Sunniland Formation but they are almost always present in abundance,
especially the Orbitolinas, just above the "Black Shale."
The "Rubble Zone," the "Black Shale," and the light colored, miliolid-
rich, non-porous limestone constitute units 4 and 5 in J. A. Means (1977)
Sunniland report. This represents about the basal 145 feet in the Sun Oil
Red Cattle No. 1 well (P-314), Sec. 30, T45S, R29E. All of the porosity and
production in the Sunniland, except for the Lake Trafford Field, is in the
approximately 100 feet of rocks lying directly above this section. These
porous units correspond to units 1, 2, and 3 of Means Sunniland report




BUREAU OF GEOLOGY


(1977). All of these units are productive in the SouthFlorida Basin.
Bioclastic limestones composed predominantly of rudistids, algal
plates, foraminiferal and pelletal debris form the productive organic
mounds on the producing trend. These mounds, which are quite porous
and permeable, grade laterally into miliolid-rich non-porous, light col-
ored limestones.
The present length of this trend is approximately 145 miles and aver-


Figure 7. Isopach of Sunniland dark carbonate. The Sunniland Forma-
tion oil fields found to date are located on the trend where the dark car-
bonates are the thickest. Updip to the northeast all dark carbonates
gradually disappear. Downdip to the southwest dark carbonates are the
lowermost Sunniland with much of the dark carbonate section and all of
the upper Sunniland being replaced by anhydrite.





REPORT OF INVESTIGATION NO. 89


ages about 12-miles wide (figure 8). Of the 11 fields found to date pro-
duction comes-from 19,180 acres of the estimated 1,100,000 acres in the
producing trend.
On the producing trend (figures 6,8, and 9) the dolomite in the forma-
tion attains a maximum thickness of 60 feet, which is 20 percent or more
of the total thickness of the Sunniland Formation. Updip from the pro-
ducing trend, the dolomite thickness decreases to less than 20 feet and
then gradually increases to a maximum thickness of approximately 100
feet in Palm Beach County. To the southwest of the reef trend in the
deeper part of the basin (figure 9) dolomite quickly decreases to 0 feet.
Dolomite is associated with replacement of limestone, especially in the


Figure 8. Equivalent good porosity map of the Sunniland Formation.
Note northwest-southeast alignment, where porosity is concentrated
along reef trend. (See Appendix A for derivation of porosity values.)





BUREAU OF GEOLOGY


Bear Island Field. In this field dolomite is important for porosity and
permeability enhancement.
As previously described the Sunniland-Punta Gorda contact is sharp.
As one moves updip to the northeast the Punta Gorda, Sunniland, and
Lake Trafford Formations thin. There is also an increase in dolomite at
updip locations and a marked decrease in dark carbonates.
Lake Trafford Formation
The term Lake Trafford Formation was proposed by Oglesby (1966) to


Figure 9. Dolomite isolith map of the onshore portion of South Florida
Basin. Dolomite thickness decreases to zero downdip from the reef
trend; updip dolomite thickness decreases just northeast of trend, then
increases to approximately 100 feet in Palm Beach County.





REPORT OF INVESTIGATION NO. 89


replace the names "Upper Anhydrite" or "Upper Massive Anhydrite"
The "Upper Anhydrite" is an impervious bed directly overlying the Sun-
niland Formation. The Lake Trafford Formation consists of this "cap
rock" and non-porous, gray limestones and anhydrite beds. In the type
well (P-222) the formation is 134-feet thick and has 38 feet of anhydrite.
On the producing trend the Sunniland Formation thickens with a result-
ant thinning of the Lake Trafford Formation. In the deeper part of the
basin the formation thickens and is predominantly anhydrite. Because
the Sunniland and Lake Trafford formations closely resemble each


Figure 10. Bouguer anomaly map of south Florida. Note minimum grav-
ity anomalies from Lee to Dade counties. Production is associated with
the two northernmost anomalies. Modified from Oglesby et al., 1973.





BUREAU OF GEOLOGY


other southwest of the producing trend, there is some question as to
the placing of the contact between the formations. Updip of the pro-
ducing trend the anhydrite content of the formation decreases rapidly.
The entire section of the type well was cored. Portions of this core are
available for study at the Florida Bureau of Geology.
GRAVITY
Three pronounced minimum gravity anomalies (figure 10) aligned in a
northwest-southeast direction from Lee County to Dade County can be
identified. The fields found to date are on or near the two northernmost
anomalies. The drilling location for the discovery well of the Sunniland
was drilled in the saddle between the two northernmost gravity minima,
which are located in Lee and Collier counties, respectively. The dis-
covery well, Gulf Coast Realties Corporation No. 1, was drilled on a dip
reversal at the top of the Ocala Group found by core drilling. This dip
reversal was later found to be the result of a large sinkhole in the Ocala
Group caused by the collapse of a cavern in the underlying Lake City
Limestone, and the structure present in the Lower Cretaceous was
unrelated to that found at the top of the Upper Eocene Ocala Group.
Oglesby (1966) believed that these negative gravity anomalies were
due to rhyolite of Late Triassic or Early Jurassic age, which might have
produced subtle topographic highs during the Early Cretaceous, thus
providing a favorable environment for the development of porous zones
in the Sunniland Formation. Because anhydrite has a high density,
excessive amounts of anhydrite may be the cause of gravity highs in
south Florida. This should be taken into account in any evaluation of the
basin, either onshore or offshore.
Rhyolite porphyry from the Bass Enterprises Collier Company 12-2
well (P-778), Sec. 12, T52S, R27E in Collier County, was dated by the
rubidium/strontium method (Denison, 1978). Cuttings taken at 18,650
feet were found to be 189 ( 5) million years old. This well lies slightly
southwest of the two most northern gravity minima and tends to con-
firm Oglesby's interpretation of rhyolite highs which are probably of
Late Triassic-Early Jurassic age (Barnett, 1975; Denison, 1978).

