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Copyright Front Cover Front Cover 1 Front Cover 2 Title Page Page 1 Introduction and structure Page 2 Page 3 Page 4 Page 5 Page 6 Lithostratigraphy Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16 Page 17 Page 18 Page 19 Page 20 Page 21 Page 22 Page 23 Page 24 Page 25 Page 26 Page 27 Page 28 Page 29 Page 30 Page 31 Page 32 Page 33 Page 34 Hawthorn group gamma-ray log interpretation Page 35 (MULTIPLE) Page 36 Page 37 Page 38 Page 39 Page 40 Bibliography Page 41 Page 42 Page 43 Page 44 Page 45 Page 46 Page 47 Page 48 Page 49 Page 50 Page 51 Page 52 Page 53 Page 54 Page 55 Page 56 Page 57 Page 58 Page 59 |
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FLRD GEOLOSk ( IC SUfRiW COPYRIGHT NOTICE [year of publication as printed] Florida Geological Survey [source text] The Florida Geological Survey holds all rights to the source text of this electronic resource on behalf of the State of Florida. The Florida Geological Survey shall be considered the copyright holder for the text of this publication. Under the Statutes of the State of Florida (FS 257.05; 257.105, and 377.075), the Florida Geologic Survey (Tallahassee, FL), publisher of the Florida Geologic Survey, as a division of state government, makes its documents public (i.e., published) and extends to the state's official agencies and libraries, including the University of Florida's Smathers Libraries, rights of reproduction. The Florida Geological Survey has made its publications available to the University of Florida, on behalf of the State University System of Florida, for the purpose of digitization and Internet distribution. The Florida Geological Survey reserves all rights to its publications. All uses, excluding those made under "fair use" provisions of U.S. copyright legislation (U.S. Code, Title 17, Section 107), are restricted. Contact the Florida Geological Survey for additional information and permissions. State of Florida Department of Natural Resources Tom Gardner, Executive Director Division of Resource Management Jeremy Craft, Director Florida Geological Survey Walt Schmidt, State Geologist and Chief Open File Report 15 The Lithostratigraphy of Nassau County in Relation to the Superconducting Supercollider Site Investigation by Thomas M. Scott Florida Geological Survey Tallahassee, Florida 1987 3 1262 04543 6259 LIBRARY THE LITHOSTRATIGRAPHY OF NASSAU COUNTY IN RELATION TO THE SUPERCONDUCTING SUPERCOLLIDER SITE INVESTIGATION .BY Thomas M. Scott Florida Geological Survey OPEN FILE REPORT NO. 15 1987 The Lithostratigraphy of Nassau County in Relation to the Superconducting Supercollider Site Investigation INTRODUCTION The State of Florida is currently conducting the initial site investi- gation in Nassau County for the proposed superconducting supercollider. Geologic parameters played a key role in the selection of several sites throughout the State. The final selection was made based on geological, environmental and socioeconomic factors with Nassau County being judged the most favorable location (Figure 1). The Florida Geological Survey provided the initial site proposals based on the geological data available from Survey publications, personnel and files. The Nassau County site was included based upon the occurrence of a thick confining section above the Floridan aquifer system, the lack of potentially cavernous carbonates within the confining beds, and the exis- tence of a surficial or shallow aquifer system that produces relatively limited quantities of water. The current Nassau County data base on file at the Florida Geological Survey is limited to lithologic samples from 30 wells (including 2 cores) and geophysical logs of 21 wells. These are listed in the appendicies. STRUCTURE Nassau County, the northeastern most county in Florida, lies on the northern and northwestern flank of the Jacksonville Basin of the Southeast Georgia Embayment (Figure 2). The Jacksonville Basin represents a localized thickening of the stratigraphic section within the Southeast Georgia Embay- ment. Figure 1 indicates the relationship of the Nassau County area to the other major structural features in Florida. 1 __ I / I *-A- -- -L - U, - -I Study area and location of cross-section Figure 1 I____ __________ _~_ 0 JACKSONVILLE NASSAU NOSE N 0 50 100 MILES SCALE "p,,,~~ Structures affecting the Hawthorn Group Figure 2 No faults have been recognized or postulated to occur in the county. Leve (1966.) and Fairchild (1977) suggested the existence of faults in Duval County. If these faults exist, they do not appear to have cut through the Hawthorn Group sediments indicating that they have not been active since at least the late Middle Miocene. Topography and Geomorphology The topography of the Nassau County area characteristically consists of higher elevations with greater relief in the western one third of the county and lower elevations and little relief in the remaining area. The western area has elevations of as much as 107 feet above MSL near Boulogne; however, the average elevation in this area ranges from 70 to 80 feet above MSL. The lowlands surrounding the St. Marys River, generally the lowest points in the area, range in elevation from near 50 feet above MSL in the southwest to less than 5 feet above MSL along the northern boundary of the county. The eastern two-thirds of the county average less than 25 feet above MSL with the lowlands generally below 10 feet above MSL. The topographic quadrangles covering Nassau County include, from west to east: Folkston, Boulogne, Kings Ferry, Kingsland, Toledo, Hillard, Hillard NE, Gross, St. Marys, Fernandina Beach, St. George, Hillard SW, Callahan, Italia, Hedges, Amelia City, McClenny NE, Bryceville, and Dinsmore. Nassau County lies in the Northern or Proximal Zone of White (1970). The high areas of the western part of the county are part of the Duval Up- lands. Most of the remainder of the county falls in the St. Marys Meander Plain. The east coast of Nassau County, the "Sea Islands", are part of the Atlantic Beach Ridges and Barrier Chain (Figure 3). *-J ST. MARYS RIVER DUVAL UPLAND GEORGIA S ATLANTIC OCEAN ST. MARS MEANDER PLAIN SCALE 0 5 10 15 20 25 Mi 0 8 16 24- 32 40Km Geomorphology of Nassau County * GEORGIA Figure 3 LITHOSTRATIGRAPHY Thin lithostratigraphic discussion of the supercollider site in Nassau County is limited to the carbonates of the upper part of the underlying Floridan aquifer system, the mixed carbonates and siliciclastics of the intermediate confining system and the sediments of the surficial or shallow aquifer system. This includes the Upper Eocene Ocala Group, the Miocene Hawthorn Group, the Pliocene Nashua Formation, and the undifferentiated Plio-Pleistocene and Holocene sediments (Figure 4). Total thickness of these sediments ranges from 400 to 500 feet within the county. Construc- tion of the proposed supercollider will most likely occur in the upper 150 feet of this section within the Hawthorn Group. Ocala Group The Ocala Group consists of very pure limestones with limited occur- rences of thin dolostone near the base of the group. The limestones are characteristically calcarenitic with varying amounts of carbonate mud in the matrix (grainstone to packstone). The grains are composed of fossil fragments, foraminifera, and biogenic debris. The limestones are generally tan or very light brown to white and range from soft, poorly consolidated to hard, well indurated and recrystallized. The dolostones are hard, gene- rally well indurated, gray to moderate brown and crystalline. The Ocala Group occurs throughout the county at elevations ranging from approximately 400 feet below mean sea level (MSL) in the western por- tion to greater than 500 feet below MSL along the east coast, dipping in a general west to east direction (Leve, 1966) (Figure 4). The thickness of the Ocala Group in this area ranges from approximately 350 feet to greater than 500 feet, thickening from west to east (Leve, 1966). Cooke (1945), Vernon (1951), Herrick and Vorhis (1963), Purl land Vernon (1964) and Stringfield (1966) provide more information on the Ocala Group. Therela- Stringfield (1966) provide more information on the Ocala Group. The rela- Figure 4 Lithostratigraphic units of the Hawthorn Group in north Florida tionship of the Ocala Group to the overlying sediments can be seen in Figures 6 and 7. The carbonates of the Ocala Group are part of the upper Floridan aqui- fer system and are