|
![]() |
|
| UFDC Home |
myUFDC Home | Help | RSS
|
|

HIDE
| Frontispiece | |
| Title Page | |
| Front Matter | |
| Foreword | |
| Acknowledgement | |
| Table of Contents | |
| List of Illustrations | |
| Main | |
| Index |
CITATION
SEARCH
THUMBNAILS
PDF VIEWER
PAGE IMAGE
ZOOMABLE
|
|||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Full Citation | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
STANDARD VIEW
MARC VIEW
|
|||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Downloads | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Table of Contents | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
Frontispiece
Page ii Title Page Page iii Front Matter Page iv Page v Foreword Page vi Acknowledgement Page vii Table of Contents Page viii Page ix Page x List of Illustrations Page xi Page xii Page xiii Main Page 1 Page 2 Page 3 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16 Page 17 Page 18 Page 19 Page 20 Page 21 Page 22 Page 23 Page 24 Page 25 Page 26 Page 27 Page 28 Page 29 Page 30 Page 31 Page 32 Page 33 Page 34 Page 35 Page 36 Page 37 Page 38 Page 39 Page 40 Page 41 Page 42 Page 43 Page 44 Page 45 Page 46 Page 47 Page 48 Page 49 Page 50 Page 51 Page 52 Page 53 Page 54 Page 55 Page 56 Page 57 Page 58 Page 59 Page 60 Page 61 Page 62 Page 63 Page 64 Page 65 Page 66 Page 67 Page 68 Page 69 Page 70 Page 71 Page 72 Page 73 Page 74 Page 75 Page 76 Page 77 Page 78 Page 79 Page 80 Page 81 Page 82 Page 83 Page 84 Page 85 Page 86 Page 87 Page 88 Page 89 Page 90 Page 91 Page 92 Page 93 Page 94 Page 95 Page 96 Page 97 Page 98 Page 99 Page 100 Page 101 Page 102 Page 103 Page 104 Page 105 Page 106 Page 107 Page 108 Page 109 Page 110 Page 111 Page 112 Page 113 Page 114 Page 115 Page 116 Page 117 Page 118 Page 119 Page 120 Page 121 Page 122 Page 123 Page 124 Page 125 Page 126 Page 127 Page 128 Page 129 Page 130 Page 131 Page 132 Page 133 Page 134 Page 135 Page 136 Page 137 Page 138 Page 139 Page 140 Page 141 Page 142 Page 143 Page 144 Page 145 Page 146 Page 147 Page 148 Page 149 Page 150 Page 151 Page 152 Page 153 Page 154 Page 155 Page 156 Page 157 Page 158 Page 159 Page 160 Page 161 Page 162 Page 163 Page 164 Page 165 Page 166 Page 167 Page 168 Page 169 Page 170 Page 171 Page 172 Page 173 Page 174 Page 175 Page 176 Page 177 Page 178 Page 179 Page 180 Page 181 Page 182 Page 183 Page 184 Page 185 Page 186 Page 187 Page 188 Page 189 Page 190 Page 191 Page 192 Page 193 Page 194 Page 195 Page 196 Page 197 Page 198 Page 199 Page 200 Page 201 Page 202 Page 203 Page 204 Page 205 Page 206 Page 207 Page 208 Page 209 Page 210 Page 211 Page 212 Page 213 Page 214 Page 215 Page 216 Page 217 Page 218 Page 219 Page 220 Page 221 Page 222 Page 223 Page 224 Page 225 Page 226 Page 227 Page 228 Page 229 Page 230 Page 231 Page 232 Page 233 Page 234 Page 235 Page 236 Page 237 Page 238 Page 239 Page 240 Index Page 241 Page 242 Page 243 Page 244 Page 245 Page 246 Page 247 |
|||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Full Text | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
BULLETIN THIRTY-FRONTISPIECE (Courtesy Miami Herald) Fire in the Everglades burning peat, April 1944. Such fires occur frequently during the dry season and destroy some of the dry, surface peat. If the Everglades were more generously flooded such fires could be reduced and the peat saved. FiLORIDA GEOLOGICAL SURVEY STATE OF FLORIDA DEPARTMENT OF CONSERVATION J. T. HURST, Supervisor of Conservation Florida Geological Survey HERMAN GUNTER, Director, Geological Survey GEOLOGICAL BULLETIN NO. 30 THE PEAT DEPOSITS OF FLORIDA Their Occurrence, Development, and Uses By JOHN H. DAVIS, JR., Ph.D Research Assistant Florida Geological Survey Published for THE FLORIDA GEOLOGICAL SURVEY Tallahassee, 1946 Published December 1, 1946 THE E. O. PAINTER PRINTING COMPANY DELAND. FLORIDA LETTER OF TRANSMITTAL Honorable J. T. Hurst, Supervisor Florida State Board of Conservation Sir: I have the honor to transmit a report of one of our investigations entitled "THE PEAT DEPOSITS OF FLORIDA, their occurrence, de- velopment, and uses" by Dr. John H. Davis, Jr., Research Assistant, Florida Geological Survey, and recommend that it be published as Geo- logical Bulletin No. 30. This bulletin describes and discusses most of the larger peat deposits of Florida and many of the smaller deposits, and estimates are given of the area and depth of many of these. From prospecting data the quantity in tons of peat in many deposits is given. The nature, origin, kinds, and composition of peats are described. Many analyses of Florida peats are presented. The geology of both surface and buried peats is described, and some possible correlations of peat and lignite layers with glacial and interglacial ages are considered. The present and possible future ways of utilizing Florida's large peat resources are considered in detail. Some experiments to determine the practicality of using peat for fuel, and in making plastics were conducted, and even though these did not give favorable results they show what difficulties must be overcome if large scale utilization of peat is attempted in the future. The present use of peat is mainly for soil improvement, as a humus, and as a fertilizer filler. Production of this horticultural peat in Florida is increasing and the industry may be further expanded as the good quality of some Florida peats become better advertised. Respectfully submitted, Herman Gunter, Director Florida Geological Survey Tallahassee, Florida July 16, 1946 FOREWORD The Florida Geological Survey has received many inquiries concerning the location, quantity, quality, and uses of peat that occurs in numerous deposits in the State because Florida is known to have the third largest amount of peat in the United States. Some of the larger of these deposits have been drained and the peat and muck soils used for agriculture, particularly in the Everglades. Such peat lands are a great agricultural resource and their use will be expanded and more nearly perfected by those persons and public agencies interested in agriculture, particularly winter vegetables, sugar cane, and cattle. Another use of peat is as a material in horticulture, flori- culture, fertilizers, as fuel, and for some industrial purposes. Thus used peat is mined and handled similar to minerals and coal and its occurrence, processing, and use are of import- ance to this Geological Survey and the United States Bureau of Mines. To learn more about these an investigation of the peat resources of Florida was undertaken and this paper prepared to give the extent and quantity of the peat deposits, the nature, kinds, and composition of peat, some of the geologic significance of the peat deposits, and the uses of peat. J. H. D., 1946 Florida Geological Survey Tallahassee, Florida. VI ACKNOWLEDGEMENTS The United States Bureau of Mines and the University of Florida's Engineering and Industrial Experiment Station were the main organizations cooperating with the Florida Geological Survey in this investigation. The former con- ducted most of the analyses of samples of peat from various deposits and aided in the test of using peat as a fuel. Mr. R. C. Specht of the Engineering and Industrial Experiment Sta- tion carried out experiments to test the use of peat in making plastics, and tested some of its distillation products. The results of this research indicate some possible industrial uses of peat. Most of the peat producers and many interested persons have kindly assisted the writer in numerous ways. Dr. Herman Gunter and other members of the staff of the Florida Geological Survey aided in the field and laboratory work, and in the preparation of the manuscript. VII CONTENTS Page Foreword ......................................................................................... V Acknowledgem ents .................................................................................. VI Introduction ............................................................................. .. ................... 1 Brief Preliminary Outline ................................................................. 2 Some processes and products of peat utilization .................. 4 Best present use .................. ................... 5 Ultimate large scale utilization .............................................. 6 Scientific interest of peat ........................................................ 6 Brief History of Utilization and Interest in Peat in Florida ...... 7 Peat for humus and fertilizer .................................................... 10 Sum m ary ................................................................ .................. 11 World Uses of Peat ............................................... ........................... 13 PART I. NATURE, ORIGIN, KINDS, AND COMPOSITION OF PEATS IN GENERAL ............................................................................... 15 Nature and Origin .......................... ................... 15 Vegetation, prelim inary ............................................................ 16 Environmental conditions ............................................................... 17 Peat stratification and plant succession ................... 19 Sedimentary peats of lakes and lake development ........... 22 Lake develop ent .............................................................. 23 Lake deposits .................................................................... 24 Kinds of Peats and their Classification ......................................... 25 A general scientific classification of peats .............................. 26 M uck and hum us ................................. .................................... 28 Diatomaceous earths or mucks ............................................... 29 Types of peat m material ................................................................ 30 Sedimentary, plastic, and pulpy peat .............................. 31 Fibrous peat ....................................................................... 31 W oody peat ....................................................... ................. 33 Kinds of peats based on utilization .......................................... 33 Peat soils ................................................................................. 34 Florida peats, preliminary ............ ................. 36 Characteristics and Composition of Peats .................................... 36 Physical-mechanical and colloidal characteristics ........... 38 Water content and absorbing capacity .................................. 41 Uses based on water-holding capacity .................................. 45 Drying characteristics ........................................................... 46 Weight, density, and specific gravity .................... 50 Volume and weight estimates .................................................. 51 Atmospheric and gas content .......................... 53 Color ........................................................................ .................... 54 Tem perature relations ................................................................ 54 Reaction or Hydrogen-ion concentration (pH) .................... 55 Summary of pH conditions of Florida peats .................. 57 Heat values .................................. ...... ..................... 60 Chemical Composition .......... .......................... 61 Inorganic constituents ............................................................ 62 Inorganic analyses .................................. ..................-... 64 Organic constituents ......................................... ...............---- 68 N itrogen .............................................. ......... .............. 70 Organic analyses ...... ......... .................. 71 Rate of Peat Form ation .................................................................... 72 M icrobiological N ature .................................................................. 75 PART II. FLORIDA PEATS AND PEAT DEPOSITS .................... 78 Methods of sampling, tests, and analyses of peats ........................ 78 Kinds of peats, and some mucks ...................................................... 81 Buried peats, preliminary ............................................................. 86 Vegetation of peat areas ...................................... ......................... 86 vTiii CONTENTS- (Continued) Page Vegetation of peat areas (continued) Marsh vegetation ............................---------------- ----------------..... 87 Saw-grass marshes .....................------------------------------ 88 Rush marshes and wet prairies .............................--------------------89 Flag pond m arshes ............................................................. 90 Salt-m arshes .......................................................................... 91 Other m arsh plants ............................................................. 92 Bog-like marshes ..............---------- ----------------------..-- 92 Swamp Forests ..........................----------- ---- ----------------. 93 Bay-tree swamps ...................------------------------- ----- 93 Other swamps .......................------------------------------ 94 Mangrove swamps .............................----------- ------------------ 95 Plants of open water habitats ..................------------------------ 96 Harper's descriptions ....................-------------------------------- 97 Analyses of Florida Peats .................................................................. 98 Use of tables ..---------------........................------------------------99 Harper's analyses of samples ....-----------............ ---------------111 Occurrence and Description of Deposits ...................--...........---.-------........ 114 Regions and Areas, Quantity ....................----------- --------------115 The Everglades region ............--------------------------.-. 117 The Lake Istokpoga area ................................................. 129 The Kissimmee River Valley ............................................ 132 The Upper St. Johns River Valley, and Fellsmere Drainage District ................------------------------------- 133 The Peace Creek Drainage District and other deposits of Polk County ...................................................................... 135 The Lake Apopka marsh ........................-------------------------. 138 Lake County deposits ...................--------------------------- 140 The Clerm ont m arsh .................................................. 141 Other deposits, Lake County ............------..------------ 141 Putnam County deposits ...............------------------------ 142 Other Peninsular Florida deposits ..................-----------.............-----.--.. 143 Northwestern Florida deposits .............--------------------.. 146 Summary .......................--------------------------- ---------- 147 Deposits of Lakes and other bodies of water ................................ 147 Diatomaceous Deposits and their Use .....................----........---------........----. 152 Occurrence and tests ..---.....--...-- ------- --------- 153 M ining and processing ................................................................ 159 Diatoms and their significance .................................................. 161 Marls associated with peat deposits ....................----.....----------------.......-..... 162 PART III. GEOLOGY OF PEAT DEPOSITS, AND SOME OF THE BURIED DERIVATIVES OF PEAT ........................------------------............. 165 Surface D eposits ............................................................... ................... 165 Effects of sea level changes of the Quaternary ....................166 Relations to sea level changes ......................------.....-----....--.....-..--------..-. 167 Postglacial and Recent coastal changes ................-......... -------------172 Pleistocene and Recent chronology ..........................................173 Sink areas ...................................................................................... 174 Recent filling of basins by peat formation .............................. 175 Significance of lake peats ......................................................... 176 Reversed deposits in lakes ............------------------------- 177 Regional rise in w ater ................................................................ 180 Evidences of sea level changes ..................-------------------.. 180 Evidences of water rise inland .......................................... 181 Reduced underground drainage ........................................181 Buried Peats and Derivatives of Peat ..............................................182 Buried Quaternary peats ............................................................ 183 Peat derivatives in Tertiary formations ............----------------- 189 Peat Deposits and Past Climates .................................................... 193 Pollen analyses ...........................................-- ... .... ............ 195 IX CONTENTS- (Continued) Page PART IV. UTILIZATION OF FLORIDA PEATS ............................ 198 P ast P reduction .................................................................................... 200 Recent and Present Production ........-...................---------------........--------..........-....-. 202 Methods of Excavation and Preparation ..................-------........-....-....-. 207 Excavating method ............................................------------------------------............---...-. 208 Cultivating method .................................................---------------------------------................. 212 Some elaborate methods of processing ................-------......---....--...... 213 Shipping and sales ..............................----------------------......................-.......... ----------214 Methods of Use for Soils and Plant Growth ..-----------------............................ 214 Fertilizers made from peat .....................................------------------------.......----..--........ 217 Possible Utilization and Tests ...................................--------------------.........-........--. 218 Peat for heat and power ......................................-------------------------.............-..-. 221 Test of preparation for use as a solid fuel ..............-........--------........ 224 Charcoal .............................................................---------------------------------------................. 227 Peat gas for fuel and power ............................-------------..--------........--...... 227 By-products .........................................---------------------------.........-....---.-----.. 230 Carbonization and by-products .........--------.....-....-------................-----. 230 Tests of Florida peats ..................................-------------------......------.......-....---....--. 232 Summary and significance of tests ..................................------ 234 Montan wax ....................----------------------...................................--------..................-------- 236 Use in making plastics ...--..-............--------------................----------.........-.......----. 236 Methods and results of tests ....................-----...........--....-----------.. 237 Difficulties encountered .......................--------------------................---. 239 INDEX .......................................................... ............................--------------------------------------------------................. 241 X ILLUSTRATIONS Frontispiece-Fire in the Everglades burning peat, April 1944. Such fires occur frequently during the dry season and destroy some of the dry, surface peat. If the Everglades were more generously flooded such fires could be reduced and the peat saved. Figures Page 1 Map of Florida showing peat deposits ..............................opposite 2 2 Seasonal rains flood many marshes where peat occurs. Here the Istokpoga marsh near Brighton is deeply flooded during September, 1945 .........................--------------------- ----.....-----------. 18 3 Profile of peat deposit and underlying sediments from a tree island in the Everglades showing peat stratification. These layers developed in a sequence due to the water conditions and kind of vegetation which slowly changed as peat filled in the basin ....................-......................................................------------------------------------....................--------.---. 20 4 Profile section across Mud Lake, Marion County, showing the deep deposit of this lake, with sedimentary, sapropel peat over fibrous, lowmoor, saw-grass peat. After E. C. Roe .................... 24 5 Peat forms soils, called muck, after cultivation, and large areas in the Everglades produce fine crops. Here at Canal Point are sugar cane fields .............................-----.......-----------------......................... ----------28 6 Recently excavated, fibrous saw-grass peat, and machete used to cut samples. Note most fibers are vertical and coarse in this peat ....................-----------------------------........----...------------32 7 Volume sample of peat (left) taken by use of brass cylinder (right). Such volume samples were used as the basis for calculating quantity of peat in the deposits .................................. ------------------47 8 Showing shrinkage of peat. Sample of Loxahatchee peat on left was size of brass cylinder before drying and shrinking........ 47 9 Hiler peat auger which was used to take most samples below the w ater table ...................................................................................... 79 10 Saw-grass vegetation of the central Everglades. The saw-grass forms a dense cover over the marsh and fibrous peat is de- veloped from its undergrowth parts and debris is formed when parts above ground die .......................-------............----------..-..............--------------......--.....-. 88 11 Peat develops in mangrove swamps which are flooded by the tide. In this red mangrove, Rhizophora mangle, swamp on Key Largo the raw fibrous peat is 4 feet thick ............................ 95 12 Aquatic plants of many kinds form sedimentary and some fibrous peat. Here the air boat floats on 1 foot of water over a deep, 10 feet, deposit of Loxahatchee peat ...................................... --------------------96 13 Isopach map of the Everglades region showing thickness of peat and some muck areas .....................-..........----------....---..---..-..................... -----------122 14 Profile across the Everglades showing layers of peat and some marl, rock, and sand sediments .............................................. ..... 123 15 Pit showing profile of sediments and peat in the Everglades near the northern part of the Hillsborough Canal. A. Saw- grass peat, 4 feet thick. B. Lake Flirt marl, 20 inches thick. C. Fort Thompson formation limestone ..... .................................... 125 16 Isopach map of the Lake Istokpoga marsh and swamp area showing thickness of Brighton peat formed in marshes, and area of Istokpoga peat and muck of swamps and bay-gall forests ............... ................................................................................. 130 17 Inspecting and sampling peat along canal bank in the Istok- poga m arshes ........................................................................................ 131 18 Map of a part of the Peace Creek Drainage District, Polk County, showing marsh and prairie areas that have some peat and some diatomaceous muck, and a few bay-tree swamp areas w ith peat .... .........-........................................... ..... ..................... 13 XI ILLUSTRATIONS-(Continued) Figures Page 19 Peat area of the Lake Apopka marshes and some peat areas of Lake County .............................................---------------------------............................................. 139 20 Excavating peat at Florahome with a long-handled spade. The blocks thus dug are piled loosely and dry quickly. This hand labor method has now been replaced by a dragline as demand has made increased production profitable .........-...-....................--------------...... 143 21 Sedimentary peat, sapropel, in dipper at Mud Lake, showing the soupy consistency. Courtesy of E. C. Roe .............................. 149 22 Diatom shells, frustules, of a few species from a deposit 15 miles south of Clermont, Lake County. Note typical markings on the shells, 1. Surirella oblonga Ehrenberg. X 929; 2, General view of diatomite material showing a number of species, X 100; Pinnularia major (Kiitzing). X 488; Pinnu- laria gibba Ehrenberg. X 592 (from McLeon Basin, Santa Rosa County; (5) Pinnularia virides (Nitzsch). X 1200 ........................ 158 23 Tamiami canal bank in the Everglades, showing a layer of marl interbedded in the peat. Photo by Robert B. Campbell .... 163 24 Mangrove peat uncovered by a hurricane which washed away the beach sand that covered the peat, at Naples beach .............. 173 25 Geological cross-section at Silver Springs Lock Site showing series of core holes with layers of buried peat .............................. 185 26 Geological cross-section at the Eureka Dam Site showing series of core holes with layers of buried peat .......................................... 188 27 This sign shows that deposits of peat being excavated are considered mines .............................................................------------------------------------..................... 198 28 Concrete drying area and peat processing plant of the Florida Humus Company, Zellwood, Orange County, in July 1932. Elaborate methods of drying and processing the peat were used at this plant .................................................................................. ---------------------------------201 29 Partly excavated peat deposit of Daetwyler Nurseries near Pinecastle showing peat excavator and board runway for trucks. From about 20 acres of this deposit approximately 350,000 cubic yards of wet peat have been obtained. Excavating 9 feet deep usually produces about 15,000 loosely piled cubic yards per acre ..-................--...........................--------------------.....------.........---..-............. 205 30 Pulverized Florahome peat in bags loaded on tram car for m ovem ent to shed or truck ..................................... ........................... 206 31 Bank of fibrous pond-prairie peat in deposit of the Florida Nursery and Landscape Company, at Leesburg. This peat rests directly on sand. Water is removed from deposit by pumping, and most of the excavating was by hand labor .......... 207 32 Peat excavator, constructed by M. J. Daetwyler, loading truck on deposit near Pinecastle, Orange County. This excavator digs about a cubic yard per minute .................................................. 209 33 Peat and muck pulverizer used by J. C. Canfield near Fort Lauderdale. D.D.T. is added to the peat in this operation, which insecticide seems to reduce insects on lawns to which this prepared peat is added ....................................... ....... ............. 211 34 Peat shredder in operation, shredding a cubic yard per minute at Daetwyler Nursery ..................................................--------------------------------..................... 211 35 Excavating peat with a dragline near a road in the Everglades. With water two feet below the surface the dump trucks could back onto the peat marsh without much difficulty ........................ 225 36 Everglades peat piled to dry in the open. Thus piled it lost moisture in spite of heavy rains but failed to become, dry enough for use as a fuel ................................................... ............. 225 XII Tables Page 1 Field water-content of some Florida peats ...................---------........-..... ---------43 2 Specific gravity of some Florida peats .......................-------------..--...........--.. 51 3 Reaction (pH values) of some Florida peats .......................--------......... 58 4 Partial analyses of some peat and muck soils in Florida, from R. E. Rose ............--- ---.---------.--. -------------63 5 Chemical composition of some Florida peats ................................ 66 6 Ratio of carbon to nitrogen, and total nitrogen, moisture free basis .........-------------------------------------------------- 70 7 Organic composition of the saw-grass plant and saw-grass peat 71 8 Condensed analyses of organic composition of Mud Lake peats.. 72 9 Occurrence of microorganisms in a lowmoor peat profile .......... 76 10 Outline of kinds of Florida peats and mucks ..............-----------..........--........ ----81 11 United States Bureau of Mines, Coal-Analysis Report.......-.......-- 98 12 County list of Florida peat analyses by United States Bureau of Mines ..---....--.....---.------------------------ 101 13 Location of places where samples were taken for analyses given in table 12 ...----- --------------------- ------------108 14 Proportions of some chemical constituents and moisture of peat of important Florida deposits ...........--..............----------------...................... -------109 15 Analyses of Florida peat for Harper by United States Geo- logical Survey --.........-------------------------- -------------- 112 16 Approximate quantity of peat in the Everglades .---........-.........--........ 115 17 Approximate quantity of peat in most Florida deposits outside the Everglades ..-----------------------------------------116 18 Quantity, ash, and B. t. u. values of peat of the Istokpoga marshes .----------------------------------------------132 19 Location of some diatomaceous deposits in Florida ....................----- 154 20 Tests of diatomaceous material, weights and per cent of diatomite --........................------ ......... ................---------------... 156 21 Characteristics of Florida diatomite ................................------------..............-. 157 22 List of some Florida wells having carbonaceous material .---........ 192 23 Florida peat production by periods from 1917 to 1941, and main producers .-----------------------..------------------ 202 24 Florida peat production 1941 to June 1946, and main producers .----------------------------------------------204 25 Uses of peat lands and peat material ............................................------------ 219 26 Results obtained from the dry distillation of Florahome and Everglades peats ---.................................. ------.................................----------- 233 27 Summary of averages of results of dry distillation ...................-----. 234 XIII THE PEAT DEPOSITS OF FLORIDA Their Occurrence, Development, and Uses JOHN H. DAVIS, JR. INTRODUCTION For a number of reasons the large and small deposits of peat in Florida have been neglected except as regards their agricultural development as soils for crops, some pasturage, and in a few places their use for horticultural peat material. The Florida deposits are the third most extensive in the United States and the Everglades region probably contains more peat than any other similar size area. Harper' made a preliminary report about these peat de- posits but it has been nearly forty years since his investiga- tion was made and some conditions of the deposits have changed. Moreover, no over-all, nearly complete survey of the many deposits had been made and such an investigation was needed to get a comprehensive view of the peat resources of the State. The large and many of the small peat deposits were studied to learn the various kinds of peat, depth and character of the deposits, and to get estimates of quantity and weight of the peat in these deposits. The utilization of peat as a material was particularly considered because very few uses have been made of it to date. Some experiments to determine whether or not Everglades peat, and other peats of large deposits, could be economically used for fuel for generating heat and power, or for making plastics, were undertaken. The present uses for soil con- ditioning, as a humus, and as a fertilizer filler were investi- gated to see if new or improved methods for handling the peat could be devised. To correlate the peat deposits and some buried peats, or peat derivatives, with numerous, known geologic conditions an investigation of the geologic significance of some peats was undertaken. 1Harper, R. M., Preliminary report on the peat deposits of Florida. Florida Geol. Survey 3d Ann. Rept., pp. 197-375, 1910. 2 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY The following report of this peat investigation is for con- venience presented in four main parts so as to clearly deal with the different conditions, kinds, and significance of the peat deposits of Florida as pointed out above. The four are: Part I. Nature, Origin, Kinds, and Composition of Peats in General; Part II. Florida Peats and Peat Deposits; Part III. Geology of the Peat Deposits; and Part IV. Utilization of Peat. To set the stage for these descriptions and discussions a Brief Preliminary Outline, stressing the utilization and scien- tific interests of peat, is presented, followed by a Brief History of the Utilization and Interest in Peat in Florida, and a short outline of World Uses of Peat. BRIEF PRELIMINARY OUTLINE Distribution and Quantity: In Florida peat occurs in the Everglades region, the Lake Istokpoga marshes, the upper St. Johns River marshes, Fellsmere Drainage District areas, the Oklawaha River valley, the Lake Apopka marsh, many Lake County marshes, the Florahome wet prairie area, the Peace Creek Drainage District area, and many scattered smaller marsh or swamp areas in many counties. This survey esti- mated that there are in Florida peat areas totaling about 3,500 square miles and containing over 1,750,000,000 tons of peat on an air dry basis. In the United States, occurring principally in Minnesota, Wisconsin, Florida, Michigan, Maine, New Jersey, New York, and a few other states, there are about 11,000 square miles of peat deposits and over 12,000,000,000 air dry tons of peat. The Florida deposits are shallower than most and contain less peat per square mile. Values: As agricultural lands there are many peat soil areas in Florida which are very productive of winter vegeta- bles, sugar cane, and other crops and these are usually more valuable for their soils than for excavated peat. Such lands when improved are valued at from $50 to $500 an acre of which there are over $50,000,000 worth in Florida. In general, excavated, partly dried, and processed peats have had in some states an average value of about $3 to $5 per ton. Florida's non-agricultural peat deposits covering some 1,500,000 acres if valued at only $1 per ton represent a potential value of over + A S EN I .c R T1r --bETY VERG \i r W AKt"^1_ ^ ^tcs ~. v FR X ^-^r EVERGL 0 ^e\^ 0nl" D E F + 13OF ," .AD L_ ^V~dl e mvI ~oiij %-umrluzo A Muck and Pe( B Loxahatchee C Loxahatchee COASTAL MANC SALT-MARSH PI CORKSCREW MA VAN SWEARING G I STOKPOGA MA H UPPER ST JOHN FELLSMERE I PEACE CREEK [ DISTRICT ARE J CLERMONT MAF K LAKE APOPKA L OKLAWAHA RIV M ORANGE LAKE N 0 4' FLORAHOME A SAMPLES TAKI PEAT AREAS STATE OF FLORI] -2 w2 a m Seats S--- tate Boundary Lines *Stat Capita ---- County Boundary Lines *County Seat -- Lar, Rivers & Canalso LarwprCiti UNIVERSITY OF FLORIDA AGRICULTURAL EXPERIMENT STATION DEPARTMENT OF CHEMISTRY & SOILS Bale Map prepared January 1938 from Map of the Department of Interior US. G*ological Survey, dated 1932 l___ _me a D A A SHOWING c-7T-TTr KEHS-0 PEAT 4l &Bell, ______ *... 30-29 32 2 3 3 1-1 SS *, 0 +.*~ya LNJ I 42 We t F 'aim 814I + GUL~rZF OF MEXI .ZCO0 4 - I Mir ! + + 0 R 6 I A 0 1 -r v _^ __MaD^ ^ _^ ^ N 1^ ^^AI ->IL T O.? ^ 1 "^ LA! giN.. : ^ ^ ^ .^ + -Peat- MW .. P .at 1- 3 -? v l- L3o v Cty LRwVE & EATSA ARSH o + i N S L O U G HI ST A|L A C U RSH & SWAMP x IS RIVER i AREA k _.pN - )RAINAGE tA 1- RSH ^^"^""]^^^^ ""1 MARSH i ER AREA SREA R EN AND SMALLER SI ASHAo 8i SWAMP-S T ) L^ E- y \i I1 Lr7 -I- - kE .st r -- aw- i THE PEAT DEPOSITS OF FLORIDA $1,500,000,000. The total value of peat and peat lands in the United States has been estimated at about $38,000,000,000; which is no mean resource. Utilization: That this great natural resource should be more extensively utilized is obvious. Uses other than agri- cultural need to be developed and expanded. At present some Florida peats are used on a small scale for horticulture, soil conditioning and with fertilizers. In the United States the greatest quantity of domestic peat used was 107,261 tons in 1918 when some of it was used for fuel. In 1942 only 71,500 tons of domestic peat was produced and 49,232 tons of peat moss was imported, whereas in Europe during this year probably 35,000,000 tons of peat were produced. Some countries and totals used during 1941 are; Russia over 30,- 000,000 tons, about 6,000,000 tons in Denmark, and 7,000,000 tons in Ireland, to cite a few of the largest users. During 1911 successful commercial operations of a large electric power station in Germany which used only peat for fuel was estab- lished near Osnabruk producing 428,870 kilowatt hours of electric current a month. Since then larger plants than this one have been put in operation in Russia and in other countries where transportation of coal and petroleum are difficult. Recently, 1946, power plants using peat for fuel are being built in Ireland on a large scale. The present uses of peat in the United States are best summarized by the sales reports of the United States Bureau of Mines, most of which are given in the Minerals Yearbook, for four recent years. Litter Production Soil Mixed for Barns, Year (Short Tons) Improvement Fertilizers Poultry, Etc. 1940 70,097 93% 2% 5% 1941 86,503 75% 20% 5% 1942 71,500 61% 30% 9% 1943 60,002 66% 27% 7% The most profitable but not all the possible uses and products of peat are briefly outlined below to give some idea of the many methods of utilization. Each of these uses will be considered in more detail in Part IV. 3 4 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY SOME PROCESSES AND PRODUCTS OF PEAT UTILIZATION 1. Peat for humus, soil improvement, and fertilizer filler. Excavated, partly dried by air, and usually shredded or pulver- ized. This is the principal use of peat in Florida, of which an average of about 7,000 tons valued at nearly $25,000 have been produced yearly since 1917, mostly in small operations. During 1945 nearly 30,000 tons worth about $150,000 was produced in Florida. 2. Machine peat. Dug by hand labor or diggers of the chain bucket type or power shovels and draglines, macerated in a pug mill similar to those used in grinding clay for brick and then forced through an orifice and cut into bricks and air dried. Two tons of this machined peat usually equal one ton of good soft coal in heat value, British thermal units or calories. 3. Powdered peat for fuel. Dug by a number of means or plowed and harrowed on the bog or marsh, then air dried and collected as it is, or pulverized to a dust or powder. In this form peat has been used as a fuel under boilers by employing various stokers. 4. Peat briquets. Peat dried to about 15 per cent mois- ture is pulverized and then mechanically molded in a press into briquets. This process involves capital and skill but yields a product that is easy to ship and stands weathering. It is a clean, easily handled, domestic fuel. 5. Dry distillation and carbonization. The main products yielded are: (1) coke, useful in refinishing metals, hardening of steel, purifying water, making gunpowder; the quality is good and B. t. u. value about 12,000 units per pound; (2) gas, 8,000 to 10,000 cubic feet per ton, having 300 to 400 B. t. u. per cubic foot can be produced, the gas is useful for illumination being burned in mantles, and it is a serviceable furnace fuel, or for power in gas engine; (3) tar, upon distillation yielding light and heavy oils, paraffin wax, creosote and resin com- pounds, and pitch; and (4) tar water, from which methyl alcohol, acetic acid, and ammonia can be derived, but the ammonia is less in quantity than that derived from the pro- ducer gas process. 6. Producer gas. Peat is excellent for this purpose the gas derived from this process being approximately the same THE PEAT DEPOSITS OF FLORIDA as that from coal, and the volume is large. More power can be developed from a ton of peat converted into producer gas and used in a gas engine than is usually developed from a ton of soft coal used under a boiler to generate steam. Furthermore, it is frequently not necessary to remove so large a percentage of moisture from peat when used in this way as compared to using it as powdered peat or machined peat. By-products from this process are mainly tars and ammonia compounds. The Mond process used extensively in England is notable be- cause this process produces large quantities of ammonium sulphate. Other processes recently developed may prove even better for obtaining ammonium sulphate which is a valuable product for agriculture. Utilization of peat for power gas is one of the most promising of its uses. The development of uses under 3, 5, and 6 are in the nature of large investments and complex industries and large reserves of peat, assured markets, and development of efficient methods will be necessary to make these processes profitable. Many other products such as millboard materials, insula- tion materials, and perhaps plastics may be developed from peat, and some of these products would also support new industries if they could be efficiently developed. 7. Material for plastics. Some kinds of peat have been used recently in mixtures with resinous plastics and pressed and heated to form a good product. BEST PRESENT USE Peat used in landscaping and horticulture for plant nurse- ries, lawns, and ornamental shrub plantings has at present the greatest sale which will probably increase because of the great increase in construction of homes. Florida peat, par- ticularly the acid pond-prairie peat, is proving to be in in- creasing demand since the close of World War II. Production in 1946 will probably exceed that produced in 1943 and 1944 combined, or for any previous year. Nurserymen and other large users are recognizing the good quality of shredded Florida peat and orders for it are exceeding rate of production at the present time. It is possible that with more advertising, better methods of excavating and processing, and a lower price the demand for 5 6 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY horticultural peat will continue particularly in the southeast- ern United States. This industry may, therefore, expand. But even if expanded to 150,000 tons per year it will be small com- pared to the possible production that can be obtained from the numerous Florida deposits if other uses of peat could be made profitable. ULTIMATE LARGE SCALE UTILIZATION Final development of large scale mining and uses of peat will depend upon: (1) the application of engineering skills to adapt processes now measurably successful abroad to the con- ditions of the United States, and Florida in particular; (2) a careful study of the market to ascertain which of the products should be in demand in various sections of the country. Florida needs more and cheaper power and fuel, fertilizer materials, and construction materials such as millboards, in- sulation materials, and plastics. Some products of peat useful in small industries might be profitably developed even though some large scale industries might prove impractical. With the results of this survey of peat resources giving analyses, estimates of quantity and quality, and characteris- tics of peat material some methods of utilization and expan- sion of the uses of Florida's peat deposits may be developed. Final promotion of large scale utilization will depend upon the initiative of private industries which can take advantage of the facts given here and develop the industrial and economic aspects of peat utilization. The chief difficulty to overcome is the removal of water from the peat in a manner that is not costly or too time con- suming. Until good methods for doing this are developed the use of peat material will remain a hazardous financial venture. SCIENTIFIC INTEREST OF PEAT Peat is of great scientific interest and investigations con- cerning peat deposits, peat soils, and peat material are amply justified as additions to the sum total of knowledge about our natural features and potential resources, even if all this infor- mation cannot be directly applied to utilization. Geologists are interested in peat because the deposits, as part of the earth's crust, often reflect past conditions to topog- raphy and climate, and peat has played an important role in THE PEAT DEPOSITS OF FLORIDA the origin of coal. In Florida some of the peat deposits, par- ticularly those that are buried, are helpful in interpreting the correlation of geologic formations of the Quaternary. More- over, the mining engineers and bureaus of mines are inter- ested in peat because it can be handled as a mined product. Part III considers some of the geologic and climatic signifi- cance of peat. Botanists, plant ecologists particularly, are interested in the plants forming peat deposits, the changes in the kinds of plants with the development of these deposits, and the topo- graphic, water, climatic, and other environmental relations that affect peat formation in marshes, bogs, swamps, and lakes. The chemists and physicists are attempting to unravel the complex nature of the peat material and soils derived from peat. Although most of their work has been connected with inorganic constituents, water conditions, and the soil reaction (pH), particularly as these apply to agriculture, recently some of them are beginning to investigate the complex or- ganic substances. Industrial chemists and engineers are con- sidering the fuel values, gas, and by-products of distillation that can be obtained from peat. Agriculturists are well informed about the nature and management of peat soils and have made thorough investiga- tions of peat lands. Because all of these fields of science are contributing to the knowledge of peat an extensive literature has developed on the subject and it is difficult for one investigator to compre- hend the many aspects of peat and its utilization. For this reason the following treatment of peat does not pretend to be exhaustive. BRIEF HISTORY OF UTILIZATION AND INTEREST IN PEAT IN FLORIDA The many areas of peat and muck widely distributed in Florida, particularly in the peninsula, led to an early develop- ment of these lands for agricultural purposes because when such lands were drained they often produce fine crops. Some small areas of muck and peat were drained before 1900 but most of the organized large drainage projects were begun 8 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY during this century, and some of the finest crop areas are now on formerly flooded peat or muck lands. This agricultural development was, and will probably re- main, the most important use of our peat and muck lands. But there have been other uses of peat and these uses may be more widely developed. The history' of attempts to develop these other, non-agricultural uses of peat is well illustrated by the following description.2, 3 "In September, 1905, the Orlando Water and Light Company, of Orlando, Fla., completed the installation of a plant for the treatment and briquetting of peat, which occurs abundantly in the low-lying lands of Florida. The plant is located about 3 miles from Orlando, on the border of a peat bog from which its supply is drawn. As originally installed, this plant consisted of a macerating machine or pug mill, in which the fiber of the peat is entirely destroyed, and a brick press. The briquettes as they came from the press were about the size of an ordi- nary building brick, but when dried in the sun shrunk to about one-fourth their former bulk and lost from 75 to 85 per cent in weight. The briquetting feature of the plant was abandoned in the summer of 1906, as it was found that this part of the work represented 75 per cent of the total cost, and that a satisfactory fuel could be made without briquetting. The method of treatment at the present consists simply of "machining" the peat in the pug mill and dumping it in masses of several hundred tons. As the peat dries it shrinks and cracks into large, irregularly rectangular blocks, which a1re broken off from the heap and stored. When thoroughly dried, these blocks make a good hard fuel, which it is stated may be used for both locomotive and stationary boilers, for household purposes, and for the manufacture of gas. Tests of the machined peat for producer gas at the Geological Survey fuel- testing plant gave excellent results. "The machine used at the Orlando plant was built by the Moore and Wyman Elevator and Machine Works, South Boston, Mass., under patents issued to the late T. H. Leavitt, of Boston. "The work of the Orlando Water and Light Company, of Orlando, Fla., may perhaps be considered typical. There is a popular impression that peat bogs are largely if not wholly confined to northern countries, but this is not correct, since Florida has some of the finest deposits in this country. The Orlando Company is working on a deposit filling a small lake basin. The company has installed a Leavitt machine with a belt conveyor for transporting the peat to the mill, where it is disinte- grated and molded into bricks without pressure. The bricks are tien laid out, and in the hot Florida sun soon lose a large percentage of their moisture. As the peat comes from the bog it carries about 85 per cent of water, but in' a few days after the bricks have been manufac- tured this is reduced to 30 per cent and finally to about 15 per cent without artificial drying. When the bricks have reached this stage they have shrunk to about one-half their original dimensions, and then they 2 Excerpt from Bulletin No. 316, Department .of the Interior, United States Geological Survey, George Otis Smith, Director; Contributions to Economic Geology, 1906, Part II-Coal, Lignite, and Peat, Marius R. Campbell, Geologist in Charge, Washington, Government Printing Office, 1906. 3 Campbell, M. R., Peat: Mineral Resources U. S., 1905.. pp. 1319-20, 1 9 0 6 ... ..... . THE PEAT DEPOSITS OF FLORIDA may be stacked out in the weather without reabsorbing an appreciable amount of water. "The business is hampered by the excessive rains which prevail in Florida during the wet season from June to November, and some means of artificial drying or protection must be resorted to before the work can be kept in continuous operation. "Although the plant has not passed the experimental stage, several hundred tons of the machine peat have been produced and used under the boilers of the electric light plant. It is confidently believed by the owners that peat fuel produced in this way can successfully stand in competition with hard-pine wood at $3 per cord and Alabama coal at $7 per ton." But according to the May 1924 issue of "Sunshine, Flor- ida's Magazine" the first use of peat for fuel was by Mr. J. M. Cheney in his power and light plant at Orlando in 1907. How- ever, both these references probably are about the same plant even though the dates given are different. Cheney was owner of the Orlando Water and Light Company. In this same article a sketch of the activities of the most enthusiastic exponent of various uses of Florida's peat is given. This person was Mr. Robert Ranson, a Civil Engineer, from Ipswich, England, who soon after coming to Florida in 1884 began experiments and projects in the use of peat. For over 35 years he industriously promoted a number of peat using projects and led in state and national conferences and societies concerned with peat. Some of his first mining operations were at Julington Creek, Crescent Lake, and near Pablo Beach. In 1906-1907 he attempted to introduce the idea of using peat for making producer gas for light, heat, and power, but when this aspect of the project failed, he dried and pulverized the dredged peat and sold it as a fertilizer filler. In 1908 he excavated 5,000 tons of peat at Julington Creek most of which was used for fertilizer or soil conditioning purposes. After a trip to England, during which Mr. Ranson obtained more ideas about uses of peat, he continued to experiment -with the production of producer gas but had little success in 'selling the idea although he satisfactorily demonstrated that such gas could be produced in quantity. His experimental plant near Canal Point in the Everglades during 1924 pro- duced power gas, ammonia, tars, oils, methyl alcohol, and some other by-products, but the expense of operating the test plant was so great that his backers and promoters discon- tinued further development of the project. 9 10 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY Big ideas prevailed during the 1920's in Florida and Robert Ranson's ideas about peat used for fuel and power were ad- vanced in the most glowing terms. One article about peat was titled "Acres of Diamonds in the Everglades" in which the conversion of millions of tons of Everglades peat into fuel for electrical and other power projects was envisioned. Ranson's idea was to use the large non-agricultural areas of peat in the Everglades which would be excavated of their peat layer and the peat used in large retorts to produce gas for power and fuel, with recovery of valuable by-products for fertilizer and industrial uses. Because a similar method, particularly well developed as the Mond Process of making producer gas, was common practice in many European countries, it was con- sidered as probably applicable to Florida. The promotion of this idea failed, however, and it has not since been tried in Florida. Among many of Ranson's estimates of the fuel value of Florida peat, one for the Everglades peat deposits states, "five hundred thousand acres there are, and they average ten feet in depth. Every such acre of deposits contains the equivalent heat of six thousand barrels of fuel oil. Each ton of Ever- glade peat, excavated and dried by my process, would cost one dollar to produce and deliver to power plants within a radius of five miles; and it would give six times more heat than the present dollar's worth of fuel oil. Furthermore, the by- products that can be obtained from peat will more than pay for the cost of production." However right Robert Ranson may have been his projects did not materialize and after his death in 1934 little has been said or done about the uses of peat for other than crop lands and fertilizer purposes. Peat for Humus and Fertilizer Peat for humus, soil conditioning, and as a fertilizer filler has been moderately useful. Some producers have made profits whereas others have failed. Considering these projects we find that those which failed financially usually had opera- tions of excavating, drying, processing, and selling on a too elaborate and costly scale. The Florida Humus Company of Zellwood was one such concern. Their dredging operation, drying platform, driers, and other processing machinery were THE PEAT DEPOSITS OF FLORIDA too costly to allow a profit on the small scales of prepared peat. Other concerns, however, as the West Florida Humus Company at Panama City, are producing dried peat for humus at a profit. Nurseries, as the Southern States Nursery, Daet- wyler Nursery, and Florida Nursery and Landscape Company are excavating peat for their own use and disposing of some commercially. The total amount of peat that was processed, used locally, or sold during 1944 in Florida probably exceeded 40,000 tons of 50 per cent air dry peat. The total quantity and value of peat produced in Florida by these and similar companies preparing peat for soil humus and fertilizer material has been about 200,000 tons of 50 per cent air dry peat sold or valued at nearly $1,200,000 for the years 1917 through 1945, as shown in tables 23 and 24. This is an average of less than 7,000 tons and about $40,000 per year for the peat industry in Florida and there has not been a progressive expansion of the industry. These figures indi- cate that some better methods of mining, processing, and using or selling the peat need to be developed to expand this industry. Summary From this brief review we see that the utilization of peat in Florida has been an unorganized industry with many failures and only a few successes. However, there remains the great possibility of a large scale use of peat if proper low cost production can be developed. This prospect is recognized in an article in the "Manufacturers Record" for January 21, 1926, which, in a discussion of "Florida's Greatest Industrial Opportunity," states, "with low-priced power from its peat deposits, Florida has a basic resource for expansion that should place it in the front rank of the industrial states of the Union." Our purpose in this investigation was to estimate the power and fuel potentialities of Florida's peat deposits and, if practical, promote their development. The present uses of peat lands for crops, and some peat for humus and fertilizer will expand, and the agricultural and commercial enterprises associated with them will probably continue to be most profitable, but no one knows or has thoroughly under- taken to estimate the possibilities of other profitable uses of peat and that was the purpose of this investigation. 11 12 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY There have been a few former investigations of Florida's peat resources, and many reports by the United States Bureau of Mines concerning the resources and utilization of peat in the United States, all of which show that there has been a long continued interest in the possible expansion of our present small scale utilization of peat. The Florida Geological Survey published a "Preliminary report on the peat deposits of Florida" in 1910 which was the result of a survey of types, dis- tribution, formation, and some uses of peat by Roland M. Harper.4 This report contains principally descriptions of the types of peat and the vegetation of peat areas in the different natural divisions of the State. It gives a few analyses of Florida peat and discusses briefly the utilization of Florida peats. The United States Bureau of Mines and the United States Geological Survey have also investigated some of the peat resources of Florida and four of their publications give some details about Florida peats.5 Moreover, these publications discuss many possible uses and are good references. Some interest in the utilization of Florida peat for fuel and industrial purposes was manifest in 1923 when efforts were made by Senator D. U. Fletcher to have the United States Bureau of Mines carry out an investigation of Florida peat deposits and their utilization, but nothing came of this pro- posal. Since that time no organized effort has been made to bring the possibilities of utilization of Florida peat resources to the attention of the public. On the other hand, peat lands used for their soil value in the growing of crops have been and will probably continue to be extensively developed by drainage. As agriculture becomes more and more intensified and the methods of handling peat or muck soils are better developed, even larger areas of bogs, 4 Harper, R. M., Preliminary report on the peat deposits of Florida. Florida Geol. Survey, 3d Ann. Rept., pp. 197-375, 1910. 5 Davis, C. A., Peat resources of the United States, exclusive of Alaska. U. S. Geol. Survey Bull. 394, pp. 62-69, 1909. 5 Davis, C. A., The uses of peat for fuel and other purposes. U. S. Bur. Mines Bull. 16, pp. 7-203, 1911. 5 Soper, E. K., and Osbon, C. C., The occurrence and use of peat in the United States. U. S. Geol. Survey Bull. 728, 1922. 5 Odell, W. W., and Hood, 0. P., Possibilities of the commercial utili- zation of peat. U. S. Bur. Mines Bull. 253, 1936. THE PEAT DEPOSITS OF FLORIDA marshes, moors, and swamps will be reclaimed. The greatest difficulties in handling these highly organic soils have been the control of water in these soils by many methods of drain- age and irrigation, and the addition of proper minerals to these soils to supplement the lack of materials in the peat. Alteration and control of the soil reaction, acidity particu- larly, and a better understanding and use of soil bacteria and other soil organisms are also leading to a more proficient use of peat lands for many different crops. The gradual loss of some of these peat soils of drained areas, however, has caused a condition difficult to overcome. Oxidation of the organic materials, compacting, fires, other forms of deterioration, and subsidence of the surface level of cultivated peat lands are all very difficult to control. In general, many peat soils are being lost or deteriorating at such a rate that their agricultural utilization is impaired. In fact, some large areas of good peat soils are becoming rapidly destroyed by cultivation, as in the Florida Everglades, and once destroyed these slowly accumulated deposits cannot be restored. In this respect, therefore, peat lands for agricul- ture are being "mined" because the soils are being used up even if not transported away. Conservation of peat lands, if they are to be of continued use, is a very important aspect of the proper utilization of peat. WORLD USES OF PEAT Evidences of the utilization of peat dates back to antiquity because it is known to have been used in early Egypt and Palestine for fuel. Among a few accounts of its use Waks- man 6 cites a quotation from the Natural History of Pliny (XVI, 1 Chauci), concerning various peoples who "mould mud with their hands and dry the mud in wind rather than in the sun; this earth they burn to cook their food and warm their bodies benumbed by cold." Where coal supplies are limited, as in Ireland, Russia, Sweden, Denmark, Holland, and Germany peat has long been used for domestic fuel. Recently, during the First World War and more recently during the Second World War, especially in 6 Waksman, S. A., The peats of New Jersey. New Jersey Dept. Cons. and Devel., Geol. series, Bull. 55, p. 13, 1942. 13 14 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY Russia, the use of peat for fuel on a large scale has increased greatly with advances in methods of burning peat under boil- ers. Russia in 1938 used 26,460,700 tons and probably has used much more since then. The application of peat on farmsteads has been its most widespread use as a material. Purcell 7 pointed out that one- seventh of Ireland was covered by peat deposits and that during the decade 1910-1920 the total consumption was six to eight million tons of air dry peat per year, most of which was for farmstead fuel purposes. This local consumption of peat for fuel in homes will probably continue in Europe as long as coal and other compet- ing fuels are more costly. But in North America with wood, coal, and petroleum abundant and transportation well de- veloped peat has not become an important domestic fuel. In Canada and some of the northern parts of the United States some domestic uses of peat were developed but never on a large scale. Moreover, it is probable that very few farmsteads and homes will ever depend upon peat for fuel in America because our fuel and power economy is becoming more and more de- pendent upon coal, petroleum, and electricity. 7 Purcell, P. F., The peat resources of Ireland. Dept. of Sci. Ind. Research, Fuel Research Board, Sp. Rept. 2. pp. 1-26, 1920. THE PEAT DEPOSITS OF FLORIDA Part I NATURE, ORIGIN, KINDS, AND COMPOSITION OF PEATS IN GENERAL NATURE AND ORIGIN Peat is an accumulation of partly decomposed and disinte- grated organic materials, derived mainly from the parts of plants, which material has usually accumulated where water abounds. The peat varies in consistency from a fibrous, matted, turf-like material to a mud-like plastic, slime or ooze. The different kinds of peats are most frequently classified on the basis of the plants which formed most of the material, and to a less extent on the basis of the texture and composi- tion of the peat. The mode of origin of the peat deposits is also important in any classification of kinds of peat. On the basis of origin two main kinds of peat have been distinguished: (1) autochthonous; and (2) allochthonous. Autochthonous peats are those that are formed in situ, little or none of the organic constituents having been transported. These are the fibrous peats of marshes, bogs, moors, some swamps, and other places where vegetation, composed of mosses, ferns, many grasses, sedges, rushes, reeds, some shrubs, and trees, grows and dies and the remains of the plants accumulate. Allochthonous peats are those that are mainly of sedimentary origin the materials forming them hav- ing been largely transported to the place of their deposition. These are the peats of lake bottoms and other bodies of water. Such peats are usually non-fibrous, plastic, colloidal, and macerated. The development of peat in deposits is a process now often referred to as paludification. This process is controlled by a number of interrelated factors each of which should be partly understood so as to understand the true nature of peat. These factors are: (1) the water conditions of the particular area where the deposit accumulated; (2) the vegetation that formed most of the peat; and (3) the climate of the region where the deposit was formed. Many persons have been interested in the conditions of formation of peat and in the kinds of peat and their utiliza- 15 16 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY tion. Recently the persons most interested have been soil chemists and biologists, such as S. A. Waksman, and A. P. Dachnowski-Stokes,8 who is publishing the most recent book about peat. C. A. Davis, and Vaino Auer are two men who wrote much of the past literature on peat in the United States and Canada respectively. Their writings should be referred to for more information than can be given here. VEGETATION Many generations of plants, which are usually special kinds adapted to certain definite water conditions and which formed one or several kinds of vegetation, have contributed to the layers of peat found in most deposits. The plants vary from those that are woody shrubs and trees of swamps and bogs to those that are herbaceous and live entirely in water. Mosses, particularly species of Sphagnum, numerous trees and shrubs of swamps, many sedges, reeds, some grasses, and a variety of other aquatic or semi-aquatic marsh plants con- tribute most to peat deposits. These peat forming plants frequently grow in fairly definite communities which are some of our most commonly recognized types of vegetation. To these types of vegetation a number of names have been ap- plied, such as; marsh, swamp, bog, moor, fen, meadow, and wet savanna or wet prairie. These terms are in some cases designations of areas as well as types of vegetation, and in both cases terminology has become very confusing. The systems of classifying peats are now usually based on the terms moor, bog, marsh, swamp, plus some habitat designa- tions such as high or low, limnic, terrestrial, aquatic (fresh water) or marine. Such classifications will be considered in more detail later. In the past many botanists, geologists, and other students of peat have been concerned mainly with the plants growing on the surface of the peat deposit and failed to discover the evidences of changes in vegetation with development of the peat. Recently, however, there have been many studies of the different layers of peat and from these studies there have come estimates of the age of the deposits and of the kinds of plants associated with them in the paludification process. In 8 Dachnowski-Stokes, A. P., Peat. Chronic Botanica, 1946. THE PEAT DEPOSITS OF FLORIDA general, during the development of a deposit the different generations of plants forming the peat change slowly from one dominant kind of vegetation to another-from a marsh to a swamp-and as a consequence of this process the deposit will have distinct layers of peat. A particular peat deposit may be the product of a number of different kinds of vegetation, and of a number of slightly different water conditions, and in some instances of different climates. Therefore, from the nature of the layers of peat in the deposit information regarding the conditions of its forma- tion, and in some cases the age of each layer, may be de- termined. Within recent years the science of plant ecology has done much to interpret the way the vegetation changes as peat deposits develop, and the science of micropaleontology (study of small fossils) has by the study of plant pollen grains and other spores made some interpretations as to the past climate of the region when a particular layer of peat was formed. The findings of both of these sciences will be con- sidered later. ENVIRONMENTAL CONDITIONS In the process of peat formation the water conditions and climate are most obviously important. Topography and past changes in sea level, surface and ground water all affect the water conditions. Climate, rainfall particularly, affects the water conditions. But by climate we here mean the changes in past, regional climates that cause changes in vegetation; such as changes from warm to cold climates during inter- glacial and glacial ages respectively. Geologic changes are therefore important in interpreting the older, usually deeper, and buried peat deposits. These geologic conditions will be considered in Part III. The present climate, topography, and water conditions work together in peat formation. Peat may be formed under very varied temperature conditions, from arctic to tropical, but the present day formation is mainly in cool temperature areas. It must not be supposed, however, as some writers have maintained, that peat formation is limited to cool climates because the mangrove swamps are definitely tropical or sub-tropical and they form peat. The great peat deposits 17 18 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY of the Florida Everglade ve developed ii ejenme when the temperature of the region most of the time has been warm temperate to sub-tropical. Figure 2.-Seasonal rains flood many marshes where peat occurs. Here the Istokpoga marsh near Brighton is deeply flooded during Sep- tember, 1945. It is not, therefore, so much temperature as precipitation and surface- or ground-water conditions which promote peat formation. In general, depressions containing quiet water in them most of the year, or large areas of low relief covered by slowly moving or still water part of the year, are the best conditions for the formation of the lowmoor or lowland peats and many of the forest or swamp peats. The upland or high- moor peats on the other hand are formed independently of flooded conditions in some instances, but they do depend upon high rainfall and high humidity for their development. Conse- quently the most important initiating causes of peat formation are the proper combination of air- and surface- and ground- water conditions which not only definitely promote the growth of peat forming plants but consistently influence the gradual accumulation of only partly decomposed organic materials. These water conditions should be continually kept in mind in all considerations of peat deposits. THE PEAT DEPOSITS OF FLORIDA The Florida peats are mostly of the lowmoor type and frequently are referred to as marsh peat. Their development is usually a consequence of poor drainage, seasonally heavy rainfall, and ground water rich in mineral salts. At present most of this Florida peat is formed in marshes and to a less extent in some swamps swamps here being considered flooded areas where trees and shrubs predominate. There are also seasonally wet prairies in Florida which have accumu- lated some peat and which become flooded but do not remain so continually. PEAT STRATIFICATION AND PLANT SUCCESSION The gradual changes in types of vegetation in the moors, bogs, swamps, marshes, lakes, ponds, lagoons, and some rivers developing peat deposits have been described by a num- ber of plant ecologists, and soil or peat scientists, of which a few are by Warming,9 Dachnowski,10 Clements," Soper,12 and Waksman.13 The description of successional stages in Minnesota swamps by Soper gives a primary sere (succession) in the filling in of a lake to form a pine forest in the following stages: (1) stonewort-waterweed stage; (2) pondweed- water-lily stage; (3) rush-wild rice stage; (4) bog-meadow stage; (5) bog-heath stage; (6) tamarack-spruce stage; (7) pine association. Waksman 14 has ably pointed out that: "The concepts relating to peat layers and horizons, to profile types of peat deposits, and to factors of peat accumulation- (furnish) a corre- lation-with reference to the profile structure of both American and European peat lands.-knowledge of the profile section of peat deposits constitutes a distinct step forward for-ecology, geography, economics, paleontology, and even archeology." 9 Warming, Eugene, Ecology of plants. Oxford Univ. Press., Trans. by Vohl., Groom and Balfour, pp. 358-363, London, 1925. 10 Dachnowski, A. P., Peat deposits of Ohio their origin, formation, and uses. Geol. Survey Ohio Bull. 16, 1922. 11 Clements, F. E., Plant Succession. Carnegie Inst. Washington Pub. 242, 1916. 12 Soper, E. K., The peat deposits of Minnesota. Minnesota Geol. Survey Bull. 16, pp. 63-70, 1919. 13 Waksman, S. A., The peats of New Jersey and their utilization. New Jersey Dept. Cons. and Devel., Geol. Ser., Bull. 55, pp. 30-37, 1942. 14 Waksman, S. A., The stratigraphic study of peat deposits. Soil Sci., Vol. 17, pp. 107-134, 1924. 19 20 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY GANDy PEAT /.' .. SAW RASS PEAT 4.5' - LOXANATCHEE PEAT 8.5' - LAKE FLIRT MAIt FT THOMPSON FM. (6esQ)A- Figure 3.-Profile of peat deposit and underlying sediments from a tree island in the Everglades showing peat stratification. These layers developed in a sequence due to the water conditions and kind of vegeta- tion which slowly changed as peat filled in the basin. THE PEAT DEPOSITS OF FLORIDA Moreover, he states: "The principle method of differentiating peat deposits into series and type-profiles is based upon the number of peat layers and horizons, and upon the combination of characteristics,-to identify units of layers it is necessary to have a certain amount of botanical information regarding the plant remains which constitute peat." When the layers of peat are considered in connection with the kinds of vegetation and other conditions forming them a fairly accurate history of the sequence of types of vegetation may be interpreted. This sequence of different kinds of vege- tation usually occurs in a fairly definite and often progressive fashion and the change from one kind of vegetation to another is known as a plant succession or sere. In Florida some peat stratification and plant successions start on underlying floor materials of sand, marl, or even lime- stone and develop through lake, marsh and swamp stages into a south temperate or sub-tropical, non-flooded forest stage which is generally known as a hammock forest of evergreen and deciduous hardwood trees with palms frequently present. One example of a Florida sequence of stages is the general oc- currence of successional vegetation stages in the Everglades. The peats formed during each stage of vegetation are shown in the following outline, in order from the bottom up: (but not all of this sequence occurs at any one place) TYPE OF PEAT VEGETATION 15 OR MUCK 16 Everglades hammock forest (association) 17 Hammock muck Bay tree forest (associes) Gandy peat Custard-apple swamp (associes) Okeechobee muck Mixed herb-shrub marsh (associes) Okeelanta peaty muck Saw-grass marsh (associes) Everglades peat Open-water, Aquatic marsh (associes) Loxahatchee peat Another succession of vegetation resulting in fairly definite layers of peat occurs in the coastal mangrove swamps in those localities where deep peat, muck, and shell marl de- posits have formed. The stages in this vegetational succes- sion and types of peat or muck formed are as follows: 18 15 Davis, J. H., Jr., Natural features of southern Florida. Fla. Geol. Survey Bull. 25, 1943. 16 Classification mostly by Henderson, Gallatin, and U. S. Soil Con- servation service. 17 Ecological names for the rank of each type of vegetation in paren- thesis. 18 Davis, J. H., Jr., The ecology and geologic role of Mangroves in Florida. Carnegie Inst. Washington Pub. 517, pp. 322-339 and 387-394, 1940. 21 22 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY TYPE OF PEAT OR VEGETATION OTHER DEPOSIT Coastal hammock forest or Hardwood Hammock muck or peat and palm forest (associations) Conocarpus transition or Buttonwood Buttonwood muck or peat zone (associes) Avicennia and salt-marsh or Black Black mangrove peat or peaty mangrove and salt-marsh zone (as- muck socies) Mature Rhizophora or Red Mangrove Red mangrove peat or peaty swamp zone (consocies) marl Pioneer Rhizophora (family) Off- Marl and muck shore pioneer mangroves These relations between types of peat and vegetation will be considered further under Vegetation of Peat Areas and in the description of Kinds of Florida Peats, Part II. SEDIMENTARY PEATS OF LAKES AND LAKE DEVELOPMENT The stratification of peat in many deposits indicates the gradual change of some lakes and other bodies of water into herbaceous marshes, then forest swamps, and in some cases finally into hammock forests. This sequence is mainly the resulting of filling up of the lake basins by the gradual ac- cumulation of deposits in the form of numerous sediments, or fibrous, or woody peats. The sediments are either predomi- nantly of organic origin or of inorganic materials. The former types of sediments are frequently known as peats, organic muds, and mucks. They are classified as allochthonous, sedi- mentary, or aquatic peats. They can be distinguished from marsh and swamp peats because they are usually without fibers, mud-like, frequently macerated, colloidal, and plastic. The term allochthonous is usually applied to them because they are a type of deposit formed by the gradual accumulation of floated, drifted and wind-blown vegetable material accumu- lated in more or less quiet bodies of open water. Studies of these lake peats by Forsaith 19 and in this in- vestigation indicate that many lakes, ponds and some rivers in Florida have great deposits of organic sediments which occur in the open water parts of these bodies of water, or in some cases below, above, or even between layers of fibrous and woody peats formed in marshes or swamps respectively. 19 Forsaith, Carl C., A report on some allochthonous peat deposits of Florida. Botanical Gazette 62: 32-52, 1916. THE PEAT DEPOSITS OF FLORIDA The present marshes and some swamps were in many in- stances formerly lakes or ponds, or parts of these, which have changed to marshes or swamps. Such changes take place so frequently in Florida that we should briefly consider lake de- velopment and aquatic or sedimentary peats in some detail. Lake Development The usual sequence of lake development is a gradual to rapid filling in of the basin until the whole deposit reaches the surface and no free open water exists, or until the bottom is entirely covered by large, attached aquatic plants and the lake becomes a pond, marsh, moor, bog, or swamp. The sequence of development of lakes or, in ecological terms, the successional stages in lake development, are fairly well known from studies of many lakes of the northern United States and Europe. There- fore, to better understand peat formation some pertinent aspects of limnology, science of lakes, should be considered. Welch 20 and other limnologists recognized three main types of lakes, as follows: (1) Oligotrophic, which are usually deep and have few or no deposits; (2) Eutrophic, which are usually shallow and have large quan- tities of organic deposits that are rapidly filling them up and most of the organic deposits of such lakes are peats of the type that are fibrous and formed in place, autochthonous; and (3) Dystrophic, lakes deep to shallow with organic bottom deposits of the aquatic peat type, alloch- thonous, and usually macerated. The oligotrophic lakes may gradually become filled with inorganic sediments and as they get shallower they may change to eutrophic or dystrophic lakes. There are few oligotrophic lakes in Florida. Both the eutrophic and dystrophic lakes form peat and in some cases these lakes become so completely filled up with organic deposits that they change to shallow ponds, meadow-like moors, marshes, bogs, or swamps. The eutrophic lakes are most apt to form marshes and moors and the dystrophic lakes bogs. The latter occur particularly in the north temperate region. The distinction between eutrophic and dystrophic lakes is in some ways arbitrary because one part of the lake, usually the central deep water part, may be dystrophic and the bordering shallow water part eutrophic as concerns organic deposits. In general, however, the dystrophic lakes are without much plant life around their border or in the shallow, littoral parts of the lake. The organic bottom deposits of the dystrophic lakes are predominantly macerated aquatic peats of the gyttja and sapropel types. Dystrophic lakes and deposits of this type of peat occur in Florida in such lakes as Newnan, Minnehaha and Weir, but over the State as a whole the eutrophic lakes and eutrophic peat deposits are more frequent. The eutrophic lakes are characterized by broad margins, littoral zones, usually covered by a marsh or swamp vegetation with an abundance of plankton and other aquatic plants. In these lakes the peat deposits are of the lowmoor, fibrous type. The peats and mucks ac- cumulate in the marsh and swamp zones of the shallow parts of the lakes, and as the gradual filling in of the lake progresses these zones become broader and the peat deeper until in some cases all open water areas are obliterated and the whole lake becomes a marsh, lowmoor, or swamp. 20 Welch, J, S., Limnology. McGraw-Hill, New York, pp. 310-315 and 318-321, 1933. 23 24 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY The natural process of maturing of a lake by the development of peat deposits that fill up the basin may be termed eutrophication. Towards the last stage of this process the changes become proportion- ately very rapid with filling in possible within a short time. This filling in process varies a great deal from lake to lake and even parts of the same lake so that the rate must be estimated for each locality. In Florida it seems fairly certain that some of the eutrophic lakes are filling with peat very rapidly, but others are doing so slowly. One condition that accelerates this process is a lowering of water levels, which has occurred in many lake basins, so that marginal vegetation more rapidly spreads over the lake causing more peat to form. The rate of filling in of dystrophic lakes in Florida seems, in general, to be slower than that 6f eutrophic lakes but further study is needed to determine these relative rates. Lake Deposits The sedimentary, macerated and colloidal organic deposits of many Florida lakes are in places over five feet deep. They occur in numerous lakes which have no attached, submerged aquatic plants, but they are also present in some lakes, Lake Apopka, where these aquatic plants are common. A con- siderable quantity of these organic sediments cover the floor of so many ponds, lakes, and rivers in Florida that extensive surveys and studies of them should be made before definite conclusions about the deposits can be drawn. ,II I I I I I I I I I I ./H H,,oneos o r vMr, os. E SAPROPEL FIBROUS SAWA.FASS PEAT Figure 4.-Profile section across Mud Lake, Marion County, show- ing the deep deposit of this lake, with sedimentary, sapropel peat over fibrous, lowmoor, saw-grass peat. After E. C. Roe. Florida lake basins usually have accumulated peat deposits in the bordering marshes and a few swamps. These are fibrous or woody autochthonous peats, formed in situ, and may be underlain by sedimentary allochthonous peats formed before the marshes and swamps developed. In the open water parts of the lakes the sedimentary, allochthonous peats partially or completely cover the floor of the lake. But THE PEAT DEPOSITS OF FLORIDA in some cases, as described later (see Part III, Significance of Lake Peats) the peat layers in a lake basin may be reversed from their usual order with fibrous autochthonous peats below sedimentary allochthonous peats indicating that the water in the basin increased in depth after the fibrous peat was formed in shallow water marshes. Lake deposits in central Florida were studied by Forsaith 21 who concluded that: "It is evident that those (peats) of lacustrine character (allochthonous) are of vastly greater numerical and quantitative importance than those of an auto- chthonous nature." But he was mistaken if all the peat de- posits of lake basins, marshes, swamps, wet prairies and coastal marshes and swamps are considered because the marshes, particularly the Everglades, contain much more peat than in sedimentary deposits of lakes. The kinds of sedimentary peats have been variously de- scribed as: (1) macerated, sapropel and gyttja; (2) colloidal, liver mud and dy; (3) and doppleritic, calcareous types. All these are generally known as aquatic, sedimentary or allochthonous peats and will be considered later. KINDS OF PEAT AND THEIR CLASSIFICATION Peats are such complex and varied substances and have been used for such a variety of purposes that a classification of the different kinds is very difficult. Physical, chemical, and physico-chemical characteristics and properties such as tex- ture, structure, organic and mineral components, water con- tent, and fuel values may be used for some classifications. The soil-like nature of peat, especially after drainage and cultivation in many cases forming muck, also leads to a variety of classifications. The origin of the peat, mainly from various peat-forming types of vegetation, and the con- ditions of formation of the peat deposits lead to still another group of classifications. And, finally, the various uses of peat as a material for fuel, chemical products, manufactured products, and some agriculture have led to still another method of classification. For practical purposes, which are usually the uses of peat , as a soil and as a material, classifications may be as numerous as the variety of uses to which it is put and the mode of origin 21 Forsaith, Carl C., op. cit. 25 26 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY or conditions of the formative processes may be entirely ig- nored. In some cases even composition, texture, structure, and color may be disregarded in the classifications of peat for utilization; viz. in the use of peat for fuel where British thermal units or calories are the chief property under con- sideration. A GENERAL SCIENTIFIC CLASSIFICATION OF PEATS There are enough combinations of easily identifiable charac- teristics of peat with those features of peat attributable to mode of origin and field conditions of the deposits to afford a reasonably uniform and universal classification. This classi- fication is based essentially on the origin and nature of the peat, particularly the vegetation forming it, and on some of the environmental conditions, such as topographic features and water conditions, and it is more generally applicable than strictly industrial or agricultural classifications. The ques- tion is: should the emphasis in classification be based upon the nature of the product or upon the formative processes? Also, are the water conditions which control the accumulation of peat or the botanical composition and sequence of vegeta- tion units forming peat most important in a classification on the basis of formative processes? Furthermore, are the chemical composition, structure, texture, color, pH values and heat values (calories or British thermal units), and water- holding capacity more important than the above in dis- tinguishing kinds? Certainly the physical, chemical, and physico-chemical characteristics of peat are most important for agriculture and industrial or commercial purposes, but classifications based on these alone, as will be shown, fail to give any idea of origin and field conditions. Therefore, and because of many former scientifically useful classifications, the classifications based on (1) botanical features; (2) controlling, basic environmental conditions; and (3) the general mode of origin of the deposit, or layers in deposits, are considered most universally applica- ble. Dachnowski,22 who has classified peats on a scientific basis, also has stated that: 22 Dachnowski, A. P., Quality and value of important types of peat material. U. S. Dept. of Agr., Bur. Plant Ind., Bull 802, pp. 1-40, 1919, or, Jour. Amer. Peat Soc. Vol. 13, pp. 219-261, 1921. THE PEAT DEPOSITS OF FLORIDA . types of peat material, their difference in botanical composi- tion, in disintegrating capacity, and in related physical and chemical characteristics have been established in Europe-. They form an adequate basis in problems which deal with methods to be practiced in the development and cultural preparation of a peat deposit, such as the well-known 'Veenkultur,' the Rimpan cultural method, the German high- moor method, and others or in operations where the removal of peat for technical uses and centralized power plants is practicable. Data such as those just mentioned, regarding the nature and behavior of the various types of disintegrating plant remains making up a peat deposit, are considered of special importance in drainage projects intended to be practicable from an engineering and agricultural standpoint; they are essential for an adequate method of dewatering peat materials that are found to be of value for manufacturing purposes. It is rather in the knowledge of the different kinds of peat material, the factors in the field which brought about their accumulation and determined their character, that a satisfactory basis has been found for the improve- ment of peat by means of suitable crops or by specific operations in the technical industries." One of the simplest and most generally useful classifica- tions of peat is proposed by Waksman,23 which has nearly uni- versal application. The European terms hochmoor and flach- moor which he uses are now becoming generally accepted. The four main kinds are: (1) upland or highmoor; (2) lowland or lowmoor; (3) swamp or forest; and (4) sedimentary or aquatic; mostly macerated, colloidal, and mud peats. To these may be added another group; (5) muck and humus, which may be developed from peat by disintegration and de- composition. But since both terms are frequently applied to other soil-like materials not definitely associated with peats, they do not constitute a definite type of peat. In one of the most recent scientific classifications of peat, Powers 24, gives four types based on the materials forming the deposits, which are: (1) Limnetic or lacustrine materials, which include various oozes and peat materials of sedimentary or allochthonous origin. (2) Telmatic materials, the marsh vegetation which is present as one of the bottom layers of almost all peat bogs. In North America, Carex or sedge forms most of the telmatic peat, which occurs widely in bogs of the marshy or lowmoor type. (3) Semiterrestrial peat materials, typified by Sphagnum peat, which is widely distributed and constitutes most of the highmoor bogs of the northern part of North America. (4) Terrestrial materials, as, for example, in the grass-herb-forest peat. Most of the peat bogs which have been studied are located in cool northerly regions, and their plant assemblages differ markedly from those in bogs of the same type in warmer lattitudes." 23 Waksman, S. A., The peats of New Jersey and their utilization. New Jersey Dept. Cons. and Devel., Geol. Ser., Bull. 55, pp. 26-30, 1942. 24 Powers, W. E., Recent advances in the study of peat. Bulletin National Research Council, Report Committee on Sedimentation 1930-32, 1932. 27 28 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY Because Florida peats are of the warmer latitudes their classification does not entirely fit those developed for the peats of more northern regions. In Part II a classification of Florida peats is given that is not entirely based on any of the above systems. MUCK AND HUMUS These soil-like materials may be derived from peats. Many disintegrated top layers of peat, especially after the peat lands have been drained and cultivated, are known as muck. In such cases the peat which may have been fibrous, woody, or even sedimentary or plastic becomes disintegrated into smaller fragments brought about mainly by changes in mois- ture content, cultivation, and by the growing roots of crop plants. Such muck is usually granular to powdery and much (Courtesy U. S. Sugar Corporation) Figure 5.-Peat forms soils, called muck, after cultivation, and large areas in the Everglades produce fine crops. Here at Canal Point are sugar cane fields. THE PEAT DEPOSITS OF FLORIDA darker in color than the peat from which it was derived. Many of the Everglades farmlands are surfaced by this type of muck formed mainly from peat. Another meaning of the term muck refers to soils that are composed of more mineral than organic matter and that are frequently of a mud or plastic character. These soil mucks a distinguished from peat muck are of less than 50 per cen> organic composition, but they are so similar to peats in may instances that distinctions can only be made after analysis. One of these soil mucks is the Okeechobee or custard-apple muck of the Everglades region near Lake Okeechobee. Throughout Florida there are many of these soil mucks frequently bordering the deeper peat areas. In Florida the soil mucks and peat mucks are not always distinguished in farming practice or soil classification. Humus is used as a term to designate decomposition products of peat as well as the organic constituents of some soils. Humus ordinarily is considered a decomposition product of organic matter that becomes the organic portion of a soil. It may be derived directly from peat principally by the action of microorganisms and biochemical processes. Because humus products are frequently soluble they become trans- ported and incorporated into many materials, such as the dy type of aquatic peat. Another type is some of the hardpans where the dark brown humus materials act as a cementing material mostly in sands. But these hardpan soils should not be considered peats, they are ground water podzol soils. DIATOMACEOUS EARTHS OR MUCKS Some peats and mucks contain such an abundance of the microscopic diatom plants that have tests of silica that these form a material generally known as diatomaceous earth. When this diatomaceous earth is burned, calcined, a nearly pure silica residue is obtained that is generally called diato- mite. This diatomite is of commercial value being used for a number of purposes, such as a filtration medium, for the ab- sorption of moisture, in making concrete and plaster, in ther- mal insulation, and some polishes. The Florida diatomaceous earths usually contain so much carbonaceous organic matter that when wet and not com- pacted they are dark brown or black and similar in appearance 29 30 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY to peat or muck. In general diatomaceous earths have an unctuous, greasy feel which distinguishes them from the fibrous peats that have a rougher firmer feel. Muck, peats and diatomaceous earths are frequently associated in the same deposit and in some instances it is difficult to distinguish diatomaceous earth from the more plastic peats or mucks. Some mucks have a similar greasy feel and black color. How- ever, upon drying the diatomaceous earths usually become lighter in color approaching a tan or cream color, whereas the mucks and peats usually become darker in color. Upon burn- ing or even slow oxidation in deposits the diatomaceous layers may be distinguished by their lighter cream to white color and eventually by their powdery texture. 7 Most of Florida's diatomaceous earths are mucks and not earth. The diatomaceous muck may change to diatomaceous earth with oxidation of the organic materials. In wet deposits the dark colored muck form is the rule and in dry deposits the light colored earth form is common. In our prospecting of diatomaceous deposits and in the descriptions to follow (see Diatomaceous Deposits and their Use) the term diatomace- ous earth is used to designate both forms of diatomaceous materials. Proportions of diatomaceous earth, peat, and muck, and the layers in which they occur vary some from place to place but, in general, the diatomaceous earth is in the upper layers of the deposits. Many peat deposits in Florida contain diatomaceous earth and for this reason the diatomaceous deposits are considered in the description of Florida peats given in Part II. TYPES OF PEAT MATERIAL The four types of peats considered above may be more generally and probably more practically described as three types of peat material in the manner suggested by Dachnow- ski,25 which are: (1) sedimentary or pulpy peat; (2) fibrous peat and (3) woody peat. The sedimentary or pulpy peats are mainly aquatic peats, the fibrous peats are both the lowmoor 25 Dachnowski, A. P., The stratigraphic study of peat deposits. Soil Sci., vol. 17, pp. 107-134, 1924. THE PEAT DEPOSITS OF FLORIDA and highmoor peats, and the woody peats are the swamp or forest peats. These may be described simply in terms of com- position, texture, structure, color, and some other characteris- tics and properties. Sedimentary, Plastic, and Pulpy Peat The texture varies from very finely divided particles of organic debris to coarse but seldom fibrous material frequently mixed with inorganic and mud-like sediments. When wet it is often a sticky, gel-like, amorphous mass. When dry it is usually dense and compact and may be heavy, stiff, and im- pervious. There are seldom any planes of bedding in the de- posit. Under pressure it frequently yields to plastic flow and when excavated it does not readily stand in vertical walls. The color is usually dark brown, black, gray, or olive green becoming darker when dried. Upon drying it usually shrinks to a remarkable degree often becoming hard and horn-like. When dry some kinds break into angular fragments because of a conchoidal frac- ture. Because disintegrated surface layers of other peats are likely to resemble sedimentary peat caution should be used in assigning peats of drained and cultivated areas to this type. Fibrous Peat The texture and structure is an interwoven network of only partly altered plant remains varying from very coarse to finely fibered materials with, in many cases, finely divided non-fibrous particles of organic and inorganic matter inter- spersed between the fibers. A large portion of this fibrous mass is pore space both between the fibers and intra- or inter- cellular space in the plant tissues. Being mainly derived from roots, rootlets, rhizomes, and in some cases as the high-moor peats from mosses, its structure often reflects the growth form of parts of the plants. Whole root systems and leaves often remain well preserved in this peat. The color is very variable depending upon the color of the plant remains, the degree of decomposition, and the mineral salts associated. Red and yellow browns are common, but grey, dark brown, and nearly black are more frequent. Upon 31 32 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY drying and oxidation many fibrous peats become darker often becoming black. Upon drying some finely fibrous peats with large propor- tions of sedimentary materials may shrink greatly, but other coarser and more matted fibrous peats may retain nearly Figure 6.-Recently excavated, fibrous saw-grass peat, and ma- chete used to cut samples. Note most fibers are vertical and coarse in this peat. their original wet dimensions. Some of these peats are very friable and many of them break by normal fracture when dried, others shatter into a powder when crushed. If they contain a large proportion of fine plastic material they may remain firm and compact when dry. Upon excavation the vertical walls stand up well in most fibrous peat. The high degree of porosity of fibrous peat is a characteris- tic that influences the water-holding capacity, absorbing ca,- pacity when once dried, air content, temperature, weight, and volume to such an extent that porosity must nearly always be considered in handling or classifying this kind of peat. Types of fibrous peats derived from different dominant plants of the vegetation that formed them may be dis- tinguished; viz., moss peat, reed peat, sedge peat, saw-grass THE PEAT DEPOSITS OF FLORIDA peat, and others that were noted under the marsh group above and will be described later in the detailed consideration of Florida peats. Woody Peat The texture and structure of this peat is much more varied than either the fibrous or sedimentary peats. Woody material of various sizes and shapes and in different stages of decompo- sition are its most outstanding characteristic. With these woody fragments both fibrous and plastic peat materials may be associated to form a very hetrogenous mass of material. In general, partly granular debris and irregular shaped woody fragments are the most common materials. In some instances this peat may vary so much that layers of woody peat may have separate horizons of a banded and bedded appearance, their distinctive characters depending upon the relative pro- portions of the woody materials and the fibrous or plastic ma- terials. The types of woody peats may be distinguished on the basis of the woody plants, trees, and shrubs which contributed to the peat. Some of these are heath, bay, cypress, willow, alder, and other deciduous, and conifer trees and shrubs. The woody particles, and in some cases whole limbs or trunks, may be so well preserved that the tree or shrub may be identified. KINDS OF PEATS BASED ON UTILIZATION Industrial and agricultural peats, other than peat soils, have been variously classified, and with the expansion of the uses of peat many other classifications will be developed. The bases of some of these classifications are the water-absorbing capacity, degree of fineness, type of fibrous condition, color, reaction expressed in terms of pH, mineral content especially nitrogen compounds, and chemical components. The United States Treasury 26 recognizes three types of peat: (1) moss peat; (2) reed muck or sedge muck; and (3) reed peat or sedge peat. These mucks are in reality peats having about 10 to 15 per cent ash and differing mainly from the similar reed or sedge peats in having more finely divided plant debris due to a more advanced state of decomposition. Therefore, these two categories may be considered only one. 26 U. S. Treasury Department, Procurement Division, Specifications for peat. No. 563, May 19, 1942. 33 34 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY The moss peat or peat moss as it is known in the trade, is poorly decomposed, fibrous to porous, and derived in large part from Sphagnum moss, with acidity of 3.5 to 5.5 pH values, and capable of absorbing 1100 to 2000 per cent water. The reed or sedge peats have water-absorbing capacities varying from 100 to 800 per cent and a pH range of 5.00 to 7.5. These types are further divided into classes, peat moss with: (a) horticultural grade, fine shreds; (b) poultry litter, medium shreds; and (c) stable bedding, coarse shreds. The reed or sedge peats have two classes; (a) acid grade, pH 4.5 to 5.5; and (b) nearly neutral grade, pH 5.5 to 7.5. Waksman 27 gives four types of peat material for practical purposes, namely: 1. Moss peat, yellowish brown, fibrous, pH 3.5 to 5.0, low in nitrogen and ash, absorbing 600 to 1500 per cent water, and marketed in various degrees of fineness for horticulture, bedding, and litter. 2. Sedge and reed peat, dark brown to black, pH 4.5 to 6.5 high in nitrogen and ash, absorbing 300 to 600 per cent water, and marketed for composts and other soil improvement pur- poses. 3. Forest peat, brown or reddish brown, and fluffy with fine to coarse particles of wood, pH 3.8 to 5.5, medium in nitrogen and ash, absorbing 400 to 800 per cent water, and marketed for mulching. 4. Peat loam, alluvial or sedimentary peat, often:known as muck, with less organic matter, 10 to 50 per cent, thani.nost peats and plastic, colloidal, or granular. These simple classifications of marketed peats reflect the few prevalent uses and do not include many other classifica- tions based on utilization in Europe or possible future utiliza- tion. Chemical analyses and heat values will probably de- termine some of the future classifications of peat used for in- dustrial and fuel purposes. A classification of peats based on utilization will be considered later in Part IV. PEAT SOILS Peat or muck soils are very diversely classified because the bases for "recognition of types and the names given are often without reference to origin or a world wide system of 27 Waksman, S. A., The peats of New Jersey and their utilization. New Jersey Dept. Cons. and Devel., Geol. Ser., Bull. 55, pp. 25-30, 1942. THE PEAT DEPOSITS OF FLORIDA classification. Soil scientists and farmers in general use only local names, such as Everglades peat, Okeechobee muck, and Loxahatchee peat, to designate kinds, and the characteristics of each must be kept in mind when comparisons or identifica- tions are made. Most peat soils are only the surface layers of peat deposits and, as pointed out above, these drained and cultivated layers frequently become fine particled, granular, dark in color, a> more plastic than they were originally. For this reason they are often referred to as muck soils even though they may be of greater organic than mineral content. Some regional classification and mapping of peat deposits as soil types is done, and in some cases the profile of the whole deposit is con- sidered in the designation of the soil. But, in most cases only surface layers are considered. Present classifications of peat lands as soils are based mainly on water conditions, mineral content, color and soil reaction. Some of these soil classifications now also recog- nize the importance of the structure, texture, conditions that influence water content, transmissibility, drying and wetting characteristics, conditions of ditch and dike banks, and the series of peat strata that may be present. The mud, marl sand, or rock, that may underlie the deposit or in some in- stances be interbedded with the peat, are also considered. From the agricultural point of view it is important to know more than just the conditions of the top or soil layer of peat deposits because if the stratification, mode of formation, the probable rate of formation, and best method of retaining good water conditions are known, the lands can be better handled for crops and pasturage. Besides the peat and muck soils other partly organic soils may develop in poorly drained areas which are known as the: (1) ground-water podzols; and (2) the half-bog soils. Some planosols and some Tundra and Alpine Meadow soils may also have organic matter in large proportions. Henderson 28 in his description of Florida soils character- izes the marsh and swamp soils as bog soils and lists five general kinds, namely: 28 Henderson, J. R., The Soils of Florida. Univ. of Florida Agr. Exper. Sta. Bull. 334, 1939. 35 36 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY "(1) Muck, dark brown to black, highly decomposed or- ganic matter containing 35 to 75 per cent mineral material, mainly fine sand and silt. "(2) Peat, dark brown to black partially decomposed or- ganic matter containing 0 to 35 per cent mineral matter. "(3) Peaty muck,-gradation between peat and muck- agricultural use-more valuable than peat and less valuable than muck. "(4) Swamp, miscellaneous unclassified (soils of) swamp areas. "(5) Tidal-marsh, (soils of) marshy areas along the coast which are subject to tidal inundation." This classification of "bog soils" has been further ex- panded in Florida by the naming and description of certain soil types under some of these five categories by Henderson and others 29 who have done their most intensive work on organic soils of some areas of southern Florida, particularly the Everglades. FLORIDA PEATS The many kinds of Florida peats may be classified accord- ing to any one, or a combination of, those systems outlined above. They are, in general, mainly lowmoor, fibrous peats in the extensive marshes and some wet prairies, some forest or woody peats in the swamps, and allochthonous, aquatic, sedi- mentary peats in the lakes. These will be classified in Part II when the kinds and quantities of peat in the deposits are considered in detail. The names of some of the Florida peats and a few of their characteristics will be used in the following descriptions of the characteristics and composition of peats and the reader will need to refer to the descriptions of these peats in Part II to become familiar with these names used. CHARACTERISTICS AND COMPOSITION OF PEATS Most of the characteristics, properties, and composition of peat materials and peat soils are based on the fact that peats are essentially a mixture of water and partly decomposed 29 Notably soil scientists of the U. S. Soil Conservation Service working in the Everglades Drainage District. THE PEAT DEPOSITS OF FLORIDA plant matter. The physical and physico-chemical characteris- tics and properties such as texture and structure, soil reac- tion, and heat values of peats vary a great deal because of the different types of vegetation from which they are derived and the different environmental conditions under which they de- velop. These characteristics and properties are many, of which the following are among the most important, namely: (1) water-holding, water-absorbing, and drying characteris- tics; (2) texture and structure; (3) weight, density, and specific gravity; (4) atmosphere and gas content; (5) col- loidal conditions; (6) temperature relations; (7) soil reac- tion (pH values) ; and (8) heat values (B. t. u. or calory). The chemical composition is related to many of these properties and characteristics and is also directly determined by the peat forming plants and environmental conditions. The organic compounds, particularly lignins, proteins, cellu- loses, hemicelluloses, and tars, are important but are not well known. The inorganic minerals and substances vary a great deal and are well known, particularly in peat soils that are used for agriculture. Although it is impossible in many cases to distinguish be- tween the chemical composition and some of the physical or physico-chemical properties the chemical composition will be considered separately here because the analyses made in this investigation were mostly chemical. Some of the characteristics and composition of the Florida peats are considered in the following descriptions, but most of the analyses of these peats are given in Part II. The general classification of peats and their distinctive characteristics need to be understood before the Florida peats can be ade- quately described and appraised. Many of the particular characteristics of Florida peats, such as drying, weight, organic composition, and microbio- logical nature need considerably more investigation before these peats can be sufficiently well understood to make the best use of them. Some of the useful characteristics and properties of peats are pointed out below but a fuller discussion of uses is pre- sented in Part IV. 37 38 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY PHYSICAL-MECHANICAL AND COLLOIDAL CHARACTERISTICS Texture and structure are the most readily recognized physical-mechanical properties, and these have been partly considered in the description of kinds of peats. The four usually recognized variations in texture and structure are: (1) fibrous; (2) sedimentary, macerated, and plastic, often colloidal; (3) granular; and (4) woody with pieces of wood or stems abundant in the peat. The fibrous peats, figure 6, vary a great deal in com- pactness or looseness of structure, and in the fineness or coarseness of texture of the fibers, and these differences ac- count for many of the various conditions of water, weight, volume, air content, and temperature relations in the deposits or of the excavated material. Great porosity is a chief characteristic of nearly all fibrous peats. The sedimentary, macerated, and plastic peats have less definite structure and texture than fibrous peats and they are more difficult to correlate with such properties as water- holding capacity, drying, and volume and weight measure- ments. They are apt to have some collodial properties such as flocculation, buffering properties, and high absorption of and coagulation with bases and salts. They often form stable emulsions with water. These properties are important but their chief characteristics are that they are mud-like, very wet, and shrink and harden more than fibrous peats upon dry- ing. Some sedimentary peats occur with fibrous, granular, or woody peats, but most often they are distinct deposits in bodies of water. The granular peats are mainly peat soils becoming granu- lar after drainage and cultivation. They can be developed from fibrous, sedimentary and woody peats. Disintegration in the case of fibrous peat and coagulation, flocculation, and other granulation processes in the case of sedimentary peats are mainly responsible for their formation. Woody peats are a mixture of fibers or plastic peat ma- terial with fragments of stems or large roots, and in some cases leaves, together forming a very heterogeneous mass. Upon drying the woody particles shrink less than the other materials. In some deposits parts of logs and stumps are well THE PEAT DEPOSITS OF FLORIDA preserved and in many cases the trees or shrubs can be identi- fied. Variability in texture and structure are due mainly to the kinds of plants, a few animals, and inorganic sediments from which the peats were formed, plus the degree of disintegra- tion and decomposition in the deposits. Layering or stratifi- cation in a deposit is generally best recognized by differences in texture and structure at different levels in the deposits. The fibrous condition of peats varies from very fine fibers matted into a felt-like mass, the fibers running in nearly all directions through the mass, to coarse fibers usually oriented vertically, figure 6, to mixtures of fine and coarse fibers with orientation of fibers in general vertical. Another condi- tion is the matted and fibrous, in which case leaves and other flat parts of plants form plate-like mats, laminae, with fibers usually vertical so that the mass pulls apart along horizontal and vertical cleavage planes. And still another fibrous con- dition is the mixture of fibers, fine to coarse with granular or flaky pieces of wood or large chunks or even limbs of wood. Between the matrix of fibers there may be small or large quantities of granular or very fine particled materials form- ing a structural mass that may when wet appear and feel almost non-fibrous or plastic. In general, this finely divided material between the fibers constitutes the greater bulk of the mass in heavy peats, as the saw-grass peat of the Everglades. Plastic organic materials and inorganic sands, silts, and clays are common constituents of all but the most fibrous peats. The top layers of raw peat with live roots, rhizomes, and other under-water parts of plants are more coarsely fibrous and matted. Usually in the lower part of a peat deposit the fibrous material decreases and the more finely divided ma- terials of sedimentary peats increase. The sedimentary, macerated, and plastic peats vary from those that have a few small, partly disintegrated parts of plants and animals to a mass of very fine particled, mud-like, organic material that can not be identified as to its source. The colloidal, jelly-like, mud peats are of such consistency that they can be fashioned into various shapes much like putty when they become partly dried. When wet some of these 39 40 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY macerated or plastic peats flow and nearly all are amorphous. Many plastic peats are sticky or soapy to the touch. A peat that has fine fibers and a large percentage of fine particled materials may be termed fibro-plastic, especially upon drying when the few fibers no longer hold the mass in a definite shape. This is the case with some of the semi-aquatic peats such as the Loxahatchee peat of the Everglades region. Granular peats are predominantly dried or partly dried, aereated, and pulverized such as commonly occur in the upper layers of drained and cultivated peat lands. Plastic or fibrous peats that have finely divided materials between the fibers form this granular peat. Coarsely fibrous peats sometime re- tain their fibrous nature even after drying. Mud-like peats often become lumpy, in cakes, or hard layers when dried. Some woody peats, especially with leaf materials, usually be- come flaky and chaffy or crumbly when dried. Waksman 30 in his discussion of the colloidal nature of peat pointed out that strongly acid peats do not form emulsions in water but high calcium peats do. Neutral and acid salts as well as acids coagulate the hydrosol formed in peat. In sedge reed peats, as the Everglades peat where there is a high con- tent of calcium, the potassium and ammonium cations are absorbed to a greater extent than in acid peats such as Sphagnum peats. The absorption of different bases by acid peats varies with the kind of base; thus CaCO is acted on least rapidly and CaO, Na2CO3 and NaOH more rapidly, in ascending order. The rate of neutralization of peat with CaCO3 increases with an increase in the initial pH value of the peat. Other physical and physico-chemical properties such as the heat values, the color, temperatures, and hydrogen-ion concentration are important, but they will be considered later after a consideration of water content and drying of peat, which are more definitely related to the above properties. The porosity of some peats is a characteristic of value in many other ways than water-holding capacity. One of these is use in briquets of magnesium oxide in the process of conversion to magnesium chloride. 30 Waksman, S. A., The peats of New Jersey and their utilization. New Jersey Dept. Cons. and Devel., Geol. Ser., Bull. 55, 1942. THE PEAT DEPOSITS OF FLORIDA WATER CONTENT AND ABSORBING CAPACITY The high water content of recently excavated and field peat, and the high water-absorbing capacity of peat that has been dried are among the most significant practical properties of peat. Different peats vary considerably in these respects depending on their origin, degree of decomposition, and chemical composition. On an oven-dry basis some of the Florida peats have as much as 934 per cent water, as in the Lake Apopka marsh peats, and as little as 349 per cent water in the shallow saw-grass peats of parts of the Everglades when the water-table is below the peat layer. Waksman 31 pointed out that some Sphagnum peats are able to hold as much as 1,500 per cent water. He 32 also showed that Florida Everglades peats varied from 432 to 805 per cent moisture. The "water holding capacity" of various commerical peats is considered so important that the "Specifications for Peat" of the Procurement Division, U. S. Treasury Department clas- sifies three types of peat on this basis: (1) moss peat (or peat moss, as it is designated by the trade) 1100 to 2000 per cent; (2) reed muck or sedge muck 100 to 350 per cent; and (3) reed peat or sedge peat 350 to 800 per cent. On this basis the Florida peats are mostly reed and sedge peats with, in a few instances, more water-holding capacity than 800 per cent and some less than 350 per cent. Laboratory tests for this "water-holding capacity" are usually made by the following procedure,33 or slight variations as follows: "Place an unweighed sample of 25 to 50 grams taken from the center of the composite sample, in a tarred, covered container having a wire screen bottom of approximately 25 meshes to the linear inch. Immerse in water at room temperature (200 to 300 C) for 18 to 24 hours. Remove the container with sample from the water and allow to drain for one hour while supported on glass rods under a bell jar. Carefully wipe the excess water from the outside of the container and weigh. Heat in an oven at 1050 to 110 C. to constant weight, before weighing, cool the container and contents in a desiccator. The per cent of water absorbed may be computed from the difference in weight between the saturated sample and the oven-dry sample, based on the oven-dry weight." "(Caution: It is important that the sample shall not have been sub- jected to partial preliminary drying, as dried or partially dried peat or muck may not reabsorb water to its original absorbing capacity.)" 31 Waksman, S. A., Op. cit., pp. 83-86. 32 Waksman, S. A., Op. cit., pp. 80-81. 33 U. S. Treasury Department, Procurement Division, Specifications for peat. No. 563, May 19, 1942. 41 42 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY The water-holding capacity of peat in laboratory tests is not the same as the water content of peat before removal from deposits. This latter is the field-water-content and it is diffi- cult if not impossible to measure accurately. It was approxi- mated in this investigation by weighing uniform size samples at or near the deposits then drying these to a nearly constant weight in the laboratory. Later, after drying in ovens with thermal control at about 105 C. to nearly constant weight, the percentage of loss of weight for both the air-dry and oven- dry conditions were then calculated based on the field weight of the sample. Some of the results of such tests are given in table 1. These percentages of water in the peat show approxi- mately the field-water-content conditions. Most of the tables presented here that give per cent of water, either oven-dry or air-dry, are similarly based on field volumes of the samples. The air dried samples were all dried to nearly constant weight in the laboratory at Tallahassee. These field-water-content data show that Florida peats in the deposits below the water table have an average of 5.2 per cent more water than the peats above the water table. Even in the cases where the water table is 3 feet below the surface the top 3 feet has only from 5.3 to 7.2 per cent less water than the underlying peat below the water table. This means that very little water in peat permeates downward by gravity most of it being held in the peat by absorption and capillarity. In table 14, Part II, the percentage of water in the peat in some of the important Florida deposits is given in terms of the air-drying loss. This air-drying loss is less than the field- water-content because in the latter case the per cent of loss after drying in an oven is added to the per cent lost upon drying only in the laboratory. Drying in the laboratory is not as uniform as drying in an oven, therefore, the data in table 1, express more accurately the amount of water in peats of various deposits. But data on only air-dried peat are more useful for purposes of handling the peat as a material. Clayton et al.,34 in their study of Everglades peat found the per cent of moisture oven dried for muck soils in the areas where these soils are cultivated. The water content is as ow 34 Clayton, B. S., Neller, J. R. and Allison, R. V., Water control in the peat and muck soils of the Florida Everglades. Univ. of Florida, Agr. Exper. Sta. Bull. 378, 1942. TABLE 1 FIELD-WATER-CONTENT OF SOME FLORIDA PEATS Oven-dry Depth in Conditions Per cent Location Kind of Peat deposit, in Inches Water Table, etc Water Everglades ....................................saw-grass, shallow ..................................top 36..........moist, above water table .................. 79.7 Everglades ....................................saw-grass, deep ........................................top 36............moist, above water table .................. 79.1 Everglades ....................................saw-grass, deep .........................................36 64-..... wet, below water table ...................... 83.4 Everglades ....................................Loxahatchee, deep ..................................top 12............moist, above water table .................. 89.7 Everglades ....................................Loxahatchee, deep .................................----------------36 110-............wet, below water table ...................... 94.6 Istokpoga marsh ..........................Brighton, deep ..........................................top 24............moist, above water table .................. 82.4 c Istokpoga marsh ..........................Brighton, deep ..........................................24 124............wet, below water table ...................... 87.6 Fellsmere marsh ..........................saw-grass, shallow ..................................top 36............moist, above water level .................. 75.9 Fellsmere marsh ..........................saw-grass, deep ........................................24 110..........wet, below water table ..-----------.................... 83.6 Lake Apopka marsh ....................saw-grass, deep ........................................top 12............moist, above water table .................. 85.4 Lake Apopka marsh ....................saw-grass, deep ........................................24 120 ..........wet, below water table ...................... 91.7 Clermont marsh ..........................Pond-prairie, deep ....................................top 12............moist, above water table .................. 84.7 Clermont marsh ..........................Pond-prairie, deep ......................................24 96............wet, below water table ...................... 92.1 Florahome ....................................Prairie, medium deep ................. ............top 24............dry, drained .......................--------------------................. 63.2 Florahome ....................................Prairie, medium deep ................................24 60....... wet, near water table .....--.....--.............- 84.8 Miscellaneous ................................Miscellaneous ...........................................top 24............dry, drained ....-...........----......................... 68.7 Miscellaneous ................................Miscellaneous ................................ 24 40............24- 40............moist, above water table .................. 76.5 Miscellaneous ................................Miscellaneous .-................--------............-..............----48 120............ wet, below water table .......--.--.............. 85.4 44 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY as 29 per cent in Okeechobee muck and 62 per cent in a saw- grass peat from the top to a depth of six inches. The average condition in cultivated or nearly constantly drained peat or muck areas in the northern part of the Everglades is 67 per cent in the upper 2 feet of soil, and 79 per cent water in the peat or muck below this 2 feet. In fact, most of the samples of peat soils below 2 feet contained over 82 per cent water. These data from cultivated peat or muck soils of the Ever- glades where conditions are much drier than most marshes, bogs, or swamps, are cited to show that even under cultivation and compaction the peat above the water table continues to hold most of its water. This water-retaining capacity of peat is a very important physical and physico-chemical property. Among other things it means that; (1) peat both drained and undrained has a high percentage of water when undisturbed; (2) peat is difficult to dry by gravity drainage; (3) lateral transmission of water through peat, seepage of water through peat, drainage of peat soils by canals, and drying of peat after excavation are all slow because they are affected by these water-holding characteristics of peat. If peat areas are to be used as soils for agriculture* a knowledge of the water-holding capacities is very important, and moreover, no general rule can be applied to any one area or any type of peat because the fibrous or plastic nature of the peat, the looseness or compactness, depth, and degree of de- composition all are important factors. Clayton, et al.,35 showed that rates of seepage vertically downward through Everglades peat vary greatly from a rate of 0.3 foot per day through the top 18 inches to a rate of 27.3 feet per day through the layer from 18 to 36 inches below the surface. Horizontal transmission of water was at a rate of 0.25 foot per day at a depth of 3 feet. Their observations showed that the top soil had been much changed by cultiva- tion and weathering causing it to be less capable of trans- mitting water downward than the lower undisturbed peat layers. Such slow transfer of water through peat affects the methods of drying after excavation of peat and piling it for 35 Clayton, B. S. et al., op. cit. THE PEAT DEPOSITS OF FLORIDA drying, or by harrowing it in the field to dry. Once the sur- face is macerated, pulverized and then dried it is difficult to wet the peat rapidly to depths very far below the surface. These characteristics of peat, therefore, are important in all operations concerning peat either as a soil or as a material. As a material for use with mixed fertilizers, or for drying sufficiently to burn, or for drying for use in processing to make manufactured products the water content and rate and conditions of drying are very important and these will be considered in more detail later. USES BASED ON WATER-HOLDING CAPACITY Because of the great water-holding capacity of peat it has found wide application, chief among which are its uses in the improvement of the physical condition of soil, as a litter in stables and poultry houses, and as a surgical absorbent dressing, which was the use made of Sphagnum or Sphagnum peat in large quantities during World War I. Some agricultural and horticultural uses that are conse- quences and corollaries of these water-holding and water- absorbing characteristics of peat are: 36 (1) Despite the fact that peat increases the water content of mineral soils, it holds the water so tight that plants may not be able to use it. Therefore, caution is advised in using peat humus as soil dressing to increase soil moisture, especially in sandy soils where added peat may actually withdraw water from the sand doing more harm than good. This water- absorbing power is related to the fact that soils treated with peat frequently develop a higher wilting point than the origi- nal soils, therefore, making moisture more unavailable to plants than before treatment. (2) Some peats, particularly sedge and reed peats, become granular when partly dried and have poor capillarity so that such peats tend to have a damming effect on soil moisture im- mediately below the surface. As a precaution most peats should be thoroughly shredded if they are to be used as horticultural peat and mixed with the soil. (3) These above characteristics frequently offset any ad- vantages which might be gained from using peat as a soil con- 36 Some of these conclusions from Waksman op. cit. 45 46 FLORIDA GEOLOGICAL S URVEY-BULLETIN THIRTY ditioner and a careful selection of soil type, water conditions, type and condition of the peat and quantity used should be exercised before applying peat to soils for their improvement. Peat once air dried, usually below 40 per cent moisture, is not readily wetted by water and, as Waksman 37 pointed out, when wetted a heat of wetting develops which his test gave as 13.7 calories per gram. This heat developed is the heat of compression due to the strong attraction of peat for water as absorption and adsorption take place. Waksman also states that wetting resistance is due to the strongly adsorbed air film and that peat may be considered, therefore, an "aerophilic" material. This property of poor re-absorption of water by dried peat is important in handling this material because if a certain water content is desired it would be difficult to re-establish the desired water content once the peat becomes too dry. Once dried for some purposes, as for fuel, or in preparing horticul- tural peat, it becomes difficult to wet. In the former case re- maining dry is a good characteristic, but in the latter case it is bad. For this reason the "Specification for Peat" of the Pro- curement Division, U. S. Treasury Department tries to ap- proximate this water-absorbing capacity by a measurement of the "water-holding capacity." This measurement, however, fails to give the exact re-absorbing power. DRYING CHARACTERISTICS When peats, which are nearly always wet in the deposits, are dried the structure, some of the texture, and other quali- ties are often radically modified. The loss of water from a mass of peat is not as simple a response to temperature, pres- sure, humidity, and other atmospheric conditions as might seem the case because the texture, structure, organic nature, and biological conditions of the peat affect this loss of water. Shrinkage of the mass, aeration, oxidation, temperature changes, and disintegration or decomposition are some of the usual results of drying. Loss of weight is the most uniform result of drying. Loss of weight is principally a loss of water, but this de- hydration is usually also accompanied by loss of volatile mat- 37 Waksman, S. A. op. Cit., p. 82. THE PEAT DEPOSITS OF FLORIDA Figure 7.-Volume sample of peat (left) taken by use of brass cylinder (right). Such volume samples were used as the basis for calculating quantity of peat in the deposits. Figure 8.-Showing shrinkage of peat. Sample of Loxahatchee peat on left was size of brass cylinder before drying and shrinking. 47 48 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY ter of various kinds such as carbon dioxide, ammonia, and hydrogen sulphide. The loss of weight upon drying is, how- ever, usually considered only as water loss and is expressed as air-drying loss or oven-drying loss in the analyses. Many of the Florida peats from the parts of a deposit above water table lose an average of 78 per cent weight when oven dried, and 86 per cent weight is the average lost from peats below the water table. The loss of weight when only air dried is less, averaging 75 per cent above the water table and 82 per cent below the water level. Shrinkage in size of the peat mass upon drying varies a great deal with different types of peat. In general, the moss peats and most fibrous, matted sedge peats shrink least and the sedimentary plastic peats shrink most. Test of some Florida peats, figures 7 and 8, showed that: (1) Everglades saw-grass peat shrank to about 20-25 per cent of its original volume when air dried, Loxahatchee semi-aquatic peat to 10-15 per cent, and woody Gandy peat to about 30-50 per cent; (2) the lake bottom sedimentary peats to about 10 per cent; (3) fibrous mangrove peat to about 40-50 per cent, and (4) the matted strongly fibrous Florahome peat only to about 45-60 per cent. The correlation between shrinkage, loss in volume, and loss of weight upon drying can be roughly estimated by com- paring specific gravities of the wet unshrunken peat and the dry shrunken peat. In general, the peats after drying are of less specific gravity than when saturated with water. For example, wet saw-grass Everglades peat averages 1.09 specific gravity, but this peat when air dried to 15 per cent moisture and usually shrunken to 25 per cent its wet size becomes about 0.69 specific gravity. Similarly, Loxahatchee peat when dried shrinks from an average wet specific gravity of about 1.05 to a dry condition of about 0.75. Florahome peat shrinks less than most Florida peats, changing from a wet specific gravity of 1.06 to specific gravity 0.29 upon drying, also losing 83 per cent in weight, and decreasing 52 per cent in volume. The size and shape of the fibers and small fragments of plants or other organic debris held together in a loose struc- ture peat may be greatly altered upon drying. Once so altered the original texture and structure usually cannot be completely THE PEAT DEPOSITS OF FLORIDA restored by rewetting the peat. For this reason peat once dried usually cannot be made to take up again as much mois- ture as was lost in drying, or return to its original size and shape. Rate of Loss of Weight on Drying The rate of loss of weight of peat during drying is not a steady decline as might be expected if only loss of water was involved. In most samples tested the rate of loss of weight increased during the first few days until a peak rate of loss was reached, then the rate declined rapidly. If the loss of weight had been only a loss of water due to evaporation from the peat the rate of loss of weight would probably have been greatest during the first few days declining in a regular man- ner to a slow rate of loss until the rate became negligible. But since this is not the case other explanations are due. The loss of weight when peat dries, therefore, seems to be due, at least partly, to the biological activities of organisms in the peat. When first extracted the wet peat sample slowly begins to dry, the bacteria and other organisms, particularly those dependent upon oxygen, begin to multiply rapidly as atmospheric oxygen is more and more incorporated in the mass of peat. Consequently the rate of loss increases due to the increased activity of these organisms until finally the peak of their activity is reached and the rate of loss and their ac- tivity both decrease. Carbon dioxide and other gases are liberated by the action of these organisms. No experiments were conducted to prove the presence or activity of these organisms but it is well known that aerobic bacteria increase in peat when air is admitted to it, and in the case of some peats the Actinomycetes become very numerous. Oxidation of the organic matter in the peat results as has been shown by measurements of the increase in CO2. Moreover, the nitrogen, sulphur, and carbohydrate compounds in the peat are also affected by the activity of these organisms. In piles of excavated peat the rate of loss of weight on drying is not due just to water loss or physical and chemical activity. The tests made of drying excavated Everglades saw-grass peat in the open at Twenty Mile Bend on State Highway No. 26 west of Fort Lauderdale indicated that the rate of drying was not similar to the rate of drying of sand or clay that had little organic matter and less organisms. 49 50 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY In general, however, peat loses weight when drying so slowly that difference in rate of loss during different intervals of the drying process are not of particular importance in handling the material. WEIGHT, DENSITY, AND SPECIFIC GRAVITY The differences in structure and composition of peats cause them to vary a great deal in weight, density, and specific gravity. Most of the living plant tissues which contribute to the formation of peat have a specific gravity less than water. The fibers and other tissues, celluloses, lignins, and other substances in the peat are heavier than water-lignin sub- stances averaging 1.4 specific gravity and celluloses about 1.5 specific gravity-but these are usually retained structurally and so arranged that the great porosity makes the peat when dry much lighter than water in all but a few cases. Davis 38 notes the specific gravity of some types of peat: turfyy peat 0.11 to 0.26; fibrous peat 0.24 to 0.67; earthy peat 0.41 to 0.90; and pitchy peat 0.62 to 1.03." Table 2 gives the specific gravity of some of the Florida peats. Inorganic content, usually given as the ash content, and the weight of the materials composing this ash are factors af- fecting weight and volume. Silica sand, particularly, adds weight to many peats in Florida. The swelling and shrinking of peats make volume and weight determination very difficult because of their usually great porosity and colloidal nature. The pore volume in peat, which varies a great deal, can be approximated by the air content of peat in a fresh condition, but at best the volume, weight, and specific gravity measurements are nearly always approximations. Even in the marsh or bog there are seasonal variations in volume and weight related to the air and water content of the peat. Clayton 39 found that the Everglades peat near the Ever- glades Experiment Station, Belle Glade, varied from 17.5 pounds per cubic foot oven-dry at the top 6 inches, to 7.7 38 Davis, C. A., The uses of peat for fuel and other purposes. U. S. Bur. Mines Bull. 16, p. 45, 1911. 39 Clayton, B. S., et al., op. cit. p. 11. Water control in the peat and muck soils of the Florida Everglades. Univ. of Florida. Agr. Exper. Sta. Bull. 378, 1942. THE PEAT DEPOSITS OF FLORIDA TABLE 2 SPECIFIC GRAVITY OF SOME FLORIDA PEATS Field Lab. Region or Area Station Depth Wet Pounds Air Dry Pounds Inches Sp. Gr. Cu. Ft. Sp. Gr. Cu. Ft. EVERGLADES Central part .... E 2 Top 6 1.09 68 0.74 46 E 2 12-18 1.09 68 0.64 40 E 2 24-30 1.02 63 0.55 34 E 3 Top- 6 0.82 51 8.80 50 E 3 12-18 1.02 63 0.76 48 E 3 24-30 1.13 70 0.68 43 E 3 36-40 1.17 72 0.56 35 Southwestern part ............... NT 1 Top 6 0.76 47 0.55 34 NT 1 20-26 0.86 54 0.78 49 NT 1 33-39 0.96 60 0.75 47 NT 3 Top 6 1.00 63 0.73 45 NT 3 20-26 1.00 63 0.94 59 ISTOKPOGA MARSH .............. I 5 Top 6 0.88 55 0.75 47 I 5 12-18 0.81 50 0.70 44 I 5 24-30 0.84 52 0.70 44 I 5 36-40 0.88 54 0.78 49 T 8 Top -12 0.70 44 0.65 41 T 8 14-20 0.84 53 0.72 45 pounds at 43-48 inches, and Waksman 40 found the specific gravity 0.63 to 0.50 for oven-dry peat from saw-grass areas of the Everglades. These figures, show a marked dissimilarity in weight because the weights given by Clayton would indicate a specific gravity range of 0.28 to 0.12, which are much less than those determined by Waksman. Similar attempts to de- termine oven-dry or air-dry specific gravity in this investiga- tion led to similar inconsistent results, mainly because of shrinking or other changes in volume caused by handling. Therefore, specific gravity determinations are not as useful as volume-weight estimates of peat under field conditions. VOLUME AND WEIGHT ESTIMATES The determinations of volume and weight were made by using cylinders of 76.3 cubic inches, or about 1230 cc. The sample thus obtained with the cylinder, figure 7, was first weighed in or near the deposit and then after air drying, the peat in the laboratory, which usually left a moisture content between 10 and 15 per cent, the samples were again weighed. 40 Waksman, S. A., op cit. The peats of New Jersey and their utilization. New Jersey Dept. Cons. and Devel. Geol. Ser. Bull. 55, 1942. 3A- 51 52 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY From these data the pounds per cubic foot, tons per acre for a depth of one foot of both the air-dry and field condition of the peat were calculated. This method of estimating weight per unit volume gave good results some of which are given in Part II. The average Florida peats with not over 20 per cent ash varied from about 10 to 5 pounds per cubic foot, or from about 220 tons per acre foot for the Everglades saw-grass peat to about 100 tons per acre foot for the Lake Apopka marsh peat. All of these volumes and weights estimates were calcu- lated on the basis of air-dry weight and field volume. The wet field weight, which is usually a saturated condition of the peats, was for the Everglades saw-grass peat about 59 pounds per cubic foot or about 1,275 tons per acre foot. These data show that excavating some wet peats involves the handling of about 50 pounds of water in every cubic foot. Air drying peat reduces not only the weight but also the volume because shrinkage is usually great. The amount of shrinkage varies from about one-third to one-twelfth the original volume. Some of the sedimentary mucks and some of the loose texture fibrous peats shrink least. For instance, samples of Everglades and Loxahatchee peats shrank from a volume of 1230 c.c. to 230 c.c. and 180 c.c. respectively when air dried to nearly constant weight. Other peats with a firmer fibrous composition, such as the Florahome peat, shrank to only 410 c.c. from 1230 c.c. The peats with a high ash content lose even more volume than some of the fibrous peats, but there seems to be no general rule about extent of shrinkage for the different types of peat. Other results of shrinkage were previously considered in the discussion of Drying Characteristics. Wet peat in the Everglades saw-grass areas averages be- tween 1400 and 1600 pounds per cubic yard, which when air- dried to about 15 per cent moisture and shrunk to about one- fourth its original size weighs between 600 and 675 pounds per cubic yard. All these estimates of air dry weights and volumes are only approximations. Therefore, for handling the peat the weight per volume under the wet and air-dry conditions should be determined for the peats of each deposit that is to be mined. In general, the more fibrous, light-colored, and poorly de- composed peats are lighter in weight than more compact, plastic, granular, darker, more thoroughly decomposed peats. THE PEAT DEPOSITS OF FLORIDA The light weight peats make more bulk and require more storage and transportation space and are, therefore, usually more costly to handle. But for some purposes the light weight peats are more useful. ATMOSPHERIC AND GAS CONTENT In marshes or bogs covered by water there is very little air in the peat because pore spaces are taken up by water, but as peat dries, particularly if there is much shrinkage or com- pacting, the air content greatly increases. For this reason alternate flooding and drying of marshes causes air to be drawn into and out of the upper layers of peat. This aeration aids in the decomposition processes by promoting the activity of bacteria and by oxidation of the organic materials. Gases are dissolved in the water of peat marshes and bogs. Wet bogs frequently contain besides gases of the atmosphere also some methane and carbon dioxide. There is a little or no oxygen in flooded peat and this oxygen deficiency is probably an important factor inhibiting both the growth of non-marsh or non-bog plants, and the growth of decomposi- tion bacteria. Aeration of the peat by drainage or the occurrence of a natural seasonally low water table causes the air and gas content to change and result in the following: (1) more rapid oxidation and loss of organic compounds; (2) hastening of decomposition; and (3) plants foreign to the wet marsh or bog become established. These conditions are very noticeable in the Everglades and other drained peat areas of Florida. Neller41 found that a carbon dioxide concentration of 8 to 15 per cent was characteristic of Everglades peat soils above the water table. At various depths below the surface he found this concentration less near the surface than near the water table level. The amount of carbon dioxide found was generally balanced by a correspondingly decreased amount of oxygen indicating that respiration of roots and decomposition of peat above the water table was usual. The relative amounts of carbon dioxide and oxygen are also probably influenced by the solubility of carbon dioxide in the soil waters and by the ab- sorption of oxygen in the formation of nitrates. 41 Neller, J. R., Significance of the composition of soil air in Ever- glades peat land. Soil Sci. Soc. America Proc., Vol. 8, pp. 341-344, 1944. 53 54 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY COLOR Peats range from light-yellowish or straw tints through various shades of yellowish-brown, reddish-brown, and dark brown to jet black. Most of the light colored peats become darker when wet and, in general, excavated wet peats change to dark brown or black when disturbed and exposed to air. Where peat soils and peat deposits have been drained and the upper layers have had access to air these layers usually be- come darkened. This darkening is generally due to oxidation of the organic compounds causing an increase in the carbon of the plant debris. Identification or description of peats on the basis of color are common. In some cases, as in the Everglades, the Loxa- hatchee peat is yellowish, the Gandy peat is reddish-brown, and the saw-grass peat is dark brown to nearly black. Color may affect temperature to a slight extent, but its effect is negligible compared to the effect of water content or temperature. Black peats are considered cold soils but this is mainly because they are usually near the surface and are frequently loose and dry. Rarely if ever can color be used as an index to mineral content, but color is used to determine the origin of peat from certain plants. For instance, in some deposits the reddish peats are formed from the roots of the red root plant, Gyro- theca, and the predominantly brown color of some peats is due to one of the sedges of the sedge genus Rynchospora, known as the beak rushes. Similarly, some woody peats of bay-tree swamps are reddish because the bark and wood of bay trees, Persea colors the peat. TEMPERATURE RELATIONS Peat bogs and marshes frequently occur in depressions where the air temperature becomes colder than the surround- ing territory, and peat soils are cold soils because peat soils do not give up heat to the atmosphere as rapidly as mineral soils. For these reasons, low temperatures tend to occur in the layers of atmosphere next to the surface of peat deposits. A wet or moist peat soil allows the movement of heat to take place more rapidly than a dry, loose peat. Therefore, the looser and drier the surface layer the greater is the danger from frosts. THE PEAT DEPOSITS OF FLORIDA These temperature conditions often result in costly frosts in cultivated peat soils when the water table lies well below the surface. In the Everglades some recent minimum temp- erature records by Clayton 42 have been very low for this section with one cold spell as low as 90 F. for March 14, 1932. In general, lower temperatures occur more frequently now than before drainage of the Everglades. Another condition of importance is that the drained but virgin, uncultivated, marsh lands have lower surface tempera- tures than cultivated lands. This is due to the fact that the looser top peat and mulch of leaves and trash on the virgin land act as an insulating cover that retards the transfer of heat from the lower wet peat to the air above, whereas, air over cleared lands obtain more heat from the soils. Also, the more decomposed a peat soil becomes the less is the probability of frost. Consequently, older reclaimed peat areas are less subject to frost than recently reclaimed areas. REACTION OR HYDROGEN-ION CONCENTRATION (pH) Most of the measurements of acidity, alkalinity, and neu- trality of peats and peat soils are now calculated in terms of the hydrogen-ion concentration and expressed by the symbol pH. These conditions of peat are also known as the peat reaction or soil reaction. Most peats have an acid reaction which is in part de- veloped in the deposits because of the type of vegetation forming the peat, the humic acids formed in the peat, and the water and oxygen conditions. The most acid peats are usually those formed from some swamp and heath plants, Sphagnum moss, and sedges like Rhynchospora or Eriophorum. The least acid, neutral, and slightly alkaline peats in Florida are the saw-grass peats of the Everglades and some other deposits where marl occurs. Some organic sediments of lakes, such as those of lakes Apopka and Harris are also calcareous and have an alkaline reaction. The salt-marsh and mangrove swamp peats range from acid to alkaline, the latter depending upon the amount of marl occurring in the deposit. The hard- ness of the water and the associated marls of peat deposits are the main cause of alkalinity in peats. 42 Clayton, B. S., Meteorologist at the Everglades Experiment Sta- tion, Belle Glade, Florida. 55 56 FLORIDA GEOLOGICAL SURVEY---BULLETIN THIRTY Kurz 4 considered the role of mosses in causing acidity in peat that it is probable the peat on which the mosses grew was made more acid by the growth of the mosses. The chemical nature of the plant tissues forming the peat, the humic acids in the peat, and some other conditions in the deposits tend to make the peat material acid. However, the free water in peat marshes or swamps particularly in parts of the Everglades and in mangrove swamps or salt-water marshes may be alka- line even though the peat material is acid. Frequently the wet peat material of alkaline water situations is alkaline but the dry peat of the same situation is acid. The reaction of the peats in each deposit should be determined before use is made of them, especially for azaleas and other acid soil plants. Waksman 4 gave four types of peats and peat soils based on pH values, which are: (1) oxidizing peats which are those having a pH of less than 3.8, the heath plants being the domi- nant type of vegetation forming this peat; (2) reducing peats with an approximate pH of 5.5 to 4.4, the peats formed from a mixed vegetation; (3) feebly oxidizing peats having an ap- proximate pH of 4.4 to 3.4 with vegetation of the highmoor type; and (4) peats feebly oxidizing at times with a pH below 3.4 and the vegetation mainly Eriophorum. But most of these kinds of peats are not common in Florida. The Procurement Division of the United States Treasury classes lowmoor sedge and reed peats into two grades; (1) horticultural, with pH values of 4.5 to 5.5; and (2) poultry litter, with pH values of 5.5 to 7.5. No doubt other com- mercial classifications of peats based on pH values will be de- veloped as peat is more abundantly utilized. The horticultural class is now mainly used with plants prefering acid soils such as azaleas and camellias. From tests made of pH values of most Florida peats table 3 was prepared to show not only the difference in these values of different kinds of peats at different places, but also the difference in pH values at different levels in some deposits. These data show that in most deposits acidity usually de- 43 Kurz, Herman, Influence of Sphagnum and other mosses on bog reactions. Ecology, vol. 9, pp. 56-69, 1928. 44 Waksman, S. A., The peats of New Jersey and their utilization. New Jersey Dept. of Conservation and Development. Geological series Bull. 55, p. 87, 1942. THE PEAT DEPOSITS OF FLORIDA creases from the surface downward in regular fashion in the peat deposits of Florida. In some cases the change from acidity toward alkalinity is rapid near the bottom of the deposit especially if the peat is underlain by marl or lime- stone. For instance, a very wide range of pH was determined by Volk and Bell 45 for a profile of the Brighton peat of the Istokpoga marshes, which was pH 3.8 near the surface and pH 7.0 near the bottom. Also very important is the fact that different peat reactions may occur in different parts of the same marsh area, as is the case in the Clermont marsh. In general, the drained aerated, cultivated peat and muck soils are more acid than the similar undisturbed peats. Summary of PH Conditions of Florida Peats The Everglades peats of three types average; (1) saw- grass peats pH 6.04 to 6.59, (2) Loxahatchee peats pH 5.61- 6.15 and (3) Gandy peats 4.43-4.90. The table shows that: (1) Lowmoor, saw-grass peats are less acid, average pH 5.96, than the lowmoor wet prairie or pond type peats, average pH 4.45; (2) the forest peats are most acid, average pH 4.34; and (3) the sedimentary peats average pH 6.14. When peat soils used for agriculture are more completely classified in Florida it is probable that the reaction charac- teristics, pH values, will determine certain types not yet dis- tinguished. The pH values will affect cultural and fertilizer practice in handling such peat soils. The present distinction between the Everglades saw-grass peat and the Brighton saw- grass peat is based mainly upon the pH values, the Brighton peat being the most acid. The pH values of peats may be determined in the field by the use of some portable apparatus but this method is not very accurate and the results can not be compared to most of the pH data already assembled because most of the past pH measurements have been based on air dried samples and measured with standard laboratory equipment. All the samples in this investigation were air dried and the pH de- terminations made by the Department of soils of the Uni- versity of Florida, Gainesville. 45 Volk, G. M., and Bell, C. E., Soil Reaction (pH), some critical factors in its determination, control and significance. Univ. of Florida Agr. Exper. Sta. Tech. Bull. 400, 1944. 57 58 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY TABLE 3 REACTION (pH VALUES) OF SOME FLORIDA PEATS Depth in Location and Kind of Peat Deposit, Average Range of In Inches pH pH Everglades Saw-grass peat ........................... Top 24 6.04 5.07 6.71 24 60 6.41 6.08- 6.77 60 96 6.59 6.11-7.16 Loxahatchee peat ....................... Top 24 5.61 5.45 5.61 24 60 6.03 5.70-6.23 60 120 6.14 5.90 6.38 Gandy peat ................................. Top 24 4.43 4.17 4.70 24 36 4.90 4.88 4.93 Istokpoga marshes and swamps Brighton peat ................................ Top 24 4.15 3.80 4.50 24 60 4.86 4.70-4.98 60 132 5.65 4.85- 7.00 Istokpoga peat ........................... Top 24 4.40 4.30 4.50 24 36 4.85 4.80-4.90 48 86 4.98 4.75 5.35 86 144 5.67 5.15 6.65 Fellsmere area and St. Johns River marshes Saw-grass peats ......................... Top 24 5.55 5.07 6.12 24 60 5.67 5.30- 6.12 60 120 6.01 5.59 6.22 Lake Apopka marsh Saw-grass peats ......................... Top 24 5.78 ................ 24 60 5.79 ................ 60 180 6.14 ................ Oklawaha River marshes Saw-grass peats ......................... Top 24 4.95 ................ 24 60 5.65 ................ 60 108 6.05 ................ Emeraldo marsh, Lake County Saw-grass peat ........................... Top 24 5.03 ................ 24 40 5.13 ................ Clermont marsh, Lake County Saw-grass peat ........................... Top 24 5.85 ................ 24 60 6.15 ................ Pond-prairie peat .................. Top 24 4.15 ................ 36 84 4.78 ................ Jumper Creek, Sumter County Saw-grass peat ... .................. Top 48 5.93 ................ 60 72 7.21 ................ Florahome, Putnam County Prairie peat ............................. Top 24 4.40 3.91 4.90 24 60 5.44 5.38-5.50 Pinecastle, Orange County Pond-prairie peat ....................... Top 24 4.60 4.40 4.80 24 60 4.85 4.75 4.95 60 228 4.90 4.75-5.08 THE PEAT DEPOSITS OF FLORIDA 59 TABLE 3-(Continued) REACTION (pH VALUES) OF SOME FLORIDA PEATS Depth in Location and Kind of Peat Deposit, Average Range of In Inches pH pH Leesburg Pond-prairie peat .......................... Top 24 3.64 3.50 3.80 24 60 4.52 4.26 4.78 60 132 4.88 4.78- 5.01 Eustis Meadow Pond-prairie peat ...................... Top 24 4.31 ................ 24 60 4.51 ................ Panama City Pond-prairie peat ....................... Top 24 3.69 3.59 3.79 24 60 3.96 3.84- 3.99 60 120 4.42 3.99 4.86 Bayport, Hernando County Salt-marsh peat ......................... Top 36 5.58 ................ 36 60 4.33 ................ Barron River, Collier County Salt-marsh peat ......................... Top 36 5.55 ................ South of Mayo, Lafayette County Bay forest peat ........................... Top 24 3.95 3.81 4.14 24 60 4.11 4.09-4.14 60 84 4.26 4.09 4.44 North of Astatula, Lake County Bay forest peat ........................... Top 24 3.92 3.80 4.15 24 60 4.16 4.06 4.26 60 84 4.48 4.26 4.71 Near Carrabelle, Franklin County Tyty-forest peat ......................... Top 24 3.97 Feather-bed Bay, Jefferson County Tyty-forest peat ......................... Top 24 3.77 ................ Mangrove swamp near Miami Red mangrove peat ................... Top 24 5.50 ................ 24 60 5.00 ................ Mangrove swamp, Key Largo Black mangrove peat ............... Top 24 7.12 ................ 24 60 6.98 ................ Lake Apopka Sedimentary peat ....................... Top 48 5.71 | Lake Harris I Sedimentary peat ....................... Top 48 7.48 | Lake Minnehaha Sedimentary peat ....................... Top 36 5.66 Lake Eustis Sedimentary peat ...................Top 36 5.63 Mud Lake, Marion County - - 1 7.31 Sedimentary peat -........ -......-.......... Top 48 60 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY Heat Values Peat is extensively used for fuel in Europe and its heat values are well known. These heat values, as with most other substances, are usually measured in terms of gram calories (metric system) or British thermal units (English system). To raise the temperature of water from the freezing to the boiling point requires 100 calories for a gram and 180 B. t. u. for a pound, one B. t. u. being equivalent to 252 gram calories. After the boiling point is reached 965 B. t. u. are required to convert one pound of water to steam and 536 calories to simi- larly convert one gram. Most heat values in the United States are expressed in terms of the British thermal units per pound of oven-dry fuel, or of moisetor wet fuel with the percentage of water in the fuel designated. Davis 46 also gives the fuel values in terms of pounds of water evaporated at 212F. per pound of fuel. Using evaporation or steaming test data and B. t. u. the comparisons between the average fuel values of a number of common fuels, ash and water content, are as fol- lows, according to Davis.47 One Pound British Pounds of water thermal units evaporated W ood ...............................-----------------------....... 5,700 ................ 3.4 Peat .....................................------------------------....... 7,165 ................ 4.4 Lignite.................................----------------------....... 7.500 ................ 4.8 Bituminous coal ...................... 11,000 ................ 6.8 Anthracite coal ...................... 14,000 ................ 8.6 This rough comparison shows that peat has heat value comparable with lignite and usually over half as much as anthracite. Florida peats vary a great deal in B. t. u. values because of a wide range of ash content. Averages of 100 samples of Florida peats taken from most deposits of the state are as follows: One Pound Moisture Moisture free Moisture and 15 per cent with ash Ash free B. t. u. Range .......... 3,860 9,150 5,830 10,750 9,440 11,650 B. t. u. Average ...... 6,767 8,454 10,494 46 Davis, C. A., The uses of peat for fuel and other purposes. U. S. Bur. of Mines Bull. 16, pp. 61-62. 47 Davis, C. A. ibid. pp. 58-64. THE PEAT DEPOSITS OF FLORIDA These averages and ranges in heat values of Florida peats include some of the poorest peat deposits as well as the best. A more detailed set of data is presented in other tables (see particularly tables 11, 14 and 15). Although peat fuel may not be extensively produced in the United States as long as there is an abundant supply of coal and petroleum, it has great potential value as a source of heat and power and may be utilized to conserve other fuels. The utilization of peat for heat and power will be considered in detail in Part IV. CHEMICAL COMPOSITION Peats, lignites, and many types of coal are complex mix- tures of more or less decomposed residues of plants, and to a lesser degree of animals and their excreta, with inorganic materials that are usually less than the organic materials. The plants contributing to peat formation are mostly herbace- ous, but some are woody, and all of these are composed of a great variety of chemical substances. Some of these numer- ous constituents of living plants are subjected to microbiologi- cal decomposition almost immediately after death and some parts do not become a part of peat, but most of the con- stituents of these plants do remain in the peat. Some of the plant tissues that contribute to peat formation are the rela- tively hard mechanical and conductive tissues that are gen- erally known as the fibrous or woody parts. The lignins are usually the most important of the carbohydrate substances retained in the peat; other substances are celluloses, hemi- celluloses, proteins, fats, waxes, and gums. The lack of oxygen, due to the abundance of water, the fermentation, oxidation, and reduction of the organic com- pounds, frequently due to bacteria and other decay organisms, and the other processes of decay and decomposition, all bring about changes in the organic constituents as peat is being formed from plant remains. A typical common product of decomposition in peat is humus and humic acids which are not homogenous chemical compounds and whose chemical struc- tures are not well known. A common characteristic of humus and humic acids is their color, brown or brownish-black. These colors are typical of most peats and waters from peat 61 62 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY marshes, bogs, and swamps. The peat humus usually turns darker on exposure to air and may become black. Lignins are generally considered the precursors of humic acids. During the course of humus formation in peat de- posits a process of oxidation (or dehydrogenation) of lignins, and perhaps other substances, forms humic acids which are similar in some respects to the familiar hydroxyquinones of photography. The colloidal nature of humic acid, as well as its characteristic brown color, is important in peat. The fats, waxes, gums, resins, and proteins of plants all contribute to the organic constituents of peats. The relative proportions of these and the carbohydrate substances vary in different layers of the same deposit of peat as well as in different peat deposits. Some of these proportions of organic materials will be discussed later. We will consider the in- organic constituents first. INORGANIC CONSTITUENTS The inorganic constituents of peats are mainly minerals. Some of these minerals were incorporated in the plant tissues, but most of them, especially in peats of high inorganic con- tent, were brought into the deposit in free water and incorpo- rated with organic materials to form the peat mass. These inorganic substances are usually considered the ash content of the peat and the organic substances the combustible portion that is lost upon burning. The usual analysis shows the inorganic content as ash expressed in per cent by weight of the air-dried or oven-dried peat. These ash components are well known but the organic constituents are not well known. Forsee 48 reported that the typical saw-grass Everglades peats, average 10 per cent ash on an oven-dry weight basis. His analyses of these peats gave an average of 3% N., 3% CaO, 0.6% MgO, 0.1% P205, 0.1% K20, 0.1% Na2O, 0.6% A1203, 1.0% Fe20O, 0.003% Mn., and 0.001% copper. The manganese and copper are in such small quantities that they are known as micro or trace elements. Besides these, other trace ele- ments in the Everglades peat and Okeechobee muck are zinc, 48 Forsee, W. T., Recent plant responses to some of the micro ele- ments on Everglades peats. Soil Sci. Soc. of Florida, vol. 2 pp. 53-58, 1940. THE PEAT DEPOSITS OF FLORIDA boron, cobalt, titanium, zirconium, strontium, barium, vana- dium, chromium, nickel, silver, molybdenum, and lead. As shown by Allison and Gaddum 49 some of these trace elements are fairly constant in quantity whereas others are very eratic. The quantities of most of these elements are so low that in many cases they are insignificant except as they concern the proper fertilization of crops raised on peat soils. Copper, manganese, zinc, and boron are the four trace elements now most generally used in connection with the fertility of peat or muck soils. Other analyses of the ash content and many elements rep- resented in peat have been less detailed than those of the Everglades region. Some few of these can be found in the literature although most analyses of minerals are made for farmers and for local purposes and the records of these are buried in the files of numerous laboratories. TABLE 4 PARTIAL ANALYSES OF SOME PEAT AND MUCK SOILS IN FLORIDA, FROM R. E. ROSE Location, Samples Ammonia Phosphoric Potash Lime Iron and Average and Range Acid Alumina Everglades Av. 34 samples 3.10 0.18 0.08 ...... ...... Maximum 4.41 0.53 0.18 ...... Range Minimum 0.44 0.04 0.03 - Fellsmere Av. 7 samples 2.59 0.091 0.046 1.77 1.54 Maximum 3.39 0.180 0.073 2.95 2.80 Range Minimum 1.76 0.024 0.028 0.83 0.71 Lake Apopka Marsh Av. 3 samples 2.66 0.223 0.069 1.96 3.46 Maximum 2.85 0.280 0.078 2.09 5.70 Range Minimum 2.28 0.181 0.060 1.83 1.65 A few of the muck and peat soil analyses, given by Rose 50 are reproduced in table 4 to show mainly the phosphorus, potash, and nitrogen value, and calcium, iron, and alumina 49 Allison, R. V., and Gaddum, L. W., The trace element content of some important soils-a comparison. Soil Sci. Soc. of Florida, vol. 2, pp. 68-91, 1940. 50o Rose, R. E., Analyses of Florida muck soils. Ann. Rept., State Chemist, Tallahassee, Florida, 1917. Rose, R. E., Florida soil analyses. Ann. Rept., State Chemist, Talla- hassee, Florida, 1914, 1919, and 1921. 63 64 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY values are given in a few cases. These elements were con- sidered the main important soil nutrients until some of the trace or micro quantity elements were discovered to be im- portant in crop nutrition. In general, the plants forming peat are richer in phos- phoric acid and potassium than the peat itself and these easily soluble salts when not in organic combination are rapidly leached out as peat is formed or ages. In the deposits calcium usually increases and nitrogen, potassium, and phosphoric acid decrease with depth. INORGANIC ANALYSES Some detailed analyses of peat and in a few instances of the plants which form it, especially the saw-grass plant, Mariscus jamaicensis (Crantz) Britton, of the Everglades, have been made by a number of workers.5- Most of these analyses are of the mineral constituents but there are a few of the organic materials, the latter mainly by Waksman and Stevens. Besides these the United States Bureau of Mines analyses of peat samples taken by Harper and in this investi- gation give the percentages of ash, carbon, hydrogen, oxygen, nitrogen, and sulphur, together with the percentages of mois- ture volatile matter, fixed carbon, and heat values expressed in British thermal units. From the analyses of peats col- lected during this investigation table 12 was prepared to show the proportions of ash, carbon, hydrogen, oxygen, nitrogen, and sulphur on a moisture free basis. From these data and many other analyses given in Part III a few general conclusions may be drawn: (1) the ash contents 51 Waksman, S. A., and Stevens, J. R., Contributions to the chemical composition of peat, I-IV. Soil Sci., vol. 26, pp. 113-137 and 239-252, 1928, vol. 27, pp. 271-281 and 389-398, 1929. Waksman, S. A., The peats of New Jersey and their utilization. New Jersey Dept. Cons. and Devel., Geol. Ser., Bull. 55, p. 67, 1942. Miller, C. F., Inorganic composition of a peat and of the plant from which it was formed. Jour. Agr. Research, vol. 13, pp. 605-609, 1918. Hammer, H. E., The Chemical composition of Florida Everglades peat soils, with special reference to their inorganic constituents. Soil Sci., vol. 28, pp. 1-14, 1929. Dachnowski, A. P., The chemical examination of various materials by means of food-stuff analysis. Jour. Agr. Research, vol. 29, pp. 69-83, 1924. Clayton, B. S., Neller, J. R., and Allison, R. V., Water control in the peat and muck soils of the Florida Everglades. Univ. of Florida Agr. Exper. Sta. Bull. 378, 1942. Harper, R. M., Preliminary report on the peat deposits of Florida. Florida Geol. Survey, 3d Ann. Rept., pp. 197-375, 1910. THE PEAT DEPOSITS OF FLORIDA of different types of peats vary greatly from place to place in the same deposit as well as in different deposits; (2) in the Everglades the peats with low ash content are the woody Gandy peats of tree islands that developed on deep saw-grass and Loxahatchee peats. Loxahatchee peats have intermediate amounts of ash, and saw-grass peats have the greatest ash content; (3) saw-grass marsh peats in general throughout the State have a relatively high ash content because these marshes are characteristically in areas where surface water with sediments frequently flood over the marshes; (4) the fibrous, matted, rush type peats, especially where developed in small ponds or peat prairies, have in many instances the lowest ash content but in some localities their ash content is high; (5) the woody or swamp peats in general have the high- est ash content, especially where the swamps are near rivers or streams and alluvial sediments become incorporated in the peat; (6) sedimentary peats of the sapropel and livermud types contain a high percentage of ash which in many in- stances are over 50 per cent, in which case they are considered mucks and muds. In any deposit, particularly if it is small or shallow, the ash content varies considerably and sampling of different parts and at different depths is advised. If used on a large scale, or for purposes where ash content is important, are planned analyses of ash content should be made of many parts of the deposit. Peats formed from sedge, rush, and grass vegetation are rich in ash because the plants which form them assimilate large quantities of minerals which remain in the plants and thus contribute to the ash content of the peat. The lower parts, rhizomes, and roots of saw-grass have 3.57 per cent ash and these parts contribute most to the formation of saw- grass peat. A few analyses 54 of the saw-grass plants show that on a moisture free basis the ash content varies from 2.7 to 3.7 per cent, whereas the peat in the same area from saw- grass plants varies from 7.8 to 11.2 per cent. These data indi- cate that saw grass peat during its development concentrates the amount of ash. Later we will consider this concentration as an index to rate of peat formation. 54 Analyses number 120 and 121 of this investigation. 65 TABLE 5 CHEMICAL COMPOSITION OF SOME FLORIDA PEATS Everglades Percentage of Dry Material Saw-grass peat Iron Oxide Silica and Lime Magnesia Soda Potash Phosphoric Nitrogen Total Alumina Acid Ash Miller's 52 analyses 2.25 0.83 3.42 0.50 0.19 0.08 0.50 3.18 8.37 Percentage-6rhe Ash Content Feustel and Byers 53 analysesI I I I SiOF2 FeO, CaO MgO NaO P20. Al O TiO KO SO, MnO CO, Saw-grass peat 14.49 2.16 41.21 6.03 0.56 0.94 2.29 0.46 0.39 6.29 0.08 25.25 Sedimentary peat 33.25 8.18 21.52 6.47 0.43 1.02 7.09 0.81 0.35 16.25 0.03 4.34 52 Miller, C. F., Inorganic composition of a peat and of the plant from which it was formed: Jour. Agr. Research, vol. 13, pp. 605-609, 1918. 53 Feustel, I. C., and Byers, H. G., The physical and chemical characteristics of certain American peat profiles: U. S. Dept. of Agr. Tech. Bull. 214, 1930. THE PEAT DEPOSITS OF FLORIDA Miller .5 made the most detailed comparison of inorganic constituents of all parts of saw-grass plants and of four typical samples of saw-grass peat. The transformation from living plant tissues, to peat he concluded, involved no change in silicon dioxide but the other constituents were leached to the following extent: Iron oxide and alumina, 12.2 per cent; lime 24 per cent; soda, 84.6 per cent; phosphoric acid, 70 per cent; and nitrogen 33 per cent. The diatomaceous earths of Florida are mainly peats and mucks and many of these have a high silica content which in some cases is over 50 per cent of the oven-dry weight, or 10 per cent of the wet weight. Similarly some sedimentary peats have a high percentage of silica derived from both diatoms and sponge spicules. Terrestrial waters brought into the peat deposits are frequently rich in minerals which add to the ash content. Highmoor peats of the Sphagnum bogs and heath type may rely partly upon atmospheric water but lowmoor marsh, forest swamp, and aquatic or sedimentary peat deposits de- pend a great deal upon surface water draining into the de- pressions. Therefore, the minerals of the deposits are fre- quently derived from the surrounding territory. Accumulations of marl, calcium carbonate, silicate sands, and some iron and aluminum in clays are common in the lower layers of many peat deposits, especially the lowmoor and sedimentary aquatic peats. Sulphur in peat deposits is derived from a number of sources and may be present in various forms. A considerable quantity of sulphur may be due to the fact that the water fed into the peat deposits contain hydrogen sulphide. Hydrogen sulphide fermentation occurs in some lake and marsh deposits because of bacterial organisms. These sources of hydrogen sulphide cause such an abundance of this evil smelling gas in many peats that this odor is frequently associated with peat. Some sapropel, sedimentary peats, the mangrove and salt- marsh peats, and peats near some springs, as on the Itchtuck- nee River near Blue Hole Spring, have an abundance of sul- phur. 55 Miller, C. F., op. cit. 67 68 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY ORGANIC CONSTITUENTS In the formation of peat the main changes are in the organic composition of the plant materials that form the peat. Only an approximate idea of these organic changes has been obtained from analyses because the rate and degree of de- composition are not well known. In general the disintegration is so slow that the chemically active elements, such as nitrogen, oxygen, and hydrogen, are released more rapidly than carbon which remains in higher concentration in the peat than in the original plant tissues. In the formation of peat (which may be given the formula C62H72024) the cellulose (which may be considered C72H120060) is broken down rapidly producing oxygen and hydrogen combines as water (H20) and carbon, hydrogen, and oxygen combined as various gasses such as carbon dioxide (CO2) and marsh gas or methane (CHJ). The following chemical reaction of cellulose de- composition to peat shows these changes. C72H120060 C6272024 + H20 + CO2 + CH4 (Cellulose) (Peat) (Water) (Carbon (Methane) dioxide) The organic composition of Florida peats are not well known but a few general conditions have been studied. The proportional amounts of carbon, hydrogen, and oxygen do not vary a great deal. When expressed in terms of ratio to hydrogen taken as unity the following ratios of carbon and oxygen for some of the types of Florida peats are: Hydrogen Carbon Oxygen Saw-grass peats 1 10.9 5.3 Swamp or woody peats 1 11.3 6.1 Pond-prairie peats 1 10.4 4.6 Sedimentary peats 1 8.7 4.3 Average 1 10.3 5.0 If the atomic weights of these elements are considered an empirical formula (C8.6H1oO3.3)X can be derived which indi- cates a higher proportion of carbon and less oxygen than in such organic compounds as cellulose (C6Hio005)X. This greater proportion of carbon is to be expected in peats because carbon- ization takes place during the formation of peat. Slow de- composition during the forming of peat causes the celluloses, THE PEAT DEPOSITS OF FLORIDA lignins, and other organic compounds to lose hydrogen and oxygen more rapidly than carbon. This change is indicated in the deep layers of peat deposits. By comparing the ratios of carbon, hydrogen, and oxygen at different depths in the ten peat deposits representing all the Florida types of peats the following ratios to hydrogen were obtained: Hydrogen Carbon Oxygen Top to 36 inches 1 9.9 4.8 36 to 72 inches 1 10.3 4.5 72 to 108 inches 1 10.9 4.2 Since the amount of hydrogen decreases very slightly, less than two per cent from the top to 10 feet, hydrogen is the best element with which to compare the others. During the formation of peat from plant tissues some of the organic constituents, especially the celluloses, decrease rapidly in proportionate quantities, whereas other constitu- ents the waxy substances, lignins and proteins, increase pro- portionately. These latter substances have a higher percent- age of carbon than the celluloses and undergo less decomposi- tion. One set of analyses of Everglades saw-grass plants, both the leaves and shoots above ground and the shoots, rhizomes, and roots underground, indicate some changes from the saw- grass plant to the saw-grass type of peat. In the plant the ratios are: Hydrogen Carbon Oxygen 1 9.2 7.1 In the peat the ratios are: Hydrogen Carbon Oxygen 1 10.9 5.3 These ratios indicate only a slight change from the saw- grass plant to the saw-grass peat, especially the upper, raw layers of peat. In general, hydrogen content decreases very slowly when peat is formed but oxygen content decreases rapidly and carbon content increases slowly. As peat continues to age and become lignite and eventually coal the carbon, hydrogen, and oxygen ratios change. In gen- eral, the lignites have less carbon but more hydrogen and oxygen than the peats. The bituminous coals have more 69 70 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY carbon, about the same amount of hydrogen and much less oxygen than peats. Nitrogen Nitrogen is an important constituent of peat when it is used as a soil for crops or distilled to obtain ammonium sul- phate. The proteins of the plants forming peat probably con- tribute most of the nitrogen. The proteins hydrolize into various amino acids as peat is formed and some ammonia may eventually be formed, but this ammonia nitrogen does not seem to accumulate. In lowmoor peats, viz., saw-grass and Everglades peat, the nitrogen content more than doubles when peat is formed, but in some highmoor peats, viz., bog peat, the nitrogen content decreases with peat formation. Everglades saw-grass plants average one per cent nitrogen and the top layers of Everglades saw-grass peat average about 3.5 per cent nitrogen, both on a moisture free basis. The use of peat to obtain ammonium sulphate has attrac- tive economic possibilities but at present there is an abundant supply and low price of this material because much of it is from coke ovens. Only a small part of the nitrogen in peat is in available form for plant nutrition because most of it is in protein or amino acid form and not in a free state or as nitrates. How- ever, little or no nitrogen need be used in fertilizers applied to peat soils because there is usually enough in available form for plants. TABLE 6 RATIO OF CARBON TO NITROGEN, AND TOTAL NITROGEN, MOISTURE FREE BASIS Per cent Nitrogen Carbon Nitrogen Everglades saw-grass peat Top-6 inches ............................ 1 15.5 3.9 12-24 inches .............................. 1 16.3 3.78 24-26 inches ............................ 1 17.1 3.55 36-64 inches .....................----------------......... 1 20.4 3.0 Florahome peat Top-6 inches ............................ 1 17.7 2.9 12-24 inches ............................ 1 18.0 3.0 25-120 inches .......................... 1 19.4 2.9 Miscellaneous types Top-36 inches .......................... 1 18.0 3.35 36-84 inches ............................ 1 19.7 3.15 60-156 inches .......................... 1 20.2 3.02 THE PEAT DEPOSITS OF FLORIDA In considering the organic compounds of peats the nitro- gen content compared to the carbon content are a good indica- tion of changes taking place in peat formation and aging of peat. The preceding table 6, carbon-nitrogen ratios from some Florida peats indicate the differences in proportions of these two elements with differences in depth in the peat de- posits. These data indicate that the nitrogenous compounds in peats which were originally proteins probably become more rapidly decomposed than some of the high carbon carbohy- drates, such as the lignins and the waxes or tars. In general, there is a decrease of total nitrogen with depth in most Florida peat deposits, but this rate of decrease in nitrogen is not as rapid as the rate of increase in carbon in most deposits. Organic Analyses The analyses of the organic composition of saw-grass plants and Everglades peat by Waksman and Stevens 56 are probably the best of any available about Florida and table 7 re- produces some of these. The ash content, alcohol soluble frac- tion, and lignin fraction increase with depth, but the other components decrease. There is about three times as much ash in the peat as in the saw-grass plant, about four times as much crude protein, and a definite increase in lignin. The most striking difference between the plant and the peat is the great decrease in cellulose and a sharp reduction in hemi- cellulose when peat is formed. These few changes show that TABLE 7 ORGANIC COMPOSITION OF THE SAW-GRASS PLANT AND SAW-GRASS PEAT Percentages of Dry Matter Everglades Q l 8 . Saw-grass peat P M O < U 0 Upper layers 9.85| 22.65 3.03 1.521 1.17 7.10 0.33 44.59 Lower layers 11.59| 20.81 2.39 1.141 1.31 5.96 0.21 48.03 Saw-grass plant 3.73 5.50j 1.04 6.041........ 21.10 29.521 29.98 56 Waksman, S. A., and Stevens, K. R., op. cit., 1928, 1929. 71 72 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY the cellulose and hemicellulose components of the living plant are about 50 per cent, but there is such a rapid decomposition of these when the plant tissues form the peat that deep layers of peat contain only about six per cent. Lignin materials, however, increase with peat formation and with depth in the peat deposits. The sapropel aquatic ooze, and the fibrous peats of Mud Lake were similarly analyzed by Waksm.an and Stevens 57 who found that the top sapropel peat had distinctly more hemicel- lulose and less lignin than the underlying fibrous peat, as shown in table 8. TABLE 8 CONDENSED ANALYSES OF ORGANIC COMPOSITION OF MUD LAKE PEATS Percentages of Dry Matter Depths from g Surface in 3 centimeters 0 0 Uo 5 - 1 60 ......... 21.62 20.00 13.41 29.76 0.14 0.26 60 180 ..... 31.42 15.28 3.28 48.88 0.50 0.86 180 300 ... 12.26 16.34 3.67 57.39 0.73 I 1.25 RATE OF PEAT FORMATION Chemical composition and observations on the rate of formation in deposits are two means of estimating the rate of peat formation. There have been so few observations of de- posits over long periods of time that this method of estimating rate of formation of peat can not yet be accurately used. We must therefore turn to chemical composition to obtain some estimates. Peat formed mainly from saw-grass vegetation in the Everglades probably developed at a fairly constant rate in the deep peat areas because conditions of plant growth, surface water, and other factors do not now vary a great deal. The inorganic constituents of this peat were obtained mainly from the minerals the saw-grass plants were able to incorporate in their tissues. 57 Waksman, S. A., and Stevens, K. R., op. cit., p. 279. THE PEAT DEPOSITS OF FLORIDA The disintegrated and decomposed products of these plants, because of the chemical changes considered above, be- came of different proportions than those in the living plant tissues. Among these inorganic constituents the one probably least changed in this process is silicon dioxide and we may use the percentages of this mineral to get some estimates of the rate of peat formation. Therefore, by comparing the amount of silicon dioxide in the saw-grass plants and in the saw-grass peat a ratio indi- cating the quantity of living plant material needed to form a similar amount of saw-grass peat can be determined. This was done by Miller.58 In his detailed analyses he found that there was an average of 0.3 per cent silicon dioxide in the saw- grass plant tissues and an average of 2.2 per cent in saw-grass peat. These proportions indicated, according to Miller: "As- suming that no silica was lost during the transformation, about 7 parts of saw-grass was required to yield 1 part of peat." If from this data we assume 7 parts of saw-grass to form 1 part of peat then some estimate of the rate of forming of a given quantity of peat may be obtained if the weight of saw- grass cover and rate of its growth were determined. To esti- mate these a number of observations and calculations were made as follows. Particular measured areas where saw-grass grew sparsely, densely, and in medium abundance, and of short, medium and tall size were chosen and the plants cut down and underground parts excavated to include what seemed to be all living parts, six areas of saw-grass growth were measured and they aver- aged 4.4 tons of plant parts air dry weight per acre, tops and underground parts included. The silicon dioxide of these plant parts would weigh 270 pounds. From many samples the weight of peat per acre one foot deep in saw-grass peat areas of the Everglades was estimated at 180 tons on an air dry basis. This peat would contain approximately 7,520 pounds of silicon dioxide. Therefore nearly 28 crops or generations of saw-grass plants would be required to form the average acre of peat one foot thick. 58 Miller, C. F., Inorganic composition of peat and of the plant from which it was formed. Jour. Agri. Research, 13: 605-609, 1918. 73 74 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY We have as yet not satisfactorily determined how much saw-grass plants grow per year, how much they die back per year and are replaced by new growth, and other data needed to determine how many years per crop of 4.5 tons per acre. From preliminary observations it seems probable however that 6 to 10 years are required per crop, or 8 years average. At this rate of plant growth approximately 225 years are re- quired to form one foot of saw-grass peat. This estimate by chemical ratios may give much too rapid a rate of peat formation because it would indicate that the 10 feet thick peat of the northern part of the Everglades required only about 2,250 years to develop. This peat, however, has probably not developed continuously without interruption. In fact layers of ash below some peat were found along the Miami Canal when it was being dredged indicating fires. These fires and other adverse conditions may have retarded the rate of peat formation. Geologically the Everglades peats seem to be younger than the age of Wisconsin glaciation because most of them rest on Lake Flirt marl which is considered of Recent origin. Also to date no pollen of plants of a glacial age have been found in these peats. The estimate of 2,250 years for the formation of 10 feet of peat is, however, probably the minimum time of formation, a longer period of 5,000 years or even 10,000 years would be more nearly in accord with estimates of the age of other de- posits of similar thickness. Further investigations will be needed to more accurately fix the time involved in peat forma- tion. Other information regarding age of peat deposits is given in Part IV. Archaelogists 59 have found wooden artifacts of Indian villages probably inhabited during the early Spanish explora- tions which were buried under peat. Peat occurs over parts of Indian Mounds in the Everglades and other places. The evi- dences of the age of the mounds are not however conclusive and the age of the peat can not be accurately determined. 59 Cushing, F. H. Preliminary report on the explorations of ancient Key-dweller remains on the Gulf Coast of Florida, 1897. Reprinted Proc. Amer. Philosophical Soc. 36: p. 36. THE PEAT DEPOSITS OF FLORIDA MICROBIOLOGICAL NATURE Bacteria, other fungi, and various other microorganisms inhabit peat deposits and have a great deal to do with the formation, nature, and composition of peats. These bring about: (1) the primary breakdown of the parts of plants, and some animals and excreta transforming them into peat; (2) the gradual changes that take place in the composition of the peat with time causing differences in successive layers; and (3) some rapid changes in peat after a deposit is drained and exposed to more air, or the peat material is excavated and dried. In general the organisms and effects are as follows. Organisms concerned in (1) are mainly aerobic bacteria which decompose cellulose and other organic compounds and aid in the rapid changes that occur in plant and some animal tissues when peat is being formed. The organisms of (2) occur in layers of peat which have little or no oxygen and are mostly anaerobic bacteria which may be found in peat layers laid down many centuries ago. These cause some of the changes pointed out above that take place with increase in depth. As peats continue to age oxygen content decreases most rapidly, the carbon content increases slowly and the hydrogen content decreases only slightly and some of these changes are caused by these anaerobic organ- isms. There is, moreover, a fairly definite change in the ratio of nitrogen to carbon the relative amount of the carbon in- creasing with age and depth. The organisms of (3) are numerous bacteria, mostly aero- bic, Actinomycetes and other fungi, which in general cause rapid decomposition which can be calculated by measuring the rate of CO2 evolution, as Neller 60 did in the Everglades. The relative abundance of these organisms in a lowmoor peat deposit are shown in table 9, which was borrowed from Waksman and Stevens.61 60 Neller, J. R., Significance of the composition of soil air in Ever- glades peat land. Soil Sci. Soc. America, 8: 341-344, 1944. 61 Waksman, S. A., and Stevens, K. R., Contribution to the chemical composition of peat: V. The role of microorganisms in peat formation and decomposition. Soil Science 28: 315-340, 1929, 34: 95-113, 1932. 4- 75 76 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY TABLE 9 OCCURRENCE OF MICROORGANISMS IN A LOWMOOR PEAT PROFILE On Basis of Fresh Peat Material 0 d W. 0 o S oS 30 4......... 6.0 72.5 350,000 40 250 + ++ ++ 45 .............. 6.2 82.3 450,000 25 175 ........ ++ ++ 60 Suae.......... 6.3 87.5 40,000 20 150 ........ + + + 75 ........... 6.3 87.1 35,000 25 33 ........ + ++ 90 ........... 6.4 80.8 20,000 15 ............ ........ .......... + + 120 ........... 6.7 83.6 100,000 2 ............ ........ .......... + + + 150 ........... 6.8 84.5 500,000 .... ............ ........ ....... ++++ 165 ........... 8.0 64.8 200,000 .... ............ ........ .......... ++++ Clay bottom + designates a few; ++ a fair number; +++ abundance of organ- isms; ++++ numerous (about 25,000 more colonies formed by 1 gram of material. Soil microbiological studies of many kinds have shown the importance of these microorganisms in peat and muck soils as well as in peat deposits. The microorganisms are now con- sidered very important in handling peat either as a soil or as a material. The study of bacteria of nitrification and denitri- fication in peat soils is becoming more and more important. The addition of bacteria, usually by adding stable manure, frequently has a favorable effect upon decomposition and ni- trification. The utilization of peat for preparation of com- posts, for soil improvement and other agricultural purposes will be benefitted by a better knowledge and use of the micro- organisms. It is also entirely probable that bacteria and some other organisms may be used to good advantage in the preparation of some industrial products from peat. In fact some recent work in Germany using peat with CaCN2 has indicated that bacteria added to peat may help increase its proportion of carbon and make it more useful as a fuel. The origin of coal from peat is due in part to the action of anaero- bic bacteria producing lignite then bituminous coal. THE PEAT DEPOSITS OF FLORIDA 77 This very brief account of microorganisms in peat only suggests their importance in any investigation of peat re- sources and their use. For further information the reader is referred to Waksman 62 and others who have outlined the subject more thoroughly. Some of these uses will be con- sidered briefly in Part III, especially as they concern the preparation of peat for soil applications and in fertilizers. 62 Waksman, S. A., The peats of New Jersey and their utilization. New Jersey Dept. of Cons. and Devel., Geological Series Bull. 55, 1942. 78 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY Part II FLORIDA PEATS AND PEAT DEPOSITS The peat resources of Florida had not been adequately estimated when this investigation was undertaken although Harper 63 had made a good preliminary report concerning them, and Soper and Osbon 64 had included some statistics about them, and Vernon 65 recently gave some figures concern- ing the mining and uses of peat. This investigation undertook to locate most of the large areas of peat of possible com- mercial quantity, or peat lands for possible agricultural use that are not now so used. The main purpose was to obtain some estimates of the quantity of the peat in the deposits. In this part of this report the kinds of peat will be described and we will give analyses of samples, estimates of quantity, and de- scribe the main deposits. Later in Part III the utilization of the peats obtained from some of these deposits will be con- sidered in more detail. Analyses of samples of peat from these deposits were made to furnish data for the estimates of quality, and as one means of distinguishing the different kinds of peats. The analyses will probably prove useful in any present and contemplated uses of peat because they give data about chemical and water conditions and heat values. METHODS OF SAMPLING, TESTS, AND ANALYSES OF PEAT In the field observations were made of the structure, tex- ture, color, water conditions in the deposit, depth and extent of the deposit, and vegetation. Where the areas were drained the condition of canal banks and top soil layers were studied if they were present. For the numerous tests and analyses many samples were taken mainly by the use of three kinds of equipment: (1) a 63 Harper, R. M., Preliminary report on the peat deposits of Florida. Florida Geol. Survey 3d Ann. Rept., pp. 197-375, 1910. 64 Soper, E. K. and Osbon, C. C., The Occurrence and Uses of Peat in the United States. U. S. Geol. Survey, Bull. 728, 1922. 65 Vernon, R. 0., Florida Mineral Industry. Florida Geo. Survey, Bull. 24, 1943. THE PEAT DEPOSITS OF FLORIDA shovel or spade; (2) a Hiler peat sampler; and (3) a brass cylinder measuring about four inches by six inches, volume .0422 cubic foot or about 1230 cubic centimeters. The Hiler or Swedish peat sampler was the standard equipment for getting Figure 9.-Hiler peat auger which was used to take most samples below the water table, 79 80 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY samples at definite depths with very little or no mixing or contamination. A Davis peat sampler was also used in some instances for the same purpose, but it was not as satisfactory an instrument. An Ekman dredge was used to get the surface of lake and pond sediments. The usual practice followed in the field was: (1) samples were obtained with the brass cylinder at intervals of one foot to as great a depth as water and work conditions would permit so as to furnish data about volume-care was taken to keep disturbance of the structure and water content at a minimum; (2) excavation with the shovel or spade to visually examine the structure, texture, color, stratification, and other easily noticed characteristics; and (3) use of the Hiler peat sampler, figure 9 to obtain samples at greater depths than the other implements could be conveniently used. In deep water areas an Ekman dredge was used to get the surface of the deposit, and a Hiler sampler was used to get samples below the sur- face. In all cases observations as to the water level in the peat deposit were made if the water was below the surface. If the water was above the surface the depth of the water was measured. The volume samples of peat taken with the brass cylinder, figure 7, were in most cases weighed on the spot or within a few hours after being taken; thus very little water had drained off or evaporated. These samples were later weighed after they had been thoroughly air dried to a nearly constant weight. From these data the water lost on drying, and air dry tons per acre one foot thick were calculated. Parts of the samples collected by all methods were used for the analyses by the United States Bureau of Mines, Coal Analysis Section, Pittsburg, Pennsylvania. Their Coal- Analysis Report for each of these samples gave a Proximate Analysis showing moisture, volatile matter, fixed carbon, and ash in per cent all calculated under four conditions: (1) air dry; (2) as received; (3) moisture free (oven dry); and (4) moisture and ash free. Similarly an Ultimate Analysis gave hydrogen, carbon, nitrogen, oxygen, sulphur, ash and also the British thermal units. One of these reports of an analysis of peat from the Triangle Area in the Everglades is given in THE PEAT DEPOSITS OF FLORIDA table 11 to illustrate the above, and in tables 12 and 13 a tabu- lation of analyses of Florida peats is given and arranged ac- cording to counties. KINDS OF PEATS, AND SOME MUCKS As a result of the field observations, inspection and tests of samples, and the analyses, the kinds of peats in Florida were classified. This classification is based upon the scientific classification outlined in Part I. Three main types are recog- nized: (1) Lowmoor, marsh peats; (2) Swamp forest, woody peats; and (3) Aquatic, allochthonous, sedimentary peats found mainly in open water parts of lakes. The names of some of these peats and mucks are those proposed by soil surveyors who have classified most of the main types in the Everglades and adjacent regions of south- ern Florida; especially the soil classification by the U. S. Soil Conservation Service.66 Other names used here are given by the author and these are entirely temporary names used for convenience in classi- fication. The following outline is not a complete classification or description of these peats and mucks. A few of the main characteristics of some of the most wide spread peats are described below, and the sedimentary peats are considered in some detail in description of lake deposits. TABLE 10 OUTLINE OF KINDS OF FLORIDA PEATS AND MUCKS I. MARSH OR LOWMOOR PEATS. A. FIBROUS. Sedge, reed, and some moss types, varying from turfy to nearly plastic; coarse to finely fibrous within which mass usually is finely divided detritus forming a matrix material; frequently occurring in layers. Mostly Autochthonous. 1. SAW-GRASS PEAT. Composed mainly of coarse fibers with rhizomes and roots of saw-grass usually distinct; with matrix material usually abundant; light-brown to nearly black, be- coming dark rapidly upon drying; reaction neutral to medium acid, pH range 7.0 to 4.0, very widely distributed in many saw-grass marshes, especially the Everglades. 66 See particularly Gallatin, M. H. and Henderson, J. R., Progress re- port on the soil survey of the Everglades. Soil Sci. Soc. of Florida, vol. 5-A, pp. 95-104, 1943. . 81 82 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY a. EVERGLADES PEAT. Coarsely fibrous with more matrix material than most saw-grass peat; often with lenses or layers of plastic peat or muck, or with marl layers; in some areas finely fibrous; Loxahatchee peat interbedded or below this peat; reaction pH 7.0 to 5.5. Name used for saw-grass peat of the Everglades and adjacent regions. b. BRIGHTON PEAT. Saw-grass peat with a high percentage of other plants forming a coarsely fibrous peat that is in some parts reddish-brown, and with some woody fragments; more acid than Everglades peat, pH 7.0 to 3.8. Name used spe- cifically for peat in Istokpoga marshes. c. MARSH PEAT. General name for all other saw-grass marsh peats; varying from coarsely to finely fibrous, and some matted fibrous; light brown to dark, nearly black; occurring in many marshes usually bordering hard water lakes. 2. PRAIRIE AND POND PEAT. A dark brown, matted, fibrous, firm peat, developed in numerous small ponds and some broad fcPt prairie-like areas, often in deep deposits, distinctly acid, PpH range 3.5 to 5.5. One of the best horticultural peats be- cause it is acid and usually easily handled. a. FLORAHOME PEAT. Coarse and fine fibered, matted with leaves of aquatic plants common, firm, and shrinks very little upon drying, retaining brown color. Typical locality is de- posit near Florahome, Putnam County. b. POND PEAT. More finely fibrous and matted than Florahome peat, light to dark brown, shrinks some upon drying, acid, good for horticulture. Found in many seasonally flooded ponds, deposits often deep. In some deposits a slick, greasy diatomaceous peat is associated. c. PRAIRIE PEAT. Turf-like to finely, matted fibrous. Deposits usually shallow. d. WOODY POND-PRAIRIE PEAT. Mixed matted fibrous pond and prairie peat with woody fragments, development in bay- tree swamps which developed over fibrous peat. 3. SALT-MARSH PEATS. Many kinds not yet distinguished. Usually coarsely fibrous with roots and rhizomes of salt- marsh plants common; with silts and clays in matrix, marls and shells common; gray to nearly black; in some areas mixed with mangrove peats; reaction usually alkaline. B. FIBROUS AND PLASTIC. Fine fibrous, loose texture peats with much plastic material in matrix; not firm, shrinking greatly on drying and losing shape easily; straw colored to nearly black. Occurring in many marshes below fibrous peats. Partly allochthonous. 1. FIBRO-PLASTIC MARSH PEAT. Many kinds not named; usually in beds below fibrous peat; few fibers and much sedi- mentary material varying from sands to muds; color very varied. 2. LOXAHATCHEE PEAT. Local name applied to nearly plastic, matted, fine fibrous, loose texture peats of the Everglades sloughs and ponds; also found below saw-grass Everglades peat in some areas; straw-colored to brown; reaction pK range 6.5 to 5.0^ THE PEAT DEPOSITS OF FLORIDA II. FOREST SWAMP PEATS AND MUCKS. A. WOODY. Varying from partly decomposed logs, stems, and woody fragments to granular, pulpy, and flaky debris associated with both plastic and fibrous materials; if much plastic ma- terial known as a muck. Some deposits of banded and bedded appearance; frequently developed on top of the Fibrous peats or the Aquatic peats. 1. BAY PEATS AND MUCKS. Reddish woody pieces mixed with fibrous to granular and some plastic materials; if very plastic known as muck; often on top of fibrous marsh peats; but frequently very shallow over sand, in which case often has top with Sphagnum moss and fern tussocks. Occurring in many widely scattered small bay-tree swamps of numerous types. Reaction usually acid, pH range 5.0 to 3.6. a. GANDY PEAT. Local name for fibrous, woody, duff-like mix- ture occurring in the bay-tree islands of the Everglades region. Material reddish-brown; pH range 5.0 to 4.0; often developed on top of Everglades or Loxahatchee peats. b. ISTOKPOGA PEAT AND MUCK. Local name for mucky peat with many pulpy, wood fragments, reddish-brown to nearly black, occurring in the bay-gall swamps near Lake Istokpoga; pH range 5.0 to 4.0; some deposits deep. c. TYTY-BAY PEATS AND MUCKS. Sandy, matted fibrous peats and mucks; in some areas with Sphagnum moss peat developed in thin layer on top. Seldom in deep deposits. 2. MANGROVE AND BUTTONWOOD PEATS AND MUCKS. Marls usually associated. Many kinds of very fibrous to plastic peats and mucks usually with shells, marl, and other sediments associated; developed in coastal, saline, mangrove swamps; three kinds partly distinguished. a. RED MANGROVE PEAT AND MUCK. An interlocking net- work of fibers of the roots of the red mangrove forming a firm mass; between the fibers a matrix of mud, marls, shells etc.; alkaline to slightly acid, pH range 7.2 to 5.0; usually in outer zone of swamp, or below the black mangrove, or salt-marsh peats. b. BLACK MANGROVE PEAT AND MUCK. Less fibrous more plastic than red mangrove peat; less reddish color and some yellowish woody fragments; usually with marls, shells, sand in places. Often developed on top of red mangrove peat. c. BUTTONWOOD PEAT OR DUFF-HUMUS. A leafy, fibrous, flaky, duff-like peat usually developed in buttonwood zone of swamps or some coastal hammocks. B. PLASTIC AND WOODY. Many kinds of swamp peats and mucks; names given usually those of dominant trees of the deposits; mostly muds with some woody fragments, very little fibrous material. 1. RIVER SWAMP MUCKS, only a few peats. Many kinds not differentiated. Alluvial materials, plastic and sandy, with logs and other woody parts, finely divided organic materials; usually dark gray to black. 2. CYPRESS AND GUM SWAMP MUCKS AND PEATS. Many kinds not differentiated. Plastic and woody; often sandy, some fibrous; seldom in deep deposits. 83 84 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY 3. OKEECHOBEE MUCK. Mostly plastic, sticky and greasy, granular, dark-gray to black, but with some woody materials; derived from custard-apple swamps and sediments from Lake Okeechobee; forming a zone around much of region near Lake Okeechobee, and a layer in saw-grass peat. A fine farming soil of the northern Everglades. 4. OKEELANTA PEAT-MUCK. Plastic and Fibrous; mixture of Okeechobee Muck and Everglades Peat; occurring in zone between pure deposits of these two. III. SEDIMENTARY, PLASTIC, AQUATIC PEATS AND MUCKS. Many organic sediments generally formed in lakes or other quiet bodies of water. Usually fine particled, macerated, plastic and often colloidal; mostly allochthonous. Variously classified as many kinds of lake sediments; name bioliths now applied. A. ORGANIC. Organic sediments rich in ignitable carbonaceous ma- terial; may be considered peats if over 50 percent loss on ignition of oven dry material. 1. GYTTJA. Fine detritus, amorphous material usually more soup- like than colloidal; black or gray-brown to greenish; no or very little H S; some nitrogen, very little humic acid; many kinds have been recognized; algal gyttja; marly gyttja; and diatomaceous gyttja, Florida kinds not yet differentiated. 2. SAPROPEL. Slimy ooze-like, more colloidal than gyttja, more decaying organic matter; usually with H9S. Algal sapropel of Mud Lake typical. 2. DY. Humus type in some places partly fibrous, often colloidal, amorphous. 4. LIVER MUD. Gel-like, very colloidal, similar to sapropel. B. MOSTLY MINERAL. Non-ignitable Peats, Mucks, and Earths; mainly marls and diatomaceous earths; usually distinctly plastic. Marls gray to whitish; diatomaceous earths gray to reddish. 1. MARLY-MUCKS. Mostly mucks not peats, plastic but some with fibrous peat, dry to gray, granular. 2. DIATOMACEOUS EARTHS. Mostly peat like with some fibers, usually with slick, greasy feel, drying to brown or gray color, occurring as layers in fibrous peat deposits. This outline is so sketchy that a few general conditions and characteristics of peats and the vegetation of peat areas need some consideration. Many marsh lands, wet prairies, borders of many lakes, borders and central portions of some ponds, deposits of some swamps, and some layers of peat below forest peats are of the lowmoor types. Most of the Everglades peat lands, the Istokpoga marsh lands, the Fellsmere and upper St. John River marshes, the Lake Apopka marsh, some of the Okla- waha River marshes some parts of the Peace Valley Drainage THE PEAT DEPOSITS OF FLORIDA District, and the areas near Florahome, Putnam County, are the largest of the lowmoor peat areas. They comprise over three-fourths of Florida peat deposits. Most inland forest peats do not occur in large areas because they are usually developed in only a few non-alluvial swamps being mainly developed in bay-tree, tyty, and some cypress , forests, most of which are of relatively small size. The larg- est tyty and bay-tree forests of northern and western FloridaK usually contain some peat but the deposits are only a few inches deep, except in some small areas. The bay-gall swamps of Lake Istokpoga, and near the marshes of the Peace Valley Drainage District are among the largest of these inland forest peat areas. The mangrove swamps along the southwest coast of the peninsula contain deep forest peat in some places but this peat is seldom pure being mixed with shells, marl, sand, and other sediments. The sedimentary, plastic, aquatic peats are organic de- posits in some of the numerous lakes, but probably do not occur in thick layers in the majority of the lakes. The depth and area of these usually collodial, macerated, mud-like peats are unknown except in a few lakes that have been studied. It is possible that the total quantity of these peats may exceed that of the forest peats. They should be distinguished from the marsh or lowmoor peats common in marshy parts of many lakes and ponds, or in some instances covering the small lakes or ponds, but in numerous instances it is difficult to distinguish between lowmoor and aquatic peats. For this reason some peats, i. e., the Loxahatchee peat of the Everglades, is con- sidered a semi-aquatic or semi-marsh peat, both fibrous and plastic. Typical highmoor peats formed in bogs from heath shrubs, Sphagnum moss, ferns, and other plants are not now being formed in large quantity in Florida. Both the Sphagnum moss and some heath shrubs occur in quantity in some bay-tree and tyty forests, or in parts of the pine flatwoods. The mats of Sphagnum and peat are, however, seldom over a few inche deep. A few of the bay-tree swamp peats and some pond or prairie peats, especially where ferns are common, are, how- ever, sold as moss peat because they are loose, fibrous, light weight and strongly acid. 85 86 FLORIDA GEOLOGICAL SURVEY-BULLETIN THIRTY In general, the physical and physico-chemical characteris- tics which are most useful in describing peats are; color, tex- ture, homogeneity, water content, pH values, and the ash content. The weight, compactness and other structural fea- tures of peat are also used in distinguishing types. For a detailed consideration of these characteristics the reader should refer to Part I, and to the Analyses to follow later. BURIED PEATS, PRELIMINARY Nearly all the organic deposits classed as peat are on or near the surface, or they occur as strata below only a few feet of other materials, marls, sands, mucks, and clays. Some shallow to deeply buried carbonaceous deposits do, however, occur in Florida that are peats or derivatives of peats. Since the recent increase in well drilling in Florida many of these buried layers of carbonaceous material are being dis- covered. Some layers are so little altered that they are still raw, fibrous peats, but others are lignites, sapropelites, and perhaps bituminous coal. The samples of these buried carbonaceous materials come from some sedimentary strata of fairly definite geologic age and, therefore, are of importance in determining the geology of Florida. The most significant of these are described in Part IV. The kinds of such materials is of secondary importance. In the U. S. Navy Cecil Field well (W-581), Duval County the deposit is a lignite about 57 feet thick. In many wells, however, there are only streaks, or even just stains, of car- bonaceous materials in the limestone and dolomite. There are a few definite layers of sapropelite probably derived from sedimentary peats, but on the whole lignite is the most common material. VEGETATION OF PEAT AREAS The marsh or lowmoor peats, swamp or woody peats, and aquatic or sedimentary peats nearly all originated from dis- tinctive kinds of vegetation composed of certain definite peat forming plants. These plants vary from place to place and usually the variations in the conditions of water level are the most frequent cause of the differences in both the vegeta- tion and the kind of peat. In many instances, the plants that THE PEAT DEPOSITS OF FLORIDA formed the peat have persisted as the vegetation of the present peat deposits, but in some cases where drainage has altered water conditions the plants growing on the deposits have changed. Over the Florida deposits those plants that are most abundant are usually definitely indicative of a certain type of peat, at least the upper layers of the peat, and the type of peat can frequently be identified by the kind of vegetation. For this particular reason it is useful to know some of the plants of the peat deposits. In the following brief descriptions of the vegetation of Florida peat areas we will consider only a few of the typical and abundant plants because a full description of the botany of each kind of peat deposit would occupy too much space. The same general classification of peats as follows: (1) low- moor peats and mucks of marshes and wet prairies; (2) forest or woody peats of swamps; and (3) aquatic peats and organic sediments of lakes, ponds, and some rivers, will be used to describe the vegetation of: (1) marshes; (2) swamps; and (3) open water habitats, each type of vegetation being re- lated to the above three general types of peat respectively. MARSH VEGETATION The marsh and wet prairie plants forming lowmoor peats are mainly sedges, rushes, grasses, a few reeds, a number of other herbs, and some broad-leaved aquatic and semi-aquatic pond and marsh plants such as water-lilies, pickerel-weeds, arrow-heads, and arums. Nearly all these plants are provided with rhizomes, fibrous roots, and frequently succulent under- water or under-ground organs. These submerged parts form a mass of matted and interlocking plant parts that contribute most to the peat material. The above-water and above-soil parts do not contribute very much to the peat that is forming. In Florida there are four main types of vegetation which cover the marsh and wet prairie areas whose plants form dis- tinctly different peats, these are: (1) the saw-grass or sedge marshes, of which the Everglades is an example; (2) the rush marsh or wet prairie vegetation forming such peats as the Florahome type; (3) the broad-leaved aquatic or flag marshes and ponds usually forming a flag peat, or muck, or a plastic peat; and (4) the salt-marsh vegetation composed of 87 |
|||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| MILLISECOND | CLASS.METHOD | MESSAGE |
|---|---|---|
| 0 | sobekcm_page_globals.constructor | |
| 0 | sobekcm_page_globals.constructor | Application State validated or built |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.constructor | Navigation Object created from URI query string |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.display_item | Retrieving item or group information |
| 0 | sobekcm_page_globals.get_entire_collection_hierarchy | Retrieving hierarchy information |
| 0 | sobekcm_assistant.get_entire_collection_hierarchy | |
| 0 | cached_data_manager.retrieve_item_aggregation | |
| 0 | cached_data_manager.retrieve_item_aggregation | Found item aggregation on local cache |
| 0 | item_aggregation_builder.get_item_aggregation | Found 'all' item aggregation in cache |
| 0 | system.web.ui.page.page_load (ufdc.page_load) | |
| 0 | sobekcm_page_globals.constructor.on_page_load | |
| 0 | html_echo_mainwriter.add_style_references | Adding style references to HTML |
| 0 | html_echo_mainwriter.add_text_to_page | Reading the text from the file and echoing back to the output stream |
| 52 | html_echo_mainwriter.add_text_to_page | Finished reading and writing the file |