GEOCHEMICAL ANALYSES
Sunniland Formation
The entire Sunniland section exhibits a strong predominance of oil-
prone amorphous-sapropel type kerogen. The updip wells exhibit a
much greater abundance of recognizable algal components than the
downdip wells. This is attributed to the depositional environment of the
back-reef lagoonal facies, where large algal populations are charac-
teristic. The sediments downdip of the reef trend are marine in orgin, as
indicated by the predominance of the amorphous-sapropel type
kerogen, but they do not exhibit an abundance of algal components.
The thermal maturity of the Sunniland Formation grades from
moderately immature in the Humble Oil No. 1 Tucson Corporation Well






REPORT OF INVESTIGATION NO. 89 15

(Permit 47) to moderately mature in the downdip Humble Oil No. 1 Col-
lier Corporation Well (Permit 130). The thermal maturity Increases gradu-
ally with depth and, in general, appears to be approaching the levels at
which considerable quantities of liquid hydrocarbons can be generated
from amorphous-sapropel type kerogen. The fact that oil is currently
being produced from nearby fields supports this conclusion.
In general, the hydrocarbon generating potential of the Sunniland
Formation grades from poor in the updip wells to very good to excellent
in the fore-reef downdip wells. Cross sections depicting the regional






o oo



SO\O oo. S







S0o T O
00 0 oa



2 c o
I1 D 6W 0= 0



W, 1,

2 0


(o '- M
L0 02 -------- \----





oe Lt
0.-o





16 BUREAU OF GEOLOGY

distribution of total organic carbon, Cis+ solvent extractable bitumen,
Ci + total hydrocarbon, show the gradation in hydrocarbon generating
potential (figures 11, 12,13, respectively).
The total organic carbon content (figure 11) in the sediments
increases with depth, and indicates that the fore-reef sediments are
richer and more capable of producing oil. Although the back-reef sedi-
ments do contain a predominance of amorphous-sapropel (algal) type
kerogen, the total organic carbon contents are too low to enable the
generation of producible quantities of liquid or gaseous hydrocarbons.


10

X \O' 0Su


0 0 L
W \ X 8|




0 \ :: co
1W -
Ce z 0 -i








cooo





.o 0 0 00
\ C1Cct o
\u 133 + B






REPORT OF INVESTIGATION NO. 89 17

A study made by Palacas (1978) of 134 core samples showed that the
Comanchean Series carbonates have an average carbon content of
0.41 percent. This was in contrast with the average values of the
Coahuilan Series, Gulfian Series, and Lower Paleocene carbonates,
which had average values of 0.28 percent, 0.18 percent and 0.20 percent,
respectively.
The values for the Comanchean Series carbonates are nearly twice as
high in organic carbon as the average (0.24 percent) of worldwide car-
bonates (Palacas, 1978).





1 az 1 .-
0 \ M
W Zw




\ \ Too r0


o000 .c
OCL





:a) ._


4. (D












0_
( o->



i0 00 5 0 ,

: Z o

LO Ca az
0i~

i7L Cd





BUREAU OF GEOLOGY


Fredericksburg Stage
A conventional core taken from Fredericksburg Stage sediments in
the Humble Oil No. 1, J. A. Curry Well (Permit 222) was submitted to
Geochem Laboratories for geochemical tests. The tests indicated that
the Fredericksburg rocks at this location have an immature, good to
very good oil and associated "wet" gas source potential. This section is
predominantly the oil-prone amorphous-sapropel type kerogen.
The immature character assigned to these sediments is based on the
greenish, light-yellow to yellow-orange coloration of the recognizable
sediments. This coloration is consistent with an immature Maturation
Index 1 + to 2- (figure 14).
The good to very good oil and associated "wet" gas source character
assigned to the Fredericksburg Stage carbonates in the local area of the
Humble Oil No. 1, J. A. Currey Well (Permit 222) is based on: good total
organic carbon contents (mean 0.41 percent) (figure 11); the very good
C,, + solvent extractable bitumen content (mean 1,665 ppm) (figure 12);
the very good to excellent total extractable hydrocarbon content (mean
891 ppm) (figure 13); and on the previously mentioned predominance of
the oil-prone amorphous-sapropel type kerogen.
It should be noted that the source potential of the Fredericksburg


GEOTHERMAL DIAGENETIC CRITERIA
(GEOCHEM LABORATORIES, INC.)


Figure 14. Correlation chart used to determine hydrocarbon source
quality. Values projected along a horizontal line.





REPORT OF INVESTIGATION NO. 89


Stage carbonates decreases near the bottom of the section. The
samples from 9,634 feet to 9,936 feet were considerably richer than
those from 9,966 to 10,038 feet.
The well was drill-stem tested by Humble Oil Company in the 9,863-
9,914 foot Interval for 20 hours and five minutes. Recovery with a 14-inch
choke opening was 15 feet of oil and 27 feet of watercut mud. The
results of this drill-stem test are on file at the Florida Bureau of Geology.
Geochemical evidence is not encouraging because of the immaturity
of the hydrocarbons in the Fredericksburg Stage. But the results of the
drill stem test and other shows of petroleum (Winston, 1971) are mildly
encouraging. A close examination of samples should be made while
drilling through this unit.
CONCLUSIONS
Geological investigations indicate that the permeability of the Sunni-
land Formation, downdip of the reefal sediments, is too low for hydro-
carbon migration. Therefore, production can be expected to occur
where the porous units are juxtaposed with the organically rich, dark
micrites. This appears to have occurred along the reef trend where the
extensive rudistid beds separate the fore-reef sediments from the back-
reef sediments. Geochemical analyses confirm that the dark micrite is
the source of the oil accumulations in the rudistic beds, and that the
source potential of the dark micrite faces increases downdip. There-
fore, new discoveries could be expected in the downdip micrite faces if
zones of suitable porosity are found.
To date, exploration activity in the South Florida Basin is low com-
pared with other producing basins. New exploration techniques and a
better understanding of the regional geology should increase the drill-
ing activity. Hopefully, this will lead to the discovery of new oil fields.





BUREAU OF GEOLOGY


SELECTED REFERENCES
Applin, Paul L and Applin, Ester R., 1965, The Comanche Series and
Associated Rocks In the Subsurface in Central and South Florida.
U. S. Geological Survey Professional Paper 447.
Bamett, Richard S., 1975, Basement Structure of Florida and Its Tec-
tonic Implications. Gulf Coast Association of Geologic Societies
Transactions, Vol. 25, pp. 122-142.
Bathurst, Robin G. C., 1976, Carbonate Sediments and Their Diagenesis.
Elsevier Scientific Publishing Company, Amsterdam, Oxford, New
York.
Denison, Rodger E., 1978, Petrography and Isotopic Age, Igneous
Rocks, Bass No. 1 Pumpkin Bay, Collier County, Florida. Open File,
Florida Department of Natural Resources, Bureau of Geology.
Means, J. A., 1977, Southern Florida Needs Another Look. Oil and Gas
Journal, Vol. 75, No. 5, pp. 212-223.
Oglesby, W. R., 1966, Folio of South Florida Basin, A Preliminary Study.
Map Series No. 19, Florida Department of Natural Resources,
Bureau of Geology.
Oglesby, W. R., Ball, M. M., and Chaki, Susan, 1973, Bouguer Anomaly
Map of the Florida Peninsula and Adjoining Continental Shelves.
Map Series No. 57, Florida Department of Natural Resources,
Bureau of Geology.
Palacas, James G., 1978, Distribution of Organic Carbon and Petroleum
Source Rock Potential of Cretaceous and Lower Tertiary Carbon-
ates, South Florida Basin, Preliminary Results. U. S. Geological
Survey, Open-File Report 78-140.
Pontigo, F. A., Applegate, A. V., Rooke, J. H., and Brown, Stephen W.,
1979, South Florida's Sunniland Oil Potential. Oil and Gas Journal,
Vol. 77, No. 31, pp. 226-232.
Winston, George 0., 1971, The Dollar Bay Formation of Lower Cre-
taceous (Fredericksburg) Age in South Florida, Its Stratigraphy and
Petroleum Possibilities. Special Publication No. 15, Florida Depart-
ment of Natural Resources, Bureau of Geology.






REPORT OF INVESTIGATION NO. 89


APPENDICES
Methods of Investigation





BUREAU OF GEOLOGY


APPENDIX A
GEOLOGICAL
Cores and ditch samples were studied under a binocular microscope
for lithology, apparent porosity, accessory minerals, microstructures,
and, where possible, fossil identification.
Wire-line logs were used to construct structural and isopachous
maps, and to aid in determining porosity in the area.
Three Sunniland interval maps were prepared to help delineate the
high-energy reef trend which lies between the chalky, low-energy back-
reef shelf beds and the deeper water, dark micrites of the fore-reef
facies. These maps are:
Figure 7. Dark carbonate map.
Figure 8. Modified isoporosity map.
Figure 9. Dolomite thickness.
A modified isoporosity map (figure 8) was prepared for the Sunniland
Formation by visually estimating the porosity during microscopic
examination of the conventional core material. A technique used in
Winston's (1971) study of the Dollar Bay Formation from the Lower Cre-
taceous (Fredericksburg Stage) in south Florida was used in the prep-
aration of the isoporosity map. Porosity was estimated in increments of
5 percent, 10 percent and 15 percent or higher. Porosity estimated at
5 percent was divided by four; porosity of 10 percent was divided by 2;
and porosity of 15 percent or higher was divided by one. By this method,
porosities of varying percentages were adjusted for realistic mapping of
porosity trends.
A Bouguer anomaly map with a four (4) milligal contour inteval was
also constructed, using some new data and data from work originally
done by Oglesby, Ball, and Chaki (1973).






REPORT OF INVESTIGATION NO. 89


APPENDIX B
by
Stephen Brown

BRIEF DESCRIPTION OF ORGANIC GEOCHEMICAL ANALYSES
CARRIED OUT BY GEOCHEM LABS, INC.


C1-C7 HYDROCARBON
The C,-C7 hydrocarbon content and composition of sediments
reflects source type, source quality and thermal maturity.
The Ci-C7 hydrocarbon content of well cuttings is determined by ana-
lyzing both a sample of the cuttings and the air space at the top of the
can. The results of the two analyses are summed to give an inventory of
the Ci-C7 hydrocarbon content of the well cuttings prior to any losses
from the cuttings during the lapsed time period between collection at
the well site and laboratory analysis.
The air space CI-C7 hydrocarbon analysis involves taking a measured
volume of the air space gas out of the can with a syringe and injecting
same into a gas chromatograph. GeoChem uses a Varian Aerograph
Model 1400 instrument equipped with a Porapec Q column. The gas
sample is taken through the column by a carrier gas and before reaching
the detector is separated into its various C, (methane), C2 (ethane), C3
(propane), iC4 isobutanee), nC4 (normal butane), and Cs, CO, C, hydro-
carbon components.
This particular analysis gives a complete separation of the C1-C4 gas-
range hydrocarbons and a partial separation of the Cs-C7 gasoline-range
hydrocarbons. (A detailed C4-C, analysis, to be discussed later, involv-
ing a capillary column, effects a complete separation of this molecular
range into its several individual molecular species.)
The electrical response of the various hydrocarbons as they reach the
detector is recorded on a paper strip chart as a peak. This response is
simultaneously fed to an integrator which computes the area of each
peak. The concentration of C,-C? hydrocarbons in the air space,
expressed as volumes of gas per million volumes of cuttings, is deter-
mined by a calculation involving the volume of cuttings, volume of air
space in the can, volume of sample injected, volume of standard gas
sample used in the calibration, calibration factor for Ci, C2, C3, etc.,
determined by gc analysis of a standard gas sample, and the gc peak
response.
The CI-C7 hydrocarbon content of the cuttings is determined by
degasification of a measured volume of cuttings (in a medium of a
measured volume of water) in a closed blender, sampling of the air
space at the top of the blender, and injection of a measured volume of
gas into the gas chromatograph.
The C0-C7 hydrocarbon data from the air space and cuttings gas





BUREAU OF GEOLOGY


analyses are summed to give a "restored" Ci-C7 hydrocarbon content of
the cuttings.
SAMPLE WASHING AND HAND-PICKING OF UNCAVED
LITHOLOGY SAMPLES
The cuttings samples are washed to remove all drilling mud from the
cuttings. Care is taken in the washing procedure not to remove any soft
clays, claystones, etc., and any loose fine sand and silt. The washed cut-
tings are usually kept under water cover until picked, to prevent loss of
any gasoline-range hydrocarbons. Using the Ci-CG hydrocarbon data
profile and the electrical well log supplied to us and our visual examina-
tion of the cuttings material under the binocular microscope, we care-
fully hand-pick and describe a suite of uncaved lithologies represent-
ative of the various stratigraphic zones penetrated by the well. The
lithological data is used to compile a gross litho percentage log which is
shown on all Figures. The 2-4 gram picked lithology samples are stored
underwater in small glass vials in those instances where we wish to run
detailed C,-C? hydrocarbon analyses. This sample set is used not only
for the C0-C, hydrocarbon analysis, but also for the visual kerogen and
total organic carbon analyses. All remaining cuttings material is dried
and packaged in labelled plastic bags for possible Cis + soxhlet extrac-
tion and/or eventual return to the client. Sample material from this study
will be retained at GeoChem until advised of disposition.
DETAILED C4-CT HYDROCARBON
The C4-C7 gasoline-range hydrocarbon content of sediments reflects
source quality, thermal maturation and organic faces. Compositional
data can be used in crude oil-parent rock correlation work.
The C4-C? hydrocarbon content and detailed molecular composition
of hydrocarbon, in hand-picked lithologies, is determined by a gc
analysis of the light hydrocarbon extracted from 1-2 gram cuttings
samples macerated in a microblender. A measured volume of sample is
placed in a sealed microblender along with a measured volume of hot
water. The rock sample is pulverized by the blades of the blender. A sam-
ple of the liberated light hydrocarbons which collect In the air space at
the top of the blender is injected into our Varian Aerograph 1400 gc unit
which is equipped with a capillary column. Data recording, com-
putations, etc., are comparable to those used for the C,-C7 analysis
discussed previously in this report. Hydrocarbon concentration is
expressed as volume gas per million volumes of cuttings.

ORGANIC CARBON
The total organic carbon content of a rock is a measure of its total
organic richness. This data is used, in conjunction with visual kerogen
and C,-C,, C4-CT and Cis + hydrocarbon content of a rock, to indicate the
hydrocarbon source quality of rocks.
The procedure for determining the total organic carbon content of a






REPORT OF INVESTIGATION NO. 89


rock involves drying the sample, grinding to a powder, weighing out
0.2729 gram sample into a crucible, acidizing with hot and cold hydro-
chloric acid to remove calcium and magnesium carbonate, and carbon
analysis by combustion in a Leco carbon analyzer.
We run several blank crucibles, standards (iron rings of known carbon
content) and duplicate rock samples in this analysis at no additional
charge to the client for the purposes of data quality control.
Cis+ SOXHLET EXTRACTION, DEASPHALTENING AND
CHROMATOGRAPHIC SEPARATION
The amount and composition of the organic matter which can be
solvent-extracted from a rock reflects source quality and source type.
C0/C12 carbon isotopic, high mass spectrometric and gc analyses of the
paraffin-naphthene and aromatic hydrocarbon fractions of the soluble
extract gives data which is used in crude oil-parent rock correlations.
This analysis involves grinding of a dry rock sample to a powder and
removal of the soluble organic matter by soxhlet extraction using a
co-distilled toluene-methanol azeotrope solvent. Where the amount of
available sample material permits, we like to use at least 100 grams of
rock for this analysis.
The extracted bitumen is separated into an asphaltene (ASPH) and a
pentane soluble fraction by normal pentane precipitation. The pentane
soluble components are separated into a C s + paraffin-naphthene (P-N)
hydrocarbon, C,5+ aromatic hydrocarbon (AROM) and Cis+ nitrogen-
sulfur-oxygen containing fraction (NSO) by adsorption chromatography
on a silica gel-alumina column using pentane, toluene and toluene-
methanol azeotrope eluants.
GC ANALYSIS OF Cis+ PARAFFIN-NAPHTHENE (P-N)
HYDROCARBONS
The content and molecular composition of the heavy Cis+ paraffin-
naphthene (P-N) hydrocarbons of rocks, as determined by gc analysis,
reflects source quality, source type and degree of thermal maturation.
In this analysis, we subject a very small fraction of the total amount of
the P-N fraction extracted from a rock sample to gc analysis. The gas
chromatograph is a Varian Aerograph Model 1400 equipped with a solid
rod injection system and a eutectic column.
The calculated C.P.I. (carbon preference index) values for the normal
paraffin data is defined as the mean of two ratios which are determined
by dividing the sum of concentrations of odd-carbon numbered
n-paraffins by the sum of even-carbon numbered n-paraffins. The C.P.
Indices A and B were obtained by the formulas:
C21 + C23 + C25+ C27 C21 + C23 + C25 + C27
C.P. Index A = C22 + C24 + C2 + C28 20 + C22 + C24 + C2