capable of producing vast quantities of water. Leve (1966) indicates flow rates measured in zones of the Ocala Group often ex- ceeded 3,000 gallons per minute. The sediments of the Floridan aquifer system will not be encountered during the construction of the supercollider. The construction activity will be separated from the Floridan aquifer sys- tem by as much as 300 feet of low permeability to relatively impermeable sediments of the Hawthorn Group. Hawthorn Group The Hawthorn Group sediments represent a dramatic deoositional change from the carbonates of the Eocene (Oligocene is absent) to the siliciclas- tic dominated section in the Miocene. The Miocene sediments exhibit tre- mendous variability both laterally and vertically. In a general sense, the Hawthorn sediments contain more carbonate beds in the lower portion of the section. Carbonates decrease in abundance higher in the section. Research by Scott (1987) in Florida and Huddlestun (1987) in Georgia provides the lithologic framework and formational breakdown of the Hawthorn Group in this area. In ascending order the formations include: the Penney Farms/Parachucla Formations, the Marks Head Formation and the Coosawhatchie Formation including the Charlton Member (Figure 4). These units are recognized in cores (Figure 7). However, in well cuttings it is difficult to separate the units due to the loss of fine grained sediments and the inclusion of material caving from above. If enough core control is available, cuttings can be utilized in a detailed study. The data pre- I EXPLANATlON -25- Z ,lou -er- 25 Feet Lfl''t C! N3,Unrn Fm Fooryt fdoed .?,e ferrej, Wells G E 0 R i A 0r7cos F LO0 R 0 .33- 5 .7 .~ ..... -a Is -U -350 -3, '0-~j~, 0 P, 0 1 .- ---- AL -325 V41" CV 0.~ ~-250 ED. fa/r\\ \\~_.1 I.~.~-\\.-VILL1I~;O=-~J~// // ~DZ f 04s-5 srlc'7 _,7~ IT C LE" CO C- ~ \-\ 4 -AV,\ -29~~\ \\-\~--: I Figure 5 * Top of Ocala Group in.Northeast Florida Lan -l r~51*C*3 .53r( C .% *5I Cross section C-C' (see figure 1 for location) (See Scott (1983) for discussion of faults) A 09 - p [F "1 "t :1. '.5 I94r, OCALs. 0*0. --- I Figure 6 W-13I 15 CLRY HfNVTY HIMS. "SHY, TN,1H. *UNDIFFERENTIATED -180 -190 -200 -210 -220 -230 - Jll7' O.....- ~i^ .* 7. ... 7 S HAWTHORN GROUP SRNO CALCT CHARLTON MEMBER CALCITE PHOSPHATE DilOiilE PHOSPHATE OOLCOITE PHOSPHATE COLONTTE PHOSPHATE PHOSPHATE PHOS PATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHT11 PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHAIE PHOSPHATE PHOSPHATE SA PHOSPHATE SO PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE A SE0H tOLMOITE PHOSPHATE DOLOMITE PHOSPHATE OOLOMAIE PHOSPHATE OOLOMIT6 PHOSPHATE DOLOMITE OOLOHITE CLTA -280 - -290 - -300 -310 - -320 -330 -30 - -350 -360 _ -370 _ -380. - -390 -400 _ -410 - SANO CLRY OOLONITE PHOSPHATE DOLOAITE PHOSPHATE DOLOMITE PHOSPHATE COLOSIIE PHOSPHATE OOLOLIE E _e=.U.TCr MIK.IIC -420 - PHOSPHATE Z 0 c- PHOSPHATE 00CLOITE PHOSPHATE PHOSPHATE SR PHOSPHATE S PHOSPHATE SRAO PHOSPHATE SAND 0) PHOSPHATE SANO PHOSPHAIE SANO ODLOIITE Y PHOSPHATE 0LOAHITE CLAY PHOSPHRIE CLRY 4 PHOSPHATE CLRAY PHOSPHATE PHOSPATIE imne*Pnllc FCcI -. -- -- -- / / y- -^ ^ 1[-4-4-4-4 [- C Z. Z. Z. -. -... :-. ., .. .. .7 z .... ,-..-. -... ..-. ' _,_.-: ...*, _\ / '.i '. / = 4 / / / / / /; / PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE SILT PHOSPHATE SANH PHOSPHATE PHOSPHATE PHOSPHATE CLAY PHOSPHATE SHND CLAY CLAY CLAY PHOSPHATE CLAY PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE PHOSPHATE CLAY PHOSPHATE PHOSPHATE CLRAY PHOSPHATE PHOSPHATE PHOSPHATE CLAY PHOSPHRAE SRND PHOSPHATE SADO PHOSPHATE SAND PHOSPHATE SAIND CLAY CLAY CLAY CLAY CLRI SAHO SANO CRLCITE CLAY CLAY CLRAY SANO CLARY SA CLA' HAWTHORN GROUP SPAS OCALA GROUP CRYSTAL RIVER FORMATION Reference core for the Charlton Member of the Coosawhatchie Formation, Cassidy #1, Nassau County (Lithologic legend Appendix B) .. ..-* -*-*.*-* .-*y-*/-*,--7 .. <. .7. .. -_ - -50 -60 -70 -80 -90 -100 -110 -120 -130 -150 _ -170 - -176- z 0 r- c4 LU z z I Figure 7 -250 - CLAY - sented below on the formations of the Hawthorn Group is excerpted from Scott (1987) with only minor changes. Penney Farms/Parachucla Formation The Penney Farms Formation, introduced by Scott (1987), occurs through- out much of northern Florida as a subsurface unit (Figures 3 and 4). It is the lateral equivalent of the Parachucla Formation in southeastern Georgia as defined by Huddlestun (1987). The faces transition between the Penney Farms and the Parachucla occurs in northern Nassau County and into Charlton and Camden counties, Georgia. As a result, cores taken in Nassau County may contain either Penney Farms or Parachucla. The primary difference be- tween the two units is the amount of carbonate present as discreet beds, with the Penney Farms containing more carbonate. The carbonates are variably quartz sandy, phosphatic, clayey dolo- stones. Sand content is variable to the point that the sediment may become a dolomitic sand. Phosphate grains may comprise twenty-five (25) percent or more with an average of approximately five (5) to ten (10) percent. Clay percentages are generally minor [below five (5) percent] but often increase in the dolostones of the upper portion of the formation. The dolostones are medium gray to pale yellowish brown. They are generally moderately to well indurated and finely to coarsely crystalline in the lower part. The dolostones of the upper portion are generally less indu- rated. Thicker, more massive beds predominate in the lower zone while thinner beds are most common in the upper section. Mollusk molds are common in the dolostones, particularly in the more coarsely crystalline type. Zones of intraclasts are common in the hard, finer grained dolostones of the lower part of the Penney Farms. The intraclasts are composed of dolostone that is essentially the same as the enclosing matrix. The intraclasts are recognizable due to a rim of phosphate replacement along the edges of the clasts. Edges of the clasts vary from angular to sub- rounded indicating very little to no transport of the fragments. They also may be bored, indicating at.least a semi-lithified state prior to being re- deposited. Limestone, in the basal portion of the Penney Farms Formation, occurs sporadically. When it does occur, it is generally dolomitic, quartz sandy and phosphatic. The quartz sands are fine to coarse grained, moderately to poorly sorted, variably phosphatic, dolomitic, silty and clayey. The phosphate grain content varies considerably, sometimes to the point of being classi- fied as phosphorite sand [fifty (50) percent or greater phosphate grains]. In general, however, the phosphate grain content averages between five (5) and ten (10) percent. The sands are typically olive gray or grayish olive to medium light gray. Clay content varies considerably in the sands. Clay beds in the Penney Farms Formation are typically quartz sandy, phosphatic, silty and dolomitic. The proportions of the accessory minerals vary from nearly zero to more than fifty (50) percent. Nearly pure clay beds are uncommon. Dolomite is very common in the clays, often being the most abundant accessory mineral. Olive gray and grayish olive green colors generally predominate, but colors may range into the lighter shades. Smectite typically dominates the clay mineralogy of this unit, with paly- gorskite, illite and sepiolite also present. X-ray analyses by Hetrick and Friddell (1984) indicate that palygorskite may become predominant over smectite in some samples. Reik (1982) indicated that palygorskite domina- tes in the lower part of the Penney Farms while smectite dominated in the upper portion in Clay County. Other minor mineralogic constituents include mica, K-feldspar and opal-ct. Clinoptilolite has been identified ih a few sample es. When abundant silt-sized, unconsolidated dolomite occurs, difficulty arises in.determining whether the actual rock type is a very dolomitic clay or a very clayey dolostone. Insoluble residue analysis is the only accu-. rate method of determining the clay and dolostone contents. Rough analysis indicates that, in general, the lighter the color of the sediment, -the higher the dolomite content. This method was employed'for determining the sediment type in these situations. The plastic beds of the Penney Farms Formation are lithologicaly very similar to those in the Parachucla Formation in southeastern Georgia (Huddlestun, 1987). As the Penney Farms Formation begins to lose its carbonate units northward and northwestward into Georgia, the characteris- tic lithologies are no longer apparent and the formation can no longer be identified as the Penney Farms. These sediments in Georgia are included in the Parachucla Formation (Huddlestun, 1987). The Penney Farms Formation unconformably overlies limestones of the Upper Eocene Ocala Group in Nassau County. The unconformity is very appa- rent due to the drastically different lithologies of a pure limestone below to a sandy, phosphatic dolostone or dolomitic, clayey phosphatic sand above. The Marks Head Formation unconformably overlies the Penney Farms Formation throughout Nassau County. The overlying Marks Head Formation consists of interbedded fuller's earth type clays, sands and dolostones which are generally lighter colored than the sediments of the Penney Farms. The top of the Penney Farms is placed at the break between the lighter colored sediments of the Marks Head and the darker colored sands and clays of the upper part of the Penney I I Farms.' Occasionally, a rubble zone marks the break between the Marks Head and the Penney Farms formations. When it occurs, the rubble consists of clasts of phosphatized carbonate. The relationship of the Penney Farms Formation to the underlying and overlying sediments can be seen in the cross section (Figures 5 and 6). The Penney Farms Formation of the Hawthorn Group occurs as a subsur- face unit in Nassau County. The top of the Penney Farms Formation ranges in cores from -333 feet MSL in Carter #1, W-14619, Duval County to +80 feet MSL in Devils Millhopper #1, W-14641, Alachua County. In Nassau County, the top of the Penney Farms Formation occurs at approximately -250 feet MSL in the northwestern area to an estimated -350 feet MSL in the southeastern to eastern area (Figure 8). The Penney Farms Formation dips in a general easterly to southeasterly direction in Nassau County toward the Jacksonville Basin with an average dip of 4 feet per mile. Locally, both the direction and angle of dip may vary. The Penney Farms Formation varies in thickness from zero on the crests of the Ocala Platform and Sanford High (Figure 2) to more than 155 feet in Carter #1, W-14619, Duval County in the Jacksonville Basin (Figure 2). The total thickness of this unit was not determined in this core as the core terminated in the Penney Farms Formation after penetrating 155 feet. This author estimates that the base of the Penney Farms should occur near.-575 feet MSL based on nearby water wells. This suggests that approximately 230 feet of the unit should be present in the deepest portion of the Jackson- ville Basin. The observed thickness of the Penney Farms in Cassidy #1, W-13815, Nassau County is 150 feet (Figure 9). The Hawthorn Group sediments of northern Florida yield very few datable fossils or fossil assemblages. Diagenetic overprinting on the -r----- A iC. T %% C. Y 7 Cj -4- 5 ----FE-T-- S C A L E N s o ,| IT -I - S0o RIOMETERS LEGEND coMIS CutIohGS ~J UMITSl Of HAWTHORN GROUP Figure 8 Top of Penney Farms Formation (shaded area indicates undifferentiated Hawthorn Group) fV-r-- -l---- ---'i "1-- ..~, 50 175 +- -- .. . oi- r A100 LC a ST i A o *" J L ._ 75 I OF I ~ '-j-- A--, -- -i DIC I LEGEND SCUTTINGSt Lii E V 1 01L O HAT SHOR AGO S I OOUGH I T US Figure 9 Isopach of Penney Farms Formation (shaded area indicates undifferentiated Hawthorn Group) sediments has obliterated the vast majority of fossils leaving mainly molds and casts. Diatom and mollusk molds are the most frequently encountered fossil remains. Nt the present time, a date has been obtained from the Cassidy 1 core, W-13815, Nassau County in the interval from -370 to -375 MSL. The sediment, a calcareous, quartz sandy clay, contained benthic and planktonic foraminifera, ostracods, spicules (sponge?-), echinoid fragments and hryozoans. The planktonicc foraminifera indicate an Aquitanian, upper Zone .4 or lower M.S.of Blow (1969)) for this interval (Huddlestun, per- sonal communication, 1983). The Penney Farms Formation of the Hawthorn Group is older than the commonly accepted age for the Hawthorn Formation as described by Purl and Vernon (1964). Purl and Vernon used a Middle Miocene age only for their Hawthorn Formation. This has been the accepted age for the Hawthorn Forma- tion by the Florida Geological Survey for sometime. Armstrong and Wise (1985) suggested a latest Oligocene age for the base of the Hawthorn in southeastern Florida. The data presented here indicate this should further be revised. The carbonate section of the Penney Farms Formation has often been referred to as the basal Hawthorn dolostone in northern Florida. The gamma-ray signature is quite distinctive, consisting of a number of very high counts per second (cps) peaks (see section on gamma ray logs). Marks Head Formation Huddlestun (1987) reintroduced the Marks Head Formation in Georgia and included it as part of the Hawthorn Group. The Marks Head Formation is extended into northern Florida as the middle unit of the Hawthorn Group. The lithologic similarities between the Marks Head Formation in southeast Georgia and in north Florida warrants the use of the same nomenclature. The Marks Head Formation in Florida consists of interbedded sands, clays and dolostones throughout its extent. Carbonate beds are more common in the Marks Head Formation in Florida than in Georgia; the proportion of carbonate, both as a rock type and an accessory (matrix) mineral, gradually increases into Florida. This unit is the most lithologically variable for- mation of the Hawthorn Group in north Florida. Miller (1978) defined his Unit 0 (equivalent to the Marks Head Formation) in the Osceola National Forest in Columbia and Baker counties, Florida as being "complexly inter- bedded shell limestone, clay, clayey sand and fine grained sandstone." The carbonate portion of the Marks Head Formation is typically dolo- stone; limestone is uncommon but does occur sporadically as is the case throughout the Hawthorn Group. The Marks Head dolostones are generally quartz sandy, phosphatic and clayey. The dolostones vary in induration from poorly consolidated to well indurated. The induration varies in inverse relationship to the amount of clay present within the sediment. Phosphate grains normally comprise up to five (5) percent; however occa- sional beds may contain significantly higher percentages. Quartz sand con- tent varies from less than 5 percent to greater than 50 percent where it grades into a dolomite cemented quartz sand. The dolostones range from yellowish gray to olive gray in color. Crystallinity varies from micro-to very finely crystalline with occasional more coarsely crystalline zones. Molds of mollusk shells are often present. The occurrence of limestone within the Marks Head Formation in Florida is quite rare. The majority of the "limestone" reported from this part of the section by other workers is actually dolostone. The limestone that does occur is characteristically dolomitic, quartz sandy, phosphatic, clayey, and fine grained. I R The quartz sands from the Marks Head Formation are generally fine to nediumi grained (occasionally coarse grained), dolomitic, silty, clayey and phosphatic. The dolomite, silt and clay contents are highly variable and gradational with the other lithologies. Phosphate grains are usually pre- sent in amounts ranging from one (1) to five (5) percent; however, phos- phate percentages may range considerably higher in thin and localized beds. The quartz sands are typically light gray to olive gray in color. Indu- ration varies from .poor .to moderate. Clay beds are quite common in the Marks Head Formation, occasionally comprising a large portion of the section. The clays are quartz sandy, silty, dolomitic and phosphatic. As is the case in the underlying Penney Farms Formation, the Marks Head clays contain highly variable percentages of accessory minerals; relatively pure clays do occur but are not common. The clays range from greenish gray to olive gray in color and are typically lighter colored than the clays of the underlying unit. Phosphate grains are present virtually throughout the Marks Head For- mation. They characteristically occur as brown to black, sand-sized grains scattered throughout the sediments. The phosphate grains are rounded and often in the same size range as the associated quartz sands. Phosphate' pebbles occur rarely. Mineralogically, the Marks Head Formation clays contain palygorskite, sepiolite, smectite and illite; kaolinite is present only in the weathered section (Hettrick and Friddell, 1984). Hettrick and Friddell (1984) indi- cated that palygorskite is often the dominant clay mineral in this unit; smectite is the second most abundant clay mineral. Smectite becomes the most abundant clay mineral when palygorskite content decreases. Other minor mineralogic constituents include mica, opal-ct and feldsoar. Huddlestun (in press) reports the occurrence of zeolite in the Marks Head Formation. The Marks Head Formation is underlain disconformably throughout Nassau County by the Penney Farms Formation. The upper part of the Penney Farms Formation consists predominantly of darker, olive gray colored sands and clays with occasional dolostone beds. The base of the Marks Head Formation is placed at the contact between the darker colored sands and clays of the upper Penney Farms and the generally lighter colored, more complexly inter- bedded sands, clays and dolostone of the Marks Head. Occasionally, the contact is marked by a rubble zone containing phosphatized carbonate clasts but the unconformity is often difficult to recognize. The Coosawhatchie Formation disconformably overlies the Marks Head Forma-tion throughout Nassau County. The Coosawhatchie-Marks Head contact is generally placed at the top of the first hard carbonate bed or light colored clay unit below the darker colored clayey, dolomitic, quartz sands and dolostones of the basal Coosawhatchie Formation. Occasionally, the contactappears grada- tional in a sequence of dolostone and interbedded sands. In this case the top of the Marks Head is placed at the uppermost hard dolostone bed in the interbedded sequence. A rubble bed sometimes marks the unconformity. The relationship of the Marks Head Formation to the underlying and overlying units is graphically illustrated in Figures 6 and 7. The Marks Head Formation of the Hawthorn Group occurs as a subsurface unit in Nassau County. The top of the Marks Head Formation in the subsur- face varies from -260 feet MSL in Carter #1, W-14619, Duval County to +114 feet MSL in Devil's Millhopper #1 W-14641 in Alachua County. The top of the Marks Head in Nassau County varies from -100 feet MSL in the south- western most corner to -250 feet MSL on the east coast (Figure 10). A Top of the Marks Head-Formation (shaded area indicates undifferentiated Hawthorn Group) Figure 10 V\ 5IF - SLT. AL OT O0 i O 0 0A OP HAWTHORN GROU-150 ILCHI STH . ,-50 SCL N CI 8 so A .EGIN-L 20 doImug t 5 20 !a K= IEa e The Marks Head Formation in Nassau County dips to the northeast and east with an average dip of 4 feet per mile. The direction and angle of dip may vary locally. The thickness of the Marks Head Formation varies from zero on the crest of the Ocala and Sanford highs to 130 feet in the core N.L. #1, W-12360, Bradford County. In northwestern Nassau County, it is 80 feet thick (Figure 11). Datable-fossil assemblages within the Marks Head Formation have not been found in north Florida. The only fossils noted were scattered molds of mollusk shells and occasional diatom molds. Lithologic correlation be- tween these sediments and those in Georgia, where fossiliferous sediments are found, indicates that the Marks Head Formation is late Early Miocene (Burdigalian) age (Huddlestun, personal communication, 1983). Planktonic foraminifera in Georgia indicate Zone N.6 or early N.7 of Blow (1969). As is the case for the Penney Farms Formation, the Marks Head Forma- tion is older than the previously accepted age for the "Hawthorn Formation" in Florida as interpreted by Cooke (1945) and Puri and Vernon (1964). Cooke (1945) and Purl and Vernon (1964) suggested a strictly Middle Miocene age for their "Hawthorn Formation". Coosawhatchie Formation The Coosawhatchie Formation of the Hawthorn Group .is used the upper unit of the group in much of north Florida. Huddlestun (1987) proposed the Coosawhatchie as a formal lithostratigraphic unit in Georgia. It extends into north Florida with only minor lithologic changes (Scott, 1987). The Coosawhatchie Formation in Florida consists of quartz sands, dolo- stones and clays. Characteristically, clayey, sandy to very sandy dolo- _ ~ II~-SPI~IY4~ '-. 25 S-50 7 A I a7 .. 50 A 0A S CAL! 0 MrLS I R0 40 1 LEGEND - coams j tIS DF MAwTHORN jaouP A - ...... .. --. o ^ --------- L 0----- - Figure 12 Top of Coosawhatchie Formation (shaded area indicates undifferentiated Hawthorn Group) 0 'AA D 'S 0.- 'n ? 'IsoN i ~' L 7 C T LTC W I - tC L -A Yl II - GIRCHftsST J.! * I A tc H o I~I~iP! 14 AIM -J, m-5 ;ji I,8 n~~i-0 F AGL I F I J v , 1 ' SCALE N C 5 FEET IT 0 20 40 MILES 0 0 40 KILMETERS -- U MT R LEGEND CORES HERIIANDO CUTTINGs I AL UIMITS OF HAWTHORN GROUP r- P -A S -C .O *.II/-.,A| ^ m~liB~ilU M 0 -,4^ S"S Ag ^* v-^- ^ .-250 6 \ e A T \~~~R -200 -150 i.~.l-100 -I ii Ni Figure 12 Top of Coosawhatchie Formation (shaded area indicates undifferentiated Hawthorn qroup) L I, ILU 1S A E M N 01 E nn a 1 j F j I stone and dolomitic, clayey sands are the most common lithologies in the upper part. In the lower part, the quartz sands and clays predominate with interbedded dolostones. The quartz sands are dolomitic, clayey and phosphatic. The sand grains are fine to medium grained, poorly to moderately sorted, and subangular to subrounded. The proportions of accessory materials vary greatly. The sands grade into the dolostones and clays in many instances. Phosphate content is quite variable ranging from a trace to more than 20 percent. Clay content varies from less than 5 percent to greater than 30 percent. The sands are often lighter colored in the upper part where there is more carbonate in the matrix and darker in the lower part. Colors range from greenish gray and light gray to olive gray. Induration is generally poor. The dolostones of the Coosawhatchie Formation are quartz sandy, clayey *and phosphatic. The percentages of quartz sand and clay vary widely and may be as much as 50 percent in transitional zones. Phosphate is quite variable also, but is generally less than 10 percent. The dolostones are micro-to finely crystalline, poorly to moderately indurated and occasionally contain nolds of fossils. They range in color from light gray and greenish gray to light olive gray. The dolostones of the upper part appear to become more calcareous in the Jacksonville Basin. The clays in the Coosawhatchie Formation are typically quartz sandy, silty, dolomitic and phosphatic. The clays are light olive gray to olive gray. Clay beds are most common in the lower member (Scott, 1983). The clay mineralogy is dominated by smectite (Hettrick and Friddell, 1984). The clay beds often contain diatoms (Hoenstine, 1984). The phosphate grains present in the Coosawhatchie Formation are nor- *mally amber colored to brown or black; lighter colors occur near the land * surface. The phosphate grains are usually well rounded and in the same size range as the associated quartz sands. Coarser phosphate sands and phosphate pebbles or rubble are not common but are present. The Coosawhatchie Formation disconformably overlies the Marks Head Formation but the disconformity is often not readily apparent. It is, however, recognized biostratigraphically in Georgia (Huddlestun, personal communication, 1983). The contact often occurs in a thin gradational sequence of interbedded sands and dolostones. Occasionally, the contact is marked by a rubble bed. The Coosawhatchie is overlain by undifferentiated Plio-Pleistocene deposits in most of northern Florida. In much of Nassau County, the Coosawhatchie is overlain disconformably by the Pliocene Nashua Formation. The relationship of the Coosawhatchie to the underlying and overlying units is indicated in Figures 6 and 7. The Coosawhatchie Formation occurs throughout much of north Florida. The top of the Coosawhatchie ranges from -93 feet MSL in Bostwick #1, W-14477, Putnam County to +168 feet MSL in Devils Millhopper #1, W-14641, Alachua County. In Nassau County, the top of the Coosawhatchie ranges from near sea level -in the southwestern corner edge to greater than -50 feet MSL along the east coast (Figure 12). It attains a maximum thickness in Florida (including the Charlton Member) of 222 feet in Carter #1, W-14619, Duval County (Figure 13). Huddlestun (1987) indicates that the Coosawhat- chie attains a maximum thickness of 284 feet in the southeast Georgia Embayment in Georgia. The Coosawhatchie Formation dips in a northeasterly to easterly direction in Nassau County. The average dip is approximately 4 feet per mile. The angle and direction of dip is variable throughout the region. 150 125 -o200 S125 A 075 50 "I A *S C IT N s 1 -So FE M as +-- _.-- k+' i : ..---. SOLEGENO C O '" - l ouGH -I 1 Figure 13 Isopach of Coosawhatchfe Formation (shaded area Indicates undifferentiated Hawthorn Group) 0 CUTING$ OFMATOA 5OP G P ;A S e_ I hL r ~-.-I-Oqb q -r r F r iI 00 s r Fiue 3 Ispcho CoawacheFomtin(saedae indiatesundfferntiaed awthrn Goup The Coosawhatchie Formation is not known to occur over the Ocala and Sanford highs or in the immediately surrounding areas. This is thought to be due primarily to erosion; nondeposition may also have played a role. The Coosawhatchie extends from Georgia southward into central Florida. Huddlestun (1987) suggests a Middle Miocene (Early Serravallian.age) for the Coosawhatchie Formation based on planktonic foraminifera. Huddlestun placed it in Zone N.11 of Blow (1969). Hoenstine (1984) studied diatoms from a few selected cores through the Hawthorn. He recognized a Middle Miocene assemblage in Florida sediments assigned in this paper to the Coosawhatchie Formation in northeastern Florida. The Coosawhatchie Formation is widespread in northern Florida and throughout most of this area the Coosawhatchie is the uppermost Hawthorn sediment encountered. In limited areas, it is shallow enough to be exposed in some foundation excavations. The Coosawhatchie Formation in the Jack- sonville Basin contains a lower clay bed of variable thickness. This clay bed correlates with the Berryville Clay Member of the Coosawhatchie Formation in southeastern Georgia. Charlton Member Of The Coosawhatchie Formation Huddlestun (1987) redefined the "Charlton Formation" of Veatch and Stephenson (1911) as a formal member of the Coosawhatchie Formation in Georgia. He found that the Charlton Member is a lithofacies of the upper part of the Coosawhatchie in south Georgia and north Florida. Huddlestun (1987) discussed the reference localities in some detail. A reference sec- tion for the Charlton Member of the Coosawhatchie Formation in Florida is the Cassidy #1 core, W-13815, Nassau County (NWV4, NWI4, Sec. 32, T3N, R24E). The surface elevation is 80 feet MSL. The Charlton Member occurs from +3 -L I- II I I -~* feet MSL to -43 feet MSL. The Charlton Member characteristically consists of interbedded carbo- nates and clays. It is less sandy than the upper part of the Coosawhatchie, into which it grades. It is typically low in sand and phosphate (Huddlestun, 1987). Huddlestun (1987) states that the clay component is often very conspicuous in the cores. This has been found to be true in Florida also. The carbonates of the Charlton Member are often dolostones but range into limestone. They are slightly sandy, slightly phosphatic to non- phosphatic and clayey. They often contain abundant molds of fossil mollusks. The dolostones are finely crystalline, light olive gray and poorly to moderately indurated. The limestones are characteristically very fine grained, slightly sandy, clayey, poorly to moderately indurated, and yellowish gray. The clays are dolomitic to calcareous, with poor to moderate indura- tion, silty, and light gray to greenish gray. The clay minerals present include smectite, palygorskite, illite and kaolinite (Hettrick and Friddell, 1984). The Charlton Member both overlies and interfingers laterally with the upper portion of the undifferentiated Coosawhatchie Formation. The Charl- ton is simply a distinct faces of the upper Coosawhatchie. It is overlain by the sediments discussed as overlying the Coosawhatchie Formation. The upper contact is unconformable. Sediments assigned to the Charlton occur at Brooks Sink (SWl/4, SWl/4, Sec. 12, T7S, R20E, Bradford County) at an elevation of +145 feet MSL. The highest elevation for the top of the Charlton in a core was in Wainwright 41, W-14283, Bradford County where it occurred at +109 feet MSL. The deepest that the top of the Charlton Member was found is in Carter #1, W-14619, Duval County where it is -38 feet MSL. The top is very near MSL to Nassau County (Figure 14). The Charlton Member of the Coosawhatchie Formation reaches its maximum recognized thickness in Florida in Cassidy #1, W-13815, Nassau County, where it is 70 feet thick (Figure 7 and 15). It is very spotty in its occurrence. The Charlton Member, as originally defined by Veatch and Stephenson (1911), was considered Pliocene. Huddlestun (1987) postulates that, based on his observations of the molluscan fauna and the lithostratigraphy of the unit, it is Middle Miocene (Seravallian) in age. Nashua Formation The Nashua Marl of Matson and Clapp (1909) was reintroduced by Huddlestun (1987) as the Nashua Formation. The name Nashua Marl had been abandoned by Cooke and Mossom (1929) who replaced it with the Caloosahatchee Marl, a presumed south Florida equivalent. The Florida Geological Survey, in following the recommendation of Huddlestun (1987), utilizes the Nashua Formation in northern Florida for the shelly sands, clays and some coquina. In Florida, the Nashua is primarily shelly sands and clay. Data on the extent of the Nashua and it's thickness in northern Florida is limited. Huddlestun (1987) indicates that the Nashua underlies most of Nassau County. The Florida Geological Survey core hole Cassidy #1, W-13815 in west-central Nassau County, encountered the Nashua at 27.5 feet above MSL with a thickness of approximately 50 feet. Lithologically, the Nashua contains fine to medium quartz sands with varying percentages of calcilutite, clay and shell. The occurrence of shell, both whole and fragmented, occasionally becomes the dominant litho- logic component. Colors range from light gray to light olive gray. SCALE N a "" 0 20 40 ILSS LEGENO cons a CUTTINGS A>I LUMITS OF HAWTHORN GROUP Figure 14 Top of the Charlton Member (dashed line indicates extent of Charlton) _) _ LEGEND cORES CUTTINGS .AXJ'4IUMITS OF HAWTHORN GROUP Figure 15 Isopach of the Charlton Member (dashed line indicates extent of Charlton) Plio-Pleistocene Undifferentiated and Holocene Sediments The Plio-Pleistocene undifferentiated sediments mantle the Nassau County area with a blanket of fine to medium quartz sands. These sediments contain variable amounts of heavy minerals, silt, clay, iron staining and organic matter. Data on the thickness of these sediments is very limited, however, a thickness of 52.5 feet is recognized in W-13815. Holocene sedi- ments occur along the modern coastline and in association with the present day rivers and streams. HAWTHORN GROUP GAMMA-RAY LOG INTERPRETATION Gamma-ray logs are of particular importance to the investigator studying the complex section of the Hawthorn Group. The gamma-ray activity in the Hawthorn Group sediments is generally significantly higher than sub- Jacent or suprajacent formations, thus allowing the delineation of this unit. Also, since these sediments are often partially or entirely cased off during well construction, the ability of gamma-ray probe to obtain information through casing is most important. In the course of this study gamma-ray logs were the only geophysical logs used. For a discussion of resistivity logs of the Hawthorn Group sediments see Johnson (1984). The Hawthorn Group of northern Florida consists of a complex sequence of clastics and carbonates containing varying percentages of uranium- bearing phosphate minerals. The resultant gamma-ray log shows widely varying peak intensities (Figure 16). The patterns of peaks are similar throughout much of the area from Duval County west to western Hamilton County and from Nassau County south to southern Putnam County. The Hawthorn thins and the gamma-ray signature changes somewhat south of Putnam County in Marion, Lake and northwestern Orange counties. This is due to CLAY COUNTY W-14219 FEET UNDIFFERENTIATED -100 COOSAWHATCHIE FFm. -200- MARKS HEAD 2-00 Fm. -300 PENNEY FARMS Fm. -400 OCALA GROUP 0 I0 PS 200 Figure 16 Gamma ray log, Jennings #1, W-14219, Clay County both erosional removal of the upper sediments and less deposition in the area between the Ocala Uplift and the Sanford High. 4 typical gamma-ray log from the north Florida area (Figure 16) con- sists of five generalized zones. This gamma-ray signature is generally present in north Florida. However, the pattern may show significant variation in the intensities of peaks and thicknesses of peak groups. Formational correlation with the gamma-ray