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FLRD GEOLOSk ( IC SUfRiW COPYRIGHT NOTICE [year of publication as printed] Florida Geological Survey [source text] The Florida Geological Survey holds all rights to the source text of this electronic resource on behalf of the State of Florida. The Florida Geological Survey shall be considered the copyright holder for the text of this publication. Under the Statutes of the State of Florida (FS 257.05; 257.105, and 377.075), the Florida Geologic Survey (Tallahassee, FL), publisher of the Florida Geologic Survey, as a division of state government, makes its documents public (i.e., published) and extends to the state's official agencies and libraries, including the University of Florida's Smathers Libraries, rights of reproduction. The Florida Geological Survey has made its publications available to the University of Florida, on behalf of the State University System of Florida, for the purpose of digitization and Internet distribution. The Florida Geological Survey reserves all rights to its publications. All uses, excluding those made under "fair use" provisions of U.S. copyright legislation (U.S. Code, Title 17, Section 107), are restricted. Contact the Florida Geological Survey for additional information and permissions. ~~~ -~ -Q --.~; LCb---~'* ' I-4; --- -t--* ;- ^'. -n4----', S - , ~ n-1-- s 4-+~~F;~-r r IUI -%. W,- - - 17~ A -A7 ~ ; - :4 I STATE OF FLORIDA DEPARTMENT OF NATURAL RESOURCES Harmon Shields, Executive Director DIVISION OF RESOURCE MANAGEMENT Charles M. Sanders, Director BUREAU OF GEOLOGY Charles W. Hendry, Jr., Chief REPORT OF INVESTIGATION NO. 84 THE HIGHLAND HEAVY-MINERAL SAND DEPOSIT ON TRAIL RIDGE IN NORTHERN PENINSULAR FLORIDA By E. C. Pirkle, William A. Pirkle and W. H. Yoho Prepared for BUREAU OF GEOLOGY DIVISION OF RESOURCE MANAGEMENT FLORIDA DEPARTMENT OF NATURAL RESOURCES TALLAHASSEE, FLORIDA 1977 QF DEPARTMENT OF NATURAL RESOURCES REUBIN O'D. ASKEW Governor BRUCE A. SMATHERS Secretary of State RALPH D. TURLINGTON Commissioner of Education GERALD A. LEWIS Comptroller BILL GUNTER Treasurer ROBERT L. SHEVIN Attorney General DOYLE CONNER Commissioner of Agriculture HARMON W. SHIELDS Executive Director LETTER OF TRANSMITTAL Bureau of Geology Tallahassee July 15, 1977 Governor Reubin O'D. Askew, Chairman Florida Department of Natural Resources Tallahassee, Florida 32304 Dear Governor Askew: The Bureau of Geology of the Division of Resource Management, Florida Department of Natural Resources, is pleased to publish as its Report of Investigations No. 84, "The Highland Heavy-Mineral Sand Deposit on Trail Ridge in Northern Peninsular Florida," by E. C. Pirkle, William A. Pirkle and W. H. Yoho. Those minerals commonly mined in Florida under the heading of Heavy Minerals are rutile, zircon, ilmenite, leucoxene and stauro- lite. Florida has consistently been a leading producer of these minerals and this study contributes significantly to the expansion of the known reserves of these minerals. Respectfully yours, Charles W. Hendry, Jr., Chief Bureau of Geology Completed Manuscript received 1976 Printed for the Florida Department of Natural Resources Division of Resource Management Bureau of Geology Tallahassee 1977 iv CONTENTS Page Abstract -- --- -- ---.................... ............... 1 Introduce tion ....... ...... ... ........................................................................................................ ...... ..... ... ... ... 1 Introduction ...........I.~..... 1 Acknowledgm ents ........................ ................. ........ ... ............ .............. 2 Characteristics and geological setting of the Highland ore body ..................... 3 Surface sands in region of Highland ore body ................ .......................... 8 Selected features of heavy minerals ........................................ 8 Distribution of Garnet and Epidote ......... .............. ....... 8 Distribution of Ilmenite and Leucoxene ............................. ........................ 9 Sphericities of heavy minerals ........ ................. ................ ...... ...... 10 Current working hypothesis on origin of ore bodies ............-... .. 11 References ....................-......... 13 Appendices ............. ..... ........................ ................ ............ ..... I. Detailed Lithologic Logs of Highland No. 1 and Highland N o. 2 D rill H oles .... .................... ............. ..................... .................. 15 II. Characteristics of Highland No. 1 and Highland N o. 2 Sedim ents ....................................... .................... ....... ......... .................. 33 III. Characteristics of surface sands in study area ..................................... 43 ILLUSTRATIONS Figure 1 Location map 2 2 Location of Highland ore body and test holes .............................. 4 3 Lithologic logs of Highland No. 1 and Highland No. 2 drill holes -.___ .. ...................... ...... 5 4 Sample sites of surface sands collected in the vicinity of the Green Cove Springs ore body _................................................ 47 5 Sample sites of surface sands collected in the vicinity of the Boulougne ore body .... ........... .............. ...................................... 50 TABLES Table 1 Highland No. 1 drill hole ... ...................... 34 2 Mechanical analyses of quartz sand, Highland No. 1 drill hole .......... 36 3 Percentages of selected heavy minerals, Highland No. 1 drill hole ...._______ ..................... 38 4 Highland No. 2 drill hole .... ......... .................... ................ .......... 40 5 Mechanical analyses of quartz sand, Highland No. 2 drill hole .... ......... ........................ .............. 41 6 Percentages of selected heavy minerals, Highland No. 2 drill hole ........__................. .... 42 7 Analyses of surface sediments collected in vicinity of Green Cove Springs ore body (Sample sites shown on fig. 4) ............. 44 8 Mechanical analyses of surface sands in vicinity of Green Cove Springs ore body (Sample sites shown on fig. 4) ............................... 45 9 Percentages of selected heavy minerals (in 1/8 to 1/16 mm heavy-mineral fraction of surface sands) collected in vicinity of Green Cove Springs ore body (Sample sites shown on fig. 4) ............ 46 10 Analyses of surface sediments collected in vicinity of Boulougne ore body (Sample sites shown on fig. 5) ......... ......... ....... ............... 48 11 Mechanical analyses of surface sands in vicinity of Boulougne ore body (Sample sites shown on fig. 5) ......................................... 48 12 Percentages of selected heavy minerals (in 1/8 to 1/16 mm heavy-mineral fraction of surface sands) collected in vicinity of Boulougne ore body (Sample sites shown on fig. 5) ........................... 49 THE HIGHLAND HEAVY-MINERAL SAND DEPOSIT ON TRAIL RIDGE IN NORTHERN PENINSULAR FLORIDA By E. C. Pirkle1, William A. Pirkle2, W. H. Yoho3 ABSTRACT A heavy-mineral ore body is present along Trail Ridge just north of the town of Highland in northern peninsular Florida. No reports of this ore body have been published. The deposit, called the Highland ore body, consists of loose to slightly indurated quartz sand with an average of 3 per cent heavy minerals. Approximately 45 per cent of the heavy minerals are titanium minerals which, with zircon, are the major ore minerals of the deposit. It is hypothesized that the ore sands accumulated as part of a beach ridge which was built at the crest of an erodinig, transgress- ingpsea. The major sourcesediments for Trail Ridge ani for the ore sands are believed-to-have-been sands of the Northern Highlands that occur to the-west of TraiLRidge and into which the transgress- ing seas eroded. This concept for the origin of Trail Ridge and the Highland ore body is consistent with heavy-mineral suites and with sedimentary and physiographic features of the region. INTRODUCTION Trail Ridge is a 130-mile long sand ridge that extends southward froThe Altamaha River in southern Georgia to the southern parts of Clay and Bradford counties in northern peninsular lorida (Fig. 1). The crest elevations of the ridge range from app-roximnately 140 to 170 feet above sea level in Georgia to slightly more than 250 feet above sea level near its southern end in northern Florida. Extensive plains areas bound the ridge on both its eastern and western sides. At most sites the plains immediately west of the ridge are about 40 to 50 feet higher than the plains at the same latitude immediately east of the ridge. For many years heavy-mineral sands have been mined in north- 1Department of Physical Sciences and Department of Geology, University of Florida, Gainesville, Florida. 2Division of Natural Sciences, University of South Carolina, Aiken, South Carolina. 3Department of Physical Sciences, University of Florida, Gainesville, Florida. BUREAU OF GEOLOGY Figure 1. Location map. Figure 1. Location map. REPORT OF INVESTIGATION NO. 84 ern Florida along the southern 18-mile stretch of Trail Ridge (Gar- nar, 1972). This deposit is the Starke Trail Ridge ore body of E. I. du Pont de Nemours and Company. Its trend is essentially north- south. Another heavy-mineral deposit along Trail Ridge is currently under study. This deposit is a northward continuation of the Starke deposit and locally is referred to as the Highland ore body (Figs. 1 and 2). The main purpose of this report is to describe the High- land ore body and to discuss its possible origin. ACKNOWLEDGMENTS This report is a contribution of the Bureau of Geology, Florida Department of Natural Resources, Tallahassee; the Division of Natural Sciences, University of South Carolina, Aiken; and the Department of Physical Sciences and the Department of Geology, University of Florida, Gainesville. The joint authors are deeply indebted to these organizations for making this work possible. Various companies have been very helpful and cooperative in studies of heavy-mineral sand deposits of northern Florida. These companies include N L Industries, Incorporated; E. I. du Pont de Nemours and Company; Humphreys Mining Company; and Titani- um Enterprises. The writers are deeply grateful to these organiza- tions. Also, thanks are due to Muriel Hunter and Joe Banks of Coastal Petroleum Company for discussing problems of the Miocene of Florida and southern Georgia with the authors and for sharing their ideas concerning the nature of these sediments. The authors are deeply indebted to T. E. Garnar, Jr., for substantial contribu- tions through discussions of the characteristics of heavy-mineral sand deposits. Gratitude is expressed to Justin Hodges and Albert Phyllips, Jr., for the care they exercised in drilling operations and to V. M. Patterson, Jr., for drafting the figures. The P205 and Fe203 analyses given in the tables were run by Thornton and Company of Tampa, Florida. Charles W. Hendry, Jr., T. Walter Herbert, and Thomas M. Scott graciously reviewed the report and added materi- ally to the accuracy and clarity of presentation. The authors are most grateful to Miss Xiomara Ortiz for typing the manuscript, organizing data, and helping in the design and preparation of tables and figures. CHARACTERISTICS AND GEOLOGICAL SETTING OF THE HIGHLAND ORE BODY The Highland heavy-mineral sand deposit has a length of 81/2 miles, an average width of nearly 11/2 miles, and an average thick- 4 BUREAU OF GEOLOGY 2 Maxvilli 36 31 DUVAL CO. CLAY CO. I HIGHLAND No. 2!, 1 | HIGHLAND '-, -- '- ORE SjBODY BAKER CO. BRADFORD CO. I/ HIGHLAND No.I 36 Highjnd ________ a\ A) Figure 2. Location of Highland ore body and test holes. REPORT OF INVESTIGATION NO. 84 HIGHLAND No.2 SURFACEt 191E SANDS ORE 169 BROWN SAND 1 ---------t-156 ***Y/ DRAB 156 ZONE 125 .