BUREAU OF GEOLOGY


C25+ C27 + C29+ C C25+ C2+ C29+ C31
C.P. Index B = C2 + C2 + C3o + C32 C24+ C2 + C28 + C30
2
VISUAL KEROGEN
A visual study of kerogen, the insoluble organic matter in rocks, can
indicate the relative abundance, size, and state of preservation of the
various recognizable kerogen types and thereby indicate the hydro-
cafbon source character of a rock. The color of the kerogen can be used
to indicate the state of thermal maturity of the sediments (i.e. their time-
temperature history). Thermal maturation plays an important role in the
generation of hydrocarbons from organic matter, and also affects the
composition of reservoired hydrocarbons.
Our procedure for visual kerogen slide preparation involves isolation
of the organic matter of a rock by removal of the rock material with
hydrochloric and hydrofluoric acid treatment and heavy liquid separa-
tion. This procedure is comparable to that used by the palynologist
except it does not include an oxidation stage. (The oxidation treatment
is deleted from our procedure because it removes a great deal of
kerogen and blanches any remaining kerogen to an extent whereby it is
useless for our kerogen color observations.) The kerogen residue is
mounted on a glass slide and is examined visually under a high power
microscope.
VITRINITE REFLECTANCE
Measurement of the reflectivity of vitrinite particles (% Ro) present in
the kerogen isolated from sedimentary rocks provides a method of
determining the state of maturation, and the diagnetic (time-tempera-
ture) history of the organic matter present in the sediments.
The kerogen, obtained from a 25 gram aliquot of crushed rock by the
acid procedure previously discussed, is dried and embedded in a Bio-
plastic plug. The surface of the plug is polished using 0.05 micron
alumina and the reflectivity determined under oil using a Ziess high
resolution microscope. A minimum of 40 values are required to ade-
quately determine the Maturation Rank.
FLUORESCENCE SPECTROPHOTOMETRIC ANALYSIS
Fluorescence spectrophotometry can be used to characterize and
fingerprint crude oils, establish crude oil-source rock relationships, and
to measure the hydrocarbon source potential of fine-grained sediments.
A one (1) microliter aliquot of either (I) a crude oil or (ii) the solvent
extractable rock bitumen, is passed through an alumina/silica gel micro
column and the Cto+ aromatic hydrocarbons isolated. The aromatic
hydrocarbon is diluted and the emission and excitation spectra deter-
mined at 240 nm and 420 nm using a Perkin-Elmer Model 512 Double
Beam Fluorescence Spectrophotometer.






REPORT OF INVESTIGATION NO. 89 27












APPENDIX C

RESULTS OF ANALYSES
(GeoChem Laboratories)
Summary of Total Organic Carbon and Visual Kerogen Analyses
Table Page
1 Summary of total organic carbon and visual kerogen analyses ............ 28
2 Summary of Cis+ Soxhlet extraction, deasphaltening and
liquid chromatography .............. ....... .............. 30
3 Saturate hydrocarbon analyses .............. ................ 33



Summary of Individual Well Organic Analyses
Figure
15 Summary of organic analyses for Humble 01 No. 1, Tuscon Corp.
(Perm it 47) ......... ......... ............................. 35
16 Summary of organic analyses for Oleum Corp., Ted Weiner Unit 12-4
(Permit662) ............................................... 36
17 Summary of organic analyses for Tribal-Exxon Gulf Coast Realty Unit 2-4
(Permit 563) ................................................. 37
18 Summary of organic analyses for Humble Oil No. 1, J. A. Curry
(Permit 222) ............................................... 38
19 Summary of organic analyses for Tribal Oil Co., Collier Corp. Unit 26-4
(Permit 775) ................................................ 39
20 Summary of organic analyses for Humble Oil No. 1, Collier Corp.
(Permit 130) ................................................. 40







BUREAU OF GEOLOGY


Table 1.
Summary of Total Organic Carbon and Visual Kerogen Analyses.
See Figure 14 for correlation chart.


VISUAL KEROGEN


Depth Interval


Organic
Carbon
(% of Rock)


TYPE
Am = Amorphous
H = Herbaceous
W = Woody
C = Coaly


ALTERATION
1 = Immature to
5= metamorphosed


0.25
0.69
0.79
0.15
0.18


0.27
0.25
0.16
0.22
0.29; 0.29R
0.20


0.16
0.61
0.23
0.24


0.36
0.12
0.17
0.42


Humble Oil
No. 1 J. A. Curry
Collier County
Sec. 26-49S.28E

Am,H,C
Am,H,C
Am,C(H)
Am,C(H)
Humble Oil
No. 1 Tuscon Corp.
Palm Beach County
Sec. 35-43S.42E


Am,C(H)
Am,C(H)
Am,C(H)
Am,C(H)
Am,C(H)


Oleum Corp.
Ted Welner Unit 12.4
Hendry County
Sec. 12-48S-32E


Am,C(W)
Am,C,H-W
Am,C,H-W
Tribal-Exxon
Gulfcoast Realty 2.4
Collier County
Sec. 2-49S-30E
Am,C,H(W)
Am,C,H(W)
Am,C,H(W)
Am,C,H(W)


to 2-
to2-
to2-
to2-


9634- 9734
9740- 9839
9839- 9936
9966-10038
10048-10193


10516-10596
10590-10619
10619-10659
10659-10699
10699-10730
10730-10744


11419-11440
11440-11460
11460-11560
11560


11544-11625
11625-11685
11685-11760
11760-11817


to 2-
to2-
to2-
to 2-
to 2-


to 2-
to2-
to2-




to2-
to2-
to 2-
to 2-







REPORT OF INVESTIGATION NO. 89


Table 1 (continued).
Summary of Total Organic Carbon and Visual Kerogen Analyses.
See Figure 14 for correlation chart.



VISUAL KEROGEN


Depth Interval


Organic
Carbon
(% of Rock)


TYPE
Am = Amorphous
H = Herbaceous
W = Woody
C = Coaly


ALTERATION
1 = immature to
5 = metamorphosed


Tribal Oil Corp.
Collier Corp. 26-4
Collier County
Sec. 26.49S-28E
Am,C

Am,H-W-C
Humble Oil
No. 1 Collier Corp.
Collier County
Sec. 27-50S-26E
H,Am-C
Am-H,W,C


0.45; 0.53R Am,H-C


0.71
0.21
0.59


11992-12012
12012-12020
12021-12080


12360-12372
12380-12396
12396-12412


2.52
1.48


1+ to2-

2- to2


2 to2+
2- to 2
2- to2













Table 2. Summary of Ci + Soxhlet extraction, deasphaltening and liquid chromatography for
Humble No. 1, J. A. Curry well, Permit 222.

