|
![]() |
|
| UFDC Home |
myUFDC Home | Help | RSS
|
|

HIDE
| Front Cover | |
| Title Page | |
| Letter of transmittal | |
| Table of Contents | |
| Main | |
| Back Cover |
CITATION
SEARCH
THUMBNAILS
PAGE IMAGE
ZOOMABLE
|
||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Full Citation | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
STANDARD VIEW
MARC VIEW
|
||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Table of Contents | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
Front Cover
Front Cover 1 Front Cover 2 Title Page Title Page 1 Title Page 2 Letter of transmittal Page i Table of Contents Page ii Main Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Back Cover Page 15 Back Cover 2 |
||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| Full Text | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
STATE OF FLORIDA DEPARTMENT OF NATURAL RESOURCES Elton J. Gissendanner, Executive Director DIVISION OF RESOURCE MANAGEMENT Jack Woodard, Director BUREAU OF GEOLOGY C. W. Hendry, Jr., Chief Special Publication No. 22 FLORIDA: THE NEW URANIUM PRODUCER By John W. Sweeney and Steve R. Windham Published by BUREAU OF GEOLOGY DIVISION OF RESOURCE MANAGEMENT FLORIDA DEPARTMENT OF NATURAL RESOURCES in cooperation with UNITED STATES DEPARTMENT OF THE INTERIOR BUREAU OF MINES From a presentation at the 1979 AIME Annual Meeting, New Orleans, Louisiana, February 18-22, 1979. TALLAHASSEE 1979 35-11 3s 22 ~tFLAA H'iTO; STATE OF FLORIDA DEPARTMENT OF NATURAL RESOURCES Elton J. Gissendanner, Executive Director DIVISION OF RESOURCE MANAGEMENT Jack Woodard, Director BUREAU OF GEOLOGY C. W. Hendry, Jr., Chief Special Publication No. 22 FLORIDA: THE NEW URANIUM PRODUCER By John W. Sweeney and Steve R. Windham Published by BUREAU OF GEOLOGY DIVISION OF RESOURCE MANAGEMENT FLORIDA DEPARTMENT OF NATURAL RESOURCES in cooperation with UNITED STATES DEPARTMENT OF THE INTERIOR BUREAU OF MINES From a presentation at the 1979 AIME Annual Meeting, New Orleans, Louisiana, February 18-22, 1979. TALLAHASSEE 1979 DEPARTMENT OF NATURAL RESOURCES BOB GRAHAM Governor GEORGE FIRESTONE Secretary of State BILL GUNTER Treasurer RALPH D. TURLINGTON Commissioner of Education JIM SMITH Attorney General GERALD A. LEWIS Comptroller DOYLE CONNER Commissioner of Agriculture ELTON J. GISSENDANNER Executive Director LETTER OF TRANSMITTAL Bureau of Geology Tallahassee October 12, 1979 Governor Bob Graham, Chairman Florida Department of Natural Resources Tallahassee, Florida 32304 Dear Governor Graham: The Bureau of Geology, Division of Resource Management, Department of Natural Resources, is publishing as its Special Publication No. 22, "Florida, The New Uranium Producer." The data presented indicate that Florida may soon produce approximately 15 percent of the United States' domestic requirements for uranium. This information should be of substantial interest to agencies or individuals involved with energy planning or assessment. Respectfully yours, Charles W. Hendry, Jr., Chief Bureau of Geology CONTENTS Page A abstract ....................................... Introduction ..................................... Geology of Florida Phosphate ......................... Resources and Reserves ............................. Present Activity .................................. R eferences ..................................... ILLUSTRATIONS Figure 1 Geologic time scale for the Cenozoic Era ................. 3 2 Distribution of phosphate in Florida .................... s TABLES Table 1 Wet-process phosphoric acid production capacity .......... .11 2 Total identified resources of phosphate rock in recoverable product tons by grade and cost ................. .............. 12 3 Announced uranium recovery from Florida ores ............. 13 FLORIDA: THE NEW URANIUM PRODUCER by John W. Sweeney and Steve R. Windham Abstract Florida is usually thought of as a vacation State, not a mining State, yet Florida has been the leading producer of phosphate rock in the United States for 85 consecutive years and in 1978 supplied over 80 percent of the national output and over 30 percent of the world's output. It is estimated that the Central and South Florida phosphates contain 412,800 short tons (374,000 metric tons) of U308, that 115,000 short tons (104,000 metric tons) of U308 will be contained in the wet-process phosphoric acid processed in the United States through the year 2000, and that 54,000 short tons (49,000 metric tons) of U308 will be available from Florida. In 1978, two companies in Florida and one in Louisiana went on-stream recovering uranium oxide from wet-process phosphoric acid and three others started construction of U308 extraction facilities. These six companies will have the capacity to recover 2,137 short tons (1,900 metric tons) of U308 annually in 1980, which will account for about 15 percent of our domestic requirements. Introduction Florida is usually thought of as a vacation State, not a mining State, yet Florida is the leading producer of phosphate rock in the United States and in 1978 supplied over 80 percent of the national output and over 30 percent of the world's output. These phosphates contain a significant amount of uranium. The potential for Florida to become a major uranium producer is great since very large resources of uranium are contained in Florida's phosphate resources, and the spot market price of uranium oxide $40+ per pound - makes extraction from wet-process phosphoric acid economically attractive. In this paper we will briefly discuss the geology of occurrence of uranium in Florida phosphate, the reserves and resources, and the potential for Florida to become a major uranium producer. Geology of Florida Phosphate Most phosphate rocks are uraniferous, and their uranium content generally increases with the phosphate content. Marine phosphate is the dominant source of phosphate and constitutes a very large resource of uranium (1). Therefore, we must look to the occurrence of marine phosphate for the origin of Florida's uranium. Sixty-five million years ago, the Florida peninsula existed as a part of a much broader plateau, the Floridan Plateau, which consists of the present peninsula and a broad shelf, now submerged, of equivalent size extending the length of the State and out into the Gulf of Mexico. This Plateau was separated from the mainland United States by the Suwannee Straits, which trended northeast from the Gulf (Apalachicola River delta area) through south Georgia to the Atlantic. To the south of the Suwannee Straits existed an environment similar to today's Bahama Banks with calcium and magnesium carbonates and associated evaporites being deposited. Shallow warm waters prevailed over the Floridan Plateau. Where circulation and oxygenation occurred, teeming numbers of marine organisms lived and pure carbonates were deposited. Where circulation was restricted, evaporation caused supersaturation of saline waters, which resulted in meager faunal assemblages and deposition of evaporites. There was little encroachment of other geologic environments into the Florida Plateau except during the Oligocene and Lower Miocene time (see Figure 1) when longshore currents transported progressively increasing amounts of fine quartz sands from the northern Gulf and intermixed these clastics with the carbonates along the western half of the present peninsula. Additionally, traces of phosphate were deposited through the Lower Miocene, signaling more profound changes to come. At the end of the Lower Miocene Epoch, significant geologic changes occurred. The Suwannee Straits ceased to exist, and the continuity of the Florida Peninsula with the mainland United States was reestablished. Sediment-laden streams, developed from higher elevations to the north, transgressed southward over the Florida Peninsula, shifting laterally back and forth as their deltas developed and matured. The long shore current from the northern Gulf developed much transport energy since currents were diverted from entering the Suwannee Straits and thus moved southward along and over the Peninsula, transporting quartz sands and clays. This commingling of two major geologic sedimentary environments (carbonate and clastic) resulted in the deposition of a geologic unit, the Hawthorn Formation; this is characterized by its heterogeneity. The Lower Hawthorn is generally dominated by carbonates, although all are impure, having varying amounts of insoluble silts and clays intermixed with occasional sand or clay lenses. Very rare fossil material signifies the near-total extinction of the prolific faunas that existed earlier in the purer carbonate environment. The Upper Hawthorn becomes sporadically more clastic with a resulting maze of intertonguing lensoidal units of limestones, sands, and clays typically intermixed, but with occasional pure clay units representing isolated low-energy depositional systems. Faunally the Hawthorn is quite sparse; however, there occur scattered fossil oyster bars, attesting to the lower salinities of the fresh water-marine water interface. In contrast to the heterogeneity of the Hawthorn Formation is the persistent occurrence of one chemical component phosphate. Throughout the Hawthorn, with rare exceptions, phosphate occurs as small, rounded, tan-to-black grains, commonly referred to as phosphorite, intermixed with all the other sediment types in the Hawthorn. The chemistry of the Hawthorn phosphorite is similar to that of the Bone Valley phosphate; however, the P2 O content is generally lower. Percentages of phosphorite occurrence are highly variable; however, 2 to 10 percent would be common, 10 to 30 percent uncommon, and over 30 percent rare. This variability is encountered both vertically and laterally, not only between lithologic units but also within a single lithologic unit. It is generally true, however, that the higher Era Period Epoch Approximate Dates (Years Before Present) Cenozoic Quaternary Tertiary Recent Pleistocene Pliocene Miocene Oligocene Eocene Paleocene 12,000 2,000,000 12,000,000 25,000,000 38,000,000 55,000,000 65,000,000 I I Figure 1. Geologic time scale for the Cenozoic Era. i phosphorite percentages occur rarely in the carbonate matrix, occasionally in the clays, and commonly in the quartz sands. The origin of phosphate in the Hawthorn is not well known. The precipitation from marine waters is the accepted hypothesis. Investigators have attributed this reaction to the upwelling of cold phosphorus-rich waters from depth spilling over the shallow warm continental shelf with the resulting chemical reaction precipitating phosphate. Where there is no direct evidence of the causal mechanism for the upwelling of deeper marine waters, the Middle Miocene sedimentary and faunal record strongly suggests crustal movement and changes in current regimes that could accommodate the companion deep-water upwelling. Whatever the origin of the phosphate, the mechanism has distributed phosphate throughout the Hawthorn Formation, which occurs over three- quarters of peninsular Florida (Figure 2) with an average thickness of approximately 200 feet. Following the Middle Miocene Epoch, much of peninsular Florida was in an emergent condition during the Late Miocene and Pliocene. From the standpoint of phosphate occurrence, the Upper Miocene- Pliocene was probably not a time of primary phosphate formation, but rather a time of redistribution and concentration of phosphate. Marine sedimentary units deposited around the margins of the emergent plateau in east, south, and northwest Florida during Upper Miocene-Pliocene time do not record any continuation of the phosphate deposition characteristic of the Middle Miocene. The Bone Valley Formation overlies the Hawthorn Formation and consists of quartz sands, clays, phosphate "pebbles," phosphorite, and a prolific and diverse assemblage of marine and terrestrial vertebrate fossils. The concentration of phosphate in the Bone Valley Formation probably took place due to a variety of circumstances that may or may not be related to the Ocala Uplift to the north. The Ocala Uplift area is a positive area exposing carbonate rocks of Eocene and Oligocene age (1). The richest of the marine deposits have been concentrated or enriched by secondary processes. The Bone Valley Formation was formed by submarine reworking of a phosphate-rich residuum. Leaching related to Pleistocene and modern weathering has further upgraded the deposits. Phosphorite in the Bone Valley Formation of Florida ranges from 6 to 7 feet in thickness over several hundred square miles and averages 0.012 to 0.024 percent U308 and 20 to 30 percent P205s (2). To the south of the Ocala Uplift is the Upper Miocene-Pliocene Bone Valley Formation. The high concentrations of phosphate in this unit are ascribed not to the continuation of phosphate deposition past the Middle Miocene, but to the reworking and concentration of preexisting phosphate. It is believed this basin received phosphates derived from partial erosion of the emergent Hawthorn Formation, from erosion of the Ocala Uplift to the north, and from the reworking of the Hawthorn in situ by wave action in the basin. Within the Bone Valley Formation, the P20s content is higher in the northern areas (Polk-Hillsborough counties) and diminishes to the south (Manatee-Hardee- DeSoto counties), indicating an enrