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| Letter of transmittal | |
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| Introduction/Cement | |
| Clays | |
| Heavy metals | |
| Magnesium compounds | |
| Oil and gas | |
| Peat | |
| Phosphate | |
| Sand and gravel | |
| Stone | |
| References | |
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Main Main Page i Page ii Letter of transmittal Page iii Page iv Contents Page v Page vi Page vii Page viii Introduction/Cement Page 1 Page 2 Page 3 Page 4 Clays Page 5 (MULTIPLE) Page 6 Page 7 Page 8 Page 9 Page 10 Heavy metals Page 11 Page 12 Page 13 Page 14 Page 15 Magnesium compounds Page 16 (MULTIPLE) Oil and gas Page 17 (MULTIPLE) Page 18 Page 19 Page 20 Page 21 Page 22 Peat Page 23 (MULTIPLE) Page 24 Page 25 Page 26 Page 27 Phosphate Page 28 (MULTIPLE) Page 29 Page 30 Page 31 Page 32 Page 33 Page 34 Page 35 Page 36 Page 37 Page 38 Page 39 Page 40 Sand and gravel Page 41 Page 42 Page 43 Page 44 Page 45 Stone Page 46 Page 47 Page 48 Page 49 Page 50 Page 51 Page 52 Page 53 References Page 54 Page 55 Page 56 Page 57 Page 58 Page 59 Page 60 Page 61 Appendix Page 62 Page 63 Page 64 Page 65 Page 66 Page 67 Page 68 Page 69 Page 70 Page 71 Page 72 Page 73 Page 74 Page 75 Page 76 Page 77 Page 78 Page 79 Page 80 Page 81 Page 82 Page 83 Page 84 Page 85 Page 86 Page 87 Page 88 Page 89 Page 90 Page 91 Page 92 Page 93 Page 94 |
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FLRD GEOLOSk ( IC SUfRiW COPYRIGHT NOTICE [year of publication as printed] Florida Geological Survey [source text] The Florida Geological Survey holds all rights to the source text of this electronic resource on behalf of the State of Florida. The Florida Geological Survey shall be considered the copyright holder for the text of this publication. Under the Statutes of the State of Florida (FS 257.05; 257.105, and 377.075), the Florida Geologic Survey (Tallahassee, FL), publisher of the Florida Geologic Survey, as a division of state government, makes its documents public (i.e., published) and extends to the state's official agencies and libraries, including the University of Florida's Smathers Libraries, rights of reproduction. The Florida Geological Survey has made its publications available to the University of Florida, on behalf of the State University System of Florida, for the purpose of digitization and Internet distribution. The Florida Geological Survey reserves all rights to its publications. All uses, excluding those made under "fair use" provisions of U.S. copyright legislation (U.S. Code, Title 17, Section 107), are restricted. Contact the Florida Geological Survey for additional information and permissions. STATE OF FLORIDA DEPARTMENT OF NATURAL RESOURCES Elton J. Gissendanner, Executive Director DIVISION OF RESOURCE MANAGEMENT Art Wilde, Director BUREAU OF GEOLOGY Walter Schmidt, Chief INFORMATION CIRCULAR NO. 102 THE INDUSTRIAL MINERALS OF FLORIDA by Kenneth M. Campbell Published for the FLORIDA GEOLOGICAL SURVEY TALLAHASSEE 1986 3w37 ~B~fi:5: DEPARTMENT OF NATURAL RESOURCES BOB GRAHAM Governor GEORGE FIRESTONE Secretary of State BILL GUNTER Treasurer RALPH D. TURLINGTON Commissioner of Education JIM SMITH Attorney General GERALD A. LEWIS Comptroller DOYLE CONNER Commissioner of Agriculture ELTON J. GISSENDANNER Executive Director II no )o-2 LETTER OF TRANSMITTAL Bureau of Geology August 1986 Governor Bob Graham, Chairman Florida Department of Natural Resources Tallahassee, Florida 32301 Dear Governor Graham: The Bureau of Geology, Division of Resource Management, Depart- ment of Natural Resources, is publishing as its Information Circular No. 102, The Industrial Minerals of Florida. This report summarizes the geology, mining and beneficiation of indus- trial minerals found in Florida. Products, uses, economic trends and envi- ronmental aspects are outlined. This report will be useful to geologists, state and local governmental agencies and the citizens of the State and will help the reader more fully realize the impact of mining on the econ- omy of Florida. Respectfully yours, Walter Schmidt, Chief Bureau of Geology Printed for the Florida Geological Survey Tallahassee 1986 ISSN No. 0085-0640 iv TABLE OF CONTENTS Page Introduction ........................................ 1 Cement .......................................... 1 D discussion ..................................... 1 Econom ic Trends ................................. 2 Environmental Concerns ................. .......... 2 C lays ............................................. 5 G eology ....................................... 5 Mining and Beneficiation ............................ 7 U ses . . .. . . .. . . . .. . 7 Transportation and Economic Trends .................. 9 Reserves ....................................... 9 Environmental Concerns ........................... 9 Heavy M inerals ..................................... 11 Geology ................. ............ ......... 11 Trail Ridge Deposit ............................ 11 Green Cove Springs and Boulougne Deposits ......... 12 Mining and Beneficiation ................... ....... 12 Products and Uses ............ ...... ............. 14 Transportation and Economic Trends .................. 15 Reserves ....................................... 15 Environmental Concerns ........................... 16 Magnesium Compounds ............................... 16 Processing ..................................... 16 Uses .......... ............... ... ..... .......... 16 Econom ic Trends ................................. 17 Reserves ....................................... 17 Environmental Concerns ........................... 17 O il and G as ........................................ 17 G eology ....................................... 17 Products and Uses ............................... 18 Transportation ................................... 19 Production Trends ................................ 19 Reserves ....................................... 19 Environmental Concerns .......................... 19 Byproduct Sulphur ................................ 23 Peat ...................... .............. .. ..... 23 G eology ....................................... 23 M ining ........................................ 24 U ses .......................................... 2 5 Transportation and Economic Trends .................. 25 Reserves ....................................... 25 Environmental Concerns ............................. 27 Phosphate ......................................... 28 Discussion .............................. ....... 28 Geology ...................... ... ............ 29 Central Florida Phosphate District ................. 29 Southern Extension of the Central Florida Phosphate D district ................ ................. 31 Northern Florida Phosphate District ................ 31 M ining ........................................ 32 Beneficiation of Phosphate Ore ...................... 33 Products and Uses ............................... 34 Transportation ................................... 34 Economic Trends ................. ................ 34 Reserves ....................................... 36 Environmental Concerns ........................... 36 Water Usage .... ........ .... ................. 36 Power Consumption ........................... 36 Radiation ................................... 36 W ater Quality ........... ..................... 37 A ir Q quality .................................. 37 Clay Waste Disposal .......................... 37 W wetlands ................................... 38 Byproduct Fluorine ............................... 38 Recovery ................................... 38 U ses ....................................... 39 Economic Trends ............................. 39 Byproduct Uranium ............................... 39 G eology .................................... 39 Extraction ................................... 40 Economic Trends ............................. 40 Reserves ........................ ....... ...... 40 Sand and Gravel .................................... 41 Geology ...................................... 41 Northwest Florida ............................. 41 North Florida ................................. 42 Central Florida ............................... 42 South Florida ......... .............. .......... 43 Mining and Beneficiation ...... .. .................. 43 U ses .......................................... 44 Transportation ............ ...... ............. 44 Econom ic Trends .................................... Reserves .......................................... Environmental Concerns ............................... Stone .................. Geology ............. Northwest Florida ... The Western One-Half Florida .......... Atlantic Coast ...... Southwest Florida ... Mining and Beneficiation Products and Uses ..... Transportation ......... Economic Trends ....... Reserves ............. Environmental Concerns ...................... ...................... ...................... North and Central Peninsular ...................... ...................... ...................... ...................... ...................... ...................... ...................... ...................... ...................... References ........................................ A ppendix .......................................... Mineral Producers in Florida ......................... Producers By Commodity .............................. Commodities By County ............................... FIGURES Figure Quantity and value of portland cement .............. Quantity and value of masonry cement ............. Fuller's earth mine, Marion County ................. Quantity and.value of clays ...................... Heavy minerals "wet mill" beneficiation plant ........ Getty Oil drilling rig, East Bay, Santa Rosa County ..... Past and present oil and gas production from Florida fields ....................................... Quantity and value of petroleum crude .............. Quantity and value of natural gas .................. Quantity and value of peat ....................... Location of the Florida phosphate districts ........... 44 44 44 46 46 46 47 49 49 50 51 51 53 53 53 54 62 62 62 89 Page 3 4 8 10 13 18 20 21 22 26 30 12 International Minerals and Chemicals Corp. Clear Springs phosphate mine, Polk County .............. ................ 32 13 Quantity and value of phosphate in Florida and North C arolina .................................... 35 14 Suction dredge used in sand mining ................ 43 15 Quantity and value of sand and gravel .............. 45 16 Limestone quarry, Citrus County ................... 50 17 Limestone quarry, mining below water level with dragline ..................................... 51 18 Quantity and value of crushed stone ............... 52 TABLES Table Page 1 Conversion factors for terms used in this report ....... 1 THE INDUSTRIAL MINERALS OF FLORIDA by Kenneth M. Campbell INTRODUCTION Although Florida is not generally thought of as a mining state, it ranked fourth nationally in total value of non-fuel minerals produced in 1985 (Boyle, 1986). In 1981, the total value of Florida's mineral production (including fuels) was in excess of 3.8 billion dollars. In 1983, the Florida phosphate industry was reported to have led the nation in phosphate production for 90 consecutive years (Boyle and Hendry, 1985). Florida and North Carolina produced 87 percent of the national production of phosphate in 1983 and approximately 27.4 percent of the world produc- tion (Stowasser, 1985a). These figures indicate the great importance of industrial minerals, and mining activities, to the economy of the State of Florida and the nation as a whole. This publication is intended to respond to the needs expressed by the general public, governmental agencies, and industry, regarding informa- tion on Florida's Economic Minerals. The report will help the reader more fully realize the impact of the mining industry on Florida's, and ultimately the nation's economy. The units of measurement utilized in this report are those commonly used by the respective industries. The metric con- version factors for terms used in this report are given in Table 1. TABLE 1 MULTIPLY BY TO OBTAIN inches 25.4 millimeters inches 2.54 centimeters feet 0.3048 meters miles (statute) 1.6093 kilometers cubic feet 0.0283 cubic meters cubic yards 0.7646 cubic meters ton (short, 2000 Ib) 0.8929 long ton (2240 Ib) ton (short, 2000 Ib) 0.9072 metric ton (2204.62 Ib) CEMENT Discussion Portland cement and masonry cement are produced from a finely ground mixture of lime, silica, alumina and iron oxide. Heating, or calcin- ing the mixture in a rotary kiln forms a silicate clinker, which is then BUREAU OF GEOLOGY pulverized. Carefully controlled proportions of these ingredients are nec- essary to produce a satisfactory product. The chemical composition of portland cement varies, depending on the end product specifications but generally ranges from Ca3SiO, through CaA1,FeO,, (Lefond, 1975). The primary ingredient of portland cement is lime (CaO) which is obtained from limestone. Secondary ingredients are silica, alumina and iron. Quartz sand is utilized to provide silica. Clay provides silica, alumina, and iron oxide. The raw materials for cement production in Florida can all be found within the state, although some manufacturers are importing various ingredients. Lime is provided primarily by limestones mined in Florida. One manufacturer, however, has imported aragonite from the Bahamas for this purpose (Wright, 1974). Quartz sand used in the manufacturing process is mined within the state, as is much of the clay. Known reserves of suitable clay in Florida are becoming depleted and portland cement producers are increasingly looking outside the state for other sources. One company is presently importing kaolin from Georgia to supplement the clay obtained in Florida. Staurolite can be used to supply the alumina and part of the iron that is required by the cement formula. The mineral staurolite is a product of heavy mineral separation in the Trail Ridge area of north Florida. Economic Trends Cement production is closely tied to construction activity. Demand for cement is expected to increase at an annual rate of about two percent through 1990 (Johnson, 1985). In 1984, production of portland cement in Florida was up seven percent from the levels of 1983, while masonry cement production was up 26 percent (Boyle and Hendry, 1985; Boyle, 1986). Preliminary figures for 1985 indicate a decrease to approximately 1983 levels for the production of portland cement, and an increase of approximately four percent in masonry cement. Value of portland cement increased five percent from 1983 to 1984 while the value for masonry cement rose 26 percent. Preliminary figures for 1985 values indicate a decrease to 1983 levels for portland cement and an increase of approxi- mately seven percent for masonry cement (Boyle and Hendry, 1985; Boyle, 1986). There are presently five cement producers active in Flor- ida, with all operations located in the central and southern portion of the state. Environmental Concerns The environmental concerns of prime importance with respect to cement manufacturing are air and water pollution. Control of fugitive dust is the main means of alleviating these problems. Current Environ- mental Protection Agency (EPA) regulations limit total suspended solids, pH and effluent temperature which can escape from kilns and clinker QUANTITY (THOUSANDS OF SHORT TONS) VALUE (MILLIONS OF DOLLARS) p PRELIMINARY DATA 4.0. 250 30 10 10 0 o2C' >. 3.5 200 o I- u. 0 o @ 00 0 1 -I 2.5 100 C TI " 0 0. 2 1976 1977 1978 1979 1980 1981 1982 1983 1984 1985 YEAR Figure 1. Quantity and value of portland cement (Boyle, 1986; U. S. Bureau of Mines, 1977- 1983). 2.0150 f 1976 1977 1978 1979 1980 1981 1982 1983 1984 1985 * QUANTITY (THOUSANDS OF SHORT TONS) - VALUE (MILLIONS OF DOLLARS) p PRELIMINARY DATA w .j 500 25 400 20 300 15 200 10 5 a a ..a 5 III wU w w o__ I 0 01 - 1982 1983 1984 1985 Figure 2. Quantity and value of masonry cement (Boyle, 1986; U. S. Bureau of Mines, 1977 1983). co o 0h 'n q N C1 n 1976 1977 1978 1979 1980 1981 YEAR INFORMATION CIRCULAR NO. 102 coolers and stacks. Electrostatic precipitators and glass bag dust collec- tors are widely utilized. When the chemical makeup of the dust is not prohibitive (excess alkali), the collected dust can be recycled to the firing and of the kiln (Hall and Ela, 1978) reducing the amount of dust which must be handled for disposal. EPA regulations require strict dust disposal control to eliminate potential water pollution with limitations on quantity of suspended solids and runoff pH. Energy demands may be considered as an environmental concern. Cement manufacturing is highly energy intensive. Oil and gas shortages, and sharply increased fuel costs have impelled cement producers to con- sider coal as a primary and/or back-up fuel. Reduction in energy con- sumption is possible with new plants being designed to be energy effi- cient. Energy efficiency may be enhanced by recycling waste heat, dry process grinding, blending and conveying, reduction in kiln size and com- puter process and blending control (Schmidt, et al., 1979). CLAYS Clay deposits are found in many parts of Florida, but only in certain locations are they found with the proper mineralogy, purity and volume necessary for commercial exploitation. External factors such as ready access to transportation facilities, power supply and the labor force must also be favorable. The U.S. Bureau of Mines classifies clays into six groups. These are kaolin, ball clay, fire clay, bentonite, fuller's earth, and common clay (Ampian, 1985a). Clays that are presently mined in Florida include fuller's earth, kaolin and common clays for use as lightweight aggregate, cement ingredients and construction material. With the exception of kaolin, these clays are generally composed of varying amounts of the minerals smectite, kaolinite, or palygorskite (formerly called attapulgite). Geology Clay is a general term for common materials which have a very fine particle size and which exhibit the property of plasticity when wet. Strictly speaking, clay is both a size term and the name of a group of minerals. Clay sized particles are those which are less than 0.000154 inches (1/256 mm) in largest dimension. Clay minerals are composed of hydrous aluminum or magnesium silicates forming the minerals kaolinite, smectite, illite, halloysite and palygorskite. These minerals combine with a large number of possible clay sized impurities including silica, iron oxides, carbonates, mica, feldspar, potassium, sodium and other ions (Hosterman, 1973). The large number of possible components increases the potential for variation from deposit to deposit. The term fuller's earth is derived from the original use of the material, that of cleaning wool and textiles. Ampian (1985a) states that, "the term has neither a compositional nor a mineralogical connotation and the BUREAU OF GEOLOGY substance is defined as a non-plastic clay or clay-like material, usually high in magnesia, that has adequate decolorizing and purifying proper- ties." Fuller's earths are composed primarily of palygorskite or varieties of smectite (Ampian, 1985a). Florida fuller's earths in the Gadsden County area are predominantly palygorskite while those located in Marion County consist primarily of smectite (Hosterman, 1973). The fuller's earth deposits in Gadsden County occur as beds and lenses in the upper part of the Hawthorn Group of Miocene age. The Hawthorn Group in the Gadsden County area is composed primarily of sand, silt and clay, thin limestone beds and minor amounts of phos- phorite. The fuller's earth generally occurs as two beds, each two to eight-feet thick, separated by a hard sandy bed as much as 11 -feet thick. Above this is a sequence of lenticular, reddish-brown, brown, and yellowish-brown clayey sands, clay beds, and local channel-fill gravel deposits known as the Miccosukee Formation. The upper part of the Hawthorn Group and the Miccosukee Formation together constitute an overburden thickness which ranges from a few feet to 75 or more feet. The fuller's earth deposits located in Marion County represent the lower Hawthorn Group and are located on the edge of the Hawthorn outcrop belt. The fuller's earth clays are the only Hawthorn material present (T. Scott, personal communication, 1983). The fuller's earth is underlain by limestone of the Eocene Ocala Group, and is overlain by undifferentiated sands, clayey sands and sandy clays (Patrick, et al., 1983; T. Scott, personal communication, 1983). The ore zone is approximately 26-feet thick and consists of several beds of clay containing various amounts of quartz sand and silt, phos- phorite granules and dendrites (Patrick, et al., 1983). The clay minerals present in the fuller's earth include illite, sepiolite, smectite and possibly palygorskite (Patrick, et al., 1983). Up to 28 feet of overburden covers the fuller's earth. The overburden is often much thinner where part of the overburden material has been removed by erosion (Patrick, et al., 1983). There is only one active kaolin mine in Florida, located in western Putnam County. This deposit is of probable Pliocene age, although, at the present time, there is uncertainty as to the formation identity and age (Scott, 1978; personal communication, 1985). The kaolin comprises less than 20 percent of the material mined (Calver, 1957); the remainder is predominantly quartz sand with minor amounts of mica, feldspar and heavy minerals. Common clays occur in essentially all of the geologic formations exposed at the surface in Florida and in most of the counties. At present, only one company is mining clay in Florida for use as lightweight aggre- gate. This deposit located in Clay County is a naturally bloating clay composed primarily of smectite and kaolinite and is thought to be lagoonal in origin (Edward Phillips, personal communication, 1983). The deposit is of Pliocene to Pleistocene age (T. Scott, personal communica- tion, 1983). Approximately 10 feet of sand overburden must be removed to expose INFORMATION CIRCULAR NO. 102 the bloating clay. The upper bed is brown clay which averages 15 feet in thickness and contains a lower percentage of kaolinite than smectite. This upper bed is separated from a lower clay bed by two feet of white quartz sand. The lower clay bed averages 20 feet in thickness and con- tains smectite as the dominant clay mineral. Both beds contain lenses of shelly clay which are not used (Edward Phillips, personal communication, 1983). Mining and Beneficiation All clays in Florida are mined by the open pit method. The overburden is first removed by a dragline or earthmover. A dragline is utilized to remove the clay, which is then trucked to the plant for processing. The kaolin-bearing sands are mined by a floating suction dredge. The processing procedures vary widely due to the different purposes for which the clay is mined. The processing required for fuller's earth consists of drying, grinding, grading by size and packaging. The kaolin-bearing sands are beneficiated by separation of the sand and clay and removal of impurities through a series of disaggregating, washing, screening, thickening, filtering, and drying operations. The sand fraction is retained, further beneficiated and classified. Clays for lightweight aggregate production are fired in a rotary kiln at high temperatures. Two conditions are necessary for bloating (expand- ing) to occur. When the bloating temperature is reached, the clay mass must be in a pyroplastic condition and, at the same time, gasses must be evolving throughout the clay mass (Conley, et al., 1948). The product is a mass comprised of thin-walled bubbles produced by the gas expansion. The expansion process is dependent on impurities in the clay such as iron compounds, alkaline earths (CaO, MgO) and alkalis (K,Na,0), carbon in some cases, and on pH (generally greater than 5) (Conley, et al., 1948). The clay structure seems to play little part in the bloating process. After firing, the expanded product is graded by size. Uses Fuller's earth is a term applied to clays and clay-like materials which have adequate decolorizing and filtration properties. These clays were originally used to "full" or remove oil from woolen cloth and fibers. The term is still used today although the primary uses of the clays have changed. Fuller's earth is used primarily as an absorbent (oil dry, kitty litter, etc.), for drilling muds, as a carrier for insecticides and fungicides, and for filtering and decolorizing. The advantage in using fuller's earth as a drilling mud is that it does not flocculate (settle out) when salt water is encountered (Hosterman, 1973). Lightweight aggregates are used to reduce the unit weight of concrete products without adversely affecting their structural strength. Some properties of lightweight aggregates are: their relative light weight, high BUREAU OF GEOLOGY I. Figure 3. Fuller's earth mine, Marion County. Photo by Tom Scott. fire resistance, substantial compressive strength, good bonding with cement, chemical inertness, and abrasion resistance. Kaolin mined in Florida has uses which include ceramics, whiteware, refractory brick, wall tile, and electrical insulators. Additional industrial applications include use in paint, paper, rubber and plastics (Ampian, 1985a). Common clays have a variety of uses, such as road construction, brick manufacturing, and manufacturing of portland cement. Very little clay is utilized in road construction, as limestone is the major road base material used in the state. Only a few county road departments maintain "clay" (usually a clayey sand) pits for local road construction and maintenance. 11 INFORMATION CIRCULAR NO. 102 There is presently only one brick-manufacturing operation in the state, ocated at the Apalachee Correctional Institution at Chattahoochee. This .s not a commercial enterprise, and all of the bricks produced are used by state agencies. All commercial brick manufacturing plants in Florida have closed due to economic reasons. Clay is commonly used as a source of silica and alumina in the manu- facturing of portland cement. In the southern part of the state, known clay deposits are very scattered and usually have a high content of impu- rities. One manufacturer of portland cement imports kaolin from Georgia for use as a source of alumina while another uses staurolite, which is obtained as a by-product of the heavy minerals industry in Clay County. Transportation and Economic Trends Transportation of clays mined in Florida is primarily by truck and rail. Demand for the various types of clay is expected to increase 2-4 percent annually through 1990 (Ampian, 1985b). Production of clay increased approximately 13 percent in 1984 from 1983, while value (excluding kaolin) increased approximately eight percent (Boyle and Hendry, 1985; Boyle, 1986). Preliminary figures for 1985 indicate an increase of approximately 16 percent and 47 percent for production and value respectively over the 1984 figures (Boyle, 1986). Reserves The majority of the state, with the exception of south Florida, contains abundant quantities of common clays. The U.S. Bureau of Mines (Ampian, 1985a) states that Florida reserves of common clays are virtu- ally unlimited. Individual deposits, however, are not necessarily suitably located or suitable for specific purposes. Identified deposits of common clays suitable for lightweight aggregate are quite limited. This situation probably reflects lack of exploration and testing. Fuller's earth resources are estimated to be 300 million short tons (Ampian, 1985a). Reserves for kaolin are not specified by Ampian (1985a), but can be considered lim- ited to moderate. Environmental Concerns Environmental concerns related to clay mining are primarily associated with air and water pollution. Dust control measures and settling ponds are used to help alleviate these problems in and around production plants and storage areas. Timely land reclamation and revegetation will mini- mize the effects of dust and runoff from mining areas. 1300 50 1200 46 1100 40 1000 35 900 30 N ON 0 1976 1977* 1978 19794 1980* YEAR 1981 1982 1983 1984 1985 Figure 4. Quantity and value of clays (Boyle, 1986; U. S. Bureau of Mines, QUANTITY ( THOUSANDS OF SHORT TONS ) VALUE ( MILLIONS OF DOLLARS ) P PRELIMINARY DATA * EXCLUDES KAOLIN VALUE 0 0 in s ! UJ 25 20 800 700 600I5 500 10 ,i lHgH B ig .,.r ,i,, i, i.. ., -- . 1977-1983). INFORMATION CIRCULAR NO. 102 HEAVY MINERALS Geology The history of the Florida heavy mineral deposits began millions of years before their deposition in Florida sediments. The heavy minerals were originally formed in the igneous and metamorphic rocks of the Blue Ridge and the Piedmont regions in the southern Appalachians (Gilson, 1959). Following extensive weathering and erosion of the crystalline rocks the heavy mineral grains were subjected to a lengthy period of abrasion and winnowing as they were transported by fluvial and marine longshore currents. Finally, they were deposited as sedimentary grains in Florida. None of the economically important detrital minerals found in Florida sediments are known to occur in Florida sedimentary rocks as primary minerals (Garner, 1972). Heavy minerals are associated with essentially all of the quartz sands and clayey sands in Florida, however, economically valuable concentra- tions are much less widespread. The areas which are of economic impor- tance are the Trail Ridge and Green Cove Springs deposits located in the northeast peninsula of Florida. All of the commercially valuable heavy mineral deposits in Florida are inland from the present shoreline, and are genetically associated with older, higher shore lines (Pirkle, et al., 1974). TRAIL RIDGE DEPOSIT The Trail Ridge is a sand ridge which extends southward from the Altamaha River in southeast Georgia into Clay and Bradford counties in the peninsula of Florida, a distance of approximately 130 miles. Ridge crest elevations range from approximately 140 feet in southern Georgia to approximately 250 feet near its southern end in Florida (Pirkle, et al., 1977). The Trail Ridge heavy mineral ore deposit is located at the southern end of the Trail Ridge in Bradford and Clay counties. The ore body, which has an average thickness of 35 feet, measures approximately 17-miles long by one or two miles wide. Heavy minerals (specific gravity greater than 2.9) comprise approximately four percent of the deposit. The titanium minerals rutile, ilmenite and leucoxene make up 45 percent of the heavy mineral fraction (Carpenter, et al., 1953). Staurolite, zircon, kyanite, sillimanite, tourmaline, spinel, topaz, corundum, monazite and others make up the remainder of the heavy mineral fraction (Pirkle, et al., 1970). The base of the ore body rests either on barren quartz sands and clayey sands or on a compacted layer of woody and peaty materials including tree branches, roots and trunks (Pirkle, et al., 1970). The current hypothesis for the formation of the ore body is that Trail Ridge was formed at the crest of a transgressive sea (rising sea level) which was eroding the sediments of the Northern Highlands of Florida (Pirkle, et al., 1974). The Trail Ridge is the highest and oldest shoreline BUREAU OF GEOLOGY along which commercial concentrations of heavy minerals have been found in Florida. The Trail Ridge deposit is significantly coarser in mean grain size than the sediments of the Northern Highlands because fine sediments were winnowed out by wave and current activity. The compo- sition of the heavy mineral suite of the Trail Ridge deposit closely matches that of the Northern Highlands (Pirkle, et al., 1974). Pirkle, et al. (1977) concluded from a study of heavy mineral grain sphericities that the high terrace sands of the Northern Highlands were the only possible source of sand for the Trail Ridge. Thus, this interpretation of the origin of the Trail Ridge is consistent with the mineral suite of the Northern High- lands as well as the physiographic and sedimentary features of the area (Pirkle, et al., 1977). GREEN COVE SPRINGS AND BOULOUGNE DEPOSITS The Green Cove Springs and Boulougne (now mined out) heavy min- eral deposits are located within the Duval Uplands. These deposits are believed to have formed within beach ridges on a regressional (falling sea level) beach ridge plain associated with a sea level of 90-100 feet, with the elevation becoming lower to the east (Pirkle, et al., 1974). The Green Cove Springs ore deposit, which is oriented along a north- west to southeast trend, is located in southeastern Clay and northeast- ern Putnam counties. The deposit is approximately 12-miles long, 3/4- mile wide and 20-feet thick (Pirkle, et al., 1974). The Boulougne ore body (now mined out) is located several miles south of the Florida- Georgia border in Nassau County and measures three-miles long (N-S trend) by 1/2 to 3/4-mile wide and ranges from 5 to 25-feet thick (Pirkle, et al., 1974). The Green Cove Springs and Bolougne heavy mineral deposits are finer grained than the Trail Ridge deposit. The sediment source for a regres- sional beach ridge plain would be, predominantly, sediments delivered by the coastal littoral drift system. These sediments would tend to be rela- tively fine and would contain heavy mineral suites characteristic of their source areas. This can explain the finer texture of the Duval Upland beach ridge sediments as well as the occurrence of garnet and epidote in the heavy mineral suite (Pirkle, et al., 1974). Mining and Beneficiation The mining process begins with harvesting any timber present and clearing the land of vegetation. Top soil, if present, is stockpiled for later use in reclamation. Heavy mineral sands are mined by a floating suction dredge equipped with a cutter head. The dredge and wet mill float in a man-made pond. The dredge cuts into the banks of the pond, while waste sand, after processing in the wet mill, is backfilled into the pond behind the dredge. Initial heavy mineral separation is carried out within the wet mill by the INFORMATION CIRCULAR NO. 102 TL--~;aa -.. .- Heavy minerals "wet mill" beneficiation plant. Photo courtesy of the Florida Bureau of Mine Reclamation. use of Humphreys Spiral Concentrators. Spiral concentrators treat an ore which contains approximately four percent heavy minerals, and produce, after several stages, a concentrate which averages 85 percent heavy minerals (Garner, 1971). Based on the acreage mined in 1985 (Florida Bureau of Mine Reclamation figures) and assuming the 'average' thick- ness of the two deposits presently being mined (Trail Ridge and Green Cove Springs), approximately 43 million cubic yards of material were processed through the wet mills, resulting in approximately 1.6 million cubic yards of wet mill concentrate. Wet mill concentrates are pumped to land based dry. mills for further processing. Figure 5. 'a a J ii _~a~l-" ;'~ 'T .-*;.,~1 ~ir--; *. ,~,, "X~L. '~ - "- --p~L~U. ~W1~~ r- .i .. .. - ' ,, ~~~4-4 BUREAU OF GEOLOGY The initial step in processing wet mill concentrates is scrubbing using sodium hydroxide to remove organic coatings and clay minerals from the grains. Scrubbed material is dried and then separated on a series of high tension separators which take advantage of the variation in the electrical conductivity of the different minerals (Garner, 1971). Titanium minerals (ilmenite, rutile, and leucoxene) have relatively good electrical conduc- tance and are separated from the heavy silicate minerals (includes staurolite, zircon, kyanite, sillimanite, tourmaline and topaz) and quartz which pick up an electrical charge and adhere to the separator rotor (Evans, 1955). The concentrate is thus separated into titanium minerals, tailings composed of heavy silicate minerals and quartz, and a middling fraction of poorly separated grains which is recycled through the high tension separator. Concentrate from the high tension separator is separated magnetically. The magnetic portion is shipped as ilmenite which contains 98 percent titanium mineral and averages 64.5 percent TiO, (Garner, 1971). The nonmagnetic fraction is recycled through high tension separators to sep- arate leucoxene and rutile as a product which analyzes 80 percent TiO,. After ilmenite, leucoxene and rutile are removed, tailings are recycled to the initial high tension separators, and high intensity magnets separate staurolite from zircon. Tailings from the staurolite separation are treated in spirals to remove heavy silicates and quartz sand (Garner, 1971). Through continuous control and recycling of materials nearly all of the heavy minerals are recovered. Products and Uses The major use for the titanium-rich heavy minerals (ilmenite, rutile and leucoxene) is for titanium dioxide pigment (known for its whiteness, spreading quality and chemical stability). Ninety-nine percent of the ilmenite and 84 percent of the rutile was utilized in the manufacture of white pigments in 1984 (Lynd, 1985a). Staurolite is an iron-aluminum silicate mineral containing 45 percent Al O, and 13 to 15 percent Fe203. Staurolite product also contains tour- maline and spinel as well as silicates with magnetic inclusions. This material is utilized primarily as a source of iron and alumina in the manu- facture of portland cement and as an abrasive (Garner, 1971). Zircon is found in economic quantities in the Trail Ridge area, and is recovered from the ore after the ilmenite and rutile have been removed. Zircon is a silicate of zirconium with a theoretical composition of 67.2 percent ZrO, and 32.8 percent SiO2 (Dana, 1946). It is a constituent of practically all stream and beach sands, however, it occurs in rather small quantities in most deposits. The consumption of zircon in the U.S. in 1984 was as follows: 45 percent was used in foundry sands, 20 percent in refractories, 12 percent in ceramics, six percent in abrasives and the rest in making zirconium metal and alloys and in chemical manufacturing (Adams, 1985). INFORMATION CIRCULAR NO. 102 Monazite is a phosphate mineral which concentrates the rare-earth elements ceriumm, yttrium, lanthanum, and thorium) and contains up to 12 percent thorium oxide and one percent uranium oxide. Monazite is not present in commercial quantities in the Trail Ridge deposit but is pres- ently recovered from the Green Cove Springs deposit. Thorium that is derived from monazite is used as a fertile material in commercial high- temperature gas-cooled nuclear reactors and experimental nuclear reac- tors to produce fissionable U-233. The major use at present is to produce catalysts utilized in cracking petroleum crude. Non-energy uses include the manufacture of gas mantles, high temperature alloys used in the aerospace industry, refractory materials, optical glass, and other miscel- laneous uses. Cerium is also extracted from monazite and is used in the production of iron alloys, mischmetal (a metallic mixture of rare earth elements), ferrocerium, carbon arc electrode cores, glass polishing proc- esses and other miscellaneous uses (Moore, 1980). Transportation and Economic Trends Heavy mineral concentrates are shipped primarily by rail. Covered hop- percars are utilized in bulk shipments (Lynd, 1980). Production and value figures for heavy minerals in general (and the individual mineral compo- nents) are withheld to protect the confidentiality of individual compan- ies. In 1983, Florida was the only U.S. producer of staurolite, rutile, zircon and rare earth minerals from mineral sands and was one of only two states with ilmenite production (Boyle and Hendry, 1985). From a 1984 level, demand for titanium sponge metal is expected to increase at an annual rate of five percent through 1990. Titanium sponge metal is a spongy metal produced by reducing purified titanium tetrachloride with sodium or magnesium in an inert atmosphere. Residual chlorides are removed by leaching, inert gas sweep or vacuum distillation. The sponge is compacted and formed into ingots by vacuum arc melting (Lynd, 1985b). Demand for TiO2 pigments will increase from a 1981 base at two percent annually (Lynd, 1985a). U.S. production of ilmenite in 1982 was the lowest since 1954 at 263,000 short tons of contained TiO, (Lynd and Hough, 1980; Lynd, 1985a). Zirconium demand is expected to increase at a four percent annual rate through 1990 (Adams, 1985). Rare earth metals demand is expected to increase at an annual rate of three percent through 1990 (Hedrick, 1985). Reserves Florida reserves of titanium minerals consist of 5.2 million short tons of contained titanium from ilmenite and rutile (Lynd, 1985b). Reserves of rare earth minerals are considered limited. BUREAU OF GEOLOGY Environmental Concerns Environmental problems associated with heavy mineral mining in Flor- ida are relatively minor. Water quality problems related to suspension of clay and organic material are the most prevalent and may require use of settling ponds to maintain water quality. Land reclamation is required by the state of Florida on all land mined for heavy minerals. Recontouring and revegetation are among the require- ments. Timely reclamation will help minimize the impacts of mining. MAGNESIUM COMPOUNDS Florida ranked second in the nation in the production of caustic- calcined and refractory grade magnesium compounds recovered from seawater in 1983 (Boyle and Hendry, 1985). One company produced magnesium compounds in Florida. Processing Seawater is utilized as a source in the production of caustic-calcined and refractory magnesia as well as magnesium metal (Kramer, 1985a). Carbonate and sulfate levels in the feed water must be reduced to pre- vent the precipitation of insoluble calcium compounds. Carbonate and sulfate level reduction is accomplished by treatment with slaked lime to precipitate calcium carbonate (CaCO,) or by treating with acid to release carbon dioxide (CO,). The treated solution is mixed with dry or slaked lime to precipitate magnesium hydroxide which is thickened, washed with fresh water and filtered. The filter cake is then calcined to produce caustic-calcined or refractory magnesia or may be calcined and pelletized prior to dead burning (Kramer, 1985a). Caustic-calcined magnesia is pre- pared at temperatures up to 16400F and is water reactive. Dead burned, or refractory, magnesia is prepared at temperatures greater than 26400F and is not reactive with water (Kramer, 1985a). Uses In 1985, 85 percent of the magnesium consumed in the U.S. was in the form of magnesium compounds. The majority of magnesium com- pound use is in the form of refractory magnesia (Kramer, 1985a; Adams, 1984) used primarily by the iron and steel industry for furnace refracto- ries (Kramer, 1985a). Caustic-calcined magnesia is used primarily in the manufacture of chemicals (Kramer, 1985a). Magnesium compounds are used to prepare animal feeds, fertilizer, rayon, insulation, metallic magne- sium, rubber, fluxes, chemical manufacturing and processing, petroleum additives and paper manufacturing (Kramer, 1985a; Adams 1984). INFORMATION CIRCULAR NO. 102 Economic Trends Production figures for Florida are not available, to protect the confiden- tiality of individual company data. Adams (1984) shows the production capacity of Basic Magnesia Co. (the sole Florida producer) as 100,000 short tons of MgO equivalent. Kramer, (1985b) estimates that in 1984, the magnesium compounds industry operated at almost 70 percent of capacity. Reserves Reserves of magnesium compounds from seawater are virtually unlim- ited. Magnesium is the third most common element in seawater with an average content of 0.13 weight percent (Kramer, 1985a). Environmental Concerns Magnesium plants which utilize seawater as a source return the water to the ocean after magnesia removal. Turbidity of the return water has been a problem in the past, however, modern treatment processes have reduced the degree of turbidity. The return water is not noxious (Kramer, 1985a). OIL AND GAS Florida's oil and gas production is from two widely separated groups of fields. The first group is located in Collier, Dade, Hendry and Lee counties and includes the Sunniland, Forty Mile Bend, Sunoco Felda, West Felda, Lehigh Park, Lake Trafford, Bear Island, Mid-Felda, Seminole, Baxter Island, Townsend Canal, Raccoon Point, Pepper Hammock and Cork- screw fields. The other group, located in Santa Rosa and Escambia coun- ties includes the Jay, Mount Carmel, Blackjack Creek and Sweetwater Creek fields and a presently unnamed field. The Forty Mile Bend, Semi- nole, Baxter Island and Sweetwater Creek fields have been plugged and abandoned. Geology The south Florida fields produce from a combination of subtle struc- tural traps and stratigraphic traps in the Sunniland Formation of Early Cretaceous Age. Production is from porous limestone containing abun- dant disoriented gastropods and pelecypods (rudistids) (Al Applegate, Florida Geological Survey, personal communication, 1983). The oil and gas fields of northwest Florida produce from a combination of structural and stratigraphic traps in the Jurassic Smackover Formation (Sigsby, 1976). The productive interval of the Smackover is a porous dolomite which includes a lower transgressive interval of mud flat and BUREAU OF GEOLOGY :Lrp - : ri Figure 6. Getty Oil drilling rig, East Bay, Santa Rosa County. Photo by Walt Schmidt. algal mat deposits and an upper regressive interval composed of hard- ened pellet grainstones (Ottmann, et al., 1973). Products and Uses Crude oil and natural gas are utilized primarily as fuels of various types. Gasoline, kerosene, diesel fuel, jet fuel, fuel oil and propane, ethane, and methane gases are examples. Lubricants, synthetic fibers, plastics, asphalt and paraffin wax are examples of other products produced from INFORMATION CIRCULAR NO. 102 petroleum (U.S. Dept. of Energy, 1979). Sulphur is produced as a by- product from the northwest Florida fields. Transportation All crude oil produced in Florida is shipped by pipeline or barge to refineries in other states (Christ, et al., 1981). Crude oil from the south Florida fields is shipped by truck and pipeline to Port Everglades for distribution. Crude from the northwest Florida fields is transported by 16-inch pipeline to storage facilities in Alabama (Christ, et al., 1981). Natural gas from the northwest Florida fields is shipped by pipeline and truck after natural gas liquids are stripped from the gas. Florida Gas Transmission Pipeline Company and Five Flags Pipeline Company market natural gas to residential, commercial and industrial customers within the state (Sweeney and Hendry, 1981). Production Trends In 1978, Florida ranked ninth nationally in production of petroleum crude with 1.4 percent of the national production (Independent Petro- leum Association of America, 1979). Production of petroleum and natu- ral gas in Florida has been declining since 1978. Estimated 1985 oil production is down 76 percent from the 1978 figure and 20 percent from 1984. Natural gas production is down 77 percent from 1978 and 15 percent from 1984. This trend is expected to continue unless additional reserves are discovered in the near future (Florida Bureau of Geology, unpublished data). Reserves Proven crude oil and natural gas reserves as of December 31, 1984, consisted of 82 million barrels of oil and 90 billion cubic feet of natural gas (U.S. Dept. of Energy, 1985). Statewide cumulative oil production, through 1984, totals 474.976 million barrels. Cumulative natural gas production totals 483.877 billion cubic feet (Applegate and Lloyd, 1985). In 1984, 76.5 percent of the crude oil production and 98 percent of the natural gas was from the northwest Florida fields (Florida Bureau of Geology, unpublished data). Environmental Concerns The environmental concerns associated with oil and gas drilling in Florida center on fresh water resource protection, protection of environ- mentally sensitive lands and endangered species. Aquifer protection is ensured by proper well construction techniques, which are designed to isolate freshwater aquifers from deeper saline water zones by cementing casing in place through the entire fresh water zone and into the salt SOIL IN THOUSANDS OF BARRELS --- GAS IN THOUSANDS OF MCF I I I \ I \ i I I I I I I I I I I 19431945 1950 1955 1960 1965 1970 1975 1930 1935 Figure 7. Past and present oil and gas production from Florida fields (Florida Bureau of Geology figures). 50,000 45,000 70 1400 T - ~~ &~ & L,- 1977 1978 1979 1980 YEAR 1981 o a 01 1 Figure 8. Quantity and value of petroleum crude (production: Florida Bureau of Geology figures; value: Independent Petroleum Association of America, 1978 1984). QUANTITY (MILLIONS OF BARRELS) (1 BARREL-42 U.S. GALLONS) W| VALUE (MILLIONS OF DOLLARS) p PRELIMINARY DATA 1200 1000 0 oo00 8.00 >60 40 40 a 3 6&00 20 400 10 200 1976 QUANTITY ( BILLIONS OF CUBIC FEET ) I Dl VALUE I MILLIONS OF DOLLARS I p PRELIMINARY DATA o o 50 100 6 s En p hn > I. 2 040 80 c V U, 3060 I s H n n G) 20 40 1976 1977 1978 1979 1980 1981 1982 1983 1984 1985 YEAR Figure 9. Quantity and value of natural gas (production: Florida Bureau of Geology figures; value: Independent Petroleum Association of America, 1978- 1984). INFORMATION CIRCULAR NO. 102 water zone. Personnel from the Florida Bureau of Geology, Oil & Gas Section, inspect the well construction. Proposed well locations in the Big Cypress Swamp of south Florida are inspected by the Big Cypress Swamp Advisory Committee which was set up by the Governor and Cabinet of Florida. This five-member commit- tee consists of the State Geologist, a professional hydrologist and a professional botanist, as well as one representative from a statewide environmental group, and one member from industry. Well drilling and related plans are modified as necessary to minimize the impact on wild- life and surface habitats. Byproduct Sulphur Crude oil from Jay Field area contains 87 percent hydrocarbons, 10 percent hydrogen sulfide and three percent carbon dioxide and nitrogen (Ottmann, et al., 1973). The gas produced in this area also contains hydrogen sulfide. The removal of the hydrogen sulfide from crude oil and natural gas has resulted in a significant byproduct sulphur resource. A plant treating 12,000 barrels a day will produce 80 long tons (89.6 short tons) of sulphur per day (Ottmann, et al., 1973). Sulphur is shipped by truck in liquid form to Mobile, Alabama. PEAT The following discussion is summarized in large part from a detailed Florida Geological Survey publication on the peat resources of Florida (Bond, et al., 1984) entitled An Overview of Peat in Florida and Related Issues. Geology The conditions under which peat occurs in Florida are highly variable. The geological and hydrologic relations of peat to adjacent materials are poorly understood. Davis (1946) divided the peat deposits of Florida into a number of groups based on their locations. These groups include: 1) Coastal associations, including marshes and mangrove swamps, lagoons and estuaries as well as depressions among dunes, 2) large, nearly flat, poorly-drained areas as exemplified by the Everglades, 3) river-valley marshes such as the marsh adjacent to the St. Johns River, 4) swamps of the flat land region, 5) marshes bordering lakes and ponds, 6) seasonally flooded shallow depressions, 7) lake bottom deposits, and 8) peat layers buried beneath other strata. In Florida, peat deposits may be either wet or dry, (Davis, 1946; Gurr, 1972). Wet peat deposits occur if the water- table remains relatively high. Peat may be actively accumulating in these deposits. Certain areas within the Everglades, the coastal mangrove peats, and some lake-fringing peat deposits, such as the one associated with Lake Istokpoga, are examples of undrained deposits in the state. In BUREAU OF GEOLOGY other instances, peat deposits are dry. This drainage may have been initiated to enhance the land for agricultural use. The Everglades agricul- tural region contains numerous tracts drained for this purpose. Other deposits have apparently been drained as a result of regional lowering of the water table. Peat forms when the accumulation of plant material exceeds its destruction by the organisms which decompose it. Certain geologic, hydrologic and climatic conditions serve to inhibit decomposition by organisms. Ideally, areas should be continually waterlogged, tempera- tures generally low, and pH values of associated waters should be low (Moore and Bellamy, 1974). Certain geologic characteristics are associated with waterlogged sur- face conditions. The tendency toward waterlogging is enhanced if topo- graphic relief is generally low and topographic barriers exist which restrict flow and allow water to pond. Additionally, waterlogging is encouraged if highly permeable bedrock is covered with material of low permeability (Olson, et al., 1979). The chemical nature of the plant litter may also serve to reduce its susceptibility to decomposition. Moore and Bellamy (1974) note the association of cypress and hardwood trees with peats characteristic of the hammocks or tree islands of the Everglades. These hammocks occur on peat deposits which are situated on limestone bedrock. The trees, which are responsible for the peat beneath them, contain enormous amounts of lignin, an organic substance somewhat similar to carbohy- drates which occurs with cellulose in woody plants. Lignin is very resist- ant to decay and acts as a 'preservative' (Moore and Bellamy, 1974). Rates of peat accumulation computed from radiocarbon age dating are grouped about an average of 3.6 inches per 100 years. The rate of peat accumulation can vary with climate (which also varies with time), the position of the water table, and nutrient supply (Moore and Bellamy, 1974). Mining Almost all peat presently mined in Florida is utilized for agricultural or horticultural purposes. Draglines and other earthmoving equipment are utilized in removing vegetation and peat. Moisture must be reduced to approximately 90 percent for the bog to bear the weight of machinery. Drainage is an integral and necessary first step in most large scale mining operations. After excavation, the material is partially air dried and shred- ded or pulverized (Davis, 1946). If peat is utilized on a larger scale for fuel, more technologically advanced methods will need to be employed and will probably be similar to current European peat technology. This implies that peat will be air dried and burned directly (Kopstein, 1979). INFORMATION CIRCULAR NO. 102 Uses The principal extractive use of Florida peat is as a soil conditioner, with large amounts used for lawns, golf courses, and in nurseries and green- houses. The benefits derived from the use of peat result largely from improved physical conditions in the soil. Also, peat's ability to hold eight to 20 times its own weight in water makes it valuable in the improvement of soils. Farming is the major consumptive nonextractive use of peat in Florida. One major effect of farming is the deterioration of peat by the various processes which result in subsidence. Subsidence occurs when organic soils decrease in volume and is the net result of a number of causes: 1) shrinkage due to desiccation, 2) consolidation which occurs with loss of the buoyant force of water, as well as from loading, 3) compaction accompanying tillage, 4) erosion by wind, 5) fire damage, and 6) bio- chemical oxidation (Stephens, 1974). Biochemical oxidation results in actual soil loss, as opposed to volume decrease. It is the primary cause of declining soil thickness in south Florida. Transportation and Economic Trends Both bulk and packaged peat are shipped primarily by rail and truck (Searls, 1980). In 1984 Florida ranked first in U.S. peat production (Davis, 1985a). Florida peat production reported in 1984 increased dra- matically from 114,000 short tons in 1983 to 263,000 short tons in 1984 due to a large increase in companies reporting production (Boyle, 1985). The U.S. Bureau of Mines production figures up to 1983 repre- sented production reported by five companies. In 1984, there were 21 peat producers in Florida (Bond, et al., 1984), however, only 15 reported production to the U.S. Bureau of Mines. Nationwide demand is expected to increase from a 1983 base at an annual rate of approximately 3.3 percent through 1990 (Davis, 1985b). Reserves The known original reserves of peat in Florida were estimated by Soper and Osbon (1922) at 2 billion short tons (air dried). Recent reserve esti- mates have varied widely. The American Association of Petroleum Geol- ogists (1981) reported the estimate of 6.8 billion short tons (air dried). Griffin, et al. (1982) report that, 'It is now estimated that Florida could produce 606 million tons of moisture free peat' of fuel grade if no other constraints were present (cost, environmental problems, land use con- flict, etc.). . Z z 0 2 .repau of Minminn 1.977 -19 3 __ 1976 1977 1978 1979 1980 1981 YEAR Figure IU. Uuantity and value of peat (Bovle. 1988: U. S. BL 1 I t - INFORMATION CIRCULAR NO. 102 Environmental Concerns Drainage, or water level control undertaken in order to create a work- able substrate affects the vegetation in two primary ways. Within the area to be mined and also in areas designated for processing, storage, roads, and parking lots, vegetation must simply be cleared or eliminated. The ditch system devised for drainage lowers the water table both beyond and within the boundaries of the area to be mined (Minnesota Department of Natural Resources, 1981). The lowering of the water table affects vegetation in that original plants adapted to wetland situations will be replaced by plants tolerant of drier conditions. The elimination of vegetation destroys wildlife habitat and results in displacement of wild- life. The changes in vegetation which accompany drainage will result in changes both in population and species make-up of wildlife inhabiting an affected area (Minnesota Department of Natural Resources, 1981). Surficial waters will be affected by drainage. Ditches used in drainage may disrupt flow down slope from a bog. Drainage may also alter the hydrologic budget of a peatland. Evapotranspiration will be reduced because the water resides deeper within the ground due to the lowering of the water table. It is thus more difficult for moisture to reach the surface. The Minnesota Department of Natural Resources (1981) reports that changes in evaporation and water stored must affect runoff, but the effects are poorly understood. It seems that drainage results in decreased peak runoff so that runoff is distributed more uniformly throughout the year. Recharge to the shallow aquifer occurs in Florida's wetlands (McPher- son, et al., 1976). Drainage canals constructed in the Everglades have resulted in accelerated runoff which, in consequence, has reduced the amount of water available to recharge the shallow aquifer (McPherson, et al., 1976). This relationship between canals, runoff, and water avail- able for recharge should be considered if peat mining requires drainage. The effects will, of course, depend on the size of the area to be mined and its relation to the regional aquifers. The last implication of drainage is that of peat subsidence. The caus- ative relationship between drainage and subsidence is well known in Florida. Experience in the Everglades has shown that subsidence itself has very serious implications. Stephens (1974) reviews various aspects of drainage and subsidence in the Everglades. Most environmental problems associated with construction of pro- cessing, storage, and transportation facilities are short-lived. Excavation and landscaping will temporarily be associated with increased erosion and sediment in runoff water (Minnesota Department of Natural Resources, 1981). The construction and presence of roads, parking lots, and buildings will result in some further decrease in wildlife habitat. Certain species will be vulnerable to traffic. The low permeability of paving materials will generate some further increase in runoff. The effects of mining universally include both removal of peat from the BUREAU OF GEOLOGY site and alteration of the configuration of the landscape (Minnesota Department of Natural Resources, 1981). If drainage is required, the previously discussed environmental effects of drainage must be consid- ered. Wet mining methods do not require drainage. The effects of wet mining on water quality and quantity depend strongly on the design of the operation. Specifically, if the mined area discharges to surface streams, both water quality and quantity may be affected (Minnesota Department of Natural Resources, 1981). Additionally, and critically, given the already enormous demand for water in Florida, wet mining methods may require water beyond that available in the peatland. Since peat is characterized by a high moisture content, dewatering is often necessary during processing. This water may contain an abun- dance of peat fibers as well as nutrients. Water released during dewa- tering, as well as waste water from gasification operations, can generate water quality problems, although the effects may be mitigated if waste water is treated (Minnesota Department of Natural Resources, 1981). The effects of exhaust emission and noise creation are universal in all phases of mining operations. Peat, due to its high moisture content is heavy. The large amounts of it necessary for fuel operations cannot be economically transported. For that reason peat will probably be burned near the site at which it is mined. Emissions from peat combustion are similar to those resulting from combustion of coal. These include nitrogen oxides, sulphur oxides, carbon monoxide, carbon dioxide, hydrocarbons, particulates and com- pounds of trace elements, including mercury and lead (Minnesota Depar- ment of Natural Resources, 1981). PHOSPHATE Discussion River pebble phosphate was discovered in central Florida in the early 1880's in the Peace River near the town of Fort Meade. The river had eroded away the overburden and finer fractions of the Bone Valley Mem- ber, leaving behind concentrations of pebble-size phosphate rock (known as "river pebble") on the river bottom and in the sand bars. The earliest mining of these deposits was in the river channel by hydraulic dredging. The residual or spoil material was returned to the river, thus obliterating any visual record of the activity. Mining of this type was intermittent and records of ore removal are poor. However, it appears that approximately 1.3 million long tons were removed over a period of 20 years before extraction costs caused cessation of opera- tions (Zellars-Williams, 1978). Land pebble phosphate was discovered in the late 1880's, also in the vicinity of Fort Meade. It was this discovery that led to the eventual demise of the hard rock phosphate (so named because it is found as a replacement mineral in limestone) and soft rock phosphate (mined from INFORMATION CIRCULAR NO. 102 the waste ponds of hard rock phosphate operations) industries. The hard rock phosphate district is located in portions of Taylor, Lafayette, Dixie, Gilchrist, Alachua, Levy, Marion, Citrus, Hernando and Sumter counties. Land pebble has larger reserves, is easier to mine, and has lower benefi- ciation costs. The vast majority of phosphate produced in Florida is land pebble, with only a few small companies producing colloidal (soft rock) phosphate. The land pebble deposits of economic importance at the present time are the Central Florida Phosphate District, the Southern Extension of the Central Florida Phosphate District and the Northern District. The Central district is located in portions of Polk, Hillsborough, Hardee and Manatee counties, and the Southern Extension in portions of Hardee, DeSoto, Manatee, Sarasota and Charlotte counties. The Northern District is located in parts of Hamilton, Columbia, Baker, Suwannee, Union, Brad- ford, Alachua and Marion counties (Zellars-Williams, 1978). Geology CENTRAL FLORIDA PHOSPHATE DISTRICT The Central Florida Phosphate District encompasses the southwest corner of Polk County, the southeast corner of Hillsborough County, and extends southward into Hardee and Manatee counties. The phosphate deposits occur as a thin sheet of highly reworked marine and estuarine sediments deposited on the southern flank of the Ocala Arch. The phos- phate appears to have been deposited (for the most part) during the Miocene in warm shallow seas and generally near shore. The Bone Valley Member, Peace River Formation, Hawthorn Group is the primary phosphorite horizon being mined in the phosphate district. The most popular explanation for the formation of the Bone Valley phos- phate deposits is summarized by Altschuler, et al. (1964), "The Bone Valley Formation (Member) is a shallow water marine and estuarine phosphorite .. (it) ... is an excellent example of marine transgression during which the phosphate was derived, by reworking, from the under- lying, weathered, Hawthorn Formation (Group)". The Hawthorn Group, in the Central Florida Phosphate District consists of sandy, phosphatic dolomite or dolomitic limestone of the Arcadia For- mation which is overlain by a predominantly plastic unit of interbedded phosphatic sands, clayey sands, clays and dolomite of the Peace River Formation, including the Bone Valley Member. The Bone Valley Member is the uppermost unit of the Peace River, and may contain several uncon- formities (Scott, 1986). In the central and northern part of the district, the Bone Valley overlies the Arcadia Formation unconformably. In this area, the bottom of the "matrix" (ore zone) is generally marked at the contact between the eroded carbonate surface of the Arcadia and the phosphate-rich sands and clays. Occasionally, a palygorskite-rich clay underlies the matrix. In the southern portion of the Central Florida Phos- BUREAU OFGEOLOG SNORTHEAS SHARROC U SOTHERN L~~' I Il(.hi)r~ J ~I i` r~n, ' 'Oll.r i : -- i i. i, I ..., j% ~~1 .v ' Fi 1 S- Loc lers / r r 5L n 1, I r o n I: ' i c e c c o INFORMATION CIRCULAR NO. 102 phate District the Peace River Formation (undifferentiated) has not been removed by erosion (Scott, 1986). The Bone Valley sediments are generally represented by approximately equal amounts of quartz, clays (chiefly smectite) and carbonate- fluorapatite, although proportions may change significantly within short distances (Altschuler, et al., 1956). Post-depositional alteration of the Bone Valley Member has been severe, and may either diminish or enrich the phosphate concentration. Weathering in the sub-tropical climates of Florida has resulted in lateritic types of leaching, mobilization and super- gene enrichment of phosphate. The weathering results in the alteration of carbonate-fluorapatite to calcium phosphates and aluminum phos- phates. Aluminum phosphates are less soluble than the calcium phos- phates and remain after the upper zones have been leached. Enrichment of uranium is widespread within the leached zone. The more soluble calcium phosphates enrich the lower (ore) zones. The Pleistocene sediments overlying the Bone Valley Member consist of loose quartz sands. The origin of these sands is a subject of debate. Altschuler and Young (1960) consider these sands to be a weathering residuum of the Bone Valley, while Cathcart (1962), supports a primary depositional origin as the result of transgressive Pleistocene seas. Pirkle, et al. (1965) states that the surface sands are not the result of in situ weathering of the Bone Valley Member. SOUTHERN EXTENSION OF THE CENTRAL FLORIDA PHOSPHATE DISTRICT The Southern Extension of the Central Florida Phosphate District encompasses portions of Hardee, Manatee, DeSoto, Sarasota and Char- lotte counties. Initial exploration efforts within the Southern Extension were directed toward the location of high grade deposits similar to the Central District. It was soon realized, however, that the deposits of the Southern Extension had an entirely different depositional history and geologic setting from the Bone Valley type deposits. The Southern Exten- sion contains vast reserves of lower grade material (lower BPL, increased contaminants, especially MgO) which are predominantly contained within an upper plastic section (Peace River Formation) of the Hawthorn Group (Hall, 1983). The sediments of the upper plastic section of the Hawthorn are highly variable in lithologic composition both horizontally and vertically and exhibit evidence of reworking of previously deposited material (Hall, 1983). The traditional Bone Valley type sediments are found only in northwestern Hardee County (Hall, 1983). NORTHERN FLORIDA PHOSPHATE DISTRICT The Northern Florida Phosphate District is present in parts of Hamilton, Baker, Columbia, Union, Bradford, Suwannee, Marion and Alachua coun- ties. This area is within the Northern Highlands physiographic province of BUREAU OF GEOLOGY Figure 12. International Minerals and Chemicals Corp. Clear Springs phosphate mine, Polk County. Photo by Kenneth Campbell. Florida (White, 1970). The Miocene beds pinch out against the flanks of the Ocala Arch to the west. Tertiary sediments deposited earlier than the Miocene in this area are predominantly porous marine limestones which form the Floridan Aquifer. The Miocene sediments are phosphatic sands, clays, clayey sands and carbonates, primarily dolomite. The Hawthorn Group consists of four basic units (Scott, 1983): A basal dolomite is overlain by sands and clays which are overlain by a dolomitic unit. The uppermost unit is a quartz sandy and clayey phosphatic unit. The uppermost plastic unit is the only portion of commercial interest. Sediments overlying the Hawthorn are predominantly comprised of reworked Hawthorn material, marine terrace sediments or fluvial sedi- ments associated with topographic lows. The Pliocene and Pleistocene sediments comprise overburden in the phosphate district approximately 30-feet thick. Mining Although there are several types of phosphate deposits found in Flor- ida (land pebble, hard rock, and soft rock), land pebble is the only source being extensively mined today. The land pebble deposits include the vast majority of the Central Florida and North Florida phosphate districts. ~-lY4 CL---r ~ -QS-r~~c~ INFORMATION CIRCULAR NO. 102 Modern day mining techniques include the almost exclusive use (in Florida) of large electrically powered walking draglines equipped with buckets as large as 71 cubic yards. Only one company has mined with dredges in the recent past. Draglines remove overburden and place it either on adjacent unmined land or into the preceding mined-out cut. After stripping of overburden, the dragline removes the matrix which is then placed in a shallow pit where it is slurried with high pressure water and pumped to the beneficiation plant. Beneficiation of Phosphate Ore Beneficiation of phosphate ore prior to 1929 was a relatively simple and extremely wasteful process. Screens were utilized to separate and recover the coarse phosphate. The sand-sized phosphate was not recov- erable, because no technique existed to separate the sand-sized phos- phate from the quartz sand. More phosphate was lost to the waste "debris" than was recovered. In 1929 a process was introduced which revolutionized the phosphate industry. The advent of the froth flotation process allowed separation of sand-sized phosphate grains from waste grains (primarily quartz sand) of essentially the same size, and resulted in a significant increase in the percent of phosphate recovered from the matrix. Specific reagents are utilized to create a froth to which the treated material adheres, while the other material sinks. Either the phosphate or the waste material can be treated to cause them to float. In a "reverse" process, two flotation stages are utilized to float first phosphate then to float the waste mate- rial which was included in the first float. The reagents used create either an oily or a soapy film on the treated particles. Fuel oil, pine oil, caustic soda, fatty acids, and oleates are examples of the reagents used (Hoppe, 1976). In a typical beneficiation plant, the rougher flotation utilizes anionic reagents (crude fatty acid, fuel oil/kerosene) in agitated tanks with the feed material dewatered to 65 percent solids. Addition of ammonia controls pH (between 9.0-9.5) and helps promote absorption of the reagent coating. Prior to entering the cleaner flotation stage (cat- ionic) the rougher flotation products are scrubbed with water and sulfuric acid to remove the anionic reagents. The cleaned rougher product goes to the cleaner circuit where amine reagents (chemical derivatives of ammonia in which the hydrogen atoms have been replaced by radicals containing carbon and hydrogen: ex. methyl amine) and kerosene condi- tion the surface of any sand particles remaining causing them to float (Hoppe, 1976). Typical recovery from a two stage flotation circuit rejects 99 percent of the free quartz sand and recovers 80 percent of the phosphate grains from the feed (Zellars-Williams, 1978). Flotation concentrate comprises between 10-25 percent of the ore weight. BUREAU OF GEOLOGY Products and Uses Essentially all of the Florida phosphate rock destined for the domestic market is utilized to form wet process phosphoric acid. The rock is digested by sulfuric acid to produce phosphoric acid and waste gypsum (too impure to be commercially useful). Phosphoric acid is then utilized to produce normal superphosphate, triple superphosphate (TSP) and nitrogen-phosphorous-potassium (NPK) complete fertilizer. Phosphoric acid is also reacted with ammonia to produce diammonium phosphate (DAP) and monoammonium phosphate (MAP). Defluorinated phosphate rock is utilized for mineral supplements to livestock and poultry feed. Defluorination is necessary because fluorine is toxic to animals (Opyrchal and Wang, 1981). Elemental phosphorus is utilized in the production of sodium phos- phate detergents among others. Elemental phosphorus is obtained by smelting phosphate rock with coke and quartz in electric furnaces (Opyr- chal and Wang, 1981). Approximately 90 percent of the phosphate produced in recent years has been utilized for agricultural fertilizers. The remainder is utilized in various industrial applications mostly as elemental phosphorus. Some of the common uses include: food preservatives, dyes for cloth, vitamin and mineral capsules, hardeners for steel, gasoline and oil additives, tooth paste, shaving cream, soaps and detergents, bone china, plastics, optical glass, photographic films, light filaments, water softener, insecti- cides, soft drinks, flame resistant lumber, fire fighting compounds and aluminum polish (Florida Phosphate Council, 1984a). Transportation Approximately 85 percent of phosphate rock is transported by rail to port facilities or fertilizer plants. The remainder is transported by truck. Truck transport is utilized during periods of peak production to augment rail transportation, when rail service is interrupted or where low volumes are involved (Opyrchal and Wang, 1981). Transportation by rail and ship or barge is utilized for the majority of shipments out of the state. In 1979 phosphate rock and phosphate prod- ucts accounted for 93 percent of all exports from the Port of Tampa (Boyle and Hendry, 1981). Extensive exports are also shipped from Jack- sonville. Economic Trends In 1983, Florida and North Carolina accounted for 87 percent of the total U.S. and 27 percent of the total world phosphate production (Sto- wasser, 1985a). According to data collected by the U.S. Bureau of Mines, phosphate production increased 10 percent in 1983 from the 1982 figures. Preliminary 1984 figures indicate an increase of approxi- E QUANTITY (MILLION METRIC TONS) W VALUE (MILLIONS OF DOLLARS) P PRELIMINARY DATA W > 46 1000 9 - Z 0 h 00 0C 42 800 N 38 600 34 400 30 200 26 0 1976 1977 1978 1979 1980 1981 YEAR Figure 13. Quantity and value of phosphate in Florida and 1986; U. S. Bureau of Mines, 1977-1983). North Carolina (Boyle, BUREAU OF GEOLOGY mately 18 percent from 1983's depressed levels (Stowasser, 1985a). From a 1983 baseline, phosphate rock demand is expected to increase at an average annual rate of about 1.8 percent through 1990 (Stowasser, 1985a). Reserves The Florida phosphate districts contain 520 million metric tons of phosphate rock reserves (cost less than $35.00 per metric ton) and a reserve base (reserves and resources recoverable at a cost of less than $100 per metric ton) of 2.4 billion metric tons (Stowasser, 1985b). Florida reserves will last more than 250 years at current mining rates (Florida Phosphate Council, 1984b). Environmental Concerns The environmental concerns generally associated with phosphate min- ing include water consumption and power demands, radiation, water and air quality, waste disposal, and wetlands. Steps are being taken to miti- gate these concerns. WATER USAGE Reduction of water usage required by the phosphate industry is being addressed in several ways. Recirculation of mine process water is exten- sive and averages 90 percent throughout the industry. The major mine process which uses water is the clay settling system. Progressive clay settling techniques such as sand-clay mixing, the dredge mix process and chemical flocculation all speed the initial release of this water. Recharge wells are being utilized in pre-mining dewatering. The water in the surficial aquifer is gravity fed into the Floridan Aquifer. This has the dua! advantage of recharging the aquifer to some extent and reducing pumping requirements for mine cut water control. POWER CONSUMPTION Power consumption can be reduced by elimination of phosphate rock drying except where actually necessary. Optimum mine planning can provide an efficient operation thus reducing power consumption. In addi- tion, co-generation of power at chemical plants may afford reduction in the quantity of purchased electrical power. RADIATION Uranium is associated with the phosphate ore. The majority of the uranium in the ore can be extracted as a byproduct. Some uranium remains in overburden materials and waste sands and clays. Radium- 226, a decay product of uranium, has received the most attention INFORMATION CIRCULAR NO. 102 because its decay generates radon gas (Zellars and Williams, 1978). There are not any established limits for allowable radiation in reclaimed mined lands. Pre-mining and post-reclamation radiation readings are now required by the Florida Department of Health and Rehabilitative Services (HRS) which will provide a data base for future decisions. HRS has, in proposed rules, set a limit of 0.020 annual average working level concen- tration of radon gas in new residences built on reclaimed land after the effective date of the rules (Mason Cox, personal communication, 1985). Proposed HRS rules also include recommended construction techniques to ameliorate radon gas concentrations. The primary construction tech- niques include "ventilated crawl space designs" and "improved slab designs" which provide a barrier to radon gas migration. WATER QUALITY Water discharged from phosphate mines must meet requirements specified in discharge permits. The primary water quality problems of the past were associated with breaks in the walls of clay settling ponds. There have been no such breaks since 1971 when the State instituted dam construction standards and mandated regular inspection and main- tenance programs (Zellars and Williams, 1978). Timely land reclamation and revegetation, as now required by the State, minimizes water quality problems associated with mined land. AIR QUALITY Air quality problems associated with phosphate mining are relatively minor. Airborne dust is generated by earth moving activities and expo- sure of bare soil materials and by the dry grinding of phosphate rock. Dust from these sources will be reduced from past levels by timely land reclamation and reclamation of previously mined but unreclaimed lands. As more plants are built utilizing wet grinding, or are converted to the wet process, airborne dust from that process will be limited. Fluorine is extracted from flue gases as an environmental safeguard and is utilized as a byproduct. CLAY WASTE DISPOSAL Conventional clay waste disposal has been done by above ground settling ponds. The clays present in the "matrix" (predominantly smec- tite and palygorskite) are disassociated when the ore is slurried and pumped to the beneficiation plant. These materials are highly resistant to settling and require more storage space as waste clay than they occupied prior to mining. Large quantities of water are thus removed from the recirculating water system both as interstitial water and by evaporation from the settling ponds. Reclamation of full settling ponds is delayed for many years as the clays gradually dewater and settle. The current trend BUREAU OF GEOLOGY is to minimize the surface area covered by settling areas and to maxi- mize clay storage in existing settling ponds (R. Bushey, Florida Bureau of Mine Reclamation, personal communication, 1986). This will require the use of alternative methods of dewatering waste clays such as mixing with sand tailings, dredging pre-settled clay and mixing with sand tail- ings, capping of pre-thickened clays and chemical flocculation (Yon, 1983). These methods are capable of producing ultimate solids contents of 36-42 percent compared to 31 percent for conventional clay settling (Lawver, 1983, citation in Yon, 1983). WETLANDS The State of Florida contains approximately 20 percent of the wet- lands remaining in the U.S. (Zellars and Williams, 1978). These areas are of use as wildlife habitat, for surface water retention, sediment removal and nutrient uptake. In some areas the wetlands may enhance aquifer recharge. Swamps, marshes and river flood plains are common examples of these areas. The decision to mine wetland areas must take into account the value of the phosphate, as well as the ability to reconstruct a functioning wetland. Byproduct Fluorine Fluorine production, in the form of fluosilicic acid (H2SiF,), in Florida is a byproduct of wet-process phosphoric acid production (Boyle and Hen- dry, 1985). The most common ore of fluorine is the mineral fluorite (CaF,) which is commonly known as fluorspar. U.S. reserves of fluorite are not sufficient to meet U.S. demand to the year 2000 (Pelham, 1985). By the end of the century, phosphate rock may be the primary domestic source of fluorine (Pelham, 1985). RECOVERY Phosphate rock (fluorapatite) contains 3-4 percent fluorine (Nash and Blake, 1977). When fluorapatite is treated by the wet-acid process, solu- ble phosphates are formed and part of the fluorine contained in the phos- phate rock is volatilized as HF. HF reacts with silica which is present as an impurity in the fluorapatite, forming the volatile gas silicon tetraf- luoride (SiFj). As SiF, gas evolves it is scrubbed from the gas column and hydrolyzes, fluosilicic acid and silica are formed (Nash and Blake, 1977). Nash and Blake (1977) state, "In the wet acid process about 41 percent of the fluorine in the phosphate rock is volatilized, 13 percent remains in the concentrated acid, and 46 percent is discarded with the gypsum filter cake." Stowasser (1985b) states that overall recovery is rarely greater than 75 percent of the fluorine in the phosphate rock. The remainder is retained as waste in the coolant water pond. U.S. Environmental Protec- INFORMATION CIRCULAR NO. 102 tion agency regulations require that volatile fluorine be scrubbed from stack gasses (Opyrchal and Wang, 1981). USES Fluorine is required in the manufacturing of aluminum, steel, and many chemical compounds (Opyrchal and Wang, 1981), as well as for water fluoridation (Boyle and Hendry, 1985). In 1983 fluosilicic acid from Flor- ida phosphate was used to produce synthetic cryolite, aluminum fluoride and sodium silicofluoride and for water fluoridation (Boyle and Hendry, 1985). ECONOMIC TRENDS In 1985, byproduct fluosilicic acid production from phosphoric acid (nationwide) totaled 63,000 tons, the equivalent of 110,000 tons of fluorspar (Pelham, 1986). Estimated primary fluorspar production for the same period is 70,000 tons. Demand for fluorine is expected to increase at an annual average rate of 3.7 percent through 1990 (Pelham, 1986). Resources of fluorine in U.S. phosphate rock are estimated to be 35 million tons of fluorspar equivalent (Pelham, 1986). Byproduct Uranium GEOLOGY Uranium is produced as a byproduct of Florida's phosphate mining and beneficiation in the Central Florida Phosphate District and its southern extension. Uranium was discovered to be associated with the phos- phates found in Florida in 1949 (Altschuler, et al., 1956). Because of the lack of suitable technology, only recently has it become economically feasible to remove the uranium from phosphate rock. Uranium is present in the pebble-size phosphate of the Central Florida Phosphate District at concentrations ranging from 0.010 percent to 0.020 percent, and from 0.005 percent to 0.015 percent in the finer phosphates (Cathcart, 1956). The phosphate deposits of North Florida contain an average of 0.006 percent uranium which is not presently economically recoverable by the wet process method. The uranium content of the quartz sand fraction of the matrix is generally less than 0.001 percent while phos- phatic waste clays generally have a uranium content of less than 0.005 percent. A potential source of uranium, phosphate, and alumina in the Central Florida Phosphate District is the leach zone. This zone overlies the phos- phate matrix and derives its name from its being a residuum of weather- ing of the matrix. It is also known as the aluminum phosphate zone, as the leaching has enriched the phosphate in aluminum. Because of its low phosphate content, it is not always sent to the plant for processing. The BUREAU OF GEOLOGY average thickness of this zone is six to seven feet, and its uranium content ranges from 0.010 percent to 0.015 percent (Altschuler, et al., 1956). EXTRACTION Uranium is extracted from phosphate by a two phase solvent extrac- tion system. In the first phase, the uranium is removed from wet process phosphoric acid by solvent extraction. The resulting uranium-bearing solution then undergoes a second solvent extraction and stripping stage to produce specification grade uranium oxide (U308) called yellow cake (Sweeney and Windham, 1979). One ton of U3O, yields one pound of fuel grade U2a,. ECONOMIC TRENDS In 1980, the only year for which information is available, Florida ura- nium oxide production was approximately 1.5 million pounds (750 short tons). Nuclear Exchange Corporation (1986) reports that in 1985 3.3 million pounds (1650 short tons) of uranium oxide were produced from phosphoric acid. The vast majority of this would be from Florida phos- phate rock. The U.S. Bureau of Mines (Stowasser, 1985b) reports five companies with a combined annual recovery potential of 1,870 short tons of U30, from the Central Florida Phosphate District. Based on the production capacity figures above, up to 15 percent of the U.S. uranium demand could be met by byproduct uranium recovery from Florida phosphate rock (Sweeney, 1979). RESERVES Florida's reserves of uranium are directly dependent on the reserves of phosphate. Only the uranium oxide contained in phosphate rock treated by the wet-process phosphoric acid method is economically feasible for recovery. The central and southern Florida phosphate deposits contain approximately 1.5 billion short tons of phosphate rock recoverable at $ 15-20 per short ton (Zellars and Williams, 1978). Assuming an average uranium oxide content of 0.015 percent, approximately 225,000 short tons of uranium oxide are present in the deposits (Sweeney, 1979). In general, for central and southern Florida deposits one pound of U,30 can be extracted from one short ton of P20s (Sweeney, 1979). INFORMATION CIRCULAR NO. 102 SAND AND GRAVEL Geology Quartz sand is one of Florida's most abundant natural resources. Almost all of Florida is blanketed with a veneer of sand. Very few areas within the state do not have deposits of general purpose sand located within reasonable distances (Scott, et al., 1980). Commercial quantities of gravel are present only in the western panhandle of Florida, associated with modern day river deposits. The identification of terraces and previous shorelines has been based on elevation. Terraces which have been mapped in Florida include the Silver Bluff, Pamlico, Talbot, Penholoway, Wicomico, Sunderland, Coha- rie and the Hazelhurst. Shorelines associated with these terraces were at approximately 10, 25, 50, 70, 100, 170, 220 and 320 feet, respectively (Cooke, 1945; Healy, 1975). The sand deposits associated with the marine terraces are composed primarily of quartz sand with various amounts of silt, clay and organic matter. According to Cooke (1945) the older (high) terraces contain the coarsest material while the younger (low) terraces contain finer sand plus clay and carbonate. In addition, the lower deposits are thinner and con- tain more clay, silt and organic in south Florida relative to the northern deposits (Cooke, 1945). Scott, et al. (1980) divided sand and gravel deposits in Florida into four categories: 1) recent beach type deposits (wave or wind derived); 2) river alluvium; 3) marine terrace deposits, including associated relict bars, dunes and beach ridges; and 4) sand and gravel from a particular geo- logic formation. NORTHWEST FLORIDA The plastic sediments found in northwest Florida overlie sediments which range in age from Eocene to Pleistocene. Thickness of the clastics ranges from a thin veneer in the vicinity of Leon and Wakulla counties to greater than 1,500 feet in the Pensacola area. Most of the sand and gravel mined in northwest Florida is derived from marine terrace sands (Leon and Wakulla counties south of Tallahassee) and from the Citronelle Formation in Escambia County where sand and gravel are mined (Scott, et al., 1980). The Citronelle Formation is of Pliocene or early Pleistocene age (Vernon, 1951) and consists of "angu- lar to subangular, very poorly sorted, fine to very coarse grained quartz sand." Lenses of gravel and clay are also present (Scott, et al., 1980). The Citronelle Formation, and fluvial sediments derived from it are the only appreciable. source of gravel found in the state. BUREAU OF GEOLOGY NORTH FLORIDA Several units containing significant quantities of sand are present in north Florida. Scott, et al. (1980) lists them as the Hawthorn Group, Miccosukee and Alachua formations, an unnamed coarse plastic unit and the undifferentiated Pliocene and younger sands, which include the ter- race deposits. Utility of the sands contained in the Hawthorn Group and Miccosukee Formation is limited by wide variability of lithologic characteristics. Tex- ture and lithology of both formations vary widely in both the horizontal and vertical directions. Use is precluded except for local uses such as fill and road base material (Scott, et al., 1980). The Alachua Formation, Which locally reaches thickness of 100 feet is considered to be residuum of the Hawthorn Group. Material from the Alachua Formation is suitable for road base and fill material (Scott, et al., 1980). The Lake Wales Ridge extends from western Clay County southward into Highlands County. The ridge is composed of thick deposits (up to 150 feet) of plastic sediments of relatively uniform lithology. The clastics consist of loose surface sands which overlie red, yellow, and white clayey sands. Locally, quartz gravel and quartzite pebbles are present. Terrace deposits are of variable thickness, with clay and organic mat- ter as the major contaminants. The terrace sand deposits comprise a significant resource (Scott, et al., 1980). CENTRAL FLORIDA The numerous sand ridges of the Central Highlands contain the sand deposits of greatest importance in central Florida. The majority of the construction sand mined in Florida comes from these deposits which are composed of Mio-Pliocene age clastics (Cooke, 1945; Scott, 1978). The plastics are predominantly poorly sorted quartz grains ranging in size from fine sand to pebble. With the exception of surface sands, the sands contain, in most cases a kaolinite matrix. Recent dune and alluvium sand deposits are present, but are of varia- ble quality and low volume. These deposits are economically important only on a local scale. Scott, et al. (1980) states that although the Atlantic Coastal Lowlands do not contain large sand deposits there is potential for limited produc- tion. This production is from discontinuous beds in the Pleistocene age Anastasia Formation and Pleistocene terrace deposits as well as recent alluvial and dune deposits. These deposits are only locally important. The majority of sand deposits in the Gulf Coastal Lowlands are related to Pleistocene terraces. Although these deposits are too fine grained for construction uses, they have been mined for glass sand in the Plant City area (Wright, 1974). INFORMATION CIRCULAR NO. 102 oil Figure 14. Suction dredge used in sand mining. Florida Bureau of Geol- ogy file photo. SOUTH FLORIDA The majority of the sand deposits in the south Florida region are of local importance only and are utilized for construction sand, blasting grit and fill material. The Pleistocene terrace sands, Anastasia Formation, Fort Thompson Formation, and the Pliocene-Pleistocene Caloosahatchee Formation, all contain sand deposits of local importance. The Pliocene age Tamiami Formation is presently being mined for sand in Glades County (Scott, et al., 1980). Mining and Beneficiation The sand mined in Florida is produced by surface mining. Depending on the level of the water table, either earthmoving equipment or suction dredges are utilized to mine sand. For most purposes, sand must be graded by size. The typical operation pumps sand in a slurry to a set of screen shakers to separate the coarse fraction into several size fractions. The fines are pumped to a settling pond while the coarse fraction is loaded or stockpiled (Scott, et al., 1980). 43 BUREAU OF GEOLOGY Uses In 1984, construction sand and gravel made up approximately 96 per- cent of total United States sand and gravel production (Tepordei, 1985a). Industrial sand and gravel made up 7.3 percent of Florida's 1984 production (Boyle, 1985). Glass, foundry, and abrasive sands are produced as byproducts of the kaolin and heavy mineral industries. The major uses of construction sand and gravel are concrete aggregates, roadbase material, construction fill, and asphalt mixtures. For industrial sand the major uses are glass making and foundry sand. Transportation Sand and gravel are transported by truck, rail and barge. In 1982, 87 percent of all construction sand and gravel was shipped by truck, four percent by rail and waterway with the remainder utilized on site (Tepor- dei, 1983). Construction sand and gravel in Florida are transported almost exclusively by truck. Industrial sand and gravel, however, are transorted by both truck and rail. In 1983 truck transport accounted for 68 percent while rail accounted for 27 percent and barge accounted for four percent of the national industrial sand and gravel total (Tepordei, 1984a). Economic Trends Production of sand and gravel in Florida increased in 1985 from 1984 levels, according to preliminary U.S. Bureau of Mines figures for 1985. Construction sand and gravel production was up seven percent while industrial sand and gravel produced during the same period rose less than two percent, while value for industrial sand and gravel rose approxi- mately 12 percent from 1984 levels (Boyle, 1986). Demands for sand and gravel can be expected to increase at an approximate one to two percent annual rate through 1990 (Tepordei, 1985a). Reserves Reserves of sand in Florida are large. Due to the low value per ton many constraints such as distance to market and conflicting land uses play a part in determining whether deposits are mineable. Environmental Concerns Environmental concerns associated with sand and gravel mining in Florida are relatively minor. Water pollution from organic and clays sus- pended during wet pit mining operations is the primary problem. This can be controlled in most cases as fines are pumped back into mined out areas. In some cases settling ponds may be needed to ensure quality of water to be discharged. QUANTITY ( MILLIONS OF SHORT TONS ) cc "4 I VALUE ( MILLIONS OF DOLLARS ) 5) e 1976 1977 1978 1979 1980 1981 1982 1983 1984 1985 YEAR Figure 15. Quantity and value of sand and gravel (Boyle, 1986; U. S. Bureau of Mines, 1977 1983). BUREAU OF GEOLOGY STONE Geology Limestones and dolomites ranging in age from late Middle Eocene to Pleistocene are presently mined in Florida (Schmidt, et al., 1979). The primary geologic factors which control the mining potential of limestones and dolomites are lithology, structure and geomorphology. Lithology is the most important factor and it is the most variable. Structure and geomorphology, however, control unit thickness and overburden depth which are important as limiting factors in determining whether mining is economically feasible. NORTHWEST FLORIDA Most of the panhandle of Florida is underlain by thick plastic sequences. Limestone and dolomite crop out in Holmes, Jackson, Walton and Washington counties. The lithologic units which make up the limestone and dolomite resources in this area range from the Upper Eocene Ocala Group through the Oligocene age Marianna and Suwannee limestones to the Upper Oligocene and Miocene (Poag, 1972) Chatta- hoochee Formation (Schmidt, et al., 1979). The Ocala Group limestones are white to cream colored, poorly indu- rated, permeable, fossiliferous limestones of high purity. Textures range from very chalky to a foraminiferal microcoquina to a coarse allochemical limestone composed almost entirely of fossil material (Schmidt, et al., 1979). The Ocala Group is 200 to 300-feet thick in this region according to several authors (Vernon, 1942; Moore, 1955; Puri, 1957; Reves, 1961) and dips to the south and southwest at 12 to 20-feet per mile (Vernon, 1942; Reves, 1961). The Marianna Limestone overlies the Ocala Group and crops out in a narrow band to the south and southwest of the Ocala Group. This lime- stone is white, cream or light gray in color, is massive, calcilutitic and is poorly indurated in fresh exposures, but casehardens after exposure. Some beds may be composed almost completely of large foraminifera (Moore, 1955). The Marianna Limestone is generally 25 to 40-feet thick but thins to zero due to erosion toward the area of the Eocene outcrop (Schmidt, et al., 1979). The Marianna Limestone dips to the south at 11 to 18-feet per mile (Vernon, 1942). The Suwannee Limestone overlies the Marianna Limestone and crops out to the south of the Marianna Limestone outcrop belt. The Suwannee Limestone is cream to buff colored, poorly to well indurated, porous, massive and highly fossiliferous (Schmidt, et al., 1979). The thickness ranges from a feather edge at the Marianna outcrop to over 200-feet thick down dip. The Chattahoochee Formation overlies the Suwannee Limestone unconformably and crops out to the south of the Suwannee Limestone INFORMATION CIRCULAR NO. 102 )utcrop belt. The lithology of the Chattahoochee Formation is quite vari- 3ble and ranges from a sandy, silty, dolomite with greenish, clayey silts at its base to a white to cream colored, very silty to sandy, chalky to crys- talline dolomite of variable induration which contains lenses of clay. Locally, the base of the formation may consist of cream to brown, finely sucrosic dolomite (Hendry and Yon, 1958). The Chattahoochee Forma- tion ranges from 50 to 227-feet thick and dips to the south at 12 to 20- feet per mile (Vernon, 1942). THE WESTERN ONE-HALF OF NORTH AND CENTRAL PENINSULAR FLORIDA This area extends from Wakulla and Jefferson counties in the "Big Bend" of Florida southward to Manatee County. The limestone resources include the Avon Park Limestone of late middle Eocene age, the Upper Eocene Ocala Group, the Oligocene Suwannee Limestone, the Miocene St. Marks Limestone, and the Miocene Hawthorn Group. The Avon Park Limestone, where it is being mined, is a tan to brown, thin bedded dolomite. The formation varies from poorly indurated and porous to well indurated and dense. Fossil molds, lignite, carbonaceous plant remains, and beds of dolosilt are common (Schmidt, et al., 1979). In Levy County where the formation crops out Vernon (1951) estimates the formation thickness to be 200 to 300 feet. East of the crest of the Ocala Uplift the Avon Park dips to the northeast and east at approxi- mately 15-feet per mile; west of the crest the formation dips to the southwest at the same rate. The Ocala Uplift plunges gently to the south- east and the Avon Park follows this trend (Schmidt, et al., 1979). The limestone of the Upper Eocene Ocala Group overlies the Avon Park and crops out in an oval pattern around the Avon Park outcrop. The Ocala Group dips in all directions off of the elongate Ocala Uplift. In this area, the Ocala Group is subdivided into three formations (Puri, 1957) in ascending order, the Inglis, Williston and Crystal River formations. The Inglis Formation is a cream to tan, porous, granular, massive, fossiliferous limestone of moderate induration which occasionally is a coquina of foraminifera, molluscs and echinoids (Vernon, 1951). The base of the unit is generally dolomitized to some degree and is generally marked by a rubble zone of Avon Park lithology (Vernon, 1951). The Inglis Formation is approximately 50-feet thick (Schmidt, et al., 1979). The Williston Formation overlies the Inglis and crops out in an annular band around the Inglis. Two lithologies which are interbedded predomi- nate in the Williston. One is a soft, friable, cream colored, foraminiferal coquina. The other is a cream to tan colored, highly fossiliferous detrital limestone (Vernon, 1951). The top of the formation is gradational with the overlying Crystal River Formation. The Williston is approximately 30- feet thick (Vernon, 1951). The Crystal River Formation overlies the Williston and crops out in a band around the Williston. Typically the formation is a white to cream BUREAU OF GEOLOGY colored, soft, massive and friable coquina consisting almost entirely of large foraminifera in a pasty calcitic matrix (Vernon, 1951). Thin beds of more granular, miliolid-rich limestone occur throughout the formation, but especially near the base, as a transition zone with the Williston For- mation (Vernon, 1951). The thickness of the formation is variable due to post-depositional erosion. The formation ranges in thickness from zero to approximately 300 feet in the subsurface of the central peninsula. The Suwannee Limestone of the Oligocene Epoch unconformably overlies the Ocala Group. The Suwannee Limestone is typically pale orange in color, thin bedded, of variable hardness and porosity, finely crystalline and highly fossiliferous. To the north in Jefferson and Taylor counties the Suwannee is dolomitized to varying degrees. Throughout the outcrop area silicified limestone boulders are common (Schmidt, et al., 1979). The Suwannee crops out at the northwest and south ends of the Ocala Group outcrop area. The thickness of the Suwannee is variable due to erosion but is greater than 200 feet in the subsurface in Pasco and Hernando counties (Schmidt, et al., 1979) The St. Marks Limestone overlies the Suwannee Limestone in the "Big Bend" area of Florida, cropping out in Wakulla and Jefferson counties. The St. Marks is considered to be Early Miocene in age (Schmidt, et al., 1979). Yon (1966) describes the St. Marks as a white to pale orange, finely crystalline, sandy, silty and clayey limestone with poor to moder- ate porosity. The formation dips to the south and has a maximum thick- ness of approximately 120 feet (Yon, 1966). The Tampa Member of the Arcadia Formation, Hawthorn Group (Scott, 1986) is present in Hillsborough, Pinellas, Sarasota, Manatee, and west- ernmost Polk, Hardee and DeSoto counties. The Tampa is considered to be Early Miocene or Late Oligocene in age, based on correlations by MacNeil (1944) and Poag (1972). King and Wright (1979) described the Tampa as a quartz sandy limestone with a carbonate mud matrix. The formation contains only trace amounts of phosphate, no clay seams and 10 30 percent fine to very fine quartz sand. Localized beds within the Tampa contain over 50 percent quartz sand. The carbonate matrix is dolomitized locally. The Tampa Member is of variable thickness. In the type core, W- 11541, SE 1/4, NW 1/4 of Section 11, Township 30S, Range 18E, Hillsborough County, the formation is 55-feet thick. Thickness is reduced to zero to the north due to erosion. The formation dips generally to the south. The Lower to Middle Miocene Arcadia Formation of the Hawthorn Group overlies and interfingers with the Tampa Member. The Arcadia Formation is predominantly a carbonate unit. Typically the carbonate is white to yellowish gray, silty, sandy, phosphatic dolomite (Scott and MacGill, 1981). The degree of dolomitization varies greatly and beds of loosely consolidated silt sized dolomite occur. The Arcadia Formation INFORMATION CIRCULAR NO. 102 dips to the south and thickens down dip ranging in thickness from zero to 250- feet thick in the subsurface (Scott, 1986). ATLANTIC COAST Limestone and lithified coquina are mined from St. Johns County in the north southward to the Keys in Monroe County. The Pleistocene Anasta- sia Formation and Miami Oolite form the backbone of the Atlantic Coastal Ridge. The lithified coquina is found in the Anastasia Formation southward to approximately the Palm Beach-Broward County line. South to the Keys the Miami Oolite is present (Schmidt, et al., 1979). The Upper Keys, from Soldier Key to Big Pine Key, are composed of the Pleistocene age Key Largo Limestone. The Lower Keys are composed of the Miami Oolite (Vernon and Puri, 1964). The Anastasia Formation lithologically consists of a sandy coquina loosely cemented with calcite (Vernon and Puri, 1964). The Anastasia represents an ancient beach and is present only in a narrow band near or on the present coast. The formation may exceed 100-feet thick in some areas according to Parker, et al. (1955). The Miami Oolite is a soft, white to yellow, stratified to massive, cross bedded, sandy to pure limestone of oolitic origin (Puri and Vernon, 1964). The formation reaches a thickness of almost 40 feet beneath the Atlantic Coastal Ridge, but thins rapidly away from the ridge. The Miami Oolite interfingers with the Anastasia Formation on the north and the upper Key Largo Limestone on the south. The Miami Oolite overlies the lower part of the Key Largo Limestone (Schmidt, et al., 1979). The Key Largo Limestone preserves a Pleistocene age coral reef tract and its associated environments. The Key Largo is a white to cream colored, coralline and skeletal limestone. Approximately 40 percent of the formation is composed of reef building corals with the remainder being a conglomerate of skeletal detritus. Skeletal material derived from coral, coralline algae, molluscs, echinoids, and foraminifera is common (Puri and Vernon, 1964). The Key Largo interfingers with the Miami Oolite and the Fort Thomp- son Formation (Schmidt, et al., 1979). The formation is reported to be about 60-feet thick by Parker, et al. (1955). SOUTHWEST FLORIDA The limestone resources of the southwest portion of Florida are extracted primarily from the Pliocene age Tamiami Formation. The area of active mining includes Lee, Hendry, and Collier counties (Schmidt, et al., 1979). The Tamiami Formation is in part a tan to white, soft to hard, sandy and abundantly fossiliferous limestone. Molluscs, barnacles, echinoids and corals are common. Preservation of the fossils is varied depending on the amount of recrystallization (Meeder, 1979). BUREAU OF GEOLOGY Figure 16. Limestone quarry, Citrus County. Photo by Tom Scott. Mining and Beneficiation All limestone, dolomite and coquina mined in Florida is mined by open pit methods. Mining methods vary depending on the position of the water table (wet or dry pit) and the hardness of the rock. In almost all cases, overburden must be removed to gain access to the rock. Overbur- den is normally stripped using bulldozers or draglines and is stacked near the mine site. In some cases the overburden material is marketable as a byproduct (sand, clay, peat, etc.). The easiest mining occurs in dry pit, soft rock conditions where bull- dozers equipped with a claw can rip the rock loose. Where pits are flooded, draglines are utilized to remove the rock. Under certain condi- tions both methods may be utilized in mining the same pit. As rock hardness increases, blasting becomes necessary prior to mining. After rock is mined it may be loaded directly for transport to a processing plant or may be crushed and stockpiled. Processing operations are those which physically change a material on the way to becoming a finished product (Schmidt, et al., 1979). For the most common uses of limestone, dolomite and coquina (crushed stone and aggregate material) size reduction and grading are the primary pro- INFORMATION CIRCULAR NO. 102 MCA . .' .- .- , . ... .... ....", .- ,'* ': ,^'5 '3 e:. . Figure 17. Limestone quarry, mining below water level with dragline. Photo by Tom Scott. cessing procedures. This involves crushing and screening to produce the desired size material. Beneficiation processes are those which upgrade the material by removing inpurities or adding desirable materials (Schmidt, et al., 1979). The most common beneficiation processes for limestone, dolomite and coquina are washing, screening, drying and blending. Products and Uses The major uses of crushed stone in Florida are for road base material, concrete and asphalt aggregate, cement manufacturing, fertilizer, soil conditioners and rip rap. Transportation Crushed stone is transported by truck and rail in Florida. Truck trans- port represents the principle method of transportation, with 84 percent of the total tonnage for 1983. Rail carried six percent while five percent was transported by waterway, while other or unspecified methods car- ried the remainder (Tepordei, 1984b). Shipment by water has been a minor method of transportation in the past. rn. * QUANTITY I MILLIONS OF SHORT TONS ) | VALUE ( MILLIONS OF DOLLARS ) p PRELIMINARY DATA 1976 1977 1978 1979 1980 1981 1982 1983 1984 1985 Figure 18. Quantity and YEAR value of crushed stone (Boyle, 1986; U. S. Bureau of Mines, __ 5 ~ 177 1983). * -1 INFORMATION CIRCULAR NO. 102 Economic Trends 1985 production and value of crushed stone in Florida increased approximately eight percent from 1984 levels (Boyle, 1985). Nationwide demand for crushed stone is expected to increase at a one percent annual rate through 1990 (Tepordei, 1985a). Reserves Florida limestone reserves are very large and may be considered practi- cally unlimited (Tepordei, 1985b). Large portions of the peninsula of Florida and portions of the panhandle are underlain by limestone. Edger- ton (1974) suggested that limestone reserves in Dade, Broward and Palm Beach counties totaled 102 billion tons, of which 34 billion tons were readily available for mining. The remainder was rendered unavail- able either by urban development or statutory constraints. Environmental Concerns The major environmental problems with the mining of stone in Florida include dust, noise, traffic, vibration (Singleton, 1980) and aquifer pro- tection. Dust control measures in the quarry and plant areas can mini- mize dust related air pollution. Examples of effective measures are sprin- kling with water and dust collection systems. Artificial or natural screens can reduce noise and visual impact of quarries and plants. Vibration problems can be controlled by ripping rock where possible and blasting only when necessary. Special blasting techniques can also reduce vibra- tion. Since most limestones and dolomites mined in the State are portions of, or are contiguous with regional aquifer systems, the quarry repre- sents a direct route of access to the aquifer. If poor quality water is allowed to enter the quarry, that water has direct access to the aquifer. Control of on and off site drainage can prevent these problems. BUREAU OF GEOLOGY REFERENCES Adams, W. T., 1984, Magnesium Compounds, in Minerals Yearbook, 1983: U.S. Bureau of Mines, Vol. I, pp. 587 592. 1985, Zirconium, in Mineral Commodity Summaries 1985: U.S. Bureau of Mines, pp. 178- 179. Altschuler, Z. S., E. B. Jaffe, and F. Cuttitta, 1956, The Florida Alumi- num Phosphate Zone of the Bone Valley Formation, Florida, and its Ura- nium Deposits: U.S. Geological Survey Professional Paper 300, pp. 495- 504. and E. J. Young, 1960, Residual Origin of the Pleisto- cene Sand Mantle in Central Florida Uplands and Its Bearing on Marine Terraces and Cenozoic Uplift: U.S. Geological Survey, Professional Paper 4008, pp. B202-B207. J. B. Cathcart, and E. J. Young, 1964, Geology and Geochemistry of the Bone Valley Formation and its Phosphate Deposits, West-central Florida: Field Trip Guidebook No. 6, Annual Meeting of the Geological Society of America, 68 p. American Association of Petroleum Geologists, Explorer, December, 1981. Ampian, S. G., 1985a, Clays, in Mineral Facts and Problems: U.S. Bureau of Mines, Bull. 675, pp. 157- 169. 1985b, Clay, in Mineral Commodity Summaries, 1985: U.S. Bureau of Mines, pp. 34 35. Applegate, A. V., and J. M. Lloyd, 1985, Summary of Florida Petroleum Production and Exploration, Onshore and Offshore, through 1984: Flor- ida Geological Survey Information Circular 101, 69 p. Bond, P. A., K. M. Campbell and T. M. Scott, 1984, An Overview of Peat in Florida and Related Issues, Report to the Florida Legislature: Florida Bureau of Geology Open File Report No. 4, 228 p. Boyle, J. R., 1986, The Mineral Industry of Florida in 1985: U.S. Bureau of Mines, Annual Preliminary Mineral Industry Survey. Sand C. W. Hendry, Jr., 1985, The Mineral Industry of Florida, 1983, in Minerals Yearbook, 1983: U.S. Bureau of Mines, V. 2, pp. 137-148. and C. W. Hendry, Jr., 1984, The Mineral Industry of INFORMATION CIRCULAR NO. 102 Florida, 1982, in Minerals Yearbook, 1982: U.S. Bureau of Mines, V. 2, pp. 133-143. and C. W. Hendry, Jr., 1983, The Mineral Industry of Florida, 1981, in Minerals Yearbook, 1981: U.S. Bureau of Mines, V. 1, pp. 127 137. and C. W. Hendry, Jr., 1982, The Mineral Industry of Florida, 1980, Minerals Yearbook, 1980: U.S. Bureau of Mines, V. 2, pp. 127- 137. and C. W. Hendry, Jr., 1981, The Mineral Industry of Florida, 1977, 1978, 1978: in Minerals Yearbook, 1978-1979: U.S. Bureau of Mines, V. 2, pp. 133-142. Calver, J. L., 1957, Mining and Mineral Resources: Florida Geological Survey Bulletin 39, 132 p. Carpenter, J. H., J. C. Detweiler, J. L. Gillson, E. C. Weichel, Jr., and J. P. Wood, 1953, Mining and Concentration of Ilmenite and Associated Minerals at Trail Ridge Florida: Mining Engineering 8/53, pp. 789- 795. Cathcart, J. B., 1956, Distribution and Occurrence of Uranium in the Calcium Phosphate Zone of the Land-Pebble Phosphate District of Flor- ida: U.S. Geological Survey Professional Paper 300, pp. 489 494. 1962, Economic Geology of the Keysville Quadran- gle, Florida: U.S. Geological Survey Bulletin, 1128, pp. 1 -82. Christ, K. D., M. D. Bently, M. B. Brewer, S. Ray, B. Sisk, M. L. Stursa and R. S. Wright, 1981, Florida Energy Resource, 1981: State of Florida, Governor's Energy Office, Tallahassee, Florida, 111 p. Conley, J. E., H. Wilson, T. A. Klinefelter and others, 1948, Production of lightweight concrete aggregate from clays, shales, slates and other materials: U.S. Bureau of Mines, RI 4401, 121 p. Cooke, C. W., 1945, Geology of Florida: Florida Geological Survey Bulle- tin 29, 342 p. Dana, E. S., 1946, Dana's Manual of Mineralogy, 5th edition (revised): C. S. Hurlbut, Jr., John Wiley and Sons, Inc. pub., New York, p. 345. Davis, C. L., 1985a, Peat Producers in the United States in 1984: U.S. Bureau of Mines, Mineral Industry Surveys, 16 p. 1985b, Peat, in Mineral Commodity Summaries, 1985: U.S. Bureau of Mines, pp. 10-111. BUREAU OF GEOLOGY Davis, J. H., 1946, The Peat Deposits of Florida, Their Occurrence, Development and Uses: Florida Geological Survey Bulletin 30, 250 p. Edgerton, C. D., 1974, Effects of Urbanization Upon the Availability of Construction Materials in Southeastern Florida: U.S. Bureau of Mines, IC- 8664, 19 p. Evans, Clarence H., 1955, Staurolite--New Industrial Mineral: American Institute of Mining and Metallurgical Engineers Annual Meeting, 1955. Florida Phosphate Council, 1984a, Phosphate Feeds You, 14 p. 1984b, Economic Fact Sheet, 1984. Garner, T. E., Jr., 1971, Heavy Mineral Mining and Processing in North Central Florida, in Geological Review of Some North Florida Mineral Resources: Southeastern Geological Society 15th Field Conference Guidebook, pp. 26- 33. 1972, Economic Geology of Florida Heavy Mineral Deposits, in Proceedings Seventh Forum of Geology of Industrial Miner- als: Florida Bureau of Geology Special Publication 17, pp. 17- 19. Gilson, J. L., 1959, Sand Deposits of Titanium Minerals: Mining Engi- neering, Vol. 11, Part 1, p. 421 -429. Griffin, George M., C. C. Weiland, L. Q. Hood, R. W. Goode, III, R. K. Sawyer, and D. F. McNeill 1982, Assessment of the Peat Resources of Florida, with a Detailed Survey of the Northern Everglades: State of Florida, Governor's Energy Office, Tallahassee, Florida, 190 p. Gurr, T., 1972, The Geology of a Central Florida Peat Bog, Section 26, Township 30 South, Range 25 East, Polk County, Florida: Unpublished Master's Thesis submitted to the University of South Florida, 86 p. Hall, R. B., 1983, General Geology and Stratigraphy of the Southern Extension of the Central Florida Phosphate District: Geological Society of America, S. E. section, Field Trip Guidebook, March 16, 1983, pp. 1 -27. Hall, W. B., and R. E. Ela, 1978, Cement: U.S. Bureau of Mines, Mineral Commodity Profiles No. 26, 21 p. Healy, Henry G., 1975, Terraces and Shorelines of Florida: Florida Bureau of Geology Map Series 71. Hedrick, J. B., 1985, Rare Earth Metals, in Mineral Commodity Summar- ies; U.S. Bureau of Mines, pp. 124- 125. INFORMATION CIRCULAR NO. 102 Hendry, C. W., Jr., and J. W. Yon, 1958: Geology of the Area in and Around the Jim Woodruff Reservoir: Florida Geological Survey Report of Investigation 16, Part I, pp. 1 52. Hoope, Richard, 1976, From Matrix to Fertilizer: Florida's Phosphate Industry Girds to Produce over 50 million TPY: Engineering and Mining Journal, September 1976, pp. 81 -93. Hosterman, John W., 1973, Clays, in United States Mineral Resources: U.S. Geological Survey Professional Paper 820, pp. 123- 131. Independent Petroleum Association of America 1978- 84, The Oil Pro- ducing Industry in Your State. Johnson, Wilton, 1985, Cement, in Mineral Commodity Summaries, 1985: U.S. Bureau of Mines, pp. 28 29. King, K. C., and Ramil Wright, 1979, Revision of The Tampa Formation, West-central Florida: Transactions, Gulf Coast Association of Geological Societies, Volume XXIX, pp. 257 262. Kopstein, Melvyn, 1979, Peat-Prospectus: United States Department of Energy, Division of Fossil Fuel Processing, 79 p. Kramer, D. A., 1985a, Magnesium Compounds, in Mineral Facts and Problems: U.S. Bureau of Mines, Bull. 675, pp. 471 -482. 1985b, Magnesium Compounds, in Mineral Com- modity Summaries, 1985: U.S. Bureau of Mines, pp. 94-95. Lefond, S. V., 1975, Industrial Minerals and Rocks, 4th ed.: Copyright by Am. Inst. of Mining, Metallurgical, and Petroleum Engineers, Inc., 1360 p. Lynd, L. E., 1980, Titanium, in Mineral Facts and Problems: U.S. Bureau of Mines, Bull. 671, pp. 961 -978. 1985a, Ilmenite and Rutile, in Mineral Commodity Summaries, 1985: U.S. Bureau of Mines, pp. 70 71 and 130-131. 1985b, Titanium, in Mineral Facts and Problems: U.S. Bureau of Mines, Bulletin 675, pp. 859-879. and R. A. Hough, 1980, Titanium, in Minerals Year- book, 1980: U.S. Bureau of Mines, Volume 1, pp. 843-856. MacNeil,F. S., 1944, Oligocene Stratigraphy of Southeastern United States: American Association of Petroleum Geologist, Bulletin V. 28, pp. 1313-1354. BUREAU OF GEOLOGY McPherson, B. F., G. V. Hendrix, H. Klein, and H. M. Tyus, 1976, The Environment of South Florida, A Summary Report: United States Geolog- ical Survey Professional Paper 1011, 81 p. Meeder, J. F., 1979, A Field Guide with Road Log to the Pliocene Fossil Reef of Southwest Florida: Miami Geological Society, 19 p. Minnesota Department of Natural Resources, 1981, Minnesota Peat Pro- gram Final Report: The Minnesota Department of Natural Resources, St. Paul, 93 p. Moore, Christine M., 1980, Rare Earth Elements and Yttrium, in Mineral Facts and Problems, 1980: U.S. Bureau of Mines, Bulletin 671, pp. 737 752. Moore, P. and D. Bellamy, 1974, Peatlands: London, Elek Science, 221 p. Moore, W. E., 1955, Geology of Jackson County, Florida: Florida Geo- logical Survey Bulletin 37, 101 p. Nash, B. D. and H. E. Blake, Jr., 1977, Fluorine recovery from phosphate rock concentrates: U.S. Bureau of Mines, RI 8205, 16 p. Nuclear Exchange Corporation, 1986, Monthly Report on the Nuclear Fuel Market, Feb. 1986. Olson, D., T. J. Malterer, D. R. Mellen, B. Leuelling, and E. J. Tome, 1979, Inventory of Peat Resources in Southwest St. Louis County, Min- nesota: The Minnesota Department of Natural Resources, Hibbing, Min- nesota, 76 p. Opyrchal, Anthony M. and Kung-Lee Wang, 1981, Economic Signifi- cance of the Florida Phosophate Industry: U.S. Bureau of Mines Informa- tion Circular 8850, 62 p. Ottmann, R. D., P. L. Keyes, and M. A. Ziegler, 1973, Jay Field-A Jurassic Stratigraphic Trap: Transactions, Gulf Coast Association of Geologic Societies, vol. XXIII, pp. 146-175. Parker, G. G., G. E. Ferguson, S. K. Love and others, 1955, Water Resources of Southeastern Florida: U.S. Geological Survey Water Supply Paper 1255, 965 p. Patrick, G. C., R. N. Strom, and S. B. Upchurch, 1983, Chemical and Mineral Stratigraphy of a Miocene Fullers Earth Deposit: Green Acres Mine, Ocala Florida: Florida Academy of Science Abs., Florida Scientist, v. 46 supl., p. 37. INFORMATION CIRCULAR NO. 102 'elham, L., 1985, Fluorspar, in Mineral Facts and Problems: U.S. Bureau 3f Mines, Bull. 675, pp. 277 290. ,1986, Fluorspar, in Mineral Commodity Summaries: U.S. Bureau of Mines, pp. 52-53. Pirkle, E. C., W. H. Yoho, and A. T. Allen, 1965, Hawthorn Bone Valley and Citronelle Sediments of Florida: Florida Academy of Sciences, Jour. v. 28 No. 1, pp. 7 58. W. H. Yoho, and C. W. Hendry, Jr., 1970, Ancient Sea Level Stands in Florida: Florida Bureau of Geology Bulletin 52, 61 p. W. A. Pirkle, and W. H. Yoho, 1974, The Green Cove Springs and Boulougne Heavy-Mineral Sand Deposits of Florida: Eco- nomic Geology, Vol. 69, pp. 1129 1137. W. A. Pirkle, and W. H. Yoho, 1977, The Highland Heavy-Mineral Sand Deposit on Trail Ridge in Northern Peninsular Flor- ida: Florida Bureau of Geology Report of Investigation 84, 50 p. Poag, C. W., 1972, Planktonic Foraminifera of the Chickasawhay Forma- tion, United States Gulf Coast: Micropaleontology, Vol. 18, No 3, pp. 257-277. Puri, H. S., 1957, Stratigraphy and Zonation of the Ocala Group: Florida Geological Survey Bulletin 38, 248 p. and R. O. Vernon, 1964, Summary of the Geology of Florida and a Guidebook to the Classic Exposures: Florida Geological Survey Special Publication 5 Revised, 312 p. Reves, W. D., 1961, The Limestone Resources of Washington, Holmes and Jackson Counties, Florida: Florida Geological Survey Bulletin 42, 121 p. Schmidt, W., R. W. Hoenstine, M. S. Knapp, E. Lane, G. M. Ogden, Jr., and T. M. Scott, 1979, The Limestone, Dolomite and Coquina Resources of Florida: Florida Bureau of Geology Report of Investigation 88, 64 p. Scott, T. M., 1978, Environmental Geology Series-Orlando Sheet: Flor- ida Bureau of Geology Map Series 85. 1983, The Hawthorn Formation of Northeastern Florida, Part 1: Florida Bureau of Geology Report of Investigation 94, pp. 1 -43. ,1986, The Lithostratigraphy of the Hawthorn Group 59 BUREAU OF GEOLOGY (Miocene) of Florida: Phd. Dissertation, Florida State University, Talla- hassee, FL, 450 p. R. W. Hoenstine, M. S. Knapp, E. Lane, G. M. Odgen, Jr., R. Deuerling, and H. E. Neel, 1980, The Sand and Gravel Resources of Florida: Florida Bureau of Geology Report of Investigation 90, 41 p. and P. L. MacGill, 1981, The Hawthorn Formation of Central Florida: Florida Bureau of Geology Report of Investigation 91, Part 1, pp. 1 -32. Searls. J. P., 1980, Peat, in Mineral Facts and Problems, 1980 edition: U.S. Bureau of Mines Bulletin 671, pp. 641 -650. Sigsby, R. J., 1976, Paleoenvironmental Analysis of the Big Escambia Creek-Jay-Blackjack Creek Field Area, Florida: Transactions, Gulf Coast Association of Geological Societies, Vol. 26, pp. 258 278. Singleton, R. H., 1980, Stone, in Mineral Facts and Problems: U.S. Bureau of Mines Bulletin 671, pp. 853-868. Soper, E. K., and C. C. Osbon, 1922, The Occurrence and Uses of Peat in the United States: U.S.. Geological Survey Bulletin 728, 205 p. Stephens, J. C., 1974, Subsidence of Organic Soils in the Florida Everglades-A Review and Update in Environments of South Florida: Present and Past: Memoir 2, Miami Geological Society, pp. 191 237. Stowasser, W. F., 1985a, Phosphate Rock, in Mineral Commodity Sum- maries, 1985: U.S. Bureau of Mines, pp. 114-115. 1985b, Phosphate Rock, in Mineral Facts and Prob- lems, 1985 ed.: U.S. Bureau of Mines Bulletin 675, Alvin W. Keoerr ed., pp. 579- 594. Sweeney, J. W., 1979, Florida Stakes Its Claim in the Uranium Market: Mining Engineering, Vol. 31, no. 9, pp. 1324-1325. and C. W. Hendry, Jr., 1981, The Mineral Industry of Florida, 7977: in Minerals Yearbook, 1977: U.S. Bureau of Mines, V. 2, pp. 145-158. and S. R. Windham, 1979, Florida: the New Uranium Producer: Florida Bureau of Geology, Special Publication 22, 13 p. Tepordei, J. V., 1983, Sand and Gravel, in Minerals Yearbook, 1982: U.S. Bureau of Mines, V. 1, pp. 731 -752. INFORMATION CIRCULAR NO. 102 1984a, Sand and Gravel, in Minerals Yearbook, 1983: U.S. Bureau of Mines, V. 1, pp. 737-750. 1984b, Crushed Stone, in Minerals Yearbook, 1983: U.S. Bureau of Mines, V. 1, pp. 801 -820. 1985a, Sand and Gravel and Crushed Stone in Min- eral Commodity Summaries, 1985: U.S. Bureau of Mines, pp. 134- 135 and 146-147. 1985b, Crushed Stone, in Mineral Facts and Prob- lems, 1985: U.S. Bureau of Mines Bulletin 675, pp. 757-768. U.S. Bureau of Mines, Minerals Yearbook, 1977- 1983. U.S. Department of Energy, 1979, Energy Data Reports, 8-79. 1985, U.S. Crude Oil, Natural Gas and Natural Gas Liquids Reserves, 1984 Annual Report, pp. 22 26. Vernon, R. O., 1942, Geology of Holmes and Washington Counties, Flor- ida: Florida Geological Survey Bulletin 21, 90 p. 1951, Geology of Citrus and Levy Counties, Florida: Florida Geological Survey Bulletin 33, 256 p. and H. S. Puri, 1964, Geologic Map of Florida: Flor- ida Bureau of Geology Map Series 18. White, W. H., 1970, The Geomorphology of the Florida Peninsula: Flor- ida Bureau of Geology Bulletin 51, 164 p. Wright, Alexandra, P., 1974, Environmental Geology and Hydrology, Tampa Area, Florida: Florida Bureau of Geology Special Publication 19, 94 p. Yon, J. W., 1966, The Geology of Jefferson County, Florida: Florida Geological Survey Bulletin 48, 115 p. 1983, Status of Phosphatic Clay Waste Disposal: Florida Bureau of Mine Reclamation Open File Report, November, 1983, 28 p. Zellars and Williams, Inc., 1978, Evaluation of the Phosphate Deposits of Florida Using the Minerals Availability System: Final report prepared for the U.S. Bureau of Mines, 196 p. BUREAU OF GEOLOGY APPENDIX Mineral Producers In Florida The Bureau of Geology has used a number of sources in compiling the following list of mineral producers in Florida. The list includes all of the mining operations known to the Bureau and is current through December 1985. The Bureau will appreciate notification of any addi- tions, corrections, or deletions that can be used for future editions of the mineral producers directory. The directory lists the name and address of each producer under the commodity that is mined. The commodities are further listed separately by commodity and by county. PRODUCERS BY COMMODITY Name & Address of Operation Mine, Quarry, Pit or Operation T R S CEMENT DADE General Portland Inc. Box 22348 Tampa. FL 33622 Lonestar Florida Inc. Box 6097 Ft. Lauderdale, FL 33310 Rinkar Portland Cement Corp. P.O. Drawer K W. Palm Beach. FL 33402 Florida Mining & Materials Corp P.O. Box 6 Brooksville, FL 33512 General Portland Inc. Box 22348 Tampa. FL 33622 Florida Division. Tampa Plant National Portland Cement of Florida Inc. Route No. 1. Port Manatee Palmetto, FL 33561 Florida Division, Miami Plant Pennsuco Cement & Aggregates Miami Plant HERNANDO i. Cement Division HILLSBOROUGH 52S 40E 31 i MANATEE Port Manatee __ INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S CLAY-FULLER'S EARTH GADSDEN Engelhard Corp. P.O. Box 220 Attapulgus, GA 31715 Floridin Co. P.O. Box 510 Quincy, FL 32351 The Milwhite Co, Inc. P.O. Box 96 Attapulgus, GA 31715 La Camelia Mine/Swisher Mine Midway Mine Complex A Mine Complex B Mine Complex C Mine McCall Mine 3W 2W 3W 3W 3W Multiple Multiple Multiple 17 35 3N 3W 4 MARION Mid-Florida Mining Co. P.O. Box 68F Lowell, FL 32663 Emthla Mine 13S 20E 1 CLAY-KAOLIN PUTNAM The Feldspar Corp. P.O. Box 8 Edgar, FL 32049 Edgar Mine 10S 24E 30 CLAY-GENERAL CLAY Florida Solite Co. P.O. Box 27211 Richmond, VA 23261 Russell Mine 5S 25,26E Multiple GADSDEN Apalachee Correctional Institute Box 699 Sneads, FL 32460 Chattahoochee Pit 3N 6W 8 LAKE Codding Sand & Soil Inc. Box 795 State Road 19A Mt. Dora, FL 32757 Codding Pit 19S 27E 33 _ __ __ BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Clay-general, cont'd. CTC Construction, Inc. P.O. Box 686 Gainesville. FL 32601 MARION Green Acres Mine 13S 20E 1 EXFOLIATED VERMICULITE BROWARD W. R. Grace & So. 62 Whittemore Avenue Cambridge. MA 02140 W. R. Grace & So. 62 Whittemore Avenue Cambridge, MA 02140 Schmelzer Sales Corp. Box 11385 Tampa. FL 33610 W. R. Grace & So. 62 Whittemore Avenue Cambridge. MA 02140 Zonolite Division, Pompano Beach Plant DUVAL Zonolite Division, Pompano Beach Plant - HILLSBOROUGH Verlite Co. Zonolite Division, Tampa Plant EXPANDED PERLITE BROWARD W. R. Grace & So. 62 Whittemore Avenue Cambridge, MA 02140 Chemrock Corp. P.O. Box 100922 Nashville, TN 37210 World Industries Inc. Armstrong House Lancaster square 1704 Lancaster, PA 17604 Zonolite Division, Pompano Beach Plant DUVAL Jacksonville Plant ESCAMBIA Escambia Plant INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Expanded Perlite, cont'd. Arlite Processing Corp. 3505 65th Street Vero Beach, FL 32960 Jim Walter Corporation 1500 N. Dale Mabry Tampa, FL 33607 United States Gypsum Co. 101 S. Wacker Drive Chicago, IL 60606 Occidental Petroleum Co. P.O. Box 25597 Tampa, FL 33622 INDIAN RIVER Processing Plant GYPSUM DUVAL Celotex Division, Jacksonville Plant Duval County Plant HAMILTON Suwannee HILLSBOROUGH National Gypsum Co. 2001 Rexford Road Charlotte, NC 28211 Standard Gypsum Corp. 3401 Bulk Street Port Everglades, FL 33316 Associated Minerals LTD, Inc. P.O. Box 1307 Green Cove Springs, FL 32043 E. I. DuPont P.O. Box 753 Starke, FL 32091 HEAVY MINERALS CLAY Green Cove Springs Mine Florida Mine 7S 25,26E Multiple 5,6S 23E Multiple Tampa Plant 65 BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S LIME GULF Basic Inc. Box 160 Port St. Joe. FL 32456 Port St. Joe Limekiln HERNANDO Chemical Lime Inc. Box 317 Leesburg. FL 32748 Brooksville Limekiln SUMTER Dixie Lime & Stone Co. Drawer 217 Sumterville. FL 33585 Sumterville Limekiln y LIMESTONE (CRUSHED AND BROKEN) AND SHELL ALACHUA Dickerson Florida Inc. Box 177 Newberry, FL 32669 Florida Rock Industries Inc. P.O. Box 4667 Jacksonville. FL 32216 Umerock Industries Inc. Drawer 790 Chieflad. FL 32626 S. M. Wall Company 1650 NE 23rd Blvd. Gainesville, FL 32601 Haile Quarry 1) Newberry Limerock Quarry 2) Haile Quarry 3) Chastain Quarry 1) Haile Quarry 2) Newberry Quarry High Springs Quarry 9S 17E Multiple N/A 9S 9S 17E Multiple 18E 18 9S 17E 24 9S 17E 25 7S 18E 30 BREVARD Blackhawk Quarry Co. of Florida, Inc. 7750 Babcock Street Palm Bay. FL 32905 Blackhawk Quarry 30S 37E Multiple C 'N I _II INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. Brevard County Department of Public Works 1948 Pineapple Ave., Suite C Melbourne, FL 32901 1) Kings Park Quarry 2) Pluckebaum Quarry 3) Rifle Range Quarry 4) Rockledge Quarry BROWARD Badgett Resources 4160 Ravenswood Road Ft. Labderdale, FL 33312 Bee Line Engineering & Construction, Inc. 10900 Griffin Road Ft. Lauderdale, FL 33328 Bergeron Sand & Rock Mining, Inc. P.O. Box 6280 SHollywood, FL 33021 Broward Paving Inc. 2001 N. State Road 7 Hollywood, FL 33021 Broward Vito's Trucking & Excavating Co. 16001 West Hwy. 84 Sunrise, FL 33314 Cherokee Crushed Stone Inc. P.O. Box 8307 Pembroke Pine, FL 33024 Devcon International Corp. P.O. Box 498 Pompano Beach, FL 33061 Hardrives Co. Inc. 846 N.W. 8th Street Ft. Lauderdale, FL 33311 Hollywood Quarries Inc. 3000 SW 64th Avenue Ft. Lauderdale, FL 33314 L. W. Rozzo Inc. 2610 S.W. 50th Avenue Ft. Lauderdale, FL 33314 Saw Grass Quarry 84 Rock & Fill Quarry 1) Hollywood Pit 2) Ponderosa Quarry 3) Snake Creek Quarry Rhodes Quarry Markham Park Pit 1) Cherokee Quarry 2) Hollywood Blvd. Quarry York Chase Ronto 1) Gateway Quarry 2) Miramar Lake Pit 3) State Road Quarry Hollywood Quarry Rozzo Quarry 52S 39E 53 49S 40E 27 51S N/A N/A 39E 12 50S 42E 31 49S 40E 50S 40E N/A 51S 40E Multiple 48S 42E 9 N/A 51S 50S 39E 36 41,42E Multiple 50S 41E 23 50S 40E 31 24S 36E 22S 35E 21S 34E 25S 36E BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. Miramar Rock Inc. Box 8819 Hollywood, FL 33024 Miramar Quarry 51S 39E 36. Pema Asphalt Paving Inc. P.O. Box 50189 Lighthouse Point, FL 33064 Vulcan Materials Co. P.O. Box 660097 Miami Springs, FL 33166 Chariotte Rock Industries P.O. Box 1428 Cape Coral, FL 33910 Desrosier Brothers Enterprises P.O. Box 43, Star Rt. A. Punta Gorda, FL 33950 Macasphalt P.O. Box 2579 Sarasota, FL 33578 Pit No. 1 Broward Quarry CHARLOTTE Route 31 Pit Pit No. 1 Charlotte Co. Pit N/A 51S 39E 24 42S 25E Multiple 40S 24E 32 41S 21E Multiple Roger A. Chase Star Route A, Box 140 Puna Gorda, FL 33950 Rowe Inc. 6629 53rd Ave. East Bradenton, FL 33508 Sunland Paving Co. Inc. 134 Electric Way Charlotte Harbor, FL 33950 County Line Pit Shell Quarry Sunland Shell Quarry CITRUS Carroll Contracting & Ready Mix, Inc. P.O. Box 1659 Inverness, FL 32651 Crystal River Quarry Inc. Box 216 Crystal River, FL 32629 1) Lecanto Quarry 2) Storey Quarry 1) Red Level Quarry 2) Lecanto Quarry 18S 18E 33 20S 19E 35 17S 16E 25 19S 18E Multiple N/A N/A N/A INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. Dolime Minerals Co. P.O. Box 1206 Crystal River, FL 32629 Crystal River Quarry 17S 16E Multiple Springs Construction Equipment Co., Inc. P.O. Box 1797 Crystal River, FL 32629 Cement Products Corporation Rt. 6, Box 1760 Naples, FL 33999 Florida Rock Corp. Box 2037 Naples, FL 33940 Florida Rock Industries Inc. P.O. Box 4667 Jacksonville, FL 32216 Harmon Brothers Rock Co. P.O. Box 14 Ochopee, FL 33943 Highway Pavers Inc. Box 8809 Naples, FL 33941 Lee Mar Route 3, Box 489 Ft. Myers, FL 33908 Macasphalt Inc. P.O. Box 7368 Naples, FL 33941 Mule Pen Rock Quarry Golden Gate Estates Area Quarry 1) Sunniland Quarry 2) Caloosa Limerock Copeland Quarry 1) Naples Limerock Quarry 2) North Quarry Quarry 31 Golden Gate Quarry 48S 26E Multiple 49S 26E 21 48S 30E 30 45S 26E 5 52S 29E 12 50S 26E 48S 26E N/A 49S 27E 16 COLUMBIA Limerock Industries Inc. Drawer 790 Chiefland, FL 32626 Columbia City Mine 5S 16E Multiple Tanner Quarry N/A COLLIER BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. DADE A. J. Capeletti Inc. P.O. Box 4944 Hialeah, FL 33014 1) Dade Quarry No. 9 2) Dade Quarry No. 10 3) Dade Quarry No. 11 4) Dade Quarry No. 12 5) Dade Quarry No. 13 6) Dade Quarry No. 15 A. J. House & Sons Inc. Box 440457 Miami, F. 33144 Coral Aggregates Inc. 3500 Pembroke Road Hollywood, FL 33021 Florida Rock Industries P.O. Box 521705 Miami, FL 33152 Florida Rock & Sand Co. P.O. Box 3004 Florida City, FL 33030 Krome Aggregates, Inc. PO. Box 260 Hollywood, FL 33022 Lone Star Florida Inc. Box 6097 Ft. Lauderdale, FL 33310 Lowell Dunn P.O. Box 2577 Hialeah, FL 33012 Loyal Rock Inc. 1385 Coral Way, Suite 407 Miami. FL 33145 Miami Crushed Rock, Inc. 9bx 650309 Miami, FL 33165 Redland Construction Co., Inc. 23379 SW 167th Avenue Homestmd, FL 33165 Quarry No. 1 Miami Mine Quarry 1) Sterling Quarry 2) Golden Prince Quarry 3) Card Sound Quarry 1) Card Sound Pit 2) Cutler Pit Kendall Quarry Pennsuco Quarry 1) Airport Pit 2) Dunn Airport Quarry 3) Indian Mound West Pit 4) Lehigh Lakes Quarry Loyal Rock Quarry Sweetwater Quarry County Line Quarry 53S 39E 13 53S 39E 27 N/A N/A 58S 58S N/A N/A 39E 17 39E 17 52S 39E Multiple 52S 39E N/A 54S 40E N/A N/A 53S 39E 24 52S 39E 1 53S 53S 53S 53S 52S 53S 39E 39E 39E 39E 39E 39E 26 23 21 Multiple 13 20 INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. Rinker-Southeastern Materials, Inc. P.O. Box 5230 Hialeah, FL 33014 Ronlee Inc. P.O. Box 660655 Miami Springs, FL 33166 Siboney International P.O. Box 6665 West Palm Beach, FL 33405 Standard Rock Pit Corp. 7855 NW 12th Street Miami, FL 33182 The Brewer Co. of Florida (Redland Construction Co.) 9800 NW 106 Street ,Miami, FL 33166 Vulcan Materials Co. P.O. Box 660097 Miami Springs, FL 33166 DeSoto County Public Works P.O. Box 1399 Arcadia, FL 33821 DeSoto Shell P.O. Box 1862 Arcadia, FL 33821 1) SCL Quarry 2) FEC Quarry 3) Rinker Lake Quarry Ronlee Inc. Quarry Royal Rock Quarry Standard Rock Pit Brewer Doctors Pit 1) 41st Street Quarry 2) Medley Quarry N/A 52S 52S 39E 25 40E 20 52S 39E 12 N/A N/A 52S 39E 1 N/A 53S 40E 10 DESOTO County Pit DeSoto Shell Pit 39S 25E 28 39S 25E 28 GLADES Macasphalt Inc. P.O. Box 1819 Winter Haven, FL 33880 Labelle Limerock Company General Delivery Labelle, FL 33935 M. E. C. Construction Inc. Drawer Q South Bay, FL 33493 Brighton Reservation Pit 40S 32E Multiple HENDRY Labelle Quarry MEC Rock Quarry 43S 28E 13 N/A BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. Ridgdill & Son Construction Inc. P. 0. Box 447 Clewiston, FL 33440 E R. Jahna Industries Inc. P.O. Drawer 168 Lecanto, FL 32661 Florida Crushed Stone Co. Box 317 Leesburg, FL 32748 Florida Mining & Material Corp. 605 Broad Street Brooksville, FL 33512 Florida Rock Industries Inc. P.O. Box 4667 Jacksonville, FL 32201 Oman Construction Co., Inc. P.O. Box 3038 Springhill, FL 33526 W. L. Cobb Construction Co. Box 3038 Springhill, FL 33526 Chapman Contracting Co. 7910 Orient Road Tampa, FL 33619 Leisey Shell Pit Inc. 3820 Gulf City Road Ruskin, FL 33570 Shell Materials Inc. P.O. Box 11554 Tampa, FL 33680 Henry Fischer & Sons, Inc. P.O. Box 68 Sebastian, FL 32958 Ridgdill Quarry HERNANDO Mills Quarry Brooksville Gay Quarry Broco Quarry Brooksville Diamond Hill Quarry Aripeka Quarry Aripeka Quarry HILLSBOROUGH Tampa Bay Pit 1) Leisey Pit 2) Cockroach Bay Shell Pit 1) 19th Ave. Quarry 2) Shell Materials Pit 43S 34E 14 23S 21E 1 21S 21S 22S 22S 18E 19E 18E 19E 36 Multiple 1 Multiple 21S 18E Multiple 21S 19E 20 23S 17E Multiple 23S 17E 19 32S 18E 1 32S 18E 16 31S 18E 15 31S 19E Multiple 32S 19E 6 INDIAN RIVER Fischer Pit N/A INFORI Name & Address of Operation Limestone (Crushed and Dolomite Inc. Box 548 Marianna, FL 32446 Green Valley Lime Co., Inc. P.O. Box 681 Marianna, FL 32446 Marianna Lime Products Inc. Box 1505 Marianna, FL 32446 NATION CIRCULAR NO. 102 Mine, Quarry, Pit or Operation T R S Broken) and Shell, cont'd. JACKSON Rock Creek Quarry Sink Creek Quarry Marianna Quarry 3N 9W Multiple 3N 9W 19 5N 10W 29 LEE Charlotte Rock Industries P.O. Box 1428 Cape Coral, FL 33910 Florida Rock Industries Inc. P.O. Box 4667 Jacksonville, FL 32216 Fugate Construction Co. 137 Texas Avenue Ft. Myers, FL 33901 Harper Brothers Inc. 5351 Six Mile Cypress Parkway Ft. Myers, FL 33912 Harper Brothers Inc. Route 39, Box 821 Ft. Myers, FL 33908 J. L. Kelley Rock Co. Inc Box 353 La Belle, FL 33953 Boutwell Construction Co., Inc. 5979 SE Mary Camp Road Ocala, FL 32672 Connell & Schultz Inc. Box 24 Inverness, FL 32650 Burnt Stove Road Pit Fort Myers Quarry Fugate No. 1 Quarry 1) Alico Quarry 2) Colonial Dolomite Quarry Alico Road Quarry 12 026 Quarry 43S 22E 24 46S N/A N/A N/A 25E 12 46S 26E 2 43S 27E Multiple LEVY Pansey Britt Mine Williston Quarry 12S 19E 31 12S 19E 31 __ BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. Florida Lime & Dolomite Co., Inc. P.O. Box 246 Gulf Hammock, FL 32678 Florida Rock Industries Inc. P.O. Box4667 Jacksonville, FL 32201 Levy County Road Department P.O. Box 336 Bronson, FL 32621 V. E. Whitehurst & Sons Rt. 1, Box 125 Williston, FL 32696 Gulf Hammock Quarry Gulf Hammock Quarry Levy County Quarries 1) Raleigh Quarry 2) Whitehurst Pit 14S 16E 21 14S 16E Multiple N/A N/A 12S 19E Multiple MANATEE Quality Aggregates Inc. P.O. Box 2719 Sarasota, FL 33578 Phase IV Shell Mine 35S 19E Multiple MARION Boutwell Construction Co., Inc. 5979 SE Mary Camp Road Ocala, FL 32672 G. P. Turner Construction Inc. 8001 NW C 25A Ocala, FL 32671 Marion County Hwy. Dept. 3330 SE Maricamp Rd. Ocala, FL 32670 M. J. Stavola Industries P.O. Box 187 Anthony, FL 32617 Monroe Road Co. Box 417 Belleview, FL 32620 Ocala Limerock Corp. P.O. Box 1060 Ocala, FL 32670 Mine Two (Bellview Mine) Britt Quarry 17S 22E 1 N/A Canal Pit Stavola Quarry No. 8 Quarry 1) Cummer Mine 2) Zuber Mine 16S 22E 15 14S 22E L9 15S 20E 19 N/A 14S 21E 14 INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. Ocala Pavers Inc. 4910 N 35th St. Silver Springs, FL 32688 Southern Materials Corp. P.O. Box 218 Ocala, FL 32670 Pedro Pit Lowell Quarry MONROE 17S 22E 24 13S 21E 23 A. J. Capeletti Inc. P.O. Box 4944 Hialeah, FL 33014 Charley Toppino & Sons Inc. Box 787 Key West, Fl 33040 Tarmac Florida Inc. P.O. Box 2035 Hialeah, FL 33012 Bell Engineering Service Co. 7755 Jog Rd., Rt. 3 Lake Worth, FL 33460 Griffin Brothers Co. Inc. 10450 W. State Road 84 Davie, FL 33324 Loxahatchee Enterprises Inc 2000 South Congress Ave. Delray Beach, FL 33445 Monroe Quarry No. 1 1) Big Pine Key Quarry 2) Cudjoe Key Quarry 3) Rockland Key Quarry 1) Cudjoe Key Quarry 2) Rockland Key Quarry 3) Big Pine Key Quarry PALM BEACH Bell Farms Pit Rock Quarry No. 2 Delray Beach Quarry 60S 40E 29 N/A N/A 67S 26E 21 66S 28E 67S 26E 66S 29E 29 Multiple 25 45S 42E 15 47S 37E 22 47S 41E 29 PASCO Belcher Mine, Inc. P.O. Box 86 State Rd. 595 Aripeka, FL 33502 International Minerals & Chemical Corp. Box 867 Bartow, FL 33830 Zephyr Rock & Lime Inc. P.O. Box 697 Zephyrhills, FL 33599 Belcher Quarry Morell Quarry Z-Rock Quarry 24S 16E Multiple 25S 22E Multiple 26S 22E Multiple BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Limestone (Crushed and Broken) and Shell, cont'd. POLK West Coast Mining & Silica Inc. P.O. Box 17237 Tampa. FL 33682 Florida Rock Industries Inc. P.O. Box 4667 Jacksonville, FL 32201 Englewood Trucking Co. 500 N. Indiana Avenue Englewood, FL 33533 Fleet Rental Inc. 700 Hall Road Nakomis, FL 33555 Macasphalt Inc. P.O. Box 2579 Sarasota, FL 33578 Morrison Trucking Co. Box 3145 Venice. FL 33595 Quality Aggregates Inc. P.O. Box 2719 Sarasota, FL 33580 1) Polk County Quarry 2) West Coast Pit N/A 26S 22E Multiple ST. LUCIE Ft. Pierce Quarry SARASOTA Laurel Road Pit Sarasota Quarry Newburn Road Pit Highway 775 Pit Brown Road Quarry 37S 38E Multiple 38S 19E Multiple 36S 17E 5 36S 18E 12 N/A 36S 19E 7 SUMTER Agri-Timber. Inc. 4801 River Road Dade City. FL 33525 Amcar P.O Drawer 217 Sumterville, FL 33585 Dixie Lime & Stone Co. Drawer 217 Sumterville, FL 33585 Agri-Timber Hi-Cal Quarry Coleman No. 2 Quarry Sumterville Quarry N/A 20S 22E 12 20S 22E 20S 23E Multiple INFORMATION CIRCULAR NO. 102 Mine, Quarry, Pit Name & Address of Operation or Operation T Limestone (Crushed and Florida Crushed Stone Co. Box 317 Leesburg, FL 32748 Ocala Limerock Corp. P.O. Box 1060 Ocala, FL 32670 St. Catherine Rock Co. P.O. Box 103 Nobleton, FL 33554 Anderson Mining Corp. P.O. Box 38 Old Town, FL 32680 Hatch Enterprises Inc. Box 238 Branford, FL 32008 Urban Mining, Inc. P.O. Box 627 Lake City, FL 32055 Anderson Contracting Co. P.O. Drawer 38 Old Town, FL 32680 Cabbage Grove Mining Co., Inc. P.O. Box 997 Perry, FL 32347 Dolime Minerals Co. P.O. Box 997 Perry, FL 32347 Florida Crushed Stone Box 719 Perry, FL 32347 Limerock Industries Inc. Drawer 790 Chiefland, FL 32626 Broken) and Shell, cont'd. Center Hill Quarry Mabel Quarry St. Catherine Quarry SUWANNEE Lanier Quarry Hatch Quarry SR 252 Quarry TAYLOR Ten Mile Quarry Perry Quarry Perry Quarry Jefferson-Taylor Quarry Cabbage Grove Quarry 21S 23E 16 22S 23E Multiple 22S 21E Multiple 6S 14E Multiple 6S 14E 16 N/A 8S 10E 21 4S 4E 3 4S 4E 13 3S 4E 32 4S 4E Multiple 3S 4E 34 77 R S BUREAU OF GEOLOGY Name & Address of Operation Mine. Quarry, Pit or Operation T R S MAGNESIUM-BRINES GULF Basic Magnesia Inc. 845 Hanna Building Cleveland. OH 44115 Port St. Joe Plant PEAT CLAY R & R Peat Farms. Inc. P.O. Box 420 Keystone Heights, FL 32656 Stricklin Peat, Inc. Rt. I. Box 577 Keystone Heights, FL 32656 L. C. Morris, Inc. P.O. Box 500 74400 N.W. 102nd Avenue' Hialeah, FL 33014 Superior Peat & Soil P.O. Box 1688 4242 W. George Boulevard Sebring, FL 33870 8S 24E 16 N/A DADE N/A HIGHLANDS 35S 29S 9 Tu-Co Peat 3320 Tubbs Road Sebring, FL 33870 Fertic Soils P.O. Box 922 7911 Williams Rd. Seffner, FL 33584 35S 29S 21 HILLSBOROUGH 28S 20E 20 Earth Stover 16328 Indian Mound Road Tampa, FL 33618 27S 18E 26 28S 21E 28 F. E. Stearns Peat Rt. 1, Box 542D Dover, FL 33527 78 INFORMATION CIRCULAR NO. 102 r'ame & Address of Operation Mine, Quarry, Pit or Operation T R S PFeat, cont'd. Anderson Organic Inc. Rt. 2, Box 138 Winter Garden, FL 32787 C & C Peat P.O. Box 443 SMinneola, FL 32755 Florida Potting Soils, Inc. P.O. Box 7008 Orlando, FL 32854 Hillary Peat Rt. 1, Box 345 Groveland, FL 32736 E. R. Jahna Industries 102 E. Tillman Avenue Lake Wales, FL 33853 Anderson Organic Inc. Rt. 2, Box 138 Winter Garden, FL 32787 Pasco Products Company, Inc. P.O. Box 628 Greenville, FL 32331 Reliable Peat P.O. Box 217 Winter Garden, FL 32787 Atlas Peat & Soil 9621 S.R. 7 P.O. Box 867 Boynton Beach, FL 33435 LAKE Clermont West Mine 22S 26E Multiple 21S 25E 11 18S 28E 25 22S 24E 8 22S 25E 22 MADISON 1S 5E 35 1N 6E 24 ORANGE 22S 27E 22 PALM BEACH 45S 43E Multiple POLK Andy's Plant Aids 1840 W. Fairbanks P.O. Box 3296 Lakeland, FL 33802 Clubhouse Road Pit 29S 24E 9 BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Peat, cont'd. Greenleaf Products, Inc. P.O. Box 312 Haines City, FL 33844 Peace River Peat P.O. Box 1192 1470 Hwy. 17S. Bartow. FL 33830 Frostproof 27S 27E 19. 31S 28E 23 PUTNAM R & R Peat Farms, Inc. P.O. Box 420 Keystone Heights, FL 32656 Traxler Peat P.O. Box 448 Florahome, FL 32635 American Peat Co. Rt. 1, Box 38 (Hwy. 466, 3.9 miles E. of Oxford) Oxford, FL 32684 Verfite Co. P.O. Box 11385 621? N. 56th Street Tampa, FL 33680 Florahome Mine 9S 24E 5 9S 24S Multiple SUMTER Cherry Lake Verlite Mine 18S 23E Multiple 22S 22E 34 Occidental Chemical Co. P.O. Box 1185 Houston, TX 77001 C. F. Industries, Inc. P.O. Box 1549 Wauchula. FL 33873 Gardinier Inc. P.O. Box 3269 Tampa, FL 33601 PHOSPHATE ROCK HAMILTON 1) Suwannee River Mine 2) Swift Creek Mine HARDEE Hardee Phosphate Complex Ft. Meade Mine 15,16E 16E 15E Multiple Multiple Multiple 33S 24E Multiple 32S 25E Multiple 80 INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Phosphate Rock, cont'd. Amax Chemical Corp. 402 S. Kentucky Avenue Suite 600 Lakeland, FL 33801 American Cyanamid Co. (Brewster Phosphates) Berdan Ave. Wayne, New Jersey 07470 Beker Phosphate Corp. P.O. Box 9034 Bradenton, FL 33506 W.R. Grace & Company Box 471 Bartow, FL 33830 Agrico Chemical Co. Box 1110 Mulberry, FL 33860 American Cyanamid Co. (Brewster Phosphates) Berdan Ave. Wayne, New Jersey 07470 Estech General Chemical Co. Box 208 Bartow, FL 33830 Gardinier Inc. P.O. Box 3269 Tampa, FL 33601 .5 International Minerals & Chemical Corp. Box 867 Bartow, FL 33830 Mobil Oil Corp. Box 311 Nichols, FL 33863 HILLSBOROUGH Big Four Mine Lonesome Mine 31,32S 32,22E Multiple 31S 22E Multiple MANATEE Wingate Creek Mine Four Corners Mine 34,35S 21,22E Multiple 33S 21E Multiple . POLK 1) Ft. Green Mine 2) Saddle Creek Mine 3) Payne Creek Mine Haynsworth Mine 1) Silver City Mine 2) Watson Mine Ft. Meade Mine 1) Clear Springs Mine 2) Kingsford Mine 3) Noralyn Mine 1) Ft. Meade Mine 2) Nichols Mine 32 33S 23W 28S 25E 32S 23,24E Multiple Multiple 31S 32E Multiple 31S 24E Multiple 31,32S 25,26E Multiple 32S 25E Multiple 30S 31S 30S 30S 31S 25E 22E 23E 24S 24S Multiple Multiple Multiple Multiple Multiple 31S 25E Multiple 30S 23E Multiple BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Phosphate Rock, cont'd. U.S.S. Agrichemicals P.O. Box 867 Ft. Meade, FL 33841 W.R. Grace & Company Box 471 Bartow, FL 33830 Rockland Mine Hookers Prairie Mine 31S 24E Multiple 31S 23E Multiple PHOSPHATE ROCK -COLLODIAL CITRUS Howard Phosphate Co. P.O. Box 13800 Orlando, FL 32809 Manko Co. P.O. Box 577 Ocala, FL 32670 The EH Kellogg Co. P.O. Box 218 Hemando, FL 32642 Lancala Phosphate Co. P.O. Box 766 High Springs. FL 32643 Howard Phosphate Mine Section 5 Phosphate Mine Kellogg Phosphate Mine 18S 19E 35 17,18S 18,19E Multiple 17S 17E 34 MARION Minehead Plant SAND BAY Fla. Asphalt Paving Co. P.O. Box 1310 Panama City, FL 32401 Gulf Asphalt Corp. P.O. Box 2462 Panama City, FL 32401 Pitts Sand Co. Rt. 4, Box 850 Panama City, FL 32401 Sykas Concrete Pipe Co. P.O. Box 1400 Panama City, FL 32402 Register Mine Bay Mine Lynnhaven Mine Calloway Mine 2S 13W 13 2S 13W 14 3S 14W 12 4S 13W 14 82 INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Sand, cont'd. BREVARD Melbourne Sand & Supply 7298 Waelti Drive Melbourne, FL 32935 Florida Commercial Development P.O. Box 5147 Ft. Lauderdale, FL 33310 Frank Newth LTD. Box 8302 Coral Springs, FL 33065 Hardrives Company ,300 West State Rd. No. 84 Ft. Lauderdale, FL 33315 Pompano Silica Sand Company 1951 N. Powerline Road Pompano Beach, FL 33060 101 Sand & Fill Inc. P.O. Box 4175 RR #2 Lyons R&D Wilburn St. Margate, FL 33063 Melbourne Mine BROWARD Prospect Mine Margate Mine State Rd. 84 Mine Tsiotis Mine 101 Mine 26S 36E 12 49S 42E 7 48S 42E 21 50 42E 30 48S 42E 28 N/A Blountstown Sand Co. Rt. 1 Mason Road Blountstown, FL 32424 CALHOUN 1) Overholt Mine 2) N/A CLAY Florida Rock Industries Inc. P.O. Box 4667 Jacksonville, FL 32201 Gold Head Mine 8S 23E 15 DADE A.J. Capeletti, Inc. P.O. Box 4944 Hialeah, FL 33014 Broward No. 1 Mine 51S 41E 29 N/A 1N 8W 27 83 BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Sand, cont'd. Arnold Sand & Gravel Co. 1717 Eagle Drive Cantonment, FL 32533 Campbell Sand & Gravel Co. Rt. 3. Box 22 Century, FL 32535 Clark Sand Co. Box 4267 Pensacola, FL 32507 Red Sand & Gravel Co. Rt. 1 Flomaton AL 36441 Site Construction Developers 2628 Hillcrest Avenue Pensacola, FL 32506 Capital Asphalt P.O. Box 5767 Tallahassee, FL 32314 Gadsden Sand Co. P.O. Box 446 Quincy. FL 32351 Radcliff Materials, Inc. P.O. Box 1685 Mobile, AL 36601 E.R. Jahna Industries Inc. First & East Tillman Lake Wales. FL 33853 Florida Rock Industries, Inc. P.O. Box 4667 Jacksonville, FL 32201 Revelle Sand Plant P.O. Box 153C Rt. 2 Caryville, FL 32427 ESCAMBIA Century Mine Century Mine Pensacola Mine 1) Century Mine 2) Sunday Rd. Mine Pensacola Mine N/A 5N 30W 4 2S 30W Multiple N/A 6N N/A 30W 33 GADSDEN Quincy Mine Chattahoochee River Plant 1N 2W 21 N/A 3N 6W 5 GLADES Ortona Sand Mine Caloosa Mine HOLMES Caryville Plant 42S 30E 23 42S 30E Multiple 5N 16W 16 84 INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Sand, cont'd. West Florida Sand Co. Route 3, Box 208 G Bonifay, FL 32425 A.B. Williams Co. P.O. Box 269 Marianna, FL 32446 Dog Lake Estates Mine JACKSON Williams Mine 4N 15W 5 3N 10W 29 LAKE E.R. Jahna Industries Inc. First & East Tillman Lake Wales, FL 33853 Eustis Sand Company P.O. Box 861 Mt. Dora, FL 32757 Florida Crushed Stone Co. Box 317 Leesburg, FL 32748 Florida Rock Industries, Inc. P.O. Box 4667 Jacksonville, FL 32201 Silver Sand Co. of Clermont Inc. Rt. 1, Box USI Clermont, FL 32711 Standard Sand & Silica Co. P.O. Box 35 Davenport, FL 33837 Clermont West Mine 2) Clermont Mine 3) Independent Mine Eustis Mine 1) Tulley Mine 2) 474 Mine 1) Lake Sand Plant 2) Orange-Clermont Mine 3) Astatula Mine Center Mine Wallace Mine 22S 25E Multiple 22S 26E Multiple 24S 25E 22 18S 27E 25 22S 36E 34 24S 25E 13 24S 24S 20S 26E 26E 26E 19 Multiple Multiple 23S 26E Multiple 24S 28E 9 LEON Johnson Sand Co. 129 Campground Pond Road Tallahassee, FL 32304 Roberts Sand Co. Inc. P.O. Box 6229 Tallahassee, FL 32302 Johnson Mine Norfleet Mine 1N 2W 34 1N 2W 35 BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Sand. cont'd. MANATEE Quality Aggregates. Inc. P.O. Box 2719 Sarasota, FL 32578 Phase IV Shell Pit 35S 19E 31 MARION Florida Rock Industries Inc. P.O. Box4667 Jacksonville. FL 32201 G. P. Turner Construction Inc. 8001 N.W. C. 25W Ocala. FL 32671 Marion County Highway Dept. 3330 S.E. Maricamp Road Ocala, FL 32670 Ocala Limerock Corp. Box 1060 Ocala. FL 32670 Ocala Pavers Inc. 4910 N. 35th Street Silver Springs, FL 32688 Southern Materials Corp. P.O. Box 218 Ocala. FL 32670 Standard Sand & Silica Co. P.O. Box 35 Davenport, FL 33837 Marion Sand Mine Britt Mine Canal Pit 17S 26E Multiple N/A 16S 22E 15 Cummar Mine Pedro Pit Lowell Quarry Lynne Mine N/A N/A 13S 21E Multiple 15S 24E 3 ORANGE County of Orange Hwy. Dept. 11 W. Kaley Orlando. FL 32813 Own Crews Mine PASCO Zephyr Rock & Lime, Inc. P.O. Box 4175 Zaphyrhills, FL 33599 Z-Rock Quarry 26S 22E Multiple N/A INFORMATION CIRCULAR NO. 102 Name & Address of Operation Mine, Quarry, Pit or Operation T R S Sand, cont'd. POLK E.R. Jahna Industries Inc First & East Tillman Lake Wales, FL 33853 Florida Mining & Materials Corp. P.O. Box 338 Polk City, FL 33868 Florida Rock Industries Inc. P.O. Box 4667 Jacksonville, FL 32201 Gall Silica Mining Co., Inc. Box 987 Lake Wales, FL 33853 Standard Sand & Silica Co. P.O. Box 35 Davenport, FL 33837 Florida Rock Industries, Inc. P.O. Box 4667 Jacksonville, FL 32201 The Feldspar Corp. P.O. Box 8 Edgar, FL 32049 1) Loughman Mine 2) Haines City Mine Devane No. 2 Mine Sandland Mine 1) 03 Mine 2) 04 Mine 1) Davenport Mine 2) Joshua Mine 3) Polk City Mine PUTNAM Keuka Mine Edgar Mine 26S 27E 27S 27E 28S 27E 11 35 Multiple 24S 25E 33 30S 28E Multiple 30S 28E 29S 28E Multiple 26S 27E 26 26S 26E 35 26S 25E 26 10S 24E 29 10S 25E 23 ST. LUCIE Ben Stewart Trucking Route 1, Box 2075 Ft. Pierce, FL 33450 Ft. Pierce Sand & Material Inc. Rt. 4, Box 27 Ft. Pierce, FL 33450 General Development Corp. 1111 S. Bayshore Drive Miami, FL 33450 Glen Blackburn Trucking Inc. Route 4, Box 157 A Ft. Pierce, FL 33450 North Mine 1) North Mine 2) South Midway Road Mine St. Lucie County Mine 1) Airport Mine 2) Morlan Mine 3) Rails Mine 34S 40E 8 N/A N/A N/A N/A 35S N/A 40S 36 _ _____ _I_~ _______I____ ___~ ____~______ __ BUREAU OF GEOLOGY Name & Address of Operation Mine, Quarry, Pit or Operation T R S Sand, cont'd. Stewart Sand & Materials 202 Tumblinking Road Ft. Pierce, FL 33450 Pace Sand & Gravel Inc. P.O. Box 395 Century, FL 32535 General Developmemet Corp. Tit S. Bayshore Drive Miami, FL 33450 Macasphalt Inc. P.O. Box 2579 Sarasota, FL 33578 Adams Sand Company Inc. Mossy Head, FL 32434 Anderson Sand, Inc. P.O. Box 243-AX Caryville, FL 32427 Indian Hills Mine SANTA ROSA Robertson Mine N/A N/A SARASOTA Sarasota-County Mine Newburn Mine 39S 22E Multiple 36E 18E 12 WALTON Mossy Head Mine WASHINGTON Anderson Mine 3N 21W 21 30N 16W 11 SULFUR SANTA ROSA Exxon Co. USA P.O. Box 4496 Houston, TX 77210 1) Blackjack Creek Field Unit 2) Jayfield 4N 29W 23 5N 29W T = Township R = Range N/A = Information Not Available S = Section 88 INFORMATION CIRCULAR NO. 102 COMMODITIES BY COUNTY County Commodity Page Alachua Limestone 66 Bay Sand 82 Brevard Limestone 66 Sand 83 Broward Exfoliated Vermiculite 64 Expanded Perlite 64 Limestone 67 Sand 83 Calhoun Sand 83 Charlotte Limestone 68 Citrus Limestone 68 Phosphate Rock-Colloidal 82 Clay Clay-General 63 Heavy Minerals 65 Peat 78 Sand 83 Collier Limestone 69 Columbia Limestone 69 Dade Cement 62 Limestone 70 Peat 78 Sand 83 DeSoto Limestone 71 Duval Exfoliated Vermiculite 64 Expanded Perlite 64 Gypsum 65 Escambia Expanded Perlite 64 Sand 84 Gadsden Clay-Fuller's Earth 63 Clay-General 63 Sand 84 Glades Limestone 71 Sand 84 Gulf Lime 66 Magnesium Brines 78 Hamilton Gypsum 65 Phosphate Rock 80 Hardee Phosphate Rock 80 Hendry Limestone 71 Hernando Cement 62 Lime 66 Limestone 72 BUREAU OF GEOLOGY Commodity Highlands Hillsborough Holmes Indian River Jackson Lake Lee Leon Levy Madison Manatee Marion Monroe Orange Palm Beach Pasco Polk Putnam St. Lucie Santa Rosa Peat Cement Exfoliated Vermiculite Gypsum Limestone Peat Phosphate Rock v Sand Expanded Perlite Limestone Limestone Sand Clay-General Peat SSand Limestone Sand Limestone Peat Cement Limestone Phosphate Rock Sand Clay-Fuller's Earth Clay-General Limestone Phosphate Rock-Colloidal Sand Limestone Peat Sand Limestone Peat Limestone Limestone Peat Phosphate Rock Sand Clay-Kaolin Peat Sand Limestone Sand Sand Sulfur County Page 78 62 64 65 72 78 81 84. 65 72 73 85 63 79 85 73 85 73 79 62 74 81 86 63 64 74 82 86 75 79 86 75 79 75 76 79 81 87 63 80 87 76 87 88 88 __ __ INFORMATION CIRCULAR NO. 102 County Commodity Sarasota Sumter Suwannee Taylor Walton Washington Limestone Sand Lime Limestone Peat Limestone Limestone Sand Sand Page __ I__ 1_1_ _____ |
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| MILLISECOND | CLASS.METHOD | MESSAGE |
|---|---|---|
| 0 | sobekcm_page_globals.constructor | |
| 0 | sobekcm_page_globals.constructor | Application State validated or built |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.constructor | Navigation Object created from URI query string |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.display_item | Retrieving item or group information |
| 0 | sobekcm_page_globals.get_entire_collection_hierarchy | Retrieving hierarchy information |
| 0 | sobekcm_assistant.get_entire_collection_hierarchy | |
| 0 | cached_data_manager.retrieve_item_aggregation | |
| 0 | cached_data_manager.retrieve_item_aggregation | Found item aggregation on local cache |
| 0 | item_aggregation_builder.get_item_aggregation | Found 'all' item aggregation in cache |
| 0 | system.web.ui.page.page_load (ufdc.page_load) | |
| 0 | sobekcm_page_globals.constructor.on_page_load | |
| 0 | html_echo_mainwriter.add_style_references | Adding style references to HTML |
| 0 | html_echo_mainwriter.add_text_to_page | Reading the text from the file and echoing back to the output stream |
| 4 | html_echo_mainwriter.add_text_to_page | Finished reading and writing the file |