Table 2A. Weights of extracts and chromatographic fractions.
Well Weight of Total Precipitated N-C5 Paraffins- Eluted Noneluted
Interval Rock Extd. Extract Asphaltenes Soluble Sulfur Naphthenes Aromatics NSO'S NSO'S
(feet) (grams) (grams) (grams) (grams) (grams) (grams) (grams) (grams) (grams)
9740- 9839 75.0 0.1896 0.0188 0.1708 N.D. 0.0242 0.0870 0.0565 0.0031
9966-10038 70.0 0.0492 0.0088 0.0404 N.D. 0.0065 0.0145 0.0185 0.0009
10516-10596 100.0 0.0352 0.0151 0.0201 N.D. 0.0062 0.0062 0.0069 0.0008
11440-11460 65.0 0.0474 0.0117 0.0357 N.D. 0.0118 0.0130 0.0108 0.0001
11460-11560 85.0 0.0749 0.0427 0.0322 N.D. 0.0138 0.0112 0.0072 0.0000
11544-11625 75.0 0.1063 0.0362 0.0701 N.D. 0.0282 0.0278 0.0141 0.0000
11992-12012 44.0 0.1125 0.0092 0.1033 N.D. 0.0389 0.0521 0.0123 0.0000
12021-12080 30.0 0.0722 0.0250 0.0472 N.D. 0.0131 0.0211 0.0126 0.0004
12360-12365 46.5 0.3767 0.1355 0.2412 N.D. 0.0623 0.1288 0.0470 0.0031
12380-12384 100.0 0.4457 0.1381 0.3076 N.D. 0.0667 0.1669 0.0551 0.0189
12396-12401 100.0 0.1272 0.0620 0.0652 N.D. 0.0206 0.0336 0.0099 0.0011


81









C


0

O
0
m
0
S
o















Table 2B. Concentration of extracted materials in rock. All ppm values are expressed on a weight/weight basis.


Hydrocarbons


Total
Extract
(ppm)


Paraffin-
Naphthene
(ppm)


Aromatic
(ppm)


Total
(ppm)


Nonhydrocarbons


Preciptd.
Sulfur Asphaltene
(ppm) (ppm)


Eluted
NSO'S
(ppm)


Noneluted
NSO'S
(ppm)


Total
(ppm)


9740- 9839 2528 323 1160 1483 251 753 41 1045
9966-10038 703 93 207 300 126 264 13 403
10516-10596 352 62 62 124 151 69 8 228
11440-11460 729 182 200 382 180 166 2 348
11460-11560 881 162 132 294 502 85 0 587
11544-11625 1417 376 371 747 483 188 0 671
11992-12012 2557 884 1184 2068 209 280 0 489
12021-12080 2407 437 703 1140 833 420 13 1267
12360-12365 8101 1340 2770 4110 2914 1011 67 3991
12380-12384 4457 667 1669 2336 1381 551 189 2121
12396-12401 1272 206 336 542 620 99 11 730


Well
Interval
(feet)
















Table 2C. Composition of extracts.


Hydrocarbons


Paraffin-
Naphthene


Aromatic


Nonhydrocarbons


Eluted
Sulfur NSO'S


Noneluted
NSO'S


Preciptd.
Asphaltene


HC'S


(feet) % % PNIArom % % % % AsphlNSO % HCINon HC
9740- 9839 12.8 45.9 0.28 29.8 1.6 9.9 0.32 58.6 1.42
9966-10038 13.2 29.5 0.45 37.6 1.8 17.9 0.45 42.7 0.74
10516-10596 17.6 17.6 1.00 19.6 2.3 42.9 1.96 35.2 0.54
11440-11460 24.9 27.4 0.91 22.8 0.2 24.7 1.07 52.3 1.10
11460-11560 18.4 15.0 1.23 9.6 0.0 57.0 5.93 33.4 0.50
11544-11625 26.5 26.2 1.01 13.3 0.0 34.1 2.57 52.7 1.11
11992-12012 34.6 46.3 0.75 10.9 0.0 8.2 0.75 80.9 4.23
12021-12080 18.1 29.2 0.62 17.5 0.6 34.6 1.92 47.4 0.90
12360-12365 16.5 34.2 0.48 12.5 0.8 36.0 2.70 50.7 1.03
12380-12384 15.0 37.4 0.40 12.4 4.2 31.0 1.87 52.4 1.10
12396-12401 16.2 26.4 0.61 7.8 0.9 48.7 5.64 42.6 0.74


C
0
on


Ir
0


Well
Interval















Table 3. Saturate hydrocarbon analyses for Humble No. 1, J. A. Curry,
Permit 222.

Table 3A. Summary of paraffin-naphthene distribution.
Well


Interval %


% C-P C-P


(feet) Paraffin Isoprenoid Naphthene Index A Index B ip19/ip20
9740- 9839 17.5 1.2 81.4 1.00 0.76
9966-10038 12.9 0.4 86.7 1.00 0.46
10516-10596 12.2 0.5 87.3 1.09 0.91
11440-11460 14.2 0.4 85.4 0.94 0.99 0.69
11460-11560 8.5 0.4 91.1 1.04 0.57
11544-11625 11.3 0.6 88.1 1.07 1.21 0.67
11992-12012 11.3 1.0 87.7 1.07 1.14 0.60
12021-12080 10.9 0.6 88.6 1.04 1.13 0.69
12360-12365 15.1 2.2 82.6 1.05 1.01 0.68
12380-12384 19.2 1.9 78.9 1.04 1.01 0.54
12396-12401 12.8 0.5 86.7 1.00 0.97 0.32

















Table 3B. Normalized paraffin distribution.


Well
Interval % % %
(feet) nC15 nC16 nC17
9740- 9839 1.3 1.9 3.0
9966-10038 0.3 0.6 1.1
10516-10596 1.3 1.5 2.0
11440-11460 0.9 0.8 1.7
11460-11560 1.2 1.2 2.5
11544-11625 1.1 1.5 2.9
11992-12012 1.2 1.9 5.2
12021-12080 1.0 1.2 2.6
12360-12365 5.5 7.5 9.4
12380-12384 5.7 7.6 9.2
12396-12401 0.3 1.0 2.4


% %
Ipl9 nC18
2.7 5.5
0.8 3.2
1.8 4.2
1.2 2.9
1.6 5.2
2.1 5.6
3.0 10.0
2.0 4.9
5.1 10.4
3.2 10.5
0.9 4.9


% % % % % % % %
ip20 nC19 nC20 nC21 nC22 nC23 nC24 nC25
3.6 8.1 10.8 12.2 13.7 12.0 9.2 6.0
1.8 6.4 10.6 13.8 17.9 16.211.3 7.0
2.0 7.7 11.4 15.9 19.0 16.2 8.7 4.4
1.7 6.5 9.5 11.5 15.2 14.011.9 8.2
2.8 7.8 9.0 11.0 14.9 15.812.0 7.6
3.2 9.0 11.4 12.7 13.6 12.2 8.5 6.4
5.1 12.7 12.6 11.5 10.5 8.8 5.8 4.4
2.9 7.5 9.4 11.4 13.8 14.1 10.6 7.1
7.6 9.7 9.0 8.3 7.7 6.3 4.2 2.7
5.8 9.9 9.2 8.7 8.3 6.9 4.7 3.2
2.8 6.8 8.8 10.9 13.0 12.3 9.6 6.7


%
nC26
4.5
4.3
1.8
6.6
3.7
4.0
2.8
4.5
2.1
2.7
6.7


% % % % %
nC27 nC28 nC29 nC30 nC31
2.7 1.6 0.9 0.2 0.1
2.0 1.4 0.6 0.4 0.1
1.1 0.6 0.2 0.0 0.0
3.3 2.4 1.2 0.3 0.1
2.0 0.8 0.4 0.2 0.2
3.0 1.6 0.7 0.3 0.2
1.9 1.3 0.6 0.4 0.3
3.0 2.0 1.0 0.4 0.3
2.0 1.4 0.4 0.3 0.2
2.1 1.3 0.4 0.3 0.3
5.4 3.2 1.6 1.4 1.0


% % 0 %
nC32 nC33 nC34 nC35
0.0 0.0 0.0 0.0
0,0 0.0 0.0 0.0
0.0 0.0 0.0 0.0
0.1 0.0 0.0 0.0
0.0 0.0 0.0 0.0
0.1 0.0 0.0 0.0
0.1 0.0 0.0 0.0
0.2 0.0 0.0 0.0
0.1 0.0 0.0 0.0
0.2 0.0 0.0 0.0
0.5 0.1 0.0 0.0








REPORT OF INVESTIGATION NO. 89


















SUMMARY OF ORGANIC ANALYSES

SOURCE CHARACTER


a 6
PN ASPH
C15. EXTRACTION DATA AROM NSO
0 soD50 1o I t i



1 .


VISUAL KEROGEN
MATURATION TYPE ORGANIC MATTER
INDEX





K Am(AI);--,C(H)


ORGANIC
CARBON
CONTENT
10500 %







10600:







10700







10800


KEROGEN KEY
PR OOMUNTt RY;R
Al ALGAL
Am AMORPHOUS- SAPROPEL
H HERBACEOUS SPORE CUTICL
W WOOOY
C COALY
U UNIDENTIFIED MATERIAL
Hm+: OEGRADED HERBACEOUS
RELICT AMORPHOUS


Figure 15. Summaryof organic analyses for Humble Oil No. 1,
Tuscon Corp., Permit 47.


0 So0 1000 1 2 3 4 1 3 4
* FW ML I 04 AiIWM.ST B1T IUII
P-N PARAFFIN-NAPHTHENE HC
AOM. AROMATIC HYDROCARBON
I ELEMENTAL FREE SULFUR
P-N AROM S NSO ASPH NSO NITROGEN-SULFUR
OXYGEN COMPOUND
MASPH. ASPHALTENE
\\ \ NO DATA
nC5 SOLUBLE FRACTION ASPH
AFTER GEOCHEM


0 0.S 1ID%
Ma M.Iflu
E33SS01012I


LITHO % LOG
0 so 100%

a a w


SO 100

CLAY
E3 51a
SSAND

SDOLOMITR







BUREAU OF GEOLOGY


















SUMMARY OF ORGANIC ANALYSES

SOURCE CHARACTER


* A


CIS5 EXTRACTION DATA


VISUAL KEROGEN
MATURATION TYPE ORGANIC MATTER
INDEX


L I rT I I J Am(AI); H C(W)




533 P Am(AI); C H-W



























0 I3S 1% a o 1000 0 1 3 4 a 11 I4
agS Srl. ,*,>,...Or... KEROGEN KEY
NP-N PARAFl'N-IP VHTHENE v4;
Cn/////:::~:::: AMOMARORMATIC HYDAOCARRO WIg*Q5-ONE
ELEMENTAL FREE SULFUR
P-N AROM S NSO ASMPH NITRAON-SULtUR l s ALGAL
OXYGN COUPOMOS I AMORPHOUS- SA*PROPE.L
__........ _..... -*m>PH. ASPHAl.TENE HERBACEOUS SPORE CUTICLE
*\\\\\ \\\\\\\\\\\\\\\\\\ NO ATA WOOOY
nC5 SOLULE FRACTION ASPH U uN IDlEVcE MATERIAL
AFTER GEOCHEM n E o O HEMACEcOU
AFTER GEOCHEM + aRELICT AMORPHOUS


Figure 16. Summary of organic analyses for Oleum Corp.,
Ted Weiner Unit 12-4, Permit 662.


ORGANIC
CARBON
CONTENT


LITHC % LG
i3 00o


30 *a

M ,

E3 -
In w
BO !X~uuur









REPORT OF INVESTIGATION NO. 89






















SUMMARY OF ORGANIC ANALYSES


SOURCE CHARACTER


ORGANIC
CARBON
CONTENT


C15I EXTRACTION DATA
0 Soo loo0






371 ea8 483


0 0.s 10% o 5s00 1oo



P-N AROM S NSO ASPH


nCS SOLUBLE FRACTION ASPH


* A
P-N ASPH
AROM NSO
0 I 4 3


VISUAL KIROGEN

MATURATION TYPE ORGANIC MATTER
INDEX
Am (A) i (W)







* Am (AI);C H (W)


KEROGEN KEY

Al ALGAL
Am AMORPHOUS- SAPROPEL
N HERSACEOUS SPORE CUTICLE
W WOODY
C COALYY
U UNIONTIFEll MATERIAL
H+ : DEGRADED HERIACEOUS
RELICT AMORPHOUS


Figure 17. Summary of organic analyses for Tribal-Exxon,

Gulf Coast Realty Unit 2-4, Permit 563.


LITHO %LOG
so I O%
.. I I ... .I


L LINE

EM SOIL
unt l


O 1 2 3 I1 3 4

P-N PARAFFIN-NAPHTHENE HC
AROM. AROMATIC HYDROCARBON
a ELEMENTAL FREE SULFUR
NS0 NITROGEN-SULFUR
OXYGEN COMPOUNDS
ASPH0 ASPHALTENE
) NO DATA


AFTER GEOCHEM







BUREAU OF GEOLOGY

















SUMMARY OF ORGANIC ANALYSES

SOURCE CHARACTER


CI*1 EXTRACTION DATA



o s0 Ic 25


I11o Ml 231


* A
P-N ASPH
AROM NSO
i 3 ,


,


> 9600-







9800.



9900-



10000



10200



10200


VISUAL KEROGEN
MATURATION TYPE ORGANIC MATTER
INDEX
i Z 3 4 3






Am ; H;C







-Am (AI); -;C(H)


KEROGEN KEY.

AI ALGAL
Am AMORPHOUS- SAPROPEL
N HERBACEOUS SPORE CUTICLE
W WOOOY
C -COALY
U UNIDENTIFIED MATERIAL
Hf: DEGRADED HERBACEOUS
SRELICT AMORPHOUS


Figure 18. Summary of organic analyses for Humble Oil No. 1,
J. A. Curry, Permit 222.


LUTHO % LG



. I




mM-^


_____________A AROMATIC YROCARON
S*ELEMENTAL FREE SULFUR
0 300 10 0 1 3 4 I 2 4


P-N AROM S NSO ASPH NITROGEN -SULF
OXYGEN COMPOUNDS
ASA ASPH UALTNE
\ v NO GATA
nc, SOLUBLE FRCTIFON ASPH
.c AFTER GEOCHEM


ORGANIC
CARBON
CONTENT
r4 %


3 1.0%
**ap-ars


a *


O mr
E3-


3O


2ze l


I









REPORT OF INVESTIGATION NO. 89





















SUMMARY OF ORGANIC ANALYSES


SOURCE CHARACTER


C15+ EXTRACTION DATA
o 4 oo looo







884 1184 280 209




437 703 433 833
WWWWM:::


VISUAL KEROGEN
P-N ASPH MATURATION TYPE ORGANIC MATTER
AROM NSO INDEX
0 i 2 3 4 3 4 5









5 a IL Am ; H; C



07 *-A I Am ;--H-W-C


0 500 1000 01 2 3 2 3
* PIM AUEI ON Aw 9wT WIGHT BUAI
P-N PARAFFIN-NAPHTHENEHC
AROM- AROMATIC HYDROCARBON
P'N AROM S NSO ASPH S -ELEMENTAL FREE SULFUR
P-N AROM S NSO ASPH NSO NITROGEN-SULFUR
OXYGEN COMPOUNDS
ASPH ASPHALTENE
~\\\\\\^^\\\\\\\\\\ ~ -NO DATA
nC5 SOLUBLE FRACTION ASPH
AFTER GEOCHEM


KEROGEN KEY
PREOOMIANT1 SEcCR.;TR42
Al ALGAL
Am AMORPHOUS- SAPROPEL
S HERBACEOUS SPORE CUTICLE
W .WOODY
C C OALY
UNIDENTIFIED MATERIAL
4+ DOEGRADEO HERBACEOUS
Sm+, RELICT AMORPHOUS


Figure 19. Summary of organic analyses for Tribal Oil Co.,

Collier Corp. Unit 26-4, Permit 775.


ORGANIC
CARBON
CONTENT


0 O.5 10%
Msl sLCt1s
COM.POSITE


LITHO %LOG
0 50 o0%
. .


SO 100

CLAY

Co3 ILT






BUREAU OF GEOLOGY


SUMMARY OF ORGANIC ANALYSES

SOURCE CHARACTER


ORGANIC
CARBON
CONTENT


VISUAL KEROOEN
A
P-N ASPH MATURATION TYPE ORGANIC MATTER
C15* EXTRACTION DATA AROM *M INDEX


H*;-; Am -C

Am-H ;W; C
Am H+-C


o0a o a 10% o Ma 000 0 1 2 i 3 1 3 4 1
3aoBmi a r ARO.AM AT-IO, WOa^,w, r KUE OGEN KEY
.W 2 HOVWLINL PFRE SULOUR A
SP-rAR NSO S A" poe Nhrro EN -SULuR .I ALGAL
OXYGEN COMPONOS A IOR U- PROPEL
N ASFI4 NSO ASPH iN ASPBN -SPORE C TICLE
0 0 NOODATA I ,WOOOV
SC, SUtE FATIoN ASPH MATERIAL
AFTER OECIEM ,, 0ORAOD HERLACXOUS
AFTER OEOCHEM E MAO"PW0U*



Rgure 20. Summary of organic analyses for Humble Oil No. 1,
Collier Corp., Permit 130.


LUTH %LOG

3 SO