signature is relatively con- sistent. The upper, high intensity zone and part of the subjacent lower intensity zone correlate with the Coosawhatchie Formation. The Marks Head Formation correlates with part of the low intensity zone, the underlying higher intensity zone, and the upper portion of the second low intensity zone. The Penney Farms Formation incorporates the remainder of this low intensity zone and the basal, high to very high intensity zone. The underlying Ocala Group has significantly lower generalized signatures than the sediments of the Hawthorn Group. The formational correlations with the gamma-ray signature are shown in Figure 15. The upper and lower boundaries of the Hawthorn Group are generally easily picked on the gamma-ray logs. However, caution must be exercised in making formational identifications based solely on the signatures. _ ~---~----I~-~- TABLE 1. GEOLOGISTS LOGS/CUTTINGS NASSAU COUNTY Location (T.R.Sec) Well Elevation Depth 4N, 24E, 19, SE4 3N, 28E, 14 Ft. Clinch/Amelia Is. 3N, 28E, 24 3N, 28E, 24 3N, 28E, 30, NE4 3N, 28E, 24, NE4 5N, 24E, 27 30-43-10/81-37-50 2N, 27E, 42, SW4 Hilliard Fernandina Beach Hilliard 2N, 28E (Fer. Bch) 3N, 24E, 9, SW4 4N, 23E, 26 3N, 27E, 50 2N, 28E, 22 2N, 28E, 39 2N, 28E, 39 3N, 27E, 50 2N, 27E, 44 3N, 24E, 22, NW4 4N, 23E, 27, NE4 99' 15' 5' 15' 11' 20' 25' 10' 5' 37' 55' 70' 95' 40' lot 10' 10'- 80' 60' 4,824' 900' 800' 750' 1,060' 2,130' 1,205' 60' 45' 905' 821' 1201' 700' 1200' 803' 98' 990' 1016' 95' 700' 580'(?) 624' 490' 905' Geol. Log 336 371 391 343 670 890 2918 1030 1026 2964 3586 4310 4875 6265 6532 10482 10715 11100 12315 12317 13074 13563 13815 15662 Yes Drillers Yes Partial Yes Yes Drillers Yes Drillers Drillers Yes Drillers Drillers Drillers Yes Core Yes Drillers Yes Yes Drillers Core p - GEOPHYSICAL LOGS NASSAU COUNTY Geol. Loq # Location (T.R.Sec) Elevation I Ft. Below LSD I Charl. Coosa. M. Head P. Farms Ocala 3N, 28E, 30 - elect. only - M M u N Ft. Clinch 543 10 3N, 28E, 24 40 Caliper only 12 3N, 28E, 35 3N, 24E, 32 (core) 80 Same as #9 SE Callahan 26 Fernan. Bch. CCA9 32 Same as #5 Fernan. Bch (Test Well) 3 CCA #6 4 CCA #10 17 2N, 28E, 5 11 4N, 23E, 27 60 2N, 28E, Gulf Coarse ? 3N, 28E, 24 11 3N, 28E, 23 9 2N, 25E, 29 20 90 47? -- 107 77 123 77 ? 75? 827 ? -- 119 ? 119 74 ? 98 129 118 111 113? 50 228? 223? 308? 252 170? ? 302? ? ? 298? 304? 310? 308? ? ? 360 384 366 332 258 387 380 380 394 357 359 366 373 390 237 529 536 545 482 421 535 546 532 558 533 307 540 547 545 388 *These are located west of Amelia Island; remainder are located in or near Fernandina Beach. 20.1 295 404 560 5 6 7 8 9 *10 *11 12 13 14 15 16 17 *18 19 20 21 *22 TABLE 2. 200 190 _ 180 170 _ 160 150 IBO 130 120 110 100 90 80 70 60 50 T -T 7- 7/ 2 ~- ,I,,* /*,. o - -/--2_ -/. - . P ... .. - P HK\I quartz sand clayey quartz sand calcareous quartz sand dolomitic quartz sand clay sandy clay calcareous clay dolomitic clay shell bed dolomite clayey dolomite sandy. dolomite calcareous dolomite limestone sandy limestone clayey limestone dolomitic limestone phosphorite chert silt no sample Appendix B BIBLIOGRAPHY/SELECTED REFERENCES Altschuler, Z. S., and Young, E, J., 1960, Residual origin of the "Pleistocene" sand mantle in central Florida uplands and its bearing on marine terraces and Cenozoic uplift: U.. S. Geological Survey, Professional Paper .400-B, p. B202-B207. Cathcart, J. B., and Young, E. J., 1964, Geology and geochemistry of the Bone Valley Formation and its phosphate deposits, west central Florida.: Geological Society of America Field Trip #6, Gelogical Society of America 1964 Meeting, 68 p. Assefa, G., 1969, Mineralogy and petrology of selected rocks from the Hawthorne Formation, Marion and Alachua counties, Florida: (unpublished M. S. thesis), University of Florida, p. 88. Badiozamani, K., 1973, The Dorag dolomization model application to the Middle Ordovician of Wis- consin: Journal of Sedimentary Petrology, v. 43, n. 4., p. 965-984. Banks, J. E., and Hunter, M. E., 1973, Post-Tampa, pre-Chipola sediments exposed in Liberty, Gadsden, Leon, and Wakulla counties, Florida: Trans., Gulf Coast Association Geological Society v.23, p. 355-363. Bentor, Y. K., 1980, Phosphorites the unsolved problems: in Marine Phosphorites (Bentor, Y. K., ed.), Society of Economic Paleontologists and Mineralogists, Special Publication 29, p. 3-18. Bergendal, M. H., 1956, Stratigraphy of parts of DeSoto and Hardee counties: U.S. Geological Survey Bulletin 1030-B, 33 p. Bermes, B. J., 1958, Interim report on geology and ground water resources of Indian River County, Florida: Florida Geological Survey, Informa- tion Circular n. 18, 74 p. Bishop, E. W., 1956, Geology and ground water re- sources of Highlands County, Florida: Florida Geological Survey, Report of Investigation n. 15, 115 p. Blow, W. H., 1969, Late middle Eocene to Recent planktonic foraminiferal biostratigraphy, in Bronnimann, P. and Renz, H. H. (eds.), Proc. First Int. Conf. Planktonic Microfossils (Geneva, 1967): E. J. Brill, Leiden, Holland, v. 1., p. 199-421. Brooks, H. K., 1966, Geological history of the Suwannee River: Southeastern Geological Society 12th Annual Field Conference Guidebook, p. 37-45. 1967, Miocene-Pliocene problems of peninsular Florida: Southeastern Geological Society 13th Field Trip Guidebook, p. 1-2. Gremillion, L. R., Olson, N. K., and Puri, H. S., 1966, Geology of the Miocene and Pliocene Series in the north Florida-south Georgia area: Southeastern Geological Society 12th Annual Field Conference, 94 p. Brown, D. W., Kenner, W. E., Crooks, J. W. and Foster, J. B., 1962, Water resources of Brevard County, Florida: Florida Geological Survey, Report of Investigation n. 28, 104 p. Burnett, W. C., 1977, Geochemistry and origin of phosphorite deposits from off Peru and Chile: Geological Society of America Bulletin v. 88, p. 813-823. Burnett, W. C., Veeh, V. H., and Soutar, A., 1980, U-series, oceanographic and sedimentary evi- dence in support of recent formation of phosphate nodules off Peru: in Y. K. Bentor, (ed.) Marine Phosphorites geochemistry, occurrence and genesis, Society of Economic Paleontologists and Mineralogists, Special Publication n. 29, p. 61-72. Carr, W. J.. and Alverson, D. C., 1959, Strati- graphy of middle Tertiary rocks in parts of west central Florida: U. S. Geological Survey .Bulletin 1092, 111 p. Cathcart, J. B., 1950, Notes on the land pebble phosphate deposits of Florida: in Proceedings, Symposium on mineral resources of the south- eastern United States: University of Tennessee Press, p. 132-151. 1963a, Economic geology of the Keysville Quadrangle, Florida: U. S. Geologi- cal Survey Bulletin 1128, 82 p. ,1963b, Economic geology of the Chicora Quadrangle, Florida: U. S. Geological Survey Bulletin 1162-A, 66 p. ,1964, Economic geology of the Lakeland Quadrangle, Florida: U. S. Geologi- cal Survey Bulletin 1162-G, 128 p. 1966, Economic geology of the Fort Meade Quadrangle, Polk and Hardee coun- ties, Florida: U. S. Geological Survey Bulletin 1207, 97 p. and Davidson, D. F., 1952, Distribu- tion and origin of phosphate in the Land Pebble Phosphate District of Florida: U. S. Geological Survey TEI-212, 14 p. and McGreevy, L. J., 1959, Results of geologic exploration by core drilling, 1953 Land Pebble Phosphate District, Florida: U. S. Geological Survey Bulletin 1046-K, 77 p. Chen, C. S., 1965, The regional lithostratigraphic analysis of Paleocene and Eocene rocks of Florida: Florida Geological Survey Bulletin n. 45, 105 p. Clark, D. S., 1972, Stratigraphy, genesis, and economic potential of the southern part of the Florida Land Pebble Phosphate Field: unpubl. Ph.D. dissertation, University of Missouri - Rolla, 182 p. Colton, R. C., 1978, The subsurface geology of Hamilton County, Florida with emphasis on the Oligocene age Suwannee Limestone: unpubl. M.S. thesis, Florida State University, 185 p. Cooke, C. W., 1936, Geology of the Coastal Plain of South Carolina: U. S. Geological Survey Bulletin 867, 196 p. 1943, Geology of the Coastal Plain of Georgia: U. S. Geological Survey Bulletin -941,'' 1-21-p. ___, 1945., Geology of Florida: Florida Geological Survey Bulletin n. 29, 339 p. and Mossom, S., 1929, Geology of Florida: Florida Geological Survey Annual Report 20, p. 29-228. Dall, W. H., 1896, Descriptions of Tertiary fossils from the Antillean region: U. S. Natural Museum, v. XIX, n. 1110, p. 303-305. and Harris, G. D., 1892, Correlation papers-Neocene: U. S. Geological Survey Bulletin n. 84, p. 85-158. Day, D. T., 1886, Phosphate rock: U. S. Geological Survey, Mineral Resources of the United States for 1885, p. 445-454. Eldridge, G. H., 189,8, Preliminary sketch of the phosphates of Florida: American Institute of Mining Engineers, v. xxi, p. 196-231. Eppert, H. C., Jr., 1963, Stratigraphy of the Upper Miocene deposits of Sarasota County, Florida: unpubl. M.S. thesis University of Florida, 66 p. Espenshade, G. H.,. 1958, Geologic features of areas of abnormal radioactivity south of Ocala, Marion County, Florida: U. S. Geological Survey Bulletin 1046-J, 14 p. Espenshade, G. H. and Spencer, C. W., 1963, Geology of phosphate deposits of northern peninsular Florida: U. S. Geological Survey Bulletin 1118, 115 p. Folk, R. L. and Land, L. S., 1975, Mg/Ca ratio and salinity: Two controls over the crystalliza- tion of dolomite: American Association of Petroleum Geologists Bulletin, v. 59, n. 1, o. 60-68. Freas, D. H. and Riggs, S. R., 1968, Environments of phosphorite deposition in the Central Florida Phosphate District: in 4th Forum on Industrial Minerals: Texas Bureau of Economic Geology, p. 117-128. Gardner, J., 1926, The.molluscan fauna of the Alum Bluff Group of Florida: U. S. Geological..Sur- vey Professional Paper 142-A, p. 1-79. Gebelein, C. D., Steinen, R. P., Garrett, P., Hoff- man, E. J., Queen, J. M., and Plummer, L. N., 1980, Subsurface dolomitization beneath the tidal- flats of central west Andros Island, Bahamas: in D. Zenger, J. Dunham, and R. Ethington, (eds.) Concepts and models of dolomitization: Society of Economic Paleontologists and Mineralogists Special Pub- lication 28, p. 31-50. Gibson, T. G., 1967, Stratigraphy and paleoenviron- ment df the phosphatic Miocene strata of North Carolina: Geological Society of America Bulletin, v. 78, p. 631-650. 1982, Depositional framework and paleoen- vironments of Miocene strata from North Caro- lina to Maryland: in Miocene of the Southeastern United States, proceedings of the symposium, Scott, T.M., and Upchurch,S. B., (eds.), Florida Bureau of Geology, Special Publication n. 25, p. 1-22. Gilboy, A. E., 1983, Correlation between lithology and natural gamma logs within the Alafia Basin of the Southwest Florida Water Management District: Southwest Florida Water Management District Technical Report n. 20 p. Goodell, H. G. and Yon, J. W., Jr., 1960, The regional lithostratigraphy of the post-Eocene rocks of Florida: Southeastern Geological Society 9th Field Trip Guidebook, p. 75-113. Gremillion, L. R., 1965, The origin of attapulgite in the Miocene strata of Florida and Georgia: unpubl. Ph.D. dissertation, Florida State University, 139 p. Grim, R. E., 1968, Clay Mineralogy (2nd edition): McGraw-Hill Book Company, 596 p. Hall, R. B., 1983, General geology and stratigraphy of the southern extension of the Central Florida Phosphate District: Geological Society of America, Southeast Section Field Trip Guidebook, March 16, 1983, p. 1-27. Hathaway, J. C., 1979, Clay Minerals: in R. Burns, (ed.) Marine Minerals v. 6, Rev. in Min. p. 123-150. Hawes, G. W., 1882, On a phosphatic sandstone from Hawthorne in Florida: in Proceedings of the U. S. Natural Museum, v. V, p. 46-48. Healy, H. G., 1975, Terraces and Shorelines of Florida: Florida Bureau of Geology, Map Series n. 71. Hendry, C. W., Jr., and Sproul, C. R., 1966, Geology and groundwater resources of Leon County, Florida: Florida Geological Survey Bulletin n. 47, 178 p. and Yon, J. W., Jr., 1967, Stratigraphy of Upper Miocene Miccosukee Formation, Jefferson and Leon counties, Florida: American Association of Petroleum Geologists Bulletin, v. 51, n. 2, p. 250-256. Heron, S. D., Jr. and Johnson, H. S., Jr., 1966, Clay mineralogy stratigraphy and structural setting of the Hawthorn Formation, Coosawhatchie District, South Carolina: Southeastern Geology, v. 7, n. 2, p. 51-63. Herrick, S.M. and Vorhis, R. C., 1963, Subsurface geology of the Georgia Coastal Plain: Georgia Department of Mines, Mining and Geology Infor- mation Circular 25, 67 p. Hettrick, J. H. and Friddell, M. S., 1984, Clay mineralogy of the Hawthorne Group: Georgia Geological Survey Open File Report 84-7, 91 p. Hoenstine, R. W., 1984, Biostratigraphy of selected cores of the Hawthorn Formation in northeast and east-central Florida: Florida Bureau of Geology, Report of Investigation n. 93, 68 p. Hopkins, O. B., 1920, Drilling for oil in Florida: U. S. Geological Survey Press Bulletin April, 1920. Hoy, N. D. and Schroeder, M. C., 1952, Age of the subsurface Tamiami Formation near Miami, Florida: Journal of Geology, v. 60, p. 283-286. Huang, Hui-Lun, 1977, Stratigraphic investigations of several cores from the Tampa Bay area: unpubl. M. S. thesis, University of South Florida, 54 p. Huddlestun, P. F., and Hunter, M. E., 1982, Strati- graphic revision of the Torreya Formation of Florida (Abstract): in Scott, T. M., and Upchurch, S. B., (edsT., Miocene of the south- eastern United States, proceedings of the symposium: Florida Bureau of Geology, Special Publication n. 25, p. 210. Huddlestun, P. F., Hoenstine, R. W., Abbott, W. H., and Woosley, R., 1982, The stratigraphic defi- nition of the Lower Pliocene Indian River beds of the Hawthorn in South Carolina, Georgia and Florida (Abstract): in Miocene of the South- eastern United States, proceedings of the sym- posium, Scott, T. M., and Upchurch, S. B., (eds.) Florida Bureau of Geology, Special Pub- lication n. 25, p. 184-185. Huddlestun, P. F., in press, A revision of the lithostratigraphic units of the Coastal Plain of Georgia: Georgia Geological Survey Bulletin. Hunter, M. E., 1968, Molluscan guide fossils in Late Miocene sediments of southern Florida: Gulf Coast Association of Geological Societies, v. 8, p. 439-450. \ S. ../ and Wise, S. W., 1980a, Possible restriction and redefinition of the Tamiami Formation of South Florida: Points of Discus- sion: Florida Scientist, v. 43, supplement n. 1, 42 p. and Wise, S. W., 1980b, Possible restriction and redefinition of the Tamiami Formation of South Florida: Points of further discussion: Miami Geological Society Field Guide 1980, p. 41-49. and Huddlestun, P. F., 1982, The biostratigraphy of the Torreya Formation of Florida: in Miocene of the Southeastern United States proceedings of the symposium, Scott, T. M., and Upchurch, S. B., (eds.) Florida Bureau of Geology, Special Publication n. 25, p. 211-223. Isphording, W. C., 1963, A study of the heavy mine- rals from the Hawthorne Formation and overlying sands exposed at the Devil's Millhopper, AlacHua County, Florida: unpub. M. S. thesis, University of Florida, p. 65. Johnson, L. C., 1885, Phosphatic rocks of Florida: Science., v. V, p. 396. 1888, Structure of Florida: American Journal of Science, 3rd Series, v. 36, p. 230-236. Johnson, R. A., 1984, Stratigraphic analysis of geo- physical logs from water wells in peninsular Florida: St. Johns River Water Management District Technical Publication SJ84-16, 76 p. Kazakov, A. V., 1937, The phosphorite facies and the genesis of phosphorites: in Geological Investigations of Agricultural Ores, Transactions, Science Institute Fert. and Insecto-Fungicides, v. 142, p. 95-113. Ketner, K. B. and McGreevy, L. J., 1959, Strati- graphy of the area between Hernando and Hardee counties, Florida: U. S. Geological Survey Bulletin 1074-C, 75 p. Kerr, P. F., 1937, Attapulgus clay: American Minerals v. 22, n. 5, p. 534-550. Kimery, J. O., 1964, The Pungo River Formation, a new name for Middle Miocene phosphorites in 3eaufort County, North Carolina: Southeastern Geology v. 5, n. 4, p. 195-205. -,_ 1965, Description .of the Pungo River Formation in Beaufort County, Nor.th Carolina: North Carolina Department of Conservation and Development Bulletin 79, 131 p. King,-.K.. C,. 1.979, Tampa Formation of peninsular Florida, a formal definition: unpubl. M. S. thesis, Florida State University, 83 p. King, K. C. and Wright, R., 1979, Revision of the Tampa Formation, west central Florida: in Gulf Coast Association of Geological Society, v. 29, p. 257-262. Kost, J., 1887, First report of the Florida Geolo- gical Survey, 33 p. Leroy, R. A., 1981, The mid-Tertiary to recent lithostratigraphy of Putnam County, Florida: unpubl. M. S. thesis, Florida,'State University, 179 p. Leve, G. W., 1965, Ground water in Duval and Nassau counties, Florida: Florida Geological Survey, Report of Investigation n. 43, 91 p. Liu, J., 1978, Petrography of the Ballast Point, Brandon and Duette drill cores, Hillsborough and Manatee counties, Florida: unpub. M. S. thesis, University of Florida, p. MacFadden, B. J., 1980, An Early Miocene land mam- mal (Oreodonta) from a marine limestone in ' northern Florida: Journal of Paleontologists, v. 54 n. 1, p. 93-101. and Webb, S. D., 1982, The succession of Miocene (Arikareean through Hemphillian) terrestrial mammal localities and faunas in Florida: in Miocene of the Southeastern United States, proceedings of the symposium, Scott, T. M., and Upchurch, S. B., (eds.) Florida Bureau of Geology, Special Publication n. 25, p. 186-199. MacNeil, F. S., 1944, Oligocene stratigraphy of the southeastern United States: American Association of Petroleum Geologists Bulletin 28, No. 9, p. 1313-1354. Mansfield, W. C., 1939, Notes on the upper Tertiary and Pleistocene mollusks of peninsular Florida: Florida Geological Survey Bulletin 18, 75 p. Matson, G. C., 1915, Phosphate deposits of Florida: U. S. Geological Survey Bulletin 604, 101 p. Matson, G. C. and Clapp, F. G., 1909, A preliminary report of the geology of Florida with special reference to the stratigraphy: Florida Geolo- gical Survey 2nd Annual Report, p. 25-173. Matson, G. C. and Sanford, S., 1913, Geology and ground water -of Florida: U. S. Geological Survey Water Supply Paper 319, 444 p. McClellan, G. H., 1962, Identification of clay minerals from the Hawthorne Formation, Devil's Millhopper, Alachua County, Florida: unpub. M. S. thesis, University of Florida, 119 p. 1964, Petrology of attapulgus clay in north Florida and southwest Georgia: unpubl. Ph.D. dissertation, University of Illinois, 119 p. McFadden, M., 1982, Petrology of porcellinites in the Hawthorn Formation, Hamilton County, Florida: unpubl. M. S. thesis, University of South Florida, 113 p. McFadden, M., Upchurch, S. B., and Strom, R. N., 1983, Modes of silicification of the Hawthorn Formation in north Florida (abs.): Geological Society of America Abstracts with Programs, Southeast Section, Tallahassee, Florida, p. 80. Meisburger, E. P. and Field, M. E., 1976, Neogene sediments of Atlantic Inner Continental Shelf off northern Florida: American Association of Petroleum Geologists v. 60, n. 11, p. 2019 - 2037. Miller, J. A., 1978, Geologic and geophysical Logs from Osceola National Forest, Florida: U. S. Geological Survey, Open File Report 78-799, 103 p. ,1982, Structural and sedimentary setting of phosphorite deposits in North Caro- lina and northern Florida: in Miocene of the Southeastern United States, proceedings of the symposium: Scott, T. M., and Upchurch, S. B., (eds.) Florida Bureau of Geology, Special Publication n. 25, p. 162-182. Hughes, G. W., Hull, R. W., Vecchioli, J., and Seaber, P. R., 1978, Impact of potential phosphate mining on the hydrology of the Osceola National Forest: U. S. Geolo- gical Survey Water Resource Investigation 78-6, 59 p. Millot, G., 1970, Geology of Clays: Springer, New York, New York 429 p. Missimmer, T. M., 1978, The Tamiami Formation- Hawthorn Formation contact in southwest Florida: Florida Scientist, v. 41, n. 1, p. 31-38. and Gardner, R. A., 1976, High resolution seismic reflection profiling for mapping shallow aquifers in Lee County, Florida: U. S. Geological Survey Water Resource Investigation 76-45, 29 p. and Banks, R. S., 1982, Miocene cyclic sedimentation in western Lee County, Florida: in Miocene of the Southeastern United States, proceedings of the symposium: Scott, T. M., and Upchurch, S. B., (eds.) Florida Bureau of Geology, Special Publication n. 25, p. 285-298. Mitchell, L. M., 1965, Petrology of selected carbo- nate rocks from the Hawthorn Formation, Devil's Millhopper, Alachua County, Florida: unpubl. M. S. thesis, University of Florida, 53 p. 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W., 1944, Late Cenozoic geology of southern Florida with a discussion or ground water: Florida Geological Survey, Bulletin 27, 119 p. and others, 1955, Water resources of southeastern Florida: U. S. Geological Survey Water Supply Paper 1255, 965 p. Peacock, R. S., 1981, The post-Eocene stratigraphy of southern Collier County, Florida: unpubl. M. S. thesis, Florida State University, 120 p. Peck, D. M., Slater, D. H., Missimer, T. M., Wise, S. W., Jr., and O'Donnell, T. H., 1979, Strati- graphy and paleoecology of the Tamiami Forma- tion in Lee and Hendry counties, Florida: Gulf Coast Association of Geological Societies, v. 29, p. 328-341. Penrose, R. A. F., Jr., 1888, Nature and origin of the deposits of phosphate of lime: U. S. Geological Survey Bulletin 46, 143 p. Peterson, R. G., 1955, Origin of the land-pebble phosphate deposits of Florida determined from their clay mineral content (abs.): Geological Society of America Bulletin, v. 66, p. 1696. Pirkle, E. C., Jr., 1956a, Pebble phosphate of Alachua County, Florida: unpubl. Ph.D. dissertation, University of Cincinnati, 203 p. 1956b, The Hawthorne and Ala- chua formations of Alachua County, Florida: Florida Scientist, .v. 19, n. 4, .p. 197-240. 1957, Economic considerations of pebble phosphate deposits of Alachua County, Florida: Economic Geology, v. 52 p. 354-373. Pirkle, E. C., Yoho, W. H., and Allen, A. T., 1965, Hawthorne, Bone Valley and Citronelle sediments of Florida: Florida Scientist, v. 28, n. 1, p. 7-58. Yoho, W. H., and Webb, S. D., 1967, Sediments of the Bone Valley Phosphate District of Florida: Economic Geology, v. 67, p. 237- 261. i Poag, W., 1972, Planktonic foraminifera of the Chickasawhay Formation: U. S. Gulf Coast: Micropaleontology, v. 18, p. 257-277. Prasad, S., 1983, Microsucrosic dolomite from the Hawthorn Formation (Miocene) of Florida: Distribution and development: inAnnual Report 1983 Comparative Sedimentology Laboratory, Fisher Island, Rosenstiel School of Marine and Atmospheric Sciences: University of Miami, p. 58-65. 1985, Microsucrosic dolomite from the Hawthorn Formation (Miocene) of Florida: Distribution & Development: unpublished M.S. thesis, University of Miami, 124 p. Pressler, E. D., 1947, Geology and occurrence of oil in Florida: America Association of Petroleum Geologists Bulletin, v. 31, p. 1851- 1862. Puri, H. S., 1953, Contribution to the study of the Miocene of the Florida panhandle: Florida Geological Survey Bulletin 36, 345 p. Puri, H. S., and Vernon, R. 0., 1964, Summary of the geology of Florida: Florida Geological Survey, Special Publication n. 5 (revised), 312 p. Reik, B. A., 1980, The Tertiary stratigraphy of Clay County, Florida with emphasis on the Hawthorn Formation: unpubl. M. S. thesis, Florida State University, 169 p. S1982, Clay mineralogy of the Hawthorn Formation in northern and eastern Florida: in Miocene of the Southeastern United States, proceedings of the symposium: Scott, T. M., and Upchurch, S. B., (eds.) Florida Bureau of Geology, Special Publication n. 25, p. 247-250. Reynolds, W. R., 1962, The lithostratigraphy and clay mineralogy of the Tampa-Hawthorn sequence of peninsular Florida: unpubl. M. S. thesis, Florida State University, 126 p. Riggs, S. R., 1967, Phosphorite stratigraphy, sedi- mentation and petrology of the Noralyn Mine, Central Florida Phosphate District: unpubl. 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A., Knapp, M. S., Waltz, D. P., and Burns, W. S., 1982, Hydrogeologic reconnaissance of Lee County, Florida: South Florida Water. Management District Technical Publication 82-1, 192 p. plus Appendices and Maps. Williams, G. K., 1971, Geology and geochemistry of the sedimentary phosphate deposits of northern peninsular Florida: unpubl. Ph.D. dissertation, Florida State University, 124 p. Wilson, W. E., 1977, Ground water resources of DeSoto and Hardee counties, Florida: Florida Bureau of Geology, Report of Investigation n. 83, 102 p. Wolansky, R. M., Haeni, F. P., and Sylvester, R. E., 1983, Continuous seismic reflection survey defining shallow sedimentary layers in the Charlotte Harbor and Venice areas, southwest Florida: U. S. Geological Survey Water Resource Investigation 82-57, 77 p. Yon, J. W., Jr., 1953, The Hawthorn Formation (Miocene) between Chattahoochee and Ellaville, Florida: unpubl. M. S. thesis, Florida State University, 94 p. 1966, Geology of Jefferson County, Florida: Florida Geological Survey, Bulletin n. 48, 115 p. Zenger, D. H., and Dunham, J. B., 1980, Concepts and models of dolomitization an introduc- tion: in Zenger, D., Dunhan, J., and Ethington, J., (eds.), Concepts and models of dolomitiza- tion: Society of Econonomic Paleontologists and Mineralogists, Special Publication n. 28, p. 1-10. |
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