- . GRAY QUARTZ SAND 64 FEET 200- 150. 100- 50- No.I FEET r200 -26 IuI .... HAWTHORN r- FORMATION -- -- -290 OCALA LIMESTONE MEAN SEA HIGHLAND 202s SURFACE I O SANDS E -----1---168 BROWN SAND 148 - DRAB -'- CLAY ZONE -- -- 80so SHELL BED 50 GRAY QUARTZ . SAND - ------ 22 FOSSILIFEROUS LIMESTONE . S SURFACE ORE . SANDS I--- SAND CLAY LIMESTONE DOLOMITE i | PHOSPHATE *"' I PEBBLES FIT t H SHELLS or I r 9, L 1 SHELL FRAGMENTS |_ __ J WOODY or FIBROUS I ORGANIC MATERIAL Figure 3. Lithologic logs of Highland No. 1 and Highland No. 2 drill holes. ness of 30 to 35 feet. Itomnsists-ofloose to slightly indurated quartz sands containing ana- e of 3rerentheavy-mineralsof which about 45 percent are the t~tanim-m'n~als&-ilmenite, leucoxene, an~ rutile. The average TiO2 content of these titanium minerals is approximately 69 per cent. Other common heavy minerals in the deposit include staurolite, zircon, kyanite, sillimailte, and tour- maline. The most significant ore minerals are ilmenite, leucoxene, and zircon. Two holes were drilled through the Highland ore body by the Florida Buireau of Geology (Figs. 2 and 3). Detailed logs of the materials penetrated with tables of data to illustrate the nature of LEVEL BUREAU OF GEOLOGY the sediments are given in Appendix I and Appendix II. The fol- lowing abbreviated log summarizes the materials and formations encountered at the site of the Highland No. 1 drill hole: Highland No. 1 Drill Hole Depth in Feet Materials or Formation and Inches 0 to 53'6".-............ Gray to moderate brown quartz sand 53'6" to 121'9"......Drab to olive-green clay zone Intercalated lenses or layers of quartz sand, clayey sand, sandy clay, and massive clay 121'9" to 152' ...... Shell bed Clayey sand with very poorly preserved shells of marine mollusks 152' to 180'----....... Gray quartz sand 180' to 227'6"-. .... Fossiliferous limestone 227'6" to 492'........Hawthorn Formation 492' to 493'--........ Ocala Limestone Total Depth-493' in Ocala Limestone The oldest and deepest rock reached in the drilling is the Ocala Limestone of Eocene age. The upper surface of this limestone oc- curs at a depth of 492 feet. Approximately 265 feet of Hawthorn sediments unconformably overlie the Ocala Limestone (from 227 feet 6 inches to 492 feet). These Hawthorn sediments consist of various mixtures of carbonate (mainly dolomite), insoluble clay, and quartz sand. Sand-size particles and small pebbles of black phosphorite occur disseminated throughout all of the Hawthorn materials and as local concentrations within some beds. The Haw- thorn Formation is usually considered Miocene in age (Espenshade and Spencer, 1963). A fossiliferous limestone about 48 feet thick rests on the Hawthorn Formation (from 180 feet to 227 feet 6 inches). Most investigators assign a late Miocene age to this lime- stone. The sediments in the interval extending from a depth of 53 feet 6 inches to a depth of 180 feet consist of intercalated lenses of quartz sand, clayey sand, sandy clay, and massive clay. A seg- ment of these materials (from 121 feet 9 inches to 152 feet) con- tains badly leached and fragmented marine mollusk shells. All of these post-Hawthorn clastics, like the underlying fossiliferous lime- stone on which they rest, are usually dated as late Miocene. REPORT OF INVESTIGATION NO. 84 Resting on these post-Hawthorn clastics are approximately 53 feet of surface sands. The surface sands are believed by some in- vestigators to be M1iocene (Alt, 1974), by others to be Pliocene (Brooks, 1966), and by_ still others to be Pleistocene (Doering, i960). A more complete discussion of post-Hawthorn sediments in the vicinity of Trail Ridge is given by William A. Pirkle (1972). The fossiliferous limestone just above the Hawthorn Formation (from 180 feet to 227 feet 6 inches) occupies the same stratigraphic position as a fossiliferous limestone exposed just above the Haw- thorn Formation at Brooks Sink in Bradford- Couinty. The lime- stone at Brooks Sink has been dated by Puri on the basis of ostra- cods as lower Choctawhatchee in age-late middle Miocene and/or late Miocene (Pirkle, 1956, p. 210). At the sites of both the Highland ore body and Brooks Sink it appears that the fossiliferous lime- stone and the underlying Hawthorn sediments grade into each other. A similar fossiliferous limestone is present locally just above the Hawthorn Formation at other localities in northern Florida. The badly leached mollusk shells in the clayey sands which extend from a depth of 121 feet 9 inches to 152 feet have been ex- amined by Muriel Hunter. In a personal communication discussing these sediments she states: Abundant Rangia shells together with a few nearshore varieties of marine mollusks suggest an estuarine or nearshore lagoonal environ- ment with very low salinity. Few of the shells in the bed were identi- fied specifically, and none of these was stratigraphically significant. Lacking diagnostic mollusk species, the presently available criteria for positioning this shell bed are vague at best, involving such incon- clusive factors as general appearance, elevation, and possible relation- ship to identified stratigraphic units mapped in contiguous areas. However, the possibility that the shell bed might represent shoreline deposition during some part of Jackson Bluff/Late Tamiami time should not be overlooked. For many years, both of these formations were assigned a late Miocene age. William Akers reported the presence of Pliocene planktonic foraminifera in the Jackson Bluff Formation (1972) and mid-Pliocene nanofossils in the upper part of the Tamiami Formation (Pinecrest Sand Member) in 1974. Akers' work has been well received, and most stratigraphers now seem to have accepted a middle Pliocene age for both units. Sediments of the lower part of the Tamiami Formation and the Area Zone of the Florida Panhandle are still generally referred to the late Miocene. If the segment from 121 feet 9 inches to 152 feet proves to be of Pliocene age, it is conceivable that a rather thick section of Pliocene materials is present at this site, namely the sediments beginning at a depth of 53 feet 6 inches and extending downward through the shell bed, the zone of gray quartz sand, the fossiliferous limestone, and the upper part of the Hawthorn Formation. BUREAU OF GEOLOGY SURFACE SANDS IN REGION OF HIGHLAND ORE BODY The sands that compose Trail Ridge are relatively coarse and are characterized by a uniform grade-size distribution. Usually between 50 and 70 per cent of the sand falls init-the inedium sand fraction (1/ to m1/m) and from 20 to 40 percent of the sand falls into the fine sand fraction (1/4 to %/8 mm). This _rad-e-ize-distri- bution of Trail Ridge sands is remarkably constant throughout the entire length and thickness of the ridge. The sands of the surface sand blanket of the Northern High- lands west of Trail Ridge are finer than Trail Ridge sands, and the size distribution of sand grains in these high terrace sands is quite variable from one locality to another. In this respect the sands of the Northern Highlands differ considerably from those of Trail Ridge. However, the high terrace sands contain a substantial per- centage of medium sand-size particles (1/2 to 1/4 mm) and there- fore are sufficiently coarse to have served as source sediments for Trail Ridge sands. The surface sands of the Duval Upland east of Trail Ridge are different from the sands of Trail Ridge and the high terraces. These sands of the Duval Upland are notable for their fine size. Throughout most of the upland more than 90 per cent of-the sand falls into the fine (1/4 to 1/8 mm) and very fine (1/8 to 1/16 mm) sand fractions. The reader is referred to a report by William A. Pirkle (1972) for additional analyses of Trail Ridge sands and for analyses of sur- face sands from the Northern Highlands west of Trail Ridge. Analyses of surface sands from the Duval Upland in the vicinities of the Green Cove Springs and Boulougne heavy-mineral sand deposits are given in Appendix III of this report (Tables 7-12). SELECTED FEATURES OF HEAVY MINERALS DISTRIBUTION OF GARNET AND EPIDOTE A study of the heavy minerals extracted from the sediments penetrated in Highland No. 1 drill hole reveals a number of inter- esting features. The loose quartz sands extending from the land surface downward for 53 feet 6 inches do not contain garnet or epidote (Table 3, Spls. 1-11, Appendix II). Samples of Trail Ridge sands have been collected from many other localities along the 130-mile long ridge. Analyses of the samples show that Trail Ridge sands rarely, if ever, contain these two minerals. In contrast, all of the post-Eocene sediments beneath the loose REPORT OF INVESTIGATION NO. 84 surface sands contain garnet and epidote. The first garnet was encountered in Highland No. 1 drill hole at a depth of 61 feet (Table 3, Spl. 14). From that depth the mineral continues down- ward through all of the various types and ages of post-Eocene sedi- ments. It increases markedly in the lower 30 feet of the Hawthorn Formation (Table 3, Spls. 63-66). An increase in garnet in the lower part of the Hawthorn Formation has been noted at other localities in northern Florida. The distribution of epidote, likewise, is of interest. This mineral was first encountered at a depth of approximately 62 feet (Table 3, Spl. 15). It increases markedly at a depth of 96_feet (Table 3, Spl. 26) and continues downward as a common heavy mineral without interruption to a depth of 304 feet (Table 3, Spl. 44). This interval with the marked increase of epidote includes the lower 36 feet of the drab to olive-green clay sequence, all of the under- lying shell bed, the zone of gray quartz sand, the fossiliferous limestone, and the upper 76 feet of the Hawthorn Formation (Table 3, Spls. 26-44). A similar distribution of epidote occurs in the same types of post-Eocene sediments at other localities in northern penin- sular Florida. Furthermore, it is of interest to note that epidote and garnet are very rare, and generally not present, in the sands underlying the Northern Highlands west of Trail Ridge. In contrast, epidote and garnet are frequently found to be a part of the heavy-mineraL suite of the sands and heavy-mineral ore bodies of the Duval Up- land east of Trail Ridge. The distribution of epidote and garnet in the surface sands of the region should be considered in any at- tempt to explain the origin of the heavy-mineral ore bodies on Trail Ridge. DISTRIBUTION OF ILMENITE AND LEUCOXENE The occurrences of heavy minerals may be significant in cer- tain stratigraphic problems of the region. For example, one in- triguing problem is the relationship of the surface sands (those sands extending from the land surface to a depth of 53 feet 6 inches, Table 1) to the underlying sediments. It is not known if the surface sands are of younger age than the underlying materials and separated from them by an unconformity, or if the surface sands are of the same general age and a continuation of the underlying sediments. Sufficient data are not available to draw a conclusion that would receive general acceptance. However, the concept that the surface sands are younger than BUREAU OF GEOLOGY the underlying sediments and separated from them by an uncon- formity is compatible with the heavy-mineral distribution. For example, the percentage of leucoxene is relatively high and that for iimenite correspondingly low in the upper 5 feet of surface sands at the site of Highland No. 1 drill hole (Table 3, Spls. 1 and 2). A substantial amount of the leucoxene in this upper surface zone is believed to have formed from the weathering in situ of ilmenite. Leucoxene is a weathering product of ilmenite and always seems to be more abundant (and ilmenite correspondingly less abundant) in the upper part of sand ridges and sand blankets in the areas of the older surface sands of peninsular Florida. Therefore, the relatively high percentages of leucoxene and the corresponding low percentages of ilmenite in the upper part of the drab to olive-green clay zone (Table 3, Spls. 12-16) suggest that this clay zone was subjected to subaerial weathering prior to the deposition of the surface sands or else that the source sediments for the drab clay zone was different from the source sediments for the surface sands. In either case the weathering to produce much of the leucoxene in the upper part of the drab clay sequence must have taken place before the deposition of the lower part of the surface sands because the ilmenite in the surface sands immedi- ately overlying the drab clay zone has not weathered to leucoxene (Table 3, Spls. 7-11). The same relationship of leucoxene to ilmenite characterizes the upper part of the drab clay zone in Highland No. 2 drill hole (Table 6, Spls. 10-12, Appendix II) and at other sites along Trail Ridge. Furthermore, a buried zone of tree trunks, tree limbs, and associated organic materials occurs just beneath the surface sands at the Trail Ridge ore body of the du Pont Company (Grogan et al., 1964). Many of the tree trunks occur in an upright position suggest- ing that the organic layer represents a forest buried in place. Such occurrences further indicate the possibility that the surface sands are separated from the underlying sediments by an old subaerial surface. SPHERICITIES OF HEAVY MINERALS A study was made comparing the sphericities of zircon and kyanite-sillimanite of Trail Ridge sands with sphericities of these same heavy minerals in sediments that might have served as source materials for Trail Ridge (Fredric L. Pirkle, 1975). The possible source materials investigated were thick surface sands that crop_ out along the Altamaha River north of Trail Ridge, sands of the high terraces west of Trail Ridge, and sands from sediments com- REPORT OF INVESTIGATION NO. 84 prising the Lake Wales Ridge south of Trail Ridge. On the basis of the sphericity studies it was concluded that of these possible source materials, only the high terrace sands of the Northern Highlands west of Trail Ridge could be the immediate source sands for Trail Ridge. CURRENT WORKING HYPOTHESIS ON ORIGIN OF ORE BODIES Any hypothesis proposed to explain the origin of Trail Ridge and the Trail Ridge heavy-mineral ore bodies must be compatible with the following features. Trail Ridge sands are relatively coarse, have a very uniform grain-size distribution, do not contain epidote or garnet, and have heavy minerals with sphericities that are the same as those of similar heavy minerals in the sands of the North- ern Highlands. Furthermore, Trail Ridge sands probably are separated from underlying sediments by an old subaerial surface. The following ideas and concepts are consistent with these features (Pirkle et al., 1974). According to the hypothesis the sand blanket of the Northern Highlands was left as a plain when ocean waters retreated from the present Coastal Plain areas of southern Georgia and northern Florida. This regressing sea was later followed by a major marine transgression. The transgressing sea eroded into sediments of the Northern Highlands. Trail Ridge with its ore bodies was built as a beach ridge at the crest of this eroding, transgressing sea. Accord- ing to this concept the immediate source sediments for much of Trail Ridge were sands of the high terraces of the Northern High- lands. It is probable that only a very minute amount of epidote or garnet was originally deposited with the quartz sands that now underlie the Northern Highlands. Moreover, the sand blanket of the Northern Highlands, being relatively old, has been subjected to a rather long period of weathering. Any epidote or garnet that was deposited with the sands would have been largely destroyed during this long weathering interval. Therefore this concept for the origin of the high terrace sands and for Trail Ridge would explain the absence of epidote and garnet in Trail Ridge and the similarity of the heavy-mineral suites of the high terrace sands and Trail Ridge sands. The size distribution of Trail Ridge sands also can be explained if the sands of the Northern Highlands were the source sediments for Trail Ridge. Along the Trail Ridge shoreline relatively fine BUREAU OF GEOLOGY sands would likely have been washed seaward leaving coarser sands to comprise shoreline features. Thus the fact that Traii Ridge sands-ar cs-ef th-aif-tli~sanIdsi underlying the Norther6nHigh- lands woiild bexp-iEiteidATso, withKlieifie Tactiofi of the sids being washed seaWard the reworked sands remaining in the shore zone would have less size-spread and would be more uniform. Theire- fore, the relative coarseness anid-the- uiiiformity of Trail Ridge sands are consistent with the hypothesis. Moreover the slightly convex outline of Trail Ridge, with its most western curvature occurring in the region of the relatively easily erodable, unconsoli- dated to slightly consolidated sands of the Northern Highlands, would be explained, as would the parallelism of the trend of Trail Ridge with that of the present shoreline (Fig. 1). Furthermore the concept is consistent with the fact that the Starke heavy-mineral sand deposit of du Pont is larger and contains a higher percentage of heavy minerals than the Highland ore body. The du Pont deposit is in that part of Trail Ridge that is banked up behind, and en- croaches on, the northern end of the_Lake Wales remnant (the Interlachen _Karstic Highland on Figure 1). This environment was conducive to the accumulation of relatively large quantities of heavy minerals and wind-blown sands (Pirkle and Yoho, 1970). The Duval Upland east of Trail Ridge (Fig. 1) is believed to be a regressional beach ridge plain. It is younger than Trail Ridge and is the remnant of a much larger plains area, much of which has been destroyed through subaerial erosion and later marine transgressions. While this regressional beach ridge plain was form- ing there were temporary halts in regression, and perhaps even slight transgressions. During these intervals more prominent beach ridges were built. Some of these ridges contain concentrations of heavy-mineral sands. Examples of these concentrations are the commercial Green Cove Springs and Boulougne deposits (Fig. 1). In summary, the high terraces of the Northern Highlands are believed tob haveiiiei7 ft as aV plain when ocean waters retreated from the present areas of southern Georgia and northe-r Floridia. At a later time transgressing seas eroded into these higi terrace deposits. Trail Ridge with its heavy-mineral sand deposits was built as a beach ridge at the height of this transgression. The Duval Upland is younger than Trail Ridge. It is believed to be a part of an ancient, regressional beach ridge plain. During its formation there were temporary halts in regression, perhaps even slight transgressions, during which times heavy-mineral oire bodies were formed. C. ,1 REPORT OF INVESTIGATION NO. 84 13 REFERENCES Akers, William 1972 Planktonic foraminifera and biostratigraphy of some Neogene formations, northern Florida and Atlantic Coastal Plain: Tulane Studies in Geology and Paleontology, v. 9. 1974 Age of Pinecrest beds, South Florida: Tulane Studies in Geology, v. 11, p. 119-120. Alt, David 1974 Arid climatic control of Miocene sedimentation and origin of modern drainage, southeastern United States, in Post-Miocene stratigraphy, central and southern Atlantic Coastal Plain: Utah State Univ. Press, p. 21-29. Brooks, H. K. 1966 Geological history of the Suwannee River, in Olson, N. K., ed., Geology of the Miocene and Pliocene series in the North Florida- South Georgia area: Atlantic Coastal Plain Geol. Assn. 7th Field Trip, Southeastern Geol. Soc. 12th Field Trip, Guidebook, p. 37-45. Cannon, Harry B. 1950 Economic minerals in the beach sands of the southeastern United States: Symposium on Mineral Resources of the Southeastern United States, Univ. of Tennessee Press, p. 202-210. Doering, John A. 1960 Quaternary surface formations of southern part of Atlantic Coastal Plain: Jour. of Geol., v. 68, p. 182-202. Espenshade, G. H. 1963 (and Spencer, C. W.) Geology of phosphate deposits of northern peninsular Florida: U. S. Geol. Survey Bull. 1118. Garnar, T. E., Jr. 1972 Economic geology of Florida heavy mineral deposits, in Puri, H. S., ed., Proc. 7th Forum Geology of Industrial Minerals: Special Pub. 17, Florida Bur. Geology, p. 17-21. Grogan, R. M. 1964 (Few, W. G., Garnar, T. E., and Hager, C. R.)Milling at du Pont's heavy mineral mines in Florida, in Milling methods in the Ameri- ca's, Nathaniel Arbiter, ed.: VII International Mineral Processing Congress, New York, Gordon and Breach Science Publishers, p. 205- 229. Pirkle, E. C. 1956 The Hawthorne and Alachua formations of Alachua County, Flori- da: Quart. Jour. Fla. Acad. Sci., v. 19, no. 4, p. 197-240. 1970 (and Yoho, W. H.) The heavy mineral ore body of Trail Ridge, Florida: Econ. Geol., v. 65, p. 17-30. 1974 (Pirkle, William A., and Yoho, W. H.) The Green Cove Springs and Boulougne heavy-mineral sand deposits of Florida: Econ. Geol., v. 69, p. 1129-1137. Pirkle, Fredric L. 1975 Evaluation of possible source regions of Trail Ridge sands: South- eastern Geol., in press. Pirkle, William A. 1972 Trail Ridge, a relic shoreline feature of Florida and Georgia: Ph.D. >- dissertation, University of North Carolina at Chapel Hill. 4. REPORT OF INVESTIGATION NO. 84 APPENDIX I Detailed Lithologle Logs of Highland No. 1 and Highland No. 2 Drill Holes 16 BUREAU OF GEOLOGY HIGHLAND DRILL HOLE NO. 14 SE1/, NEi/4, Section 25, T. 4 S., R. 22 E., Bradford County, Florida Approximately 1 Mile Northwest of Highland Surface Elevation- 202 Feet Thickness Unit Description In Feet & Inches Surface Sands5 40 Loose quartz sand, coarse to very fine. Gray to brown to black. Gray to brown soil zone from land surface to depth of 1 foot 3 inches. White sand from 1 foot 3 inches to 4 feet. Black sand from 4 feet to 20 feet. Variable from gray with brown tint to dark brown with black tint from 20 feet to 25 feet 6 inches. White sand from 25 feet 6 inches to 27 feet. Dark brown sand with black tint from 27 feet to 33 feet 9 inches. The black color is due to finely divided organic matter. Most of these black sediments are loose to moderately indurated. At a few places, how- ever, the black zones are well cemented and constitute "hard pan." The black organic zones are especially prominent from 5 feet to 8 feet 6 inches and from 14 feet to 19 feet 6 inches. The black sands are exceptionally hard from 13 feet 6 inches to 14 feet ............................... 33'9" (From land surface to 33'9") Spl. 1 -Channel sample from land surface to depth of 5 feet. 4This hole was drilled by the Bureau of Geology, Florida Department of Natural Resources. The .drilling was completed June 12, 1974. Analyses of the samples are given in Tables 1 through 3, Appendix II. 3A specially designed core barrel was used in sampling the loose sands, clayey sands, and sandy clays that occur from the land surface to a depth of 121 feet 9 inches. With the aid of this core barrel a very high per cent of recovery of undisturbed samples of these loose sands and soft sediments was obtained. The small intervals from which sediments were not recovered are indicated in the descriptions of the samples. REPORT OF INVESTIGATION NO. 84 Spl. 2 Channel sample from depth of 5 feet to depth of 10 feet. Spl. 3- Channel sample from 10 feet to 15 feet. Spl. 4 Channel sample from 15 to 20 feet. Spl. 5- Channel sample from 20 to 25 feet. Spl. 6 Channel sample from 25 to 30 feet. Moderate Brown Sand 39 Quartz sand, medium to fine. Moderate brown with zones stained black with organic matter. Black-stained zones are present from 41 feet to 46 feet, 48 feet 6 inches to 49 feet 6 inches, 51 feet 6 inches to 52 feet 9 inches, and from 53 feet to 53 feet 6 inches .--...............--,,.................19'9" (From 33'9" to 53'6") Spl. 7 Channel sample from 30 feet to 35 feet. Spl. 8 Channel sample from 35 to 40 feet. Spl. 9 Channel sample from 40 to 45 feet. Sedi- ments not sampled from 41 feet 6 inches to 42 feet 6 inches. Spl. 10 Channel sample from 45 to 50 feet. Spl. 11 Channel sample from 50 feet to 53 feet 6 inches. Drab to Olive-Green Clay Zone 38 Intercalated lenses or layers of quartz sand, clay- ey sand, sandy clay, and massive clay. Quartz sand is very fine to coarse. Most of the sand, however, is very fine. Sands are white, gray, tan to light brown, and black. Clay is gray, drab, olive-green, and black. Clay in the more massive lenses is sectile. Small particles and specks of brown to reddish- brown wood are present in the drab and black clays and are especially prominent at depths of 61 feet to 62 feet 3 inches, 63 feet to 64 feet, and from 64 feet 6 inches to 67 feet. Wood material, one inch in thickness, occurs at 66 feet. In some of the clayey sediments tubes and pockets BUREAU OF GEOLOGY of white sand are present (apparently filled burrows) .......................... ....... 68'3" (From 53'6" to 121'9") Spl. 12 Channel sample from 53 feet 6 inches to 54 feet 6 inches. Loose, white sand. Spl. 13 Channel sample from 54 feet 6 inches to 61 feet. Clayey sand, sandy clay, and sand. Gray to drab clay content is rela- tively high from 56 feet to 59 feet. Mainly gray-white sand from 59 feet to 61 feet. Spl. 14 Channel sample from 61 feet to 62 feet 3 inches. Black, massive clay with par- ticles of wood. Spl. 15 Channel sample from 62 feet 3 inches to 68 feet. Small intercalated lenses or stringers of white quartz sand and black quartz sand. Spl. 16 Channel sample from 63 feet to 64 feet. Black quartz sand and clayey sand with particles of wood. Spl. 17 Channel sample from 64 feet 6 inches to 67 feet. Massive drab clayey sedi- ments with particles of wood and oc- casional stringers of fine white quartz sand. Sediments not sampled from 64 feet to 64 feet 6 inches. Spl. 18 Channel sample from 67 feet to 70 feet. Clayey sand or sandy clay with string- ers and small lenses of massive, drab clay. Sediments not sampled from 67 feet to 67 feet 6 inches. Spl. 19 Channel sample from 70 to 75 feet. Gray, relatively coarse, loose sand. Spl. 20-Channel sample from 75 to 77 feet. Loose, relatively coarse quartz sand. Spl. 21 Channel sample from 77 feet to 77 feet 9 inches. Massive drab clay with small pockets of fine sand. Spl. 22- Channel sample from 77 feet 9 inches to 78 feet 8 inches. Relatively fine, white sand. REPORT OF INVESTIGATION NO. 84 Spl. 23 Channel sample from 78 feet 3 inches to 85 feet. Massive, olive-drab, clayey sedi- ments. No sample from 79 feet 6 inches to 80 feet. Spl. 24 Sample of clayey sand to massive gray clay. Representative of interval from 85 feet to 88 feet 6 inches. Spl. 25 Channel sample from 88 feet 6 inches to 96 feet 3 inches. Light gray to white quartz sand or clayey sand with string- ers and small 'lenses of massive clay. Spl. 26 Channel sample from 96 feet 3 inches to 101 feet 6 inches. Massive black to olive- green or drab clay. No sample from 97 feet to 97 feet 6 inches. Spl. 27 Channel sample from 101 feet 6 inches to 107 feet 6 inches. Dark gray clayey sand to sandy clay. Spl. 28- Channel sample from 107 feet 6 inches to 110 feet. Gray clayey sand with stringers of massive clay. Spl. 29- Channel sample from 110 feet to 115 feet. Gray clayey sand with stringers of massive clay. Spl. 30 -Channel sample from 115 feet to 121 feet 9 inches. Gray clayey sand with stringers of massive clay from 120 to 121 feet and small, white, marine mol- lusk shells from 116 feet 9 inches to 117 feet. Shell Bed 37 Clayey sand with abundant badly leached, white shells of marine mollusks. Gray to light gray. Quartz sand is coarse to very fine. Zone from 121 feet 9 inches to 132 feet is very fossiliferous. These sediments contain numer- ous fragments of relatively large mollusk shells. No sample obtained from the interval extending BUREAU OF GEOLOGY from 132 feet to 140 feet. The material within this interval probably is fine sand. Sediments from 140 feet to 148 feet are very fos- siliferous. These materials include abundant fragments of relatively small mollusk shells. The sediments from 148 feet to 152 feet contain numerous fragments of relatively large mol- lusk shells .............. ................. ......................... .. (From 121'9" to 152') Spl. 31 Channel sample from 121 feet 9 inches to 182 feet. Clayey sands characterized by fragments of relatively large mollusk shells. Spl. 32-Channel sample from 140 feet to 148 feet. Clayey sands characterized by frag- ments of relatively small mollusk shells. Spl. 33- Channel sample from 148 feet to 152 feet. Clayey sands with fragments of relatively large mollusk shells. Gray Quartz Sand 36 Quartz sand, fine to coarse. Gray. A few frag- ments of fossil shells are present in the sands ......5'0" (From 152' to 157') Spl. 34 Channel sample of gray quartz sand. 35 No recovery. This interval contains sands like those in the above interval (152 feet to 157 feet). However, the sands of this lower zone are probably finer with silt-size particles in- creasing with depth .......... ................................ 2 (From 157' to 180') Fossiliferous Limestone 34 Fossiliferous limestone. Light gray. Soft. Numerous shell impressions. Locally the limestone contains a considerable amount of quartz sand and insoluble clay .............6'0" (From 180' to 186') REPORT OF INVESTIGATION NO. 84 Spl. 85- Channel sample of fossiliferous lime- stone. 33 Impure limestone with a very high content of insoluble clay. Gray to light gray. Firm but soft ...16'3" (From 186' to 202'3") Spl. 36 Channel sample of limestone. 32 Fossiliferous limestone. Brownish gray. Porous and rock-like, hard. A mass of fossil impressions ........... .......... 10'3" (From 202'3" to 212'6") Sp. 37 Channel sample of hard, fossiliferous limestone. 31 Impure limestone. Contains much insoluble clay. Gray. Firm but soft. A few fossil impressions ............. ......................3'" (From 212'6" to 215'6") Spl. 38 Channel sample of limestone. 30 Fossiliferous limestone. Gray. A mass of mollusk impressions. Porous and rock- like, hard. At 227 feet 6 inches black particles of phosphorite becomes common to abundant ................... ......12'0" (From 215'6" to 227'6") Spl. 39- Channel sample of fossiliferous lime- stone. Hawthorn Formation" 29 Impure carbonate bed or mixture of carbonate, quartz sand, and insoluble clay. Light gray to gray. Firm. Common black, shiny, sand-size grains and small pebbles of phosphorite. Quartz sand is very fine to medium ......................18'6" (From 227'6" to 246') Spl. 40 Channel sample of impure carbonate sediments. oMuch of the carbonate material in the Hawthorn Formation is dolomite. No attempt was made in this study to distinguish between calcic limestone, dolomitic limestones, or dolomite. In most cases the various types of lime- stones and dolomites are simply referred to as carbonate beds. The reader is referred to the work of Espenshade and Spencer (1968) for descriptions of the carbonate beds of the Hawthorn Formation. BUREAU OF GEOLOGY 28 Impure carbonate bed. Contains much quartz sand and some insoluble clay. Light gray to gray. Firm. A phosphate zone. Sand-size grains and small pebbles of black phosphorite are abundant. This zone is similar to overlying and underlying beds except for a higher content of phosphorite ....16'6" (From 246' to 262'6") Spl. 41 Channel sample of carbonate bed. 27 Impure carbonate bed or mixture of carbonate, quartz sand, and insoluble clay. Light gray. Firm. Common black phosphorite, mainly of sand size but some of small pebble size. Quartz sand is very fine to medium ............................17'0" (From 262'6" to 279'6") Spl. 42 Channel sample of sediments. 26 Mixture of quartz sand, carbonate, and insoluble clay. Dark Gray. Firm but soft. Black shiny grains and small pebbles of phos- phorite occur throughout the sediments. The phosphorite content increases from a depth of 290 feet to the base of the bed. Quartz sand is fine to coarse. These are the first Hawthorn sediments en- countered that were so soft they could be cut with a knife while sampling ....................................15'9" (From 279'6" to 295'3") Spl. 43 Channel sample of sediments from 279 feet 6 inches to 295 feet 3 inches. 25 Mixture of quartz sand, carbonate, and insoluble clay. Gray. Firm With soft zones. Black grains of phosphorite are common. Quartz sand is fine to coarse .........................................8' (From 295'8" to 803'6") Spl. 44- Channel sample of mixture of quartz sand, carbonate, and insoluble clay. 24 Impure carbonate bed. Contains much quartz sand and some insoluble clay. Light gray. Rock- like. Common shiny grains of black phosphorite. REPORT OF INVESTIGATION NO. 84 These sediments grade into underlying materials ........9'3 (From 303'6" to 312'9") Spl. 45 Channel sample of sediments. 23 Impure quartz sand or mixture of quartz sand, carbonate, and insoluble clay. Light gray. Quartz sand is very fine to medium. Fine black phosphorite is common ...............................4'3" (From 312'9" to 317') Spl. 46 Channel sample of sediments. 22 Insoluble clay. Contains much carbonate and some quartz sand. Dark gray. Clay is banded. A few sand-size grains of black phosphorite ..............8'9" (From 317' to 325'9") Spl. 47 Channel sample of dark gray clay. 21 Mixture of insoluble clay, carbonate, and quartz sand. Dark gray to light gray. Shiny black phosphate particles are common. Quartz sand is very fine to fine ....... ............. 13'3" (From 325'9" to 339') Spl. 48 Channel sample of mixture of clay, car- bonate, and quartz sand. 20 Mixture of quartz sand, insoluble clay, and car- bonate. These sediments are cut by stringers of more nearly pure carbonate. Gray to light gray. Shiny black phosphorite, mostly of sand-size, is abundant. Quartz sand is coarse to fine .......................................... (From 339' to 347') Spl. 49 Channel sample of sediments. 19 Mixture of quartz sand, carbonate, and insoluble clay. Light gray. Firm and rock-like. Shiny grains of black phosphorite are common. Quartz sand is fine to coarse ......................................20'0" (From 347' to 367') Spl. 50 Channel sample of rock-like mixture of sand, carbonate, and clay. 18 Quartz sand with disseminated carbonate and in-' soluble clay. Dark olive to gray. Sediments are much softer than those of overly- ing bed. Sand-size, black phosphorite is common. Phos- BUREAU OF GEOLOGY phorite increases markedly at a depth of 872 feet. Quartz sand is very fine to medium ................................5'0" (From 867' to 372') Spl. 51 Channel sample of Unit 18. 17 Impure carbonate bed or mixture of carbonate, quartz sand, insoluble clay, and phosphorite. Light gray to gray. Firm. The phosphorite occurs as black, sand-size grains and as small pebbles. Quartz sand is coarse to fine. Clay increases at a depth of 382 feet ...............'......10'O" (From 872' to 382') Spl. 52 Channel sample of impure carbonate bed. 16 Mixture of carbonate, insoluble clay, and quartz sand. Gray. Black grains of phosphorite are common. Pockets containing a mixture of quartz sand and phosphorite are present in the sediments. Quartz sand is very fine to coarse. Clay decreases at a depth of 386 feet ..........................4'" (From 382' to 386') Spl. 53 Channel sample of mixture of carbonate, clay, and quartz sand. 15 Impure carbonate bed or mixture of carbonate, insoluble clay, quartz sand, and phosphorite. Gray. Firm. The sediments in this interval are similar to the sediments in the interval from 872 feet to 882 feet. Phosphorite is abundant and occurs as shiny black, sand-size particles and small black pebbles. Quartz sand is fine to coarse ..........................................2'0" (From 886' to 388') Spl. 54 Channel sample of Unit 15. 14 Impure carbonate bed. Contains a high percentage of insoluble clay and a little quartz sand. Light gray to gray. Small lenses and stringers of relatively pure car- bonate cut the sediments. REPORT OF INVESTIGATION NO. 84 Locally the materials have the appearance of a breccia. Fine black phosphorite is disseminated through the sediments and concentrated with quartz sand in pockets. This impure carbonate rock grades downward into hard limestone or dolomite 'at 400 feet 9 inches ....... ..............................................................12'9" (From 388' to 400'9") Spl. 55 Channel sample of impure carbonate bed. 13 Impure carbonate bed. Contains insoluble clay and quartz sand. Gray. Hard and rock-like. Black grains of phosphorite are present and are especially abundant in the lower six inches of the sediments ............................... ....................... '0" (From 400'9" to 401'9") Spl. 56 Channel sample of carbonate bed. 12 Impure carbonate bed or mixture of carbonate and quartz sand. Light gray. Firm but soft. Common black sand-size grains and small pebbles of phophorite. Quartz sand is medium to fine. The interval from 401 feet 9 inches to 432 feet consists of intercalated zones of hard, massive, impure dolomite or limestone and softer zones consisting of a mixture of quartz sand, insol- uble clay, and carbonate. Black, shiny, sand-size grains and small black pebbles of phosphorite are present throughout the sediments. The hard, massive dolomites contain pockets filled with quartz sand, clay, and phosphorite. The losses in sampling in this interval are of the softer mixtures of sediments ................................6' (From 401'9" to 408') Spl. 57- Channel sample of a 2-foot core from Unit 12. 11 No recovery from this interval ............. .......... ........9'0" (From 408' to 417') 10 Very impure carbonate bed or a mixture of car- bonate and quartz sand. Light gray to gray. Soft. BUREAU OF GEOLOGY Black sand-size particles of phosphorite are com- mon. Quartz sand is medium to fine ............... ............................ 8'6" (From 417' to 425'6") Spl. 58 Channel sample of a 2-foot 6-inch core obtained from Unit 8. 9 Impure carbonate bed containing insoluble clay and quartz sand. Light gray to gray. Hard and rock-like. A few grains of black phosphorite are dissemi- nated through the sediments. Lenses consisting of quartz sand, insoluble clay, carbonate, and phosphorite are present in the carbonate bed .......................... ........ ..............6'6" (From 425'6" to 432') Spl. 59- Sample of representative chips of the hard carbonate bed. 8 Impure clay or a mixture of insoluble clay, quartz sand, and carbonate. Dark gray-green. Massive. A few grains of black phosphorite are present in the clay. Quartz sand is very fine. A 2-inch thick lens of hard limestone or dolo- mite is present at a depth of 434'3". This hard carbonate rock was not included in the sample taken of these sediments. Quartz sand increases at a depth of 441 feet...............9'0" (From 432' to 441') Spl. 60 Channel sample of impure elay. 7 Quartz sand with high content of insoluble clay and carbonate or a mixture of quartz sand, in- soluble clay, an'd carbonate. Gray. Some cross bedding is present. Occasional sand-size particles of black phospho- rite. Quartz sand is very fine ...............................................5'0" (From 441' to 446') Spl. 61 Channel sample of the mixture of quartz sand, insoluble clay, and carbonate. 6 Mixture of insoluble clay, silt, carbonate, and quartz sand. Greenish-black to black. REPORT OF INVESTIGATION NO. 84 Occasional sand-size grains of black phosphorite. Quartz sand is very fine to fine ...--....................--........16'0" (From 446' to 462') Spl. 62 Channel sample of sediments. 5 Impure carbonate bed. Contains much quartz sand. Gray. Hard and rock-like. Abundant impressions of mollusks. Phosphorite is disseminated through the sediments .- ......-------------............----------.................................. 8'6" (From 462' to 470'6") Spl. 63 Channel sample of impure carbonate bed. 4 Impure carbonate bed or mixture of carbonate, quartz sand, and insoluble clay. Light gray. Hard. Black sand-size particles of phosphorite are present. Quartz sand is coarse to fine .-..--...-...--... ...................11'6 (From 470'6" to 482') Spl. 64 Channel sample of impure carbonate bed. 3 Impure carbonate bed. Contains much quartz sand and some insoluble clay. Gray. Common sand-size grains and small pebbles of black phosphorite. Only 9 inches of sample obtained from this interval ........-..... ...-................................. 5'0" (From 482' to 487') Spl. 65 Sample of 9-inch core of carbonate bed. 2 Impure carbonate bed containing much quartz sand. Light gray. Hard and rock-like. Common mollusk impressions. There are numerous mollusk borings in the lime- stone or dolomite. Also, brecciatedd" zones are present. Some of the fragments in the breccia zones are limestone or dolomite masses, several of which apparently are mollusk-bored. The borings are filled with various combinations of quartz sand, clay, and phosphorite. Fine black phosphate grains and small phosphate pebbles are abundant .............. .--.........................5'0" (From 487' to 492') Spl. 66 Channel sample of carbonate rock. BUREAU OF GEOLOGY Limestone of the Ocala Group 1 Ocala Limestone. Pure. White to cream. The top of the limestone is mollusk bored or solution riddled and the borings or solution openings are filled with the overlying gray carbonate sediments ............................................1'0" (From 492' to 493') Spl. 67 Channel sample of Ocala Limestone. Total depth of hole ........................493'0" HIGHLAND DRILL HOLE NO. 27 NEI, SE14, Section 12, T. 4 S., R. 22 E., Baker County, Florida Approximately 312 Miles Slightly West of North of Highland Surface Elevation 191 Feet Thickness Unit Description In Feet & Inches Surface Sands 9 Quartz sand. White to gray to black. Gray to brown soil zone from land surface to depth of 3 feet 6 inches. The sands are black from 4 feet to 10 feet 6 inches and from 15 feet to 22 feet 6 inches. The black color is due to the presence of finely divided organic matter. Quartz sand is medium to fine ....................................22'6" (From land surface to 22'6") -This hole was drilled by the Bureau of Geology, Florida Department of Natural Resources. The drilling was completed June 26, 1974. Analyses of the samples are given in Tables 4 through 6, Appendix II. A specially de- signed core barrel was used in sampling the sediments penetrated in this drill hole. A high recovery of undisturbed samples was obtained. The inter- vals from which sediments were not recovered are indicated in the descriptions of the samples. REPORT OF INVESTIGATION NO. 84 Spl. 1- Channel sample of white to gray sur- face sand from land surface to depth of 1 foot 9 inches. Spl. 2- Channel sample of brown to gray sand from 1 foot 9 inches to 5 feet. Spl. 3 Channel sample from 5 feet to 10 feet. Spl. 4- Channel sample from 10 to 15 feet. Spl. 5 Channel sample from 15 to 20 feet. Spl. 6 Channel sample from 20 feet to 22 feet 6 inches. Moderate Brown Sand 8 Quartz sand. Moderate brown. Sand is medium to fine ................... ................. ....12'6" (From 22'6" to 35') Spl. 7 Channel sample of moderate brown sand from 22 feet 6 inches to 25 feet. Spl. 8 Channel sample from 25 to 30 feet. Spl. 9 Channel sample from 30 to 35 feet. ,Gray to Olive-Drab Clay Zone 7 Quartz sand. Yellow brown to white. Upper 3 feet are yellow brown; lower 2 feet are white. Sand is medium to very fine. A 3-inch zone of black sand is present from 37 feet 3 inches to 87 feet 6 inches ................................5'0 (From 35' to 40') Spl. 10 Channel sample of quartz sand. 6 Clayey sand. Tan to gray. Stringers or small lenses of sandy clay are present in the clayey sand. Wood fragments are common, especially from 43 feet 6 inches to 45 feet 3 inches. Quartz sand is very fine to medium ............--.................8'0" (From 40' to 48') Spl. 11 Channel sample from 40 feet to 42 feet 6 inches. Spl. 12- Channel sample from 42 feet 6 inches to 45 feet. Spl. 13 Channel sample from 45 feet to 48 feet. BUREAU OF GEOLOGY 5 Massive clay. Quartz sand is disseminated through the clay and also occurs in stringers cut- ting the clay. Dark gray to nearly black at top. Abundant wood fragments (reddish brown). A relatively large fragment (11/ inches across) occurs at a depth of 52 feet 3 inches ......................4'6" (From 48' to 52'6") Spl. 14 Channel sample of massive clay. 4N o recovery .................................................................... '0" (From 52'6" to 55'6") 3 Sandy clay to massive clay. Dark gray to olive- drab. The clay is dark gray on a fresh surface. In the lower part of the unit the gray color readily oxidizes to an olive-drab color. From 59 feet to 60 feet 6 inches the clay is mottled dark gray and olive-drab. Stringers and small lenses of quartz sand or clay- ey sand are present in the clay. These sandy sediments occur from: 55 feet 6 inches to 56 feet 9 inches 58 feet to 58 feet 9 inches 61 feet 6 inches to 63 feet 3 inches 64 feet 6 inches to 65 feet. Large wood fragments are present at a depth of approximately 56 feet. The quartz sand is very fine to medium ..................10'0" (From 55'6" to 65'6") Spl. 15-Channel sample from 55 feet 6 inches to 59 feet. Spl. 16 Channel sample from 59 feet to 60 feet 6 inches. Spl. 17 Channel sample from 60 feet 6 inches to 65 feet 6 inches. Quartz Sand 2 Quartz sand, loose. Gray. Quartz sand is very fine to coarse. The coarsest sand occurs from a depth of 81 feet 6 inches to a depth of 82 feet 6 inches. A small REPORT OF INVESTIGATION NO. 84 discoid quartz or quartzite pebble was noted in these coarse sands ................. ............................55'0" (From 65'6" to 120'6") Spl. 18 Channel sample from 65 feet 6 inches to 69 feet 6 inches. Spl. 19 -Channel sample from 70 to 74 feet 6 inches. Spl. 20 Channel sample from 75 feet to 80 feet except for 6-inch interval from 74 feet 6 inches to 75 feet and a 6-inch interval from 77 feet to 77 feet 6 inches. Spl. 21 Channel sample from 80 to 85 feet. Spl. 22 Channel sample from 85 to 90 feet. Spl. 28 Channel sample from 90 to 95 feet. Spl. 24 Channel sample from 95 to 100 feet. Spl. 25 Channel sample from 100 to 105 feet ex- cept for a 1-foot interval from 102 feet 6 inches to 103 feet 6 inches. Spl. 26 Channel sample from 105 to 110 feet ex- cept for a 1-foot interval from 107 to 108 feet. Spl. 27- Channel sample from 110 feet to 112 feet combined with spot samples from 112 feet to 115 feet. Spl. 28 Channel sample from 115 to 118 feet. Quartz sand, loose. Gray. Sands contain fragments of white mollusk shells. These shells are especially noticeable from a depth of 120 feet 6 inches to a depth of 124 feet. Quartz sand is medium to fine ........................................6'6 (From 120'6" to 127') Spl. 29 Channel sample from 120 feet 6 inches to 124 feet of loose sands with white shell fragments. Spl. 30 Channel sample from 125 to 127 feet. Total depth ................................127'0" REPORT OF INVESTIGATION NO. 84 APPENDIX II Characteristics of Highland No. 1 and Highland No. 2 Sediments BUREAU OF GEOLOGY TABLE I Highland Drill Hole #1 SE4. NEI, Section 25, T. 4 S.. R. 22 E., Bradford County, Florida Approximately I Mile Northwest of Highland Surface Elevation 202 Feet Intoluble Residue Coarse Fine Heavy Silt Silt and Soluble Minerals Total Depth Quartz (-230 mesh Clay and P 0 F2 0 (1/8 to 1/16 Heavy in Feet Sand +325 mesh) (-325 mesh) Organic 2 5 2 3 mm Fraction) Minerals sol. snd Inches In Z In t In 2 In 2 in 2 i n % In 2 in 2 Gray to Moderate Brown Surface Sands (Elv. 202 Ft.) I 5' I 4.11 1.28 3.61 1.00 0.51 1.26 .66 1.44 2 51 o' 97.27 0. 1.20 1.20 0.32 1.2 1 .t 2.62r ) io' i 0.08 11.4 0.40 0.27 io 17.33 2.3r 15_S' 20' ~9.62 0.22 2.29 5.88 0.39 1.33 12.17 2.72 5 20' 25' 95.19 0.92 3.89 0.00 0.29 1.16 18.12 4.' 3 b 25' 30' 9436 0.66 .2 2. 0.29 .0T 2761 4.20 o30' 35' 96._3 o0. 1.88 1.50 0.2 7 72 7- W'- 0o' 8.24 0.16 1.00 0.60 0.10 1.2 21.88 1.73 9 o'- .76 0.16 o .29 1.79 0 .?3 6 2 .12 1. - 10 5a 0' 5.71 0.20 2.90 1.20 0.15 1.58 12.2 0.4 II s 5 5'" 0.3 0.60 3.5 0.15 3.3L8 5.18 0.651 Drab to Olive-Green Clay Zone Elev. 149 Ft. 2 i 5'"- 88.50 80 2.80 0.4 0.1 0. 1.3 1.62 1 5'6"- 61' 8 5 3.47 7.68 0.80 0.17 0.75 0.74 0.72 I- 61' 62'3" 31.4 .7 62.96 1.90 0.20 IS 62'3- 63 90.4 3.76 5.11 0.70 O.i 1.22 0.86 0 lb- 6 6 82.9t 2.71 12.77 1.60 0.27 7.48 1.01 ~ 0.7 17 6f'6"- 67 52.32 .66 39.80 3.22 0.22 2.01 1.26 0.4 I" r 67 O7' 61.5I 15.07 20.82 2.60 0.22 1.12 1 0.77 0.1 19 70' 75, 94.55 1.24 4.20 0.00 0.7= 3 = ..2 .63 OV47 20 75' t7' 98.98 0.02 -- .0 0.00 1.46 0.91 1=.IT 0.27 211 7' 77'9" 25.47 Ii.i 56.92 6.17 0.2 67 -- 22 77''9- 78'3" 83.43 8.13 8. ~ 0.00 0.19 1.04 1.26 0.70 2 78'"- s' 6.) ).00 .o0 .68 0.27 1.T7 0.70 .26 S -88'6 26.08 .76 56.87 7.8 1.7 1.1 0.59 0.06 2. 88'6"- 96'" 71.06 10.99 16.13 1.81 1.7 1.40 0.79 o.S1 26 4 -10o1'" 1.62 5.73 72.8 6.77 0. 1.0 1.24 0,1 z7 ol O- "-107'6" 21.33 5.52 64.06 9.09 0.56 1.52 1.32 0.28 '28 10'6"-110' 55.53 i3.85 25.54 5.09 0.32 1.1 1.26 0.58 2' 110 -I5' 76.3 6.T3 1i.11 4.20 1.71 .8 l.p 0.93 _n 115 -121'9" 64.971 3.04 24.59 7.40 0.24 1.i5 2.32 0.51 Shell Bed (Elev. 80 Ft.) 32I 122'6"- 3. 6.02 I 0.62.95 0 1 2.87 I 0.4T 132' -I 4' No Sample 12 140' -1 65. I 0.34 .99 29.22 I 0.2 I 0.84 3.27 0.38 II _Q' -152' 4.8 0.24 3.99 51.29 0.29 0.70 6.21 0.2 Gray Quartz Sand (Elev. 50 Ft.) 3 : iS2 -T"7' 9 .77 0.20 4.22 I 3 0.1 10.41 0.60 .15 0.3 1S7' -180' No Sample Fossilliferous Limestone (Elev. 22 Ft.) -1- 180' -16' Ii.31 0.1 10.46 78.09 0o.27 0.6 .76 -- 6 186' -202'3" 0.40 0.12 5.13 .35 0.32 1.25 6.22 - i 202')"-212'6" 1.52 0.08 4.30 94.11 0.32 0.31 I 1.42 0.03 =3 212'6"-215'6" 0.9 0.08 23.52 7.46 0.2 0.99 -- '3t 21t6"-227'6" .8 0. 0.0 .0 0 0.66 0.) .60 0.05 Hawthorn Formation Elev. -26 Ft. "40 221'6"-246' 37.93 0.26 .80 53.01 2.66 0.7 1.26 0.1 "1 2I 6 -262'6" 28. 3 0.16 7.67 63.84 7.93 1.14 1.89 0.16 7T2 262'6"-279'6" 8.44 0.32 i 53.13 0.9 .13 W 279 '-29 .91 0.40 20.26 2.4 1.2 2.96 0.18 4 2 -o3. 78.8 o 5.18 45.93 3.7 T 2.03 0. 1 0'6"- 12'9" 34.17 .8 .98 60.67 3.34 0.2 .2 0. 3t2z'9-17 5i.02 0.46 1- 3.7 53.20 0. 5 0.92 0.26 317" -125-6'3" .t3 1.88 _63-96 27.23 .8tT80 0. 32 0i-0 _. 2 2 . S 325' 9-339' 7.20 0.2 .6 .75 0 1.35 O.07 79 339 W -37 30.78 0.24 20.61 48.38 =9.=59 .4 .0 O 47' -367' .k 7.17 44.93 1Jt 2.0794 1.35 0.10 REPORT OF INVESTIGATION NO. 84 TABLE 1 (Continued) Insoluble Residue Coarse Fine Heavy Depth Quartm (-230 mash Clay and p 1 Fe (1/8 to 1/16 Heavy in Feet Sand +325 mesh) (-325 mesh) Organic 2 5 2) mm Fraction) Minerals Spl. and Inches In % In t n In in in t In In t 1 6' 1 72 71.29 2.46 11 .T-= '. 7 = .9 0.7 -- T72- 21 .60 0.20 S3 9 0.- 2.8 0.1 32. -36 T 0.22 40. 1 _M7-06- 2 20.10 0.0 S.6 8 0.10 40 019.-402 1; 9 2 o.8 0.7 F W.7 f7.17 0.2. .0j 01-O' 169 22 2 _3 _0. 'Ocala Lim e No Samlstoe e 11 -2 .2- 0.0 0.20 .02 0. 0.2 the percentage of the original sample consisting of quartz and heavy- 60 1 *2' -406 ?-8 22. 1 4..2 1 ,69.20 1 1,S 0070 06. 3 421T -102' ./1,42 2.L B s ~ 0.2092 0,1 I 45rZ' 70'G" -.92 O.14 2.30 1 577.92 -.50 0.7 3 6.32 Ocala Limestone (Elev. -290 Ft.) 67 1492' -493' I 0.22 I 0.02 I 0.20 I 99.02 10. 11. 1 1.25 I "" 8The value listed under the insoluble residue as the per cent quartz sand is the percentage of the original sample consisting of quartz and heavy- mineral sand. The figure given under the coarse silt column is the per cent of the original sample consisting of sediments that passed through a 230-mesh screen and were retained on a 325-mesh screen (62 microns to 44 microns). The per cent fine silt and clay represents that part of the original sample consisting of insoluble sediments that passed through a 325-mesh screen (-44 microns). Because of techniques used in separa- tions, some of the finely divided organic matter present in the surface sands (Spls. 1-11) may be recorded in the figure for fine silt and clay. The percentage figure given under the heading "Soluble and Organic" reflects mainly finely divided organic matter in the surface sands (Spls. 1-11) and carbonate and phosphate content in all samples beneath the surface sands (Spls. 12-67). The PuOn and Fe2Oi values are the percent- ages of POn and FeO.: in the original samples. The value for the % to 1/10 mm heavy minerals is the per cent of the to 1/16 mm fraction of the sediments consisting of heavy minerals. The value given for the total per cent heavy minerals is the per cent of the original sample consisting of heavy minerals. The values for the heavy minerals do not include phos- phorite, mica, pyrite, or iron concretions. BUREAU OF GEOLOGY TABLE 2 Highland Drill Hole #1 Mechanical Analyses of Quartz Sand Extracted from Sediments Percent of Quartz Sand Retained on Mesh Mean Mean Quartz 10 18 35 60 120 230 Grain Sand (4 to (2 to (1 to (1/2 to (1/4 to (1/8 to Size ISp. in % 2 mm) 1 mm) 1/2 mm) 1/4 mm) 1/8 mm) 1/16 mm) In mm Gray to Moderate Brown Surface Sands 1 94.11 0.04 .13 5. 26.77 11.24 0.32 2 97-27 0.04 5.99 0.32 33.92 9.73 0.31 3 98.T 2 0.04 4.86 540 31.01 5.69 0.32 4 91.62 3.6 2.87 26.0 0 0.32 5 95.19 0.04 7 2.57 5. 0.30 6 94.36 0.1 12.2 .2 21. . 7 9.43 0.0 8.12 2.84 0.3 3 98.24 o 0.12 8.80 527.35 5.08 0. 9 94.76 0.06 9.10 7.7 20.00 .09 0. 10 95.71 0.10 3.53 23.64 4.07 0.35 11 95.45 0.06 9.19 62.01 23.66 5.0 0.35 Drab to Olive-Green Cla Zone 12 88.50 0.45 4.05 11.78 .72 0.2 13 88.05 0.32 2.60 11.55 53 0.11 14 31.49 0.70 5.54 1 8 80.5 0.13 15 90.43 0.02 1.13 11.87 21.25 .7 0.15 15 82.91 0.02 1.16 12.18 2 64.81 0.16 17 52.32 0.04 1.73 16.71 25.3 56.17 0.18 I 61.51 0.78 8.01 7.97 2 0.13 19 94.55 7.33 67.86 21.4 3.39 0.3 20 98.98 0.02 12.27 73.81 11.7 1.93 0.39 21 25.47 0.08 1.02 8.5 15.3 74.69 0.14 22 -83.43 0.07 0.36 3.78 2.95 2.08 40.76 0.23 23 46.31 0.26 0.73 7.9 8.60 83.02 0.13 24 26. 0.46 8.11 86.00 0.12 25 71.06 0.17 1.50 7.07 13.22 78.04 0.14 26 1.62 0.14 1.09 8.04 12.13 78.61 0.14 27 21.33 0.28 1.22 9.84 13. .8 0.15 28 55.53 .04 1.47 2.37 8.98 87.14 0.12 29 76.36 0.24 3.46 18.72 29.9 47.52 0.20 30 64.97 0.77 6.74 23.85 38.86 29.78 0.25 Shell Bed 31 36.42 | 0.77 7.28 129.38 1 42.72 19.86 I 0.28 No Sample for 8-foot Interval 32 65-46 0.64 0.52 13.07 56.83 17.46 11.49 0.38 33 47.48 1.84 2.83 19.83 57.87 12.61 5.02 0.49 Gray Quartz Sand 34 91.77 .83 I 12.99 I 46.13 I 35.19 I 4.86 I 0.35 No Sample for 23-foot Interval (Material similar to Spl. 34) Fossiliferous Limestone 35 11.31 1.94 2.82 14.44 54.23 20.25 6.43 0.46 36 0.40 4.87 15.03 20.10 24.9 .07 0.34 37 1.52 1.32 .58 18.42 27.63 46.05 0.23 38 0.94 6.38 17.02 23.40 53.19 0.21 39 4.4 0.45 3.13 27.23 57.14 12.05 0.25 REPORT OF INVESTIGATION NO. 84 TABLE 2 (Continued) Percent of Quartz'Sand Retained on Mesh Mean Quartz 10 18 35 60 120 230 Grain Sand (4 to (2 to (1 to (1/2 to (1/4 to (1/8 to Size Spi. In % 2 mm) 1 mm) 1/2 mm) 1/4 mm) 1 1/8 mm) 1/16 mm) In mm Hawthorn Formation 40 37.93 0.21 2.43 15.30 47.20 34.86 0.20 Wl 28.33 40 ~ 6 23.98 3.66 17.51 0.25 42 8.4 0.65 18.74 .19 27.54 0.23 3 6.91 1.62 1121 42.04 3.79 8.34 0.36 4 8.78 .1 2.00 10.38 47.10 .6 .76 0.36 45 34. 7 0.82 21.05 .7 21.17 7.00 0.40 46 51.02 0.12 1.99 11.72 50.94 35.23 0.1 47 6.93 0.87 2.02 3.76 8.38 897 0.14 S 21.20 0. 0.56 3.8 29.14 6.5 0.13 S 30. 0.3 30.01 44.0 1 2.65 0.55 50 7.46 0.21 1.22 15.03 59.24 16.2 8.06.40 S71.29 0.11 29.4 18.26 4.3 0.22 52 7 01 52 34.60 1.33 2594 5.66 14.9 4.09 0.45 53 10.21 0.78 10.18 40.90 28.18 19.9 0. 1 54 20.72 -0.8 10.72 48.02 3.82 6.76 0.3 55 2.57 2.34 .69 15. 32.03 45.31 0.23 56 6.97 1.12 12.08 56.7 20.22 .80.37 57 46.64 0.51 p.8 .87 26.0 3.760.36 No Sample or 9-foot Interval 58 45.30 0.66 .1 2. .15 0.6 59 12. 0.16 10 2.6 1 8.25 0.2 60 22.12 0.09 0. 1.62 7.0 90.7 0.11 561 s0.226 97 0.0 012 2 0.10 62 13.5 0.72 4.73 6.74 13.92 7.8 0.17 3 19.60 .6 o.o 4. 0.07 0. 4 40.72 0.64 23.24 7.35 16.07 2.70 0.43 65 29.60 0.3 .5 21.8 2.59 18.53 12.26 0.45 66 14.63 __3.69 .2 22.98 14.09 0.31 Ocala Limestone 67 0.22 18.18 36.36 27.27 18.18 0.3 BUREAU OF GEOLOGY TABLE 3 Highland Drill Hole #1 Percentages of Selected Heavy Minerals in 1/8 to 1/16 mm Fraction Leucoxene Ilmenite Epidote Garnet Hornblende SpT. in % in % in % in % in % Gray to Moderate Brown Surface Sands 1 31.86 13.88 0.00 0.00 0.00 2 12.16 40.12 0.00 0.00 0.00 3 2.65 50.00 0.00 0.00 0.00 1.21 58.18 0.00 0.00 0.00 5 5.66 52.52 0.00 0.00 0.00 6.15 44.00 0.00 0.00 0.00 7 1.45 58.26 0.00 0.00 0.00 S 1.46 45.91 0.00 0.00 0.00 9 1.21 49.70 0.00 0.00 0.00 10 2.02 49.16 0.00 0.00 0.00 11 3.52 48.78 0.00 0.00 0.00 Drab to Olive-Green Clay Zone 12 14.50 29.91 0.00 0.00 0.00 13 11.50 22.36 0.00 0.00 0.00 1 11.56 35.03 0.00 0.25 0.00 15 13.14 23.43 2.06 1.04 0.00 16 10.03 36.05 1.57 0.00 0.00 17 6.69 38.80 0.00 0.94 1.00 1_ 9.70 36.45 0.00 1.07 0.00 19 0.70 50.35 0.00 0.35 0.00 20 1.89 53.14 0.00 1.10 0.00 21 6.59 31.78 1.16 0.67 0.39 22 4.99 46.26 0.00 2.15 0.55 23 7.62 37.09 0.00 1.03 0.00 24 8.89 33.89 0.00 0.88 0.00 25 2.38 38.44 3.06 1.79 0.00 26 2.92 24.45 17.15 2.11 0.00 27 2.29 25.14 30.86 0.79 0.29 8 0.99 25.83 30.79 0.98 0.99 29 2.90 27.54 3.55 1.00 1.16 30 2.17 23.91 26.09 2.01 2.48 Shell Bed 31 1.28 33.01 19.55 0.33 2.24 No Sample S32 1.03 24.32 30.2 1.17 6.51 33 0.67 24.58 24.24 0.61 3.37 Gray Quartz Sand 34 1.21 28.79 I 15.45 1.40 | 6.06 No Sample Fossiliferous Limestone 35 2.78 21.94 27.22 0.26 0.83 36 2.17 7.61 16.30 0.00 0.00 37 1.35 24.24 27.27 1.74 0.35 38 0.00 17.14 28.57 3.57 0.00 39 1.80 16.19 32.37 5.05 0.36 REPORT OF INVESTIGATION NO. 84 TABLE 3 (Continued) Leucoxene llmenite Epidote Garnet Hornblende Spl. in % in % in % in % in % Hawthorn Formation 40 0.62 11.15 25.39 6.56 0.00 41 1.36 21.77 22.79 10.12 0.00 42 1.58 31.96 16.77 5.88 0.00 43 3.24 27.18 11.65 9.25 0.00 44 1.32 29.80 17.22 4.08 0.00 45 2.55 35.13 9.63 4.11 0.00 46 0.85 25.35 6.48 6.94 0.00 47 0.54 20.16 3.00 4.93 0.00 48 1.55 25.47 1.86 6.12 0.00 49 2.43 34.95 3.3 4.4 0.00 50 1.55 36.65 5.28 4.56 0.00 51 3.94 38.48 5.76 5.70 0.00 52 1.34 29.77 7.36 7.43 0.00 53 1.19 43.32 1.78 6.61 0.00 54 1.24 1.49 3.10 .38 0.00 55 2.15 30.77 4.92 3.27 0.00 56 2.27 33.50 12.59 3.28 0.00 57 2.45 33.03 9.79 5.47 0.00 No Sample 58 2.32 36.81 9.86 6.95 0.00 59 2.77 50.46 1.54 4.96 0.00 60 3.00 5.67 1.33 5.72 0.00 61 3.83 45.05 3.19 4.61 0.00 62 7.57 37.85 3.47 5.25 0.00 63 1.56 19.31 19.31 21.27 0.00 64 1.58 32.91 2.22 23.4 0.00 5 4.67 41.33 1.33 14.52 0.00 66 0.62 27.08 8.00 14.51 0.00 Ocala Limestone 67 1.05 15.79 5.26 4.76 I 0.00 Per cent of the 1/8 to 1/16 mm heavy-mineral fraction that consists of leucoxene. BUREAU OF GEOLOGY TABLE 4 Highland Drill Hole "2 NE, SEk, Section 12, T. 4 S., R. 22 E., Baker County, Florida Approximately 31 Miles Slightly West of North of Highland Surface Elevation 191 Feet Insoluble Residue Coarse Fine Heavy Silt Silt and Soluble Minerals Total Depth Quartz (-230 mesh Clay and (1/8 to 1/16 Heavy in Feet Sand +325 mesh) (-325 mesh) Organic mm Fraction) Minerals Sol. and Inches in % in % in % in % in % in % Gray to Moderate Brown Surface Sands (Elev. 191 Ft.) S 0 1'9" 95.15 1.03 2.52 1.31 11.54 2.32 S 1'9"- 5' 92.97 0.94 .19 1.90 13.58 2.20 3 5' 10' 97.14 0.46 1.20 1.20 22.06 4.43 4 10' 15' 98.46 0.64 0.40 0.50 30.33 3.38 5 15' 20' 91.43 0.18 6.29 2.10 34.64 4.30 6 20' 22'6" 91.70 0.40 5.40 2.50 29.16 4.02 7 22'6"- 25' 96.22 0.38 1.20 2.20 32.88 4.75 T 25' 30' 96.60 0.10 1.20 2.10 34.40 .1 9 30' 35' 97.17 0.22 1.10 1.50 41.08 4.38 Gray to Olive-Drab Clay Zone (Elev. 156 Ft.) 10 35' 40' 92.44 3.46 2.50 1.60 4.75 2.86 11 o' 42'6" 83.04 3.89 9.18 3.89 1.19 0.90 12 2' 6- 45' 86.12 5.18 8.60 0.10 1.33 0.76 13 45' 48' 90.76 2.85 5.89 0.50 1.98 0.87 14 4' 52'6" 37.69 5.40 51.42 5.50 1.82 0.36 15 55'6"- 59' 50.20 14.44 30.65 4.71 2.66 0.81 a6 59' 60'6" 19.31 7.6 70.56 2.50 1.19 0.36 17 60'6"- 65'6" 64.56 8.16 26.37 0.90 1.23 0.54 Gray Quartz Sand (Elev. 125 Ft.)_____ id 65'6"- 69'6" 89.38 3.39 6.72 0.50 2.02 . 19 70' 74'6" 92.32 1.89 5.28 0.50 2.19 0.91 20 75' 80' 94.74 0.4 .3 0.40 2.65 0.77 21 80' 85' 93.12 0.40 .79 1.70 4.23 0.5 22 85' 90' 95.74 0.38 3 0.50 4.50 0.90 23 90' 95' 96.90 0.40 2.10 0.60 .05 0.76 2- 95' -100' 96.40 0.40 2.70 0.50 3.33 0.88 25 100' -105' 96.00 0.58 1.73 1.9 3.32 0.70 ?6 105' -110' 99 044 1. 1.10 3.13 0.82 ZI 110' -115' 98.00 0.24 0.96 0.80 3.93 0.46 2 115' -118' 94.91 0.2 2.25 2.59 .38 0.52 29 120'6"-124' 94.25 0.14 1.92 3.69 5.94 0. 30 125' -127' 91.49 0.20 3.13 5.18 5.29 0.72 REPORT OF INVESTIGATION NO. 84 TABLE 5 Highland Drill Hole #2 Mechanical Analyses of Quartz Sand Extracted from Sediments Percent of Quartz Sand Retained on Mesh Mean Mean Quartz 10 18 35 60 120 230 Grain Sand (4 to (2 to (1 to (1/2 to (1/4 to (1/8 to Size Sp1. in % 2 mm) 1 mm) 1/2 mm) 1/4 mm) 1/8 mm) 1/16 mm) in mm Gray to Moderate Brown Surface Sands 1 95.15 0.02 4.53 61.96 24.06 9.44 0.32 2 92.97 0.02 5.35 60.04 25.13 9.5 0.32 3 97.14 0.12 4.89 59.31 28.32 7.36 0.32 4 98.i46 0.02 .36 52.50 33.38 9.74 0.30 5 91.43 0.02 6.1 62.02 26.05 5.77 0.33 6 91.70 0.02 4.82 59.06 27.49 8.61 0.32 7 96.22 0.08 6.46 57.06 27.49 8.91 0.32 8 96.60 0.08 6.64 65.4 23.51 4.35 0.3 9 97.17 __ 0.02 5.53 62.48 25.01 6.96 0.33 Gra to Olive-Drab Clay Zone 10 92.44 0.11 7.16 45.80 21.58 25.35 0.29 11 3.0 0.62 13.12 33.77 52.49 0.17 12 86.12 0.02 2.95 23.6 24.45 8.90 0.20 13 90.76 0.02 0.33 16.93 48.42 34.30 0.19 14 37.69 0.05 1.13 20.53 31.23 7.06 0.19 15 50.20 0.04 1.00 28.77 26.54 43.66 0.21 16 19.31 0.31 1.86 18.94 19.4 59.42 0.18 17 64.56 0.65 3.82 15.47 23.21 56.85 0.19 Gray Quartz Sand 18 89.38 0.63 6.40 23.27 43.79 25.92 0.25 19 92.32 1.08 .67 20.88 44.55 2.82 0.25 20 94.74 0.91 1.82 9.69 23.92 47.37 16.30 0.32 21 93.12 0.71 2.74 12.43 20.18 52.86 11.08 0.34 22 95.48 0.73 6.03 22.54 58.75 11.95 0.26 23 96.90 0.58 6.41 34.37 51.59 7.05 0.29 24 96.40 0.10 1.43 15.79 64.12 18.56 0.21 25 96.00 0.15 2.74 2_i.9 53.44 18.69 0.23 26 96.99 0.16 3.95 36.38 44.12 15.39 0.27 27 98.00 0.0 0.41 7.23 59.87 26.71 5.7 0.34 28 94.91 0.08 0.54 6.87 67.57 19.28 5.66 0.36 29 94.25 0_.44 4.06 64.14 25.91 5.44 0.33 30 91.49 0.11 0.22 3.55 49.04 38.99 8.09 0.30 BUREAU OF GEOLOGY TABLE 6 Highland Drill Hole #2 Percentages of Selected Heavy Minerals in 1/8 to 1/16 mm Fraction Leucoxene Ilmenite Epidote Garnet Hornblende SpT. in % in % in % in % in % Gra to Moderate Brown Surface Sands 1 29.74 18.30 0.00 0.00 0.00 2 24.84 26.45 0.00 0.00 0.00 3 15.87 41.32 0.00 0.00 0.00 4 6.98 7.88 0.00 0.00 0.00 5 0.00 580.000.00 0.00 0.00 6 2.02 60.69 0.00 0.00 0.00 7 1.54 57.85 0.00 0.00 0.00 8 0.00 55.22 0.00 0.00 0.00 9 0.32 63.46 1.60 0.00 0.00 Gray to Olive-Drab Clay Zone 10 6.10 45.06 0.58 0.00 0.00 11 17.42 30.97 0.00 0.00 0.00 12 21.49 17.01 0.30 0.00 0.00 13 5.31 48.01 0.00 0.27 0.00 14 3.36 41.97 0.00 1.51 0.00 15 4.84 46.45 0.00 0.62 0.00 16 7.52 39.47 0.38 1.13 0.38 17 1.23 75.00 4.32 0.68 0.00 Gray Quartz Sand 18 3.08 34.93 22.26 1.23 0.00 19 1.96 26.80 22.88 2.67 0.33 20 1.64 29.67 23.13 1.52 0.23 21 1.88 30.63 28.13 1.16 2.81 22 0.68 23.05 18.64 0.95 3.05 23 1.28 15.38 27.44 1.83 5.38 24 2.10 24.32 23.72 0.99 2.10 25 0.32 26.03 20.32 2.27 4.13 26 1.26 25.55 24.92 1.43 3.47 27 0.96 19.61 21.5 0.95 6.09 28 0.88 31.76 25.29 1.30 3.24 29 1.99 29.90 28.90 1.14 2.33 30 0.92 29.05 20.80 1.15 3.98 REPORT OF INVESTIGATION NO. 84 APPENDIX III Characteristics of Surface Sands in Study Area BUREAU OF GEOLOGY TABLE 7 Analyses of Surface Sediments Collected in Vicinity of Green Cove Springs Ore Body Sample Sites Shown on Figure 4 Insoluble Residue Coarse Fine Heavy Silt Silt and Soluble Minerals Total Quartz (-230 mesh Clay and (1/8 to 1/16 Heavy Mean Grain Sand +325 mesh) (-325 mesh) Organic mm Fraction) Minerals Size of Quartz So!. in in % in % in % in % in % Sand in mm I 90.13 1.66 7.81 0. 1.87 0.88 0.15 2 1 96.70 0.50 2.80 0.00 5.93 1.66 0.20 S3 95.98 1.02 3.00 0.00 1.89 0.65 0.18 4 87.69 2.32 8.69 1.30 1.23 0.69 0.15 5 90-51 2.20 6.69 0.60 1.44 0.68 0.15 36 94.85 0.86 4.30 0.00 1.89 0.75 0.17 7 94.39 0.72 4.80 0.10 1.63 O.4 0.17 a 93.73 0.88 5.09 0.30 1.75 0.65 0.17 9 95.90 0.80 3.30 0.00 1.47 0.75 0.18 il 95.21 0.5 .02 0.20 1.57 0.70 0.17 11 95-38 0.82 3.50 0.30 3.18 1.11 0.15 12 90.34 i 0.26 6.60 2.80 4.50 1.30 0.18 13 85.54 1 1-78 11.38 1.30 1.18 0.51 0.17 i 1 95-39 I 0.80 3.51 0.30 1.65 0.36 0.18 15 90.97 1 1.44 6.50 1.10 2.04 .7 0..17 16 93.23 1 0.54 4.62 1.61 3.42 1.12 0.17 17 93.68 I 1.12 4.70 0.50 2.95 1.10 0.17 13 1 92.50 1 0.72 6.18 0.60 1.67 0.58 0.18 l 19 94-75 0.24 4.01 1.00 1.65 0.3 0.18 20 95.54 1-36 3.10 0.00 1.86 0.71 0.16 21 93.72 0.98 5.00 0.30 2.77 1.09 0.16 22 9.21 1.68 4.01 0.10 6.99 2.61 0.17 23 90.30 0.50 6.80 2.40 1.58 0.42 0.17 24 97.61 0.58 1.81 0.00 1.92 0.77 0.19 25 91.08 2.43 5.49 1.00 1.41 0.49 0.16 26 98.26 0.64 1.10 0.00 1.22 0.52 0.16 27 97-4 0.42 1.80 0.30 6.8 2.15 0.17 zi 2 95.45 0.76 3.29 0.50 5.02 1.54 0.16 29 95-87 0.62 2.50 1.00 1.07 0.56 .1 30 897 1.04 7.78 1.40 1.31 0.63 0.15 1 31 95.80 1.00 2.80 0.40 2.13 0.72 0.17 S32 94.41 1.80 2.99 0.80 0.80 0.50 0.14 33 95.79 0.62 3.50 0.10 1.44 0.47 0.17 34 94.73 0.98 4.09 0.20 1.20 0.;7 0.16 35 96.60 0.8 2.50 0.10 2.01 0.56 0.22 36 9-88 0.32 2.50 0.30 1.79 0.61 0.17 i37 96. 0-56 2.20 0.60 2.25 0.8 0.19 S3 97.15 0.84 1.60 0.I0 1.38 0.4 0.18 REPORT OF INVESTIGATION NO. 84 TABLE 8 Mechanical Analyses of Surface Sands Collected in Vicinity of Green Cove Springs Ore Body Percent of Quartz Sand in Various Sand Fractions Mean Approximate Quartz Granules Very Coarse Coarse Medium Fine Very Fine Grain Elevation Spl. Sand (4 to (2 to (1 to (1/2 to (1/4 to (1/8 to Size in No. in % 2 mm) 1 mm) 1/2 mm) 1/4 mm) 1/8 mm 1/16 m) in mm Feet 1 90.13 0.02 0.09 2.80 55.32 41.77 0.15 92 2 96.70 0.04 1.32 14.91 55.16 28.56 0.20 87 3 95.98 0.29 1.54 8.60 55.63 3.94 0.18 35 4 87.69 0.02 0.05 2.48 47.95 49.50 0.15 101 5 90.51 0.09 2.7 51.41 45.63 0.15 103 6 94.85 0.11 5.27 63.24 31.39 0.17 120 7 94.39 0.08 5.16 60.37 34.48 0.17 108 8 93.73 0.0 0.030 6.41 62.31 30-93 0.17 65 9 95.90 0.21 1.61 10.25 46.56 4138 0.18 17 10 95.21 0.06 0.76 8.19 52.86 38.12 0.17 22 11 95.38 0.04 2.87 63.61 33.48 0.15 93 12 90.34 0.13 7.00 67.12 25.75 0.18 118 13 85 54 0.02 0.21 7.54 54.20 38.03 0.17 71 14 95.39 0.02 0.15 7.31 66.22 26.30 0.18 11 15 90.97 0.09 .28 65.19 30.43 0.17 96 16 93.23 0.09 5.71 61.24 32.97 0.17 112 17 93.68 0.11 5.34 61.60 32.96 0.17 108 18 92.50 0.02 0.24 8.50 6.88 26.37 0.18 65 19 94.75 0.04 4.90 77.24 17.82 0.18 12 20 95.54 0.02 0.10 4.42 60.58 34.88 0.16 95 21 93.72 0.02 0.04 2.80 57.89 39.25 0.16 112 22 94.21 0.02 0.15 6.29 60.71 32.83 0.17 9 23 90.30 0.22 6.91 57.53 35.34 0.17 70 241 97.61 0.06 0.56 11.55 58.29 29.54 0.19 31 25 91.08 0.02 0.13 2.69 57.81 39.34 0.16 100 26 98.26 0.12 3.68 55.24 40.96 0.16 100 27 97.48 0.12 5.04 64.99 29.84 0.17 100 28 95.45 0.10 5.54 58.13 36.23 0.16 5 29 95.87 0.36 6.33 51.94 41.37 0.16 20 30 89.78 0.07 2.56 49.00 48.38 0.15 81 31 95.80 0.02 0.17 6.51 60.16 33.15 0.17 39 32 94.41 0.02 0.42 4.80 30.61 64.14 0.14 5 33 95.79 0.60 7.13 59.98 32.28 0.17 11 34 94.73 0.06 5.14 58.20 36.59 0.16 25 35 96.60 0.19 1.87 18.0 58.6 20.91 0.22 27 36 96.88 0.02 0.31 829 57.65 33.73 0.17 63 37 96.64 1.59 11.69 60.99 25.73 0.19 20 38 97.15 0.10 7.70 69.50 22.70 0.18 13 BUREAU OF GEOLOGY TABLE 9 Percentages of Selected Heavy Minerals in 1/8 to 1/16 mm Heavy-Mineral Fraction of Surface Sands Collected in Vicinity of Green Cove Springs Ore Body Leucoxene Ilmenite Epidote Garnet Hornblende Spl. in % in % in % in % in % 1 18.49 34.73 0.00 0.00 0.00 2 14.05 39.52 0.00 0.00 0.00 3 9.29 40.71 0.00 0.00 0.00 4 41.82 16.98 0.00 0.00 0.00 5 51.32 8.88 0.00 0.00 0.00 6 25.95 23.42 0.00 0.00 0.00 7 25.00 22.19 0.00 0.00 0.00 8 23.23 35.02 1.01 0.00 0.00 9 6.89 44.26 0.00 0.00 0.00 10 7.62 38.08 3.97 0.00 0.00 11 29.87 22.15 0.00 0.00 0.00 12 13.64 44.81 0.00 0.00 0.00 13 23.13 34.06 0.00 0.00 0.00 14 9.63 31.44 1.98 0.00 0.00 15 35.24 17.14 0.00 0.00 0.00 16 45.55 16.79 0.00 0.00 0.00 17 31.53 18.31 0.00 0.00 0.00 18 21.45 26.02 0.00 0.00 0.00 19 12.69 22.96 1.21 0.00 0.00 20 27.36 20.95 0.00 0.00 0.00 21 30.82 18.36 0.00 0.00 0.00 22 35.03 16.56 0.00 0.00 0.00 23 20.87 24.93 0.29 0.00 0.00 24 9.72 45.14 0.00 0.00 0.00 25 42.41 11.46 0.00 0.00 0.00 26 29.39 7.49 0.00 0.00 0.00 27 29.91 20.56 0.00 0.00 0.00 28 21.41 18.59 0.00 0.00 0.00 29 16.51 35.56 0.00 0.00 0.00 30 31.82 19.52 0.00 0.00 0.00 31 33.33 .99 0.00 0.00 0.00 32 9.84 31.91 0.00 0.00 0.00 33 10.09 23.55 0.00 0.00 0.00 34 21.53 28.77 0.00 0.00 0.40 35 11.58 36.01 0.00 0.00 0.00 36 10.67 40.17 0.00 0.00 0.00 37 15.12 30.81 0.00 0.00 0.00 3 i6.09 22.71 0.00 0.00 0.00 REPORT OF INVESTIGATION NO. 84 47 R27E R2BE / ^ ",, \ ~. ~2~K Figure 4. Sample sites of surface sands collected in the vicinity of the Green Cove Springs ore body. BUREAU OF GEOLOGY TABLE 10 Analyses of Surface Sediments Collected in Vicinity of Boulougne Ore Body Sample Sites Shown on Figure 5 Insoluble Residue Coarse Fine Heavy Silt Silt and Soluble Minerals Total Mean Grain Quartz (-230 mesh Clay and (1/8 to 1/16 Heavy Size of Sand +325 mesh) (-325 mesh) Organic mm Fraction) Minerals Quartz Sand Sol. in % in % in % in % in % In % In mm 1 94-36 0.86 4.58 0.20 0.59 0.46 0.14 2 95-01 0.80.09 0.10 1.94 0.83 0.15 3 96.33 0.96 2.51 0.20 1.59 0.90 0.15 4 51.31 13.26 33.34 2.09 0.67 0.65 0.13 5 77.37 9.16 12.77 0.70 0.57 1.06 0.13 89.71 2.81 7.28 0.20 0.64 0.70 0.14 7 93-94 0.98 4.69 o.4o 3.07 1.70 0.15 8 -9.28 0.82 4.40 0.50 9.40 2.17 0.15 9 92.91 1.10 5.89 0.10 3.48 2.09 0.15 10 91.78 i.42 5.70 1.10 0.93 0.75 0.16 11 73.19 7.6 18.36 0.80 0.68 0.82 0.12 12 94.19 1.63 3.98 0.20 0.84 0.65 0.13 13 90-52 3.39 5.99 0.10 0.83 1.01 0.12 14 91.19 0.94 7.18 0.70 1.71 0.94 0.17 15 93.77 1.54 4.59 0.10 2.73 1.75 0.14 16 91.09 1.30 7.40 0.20 3.17 2.03 0.14 17 96.47 0.74 2.79 0.00 1.51 1.06 0.15 T T80.08 7.26 11.86 0.80 1.01 1t.5 0.11 TABLE 11 Mechanical Analyses of Surface Sands Collected in Vicinity of Boulougne Ore Body Percent of sand in various size fractions Mean Approximate Quartz Very Coarse Coarse Medium Fine Very Fine Grain Elevation Spl. Sand (2 to (1 to (1/2 to (1/4 to (1/8 to Size In No. rn 1 mu) 1/2 mm) 1/4 m) 1/8 mm) 1/16 mm) in mm Feet 1 94.36 0.19 4.92 32.80 62.09 0.14 92 2 ~95.01 0.21 4.79 48.54 46.6 0.15 93 3 96.33 0.02 0.29 a4.39 46.47 48.82 0.15 58 4 51.31 0.39 1.12 3.4 13.19 81.54 0.13 18 S77.37 0.10 0.28 1.01 8.23 9038 0.13 21 6 9.71 -- 0.31 5.27 29.60 64.82 0.14 75 7 93.94 0.11 5 .20 45.08 49.61 0.15 101 34.o 0.15 5.43 45.27 49.15 0.15 101 9 92.91 0.02 0.15 3.35 43.75 52.73 0.15 93 ]0 91.78 0.17 1.09 8.32 37.93 52.48 0.16 42 11 73-19 0.14 0.52 2.97 14.70 81.67 0.12 22 12 94.19 0.15 2.90 28.78 68.17 0.13 73 13 90.52 0.13 2.27 17.53 80.06 0.12 72 14 91.19 0.02 0.39 8.90 48.68 42.01 0.17 81 15 93.77 0.02 0.15 2.77 36.97 60.09 0.14 83 16 91.09 0.13 2.57 40.22 57.07 0.14 90 17 96.47 0.10 0.6 5.14 38.17 7 5.95 0.15 0 I do.od 0.20 0.50 11.63 1 87.68 0.11 22 REPORT OF INVESTIGATION NO. 84 49 TABLE 12 Percentages of Selected Heavy Minerals in 1/8 to 1/16 mm Heavy-Mineral Fraction of Surface Sands Collected in Vicinity of Boulougne Ore Body Leucoxene Ilmenite Epidote Garnet Spl. in % in % in % in % 1 12.42 37.27 8.48 0.00 2 12.06 38.24 0.00 0.33 3 1.61 47.74 0.00 0.00 4 8.88 38.68 0.86 0.00 5 8.84 42.99 9.45 0.00 6 21.14 28.29 0.00 0.00 7 33.85 21.54 0.00 0.00 8 32.93 24.17 0.00 0.00 9 16.19 45.08 0.00 0.00 10 25.31 26.56 0.63 0.00 11 7.29 41.40 2.62 0.00 12 18.75 30.06 1.49 0.00 13 20.25 27.53 0.00 0.00 14 19.87 58.94 0.00 0.00 15 31.76 29.87 0.00 0.00 16 11.46 38.85 0.00 0.00 17 4.01 50.62 4.01 0.18 18 4.64 36.07 7.65 0.16 BUREAU OF GEOLOGY R 24E Figure 5. Sample sites of surface sands collected in the vicinity of the Boulougne ore body. R 23 E ~t~FF-' L I 0o 0 4 MLIES k i.. 7 fh Q A -- i- .'?~ :I* --.-:.ir-:1-~ .-.. --,. 1- I i. _--- .-Ii~ ;..~. 2 :-- ` I ~C'- :,).]:~:;?:~jiSl?~;f'r::;:` . ~. ~~~ ..rr ; ..-i `I-:--.;- ----?i ~;~~ .. ... ..-'- (,-~l.i;~-b-: -:--li I- r; I-.-r ;- :1: ;.;--- -- -; -:--- :-'i ~--i;- ~----- =:- |
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| MILLISECOND | CLASS.METHOD | MESSAGE |
|---|---|---|
| 0 | sobekcm_page_globals.constructor | |
| 0 | sobekcm_page_globals.constructor | Application State validated or built |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.constructor | Navigation Object created from URI query string |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.display_item | Retrieving item or group information |
| 0 | sobekcm_page_globals.get_entire_collection_hierarchy | Retrieving hierarchy information |
| 0 | sobekcm_assistant.get_entire_collection_hierarchy | |
| 0 | cached_data_manager.retrieve_item_aggregation | |
| 0 | cached_data_manager.retrieve_item_aggregation | Found item aggregation on local cache |
| 0 | item_aggregation_builder.get_item_aggregation | Found 'all' item aggregation in cache |
| 0 | system.web.ui.page.page_load (ufdc.page_load) | |
| 0 | sobekcm_page_globals.constructor.on_page_load | |
| 0 | html_echo_mainwriter.add_style_references | Adding style references to HTML |
| 0 | html_echo_mainwriter.add_text_to_page | Reading the text from the file and echoing back to the output stream |
| 29 | html_echo_mainwriter.add_text_to_page | Finished reading and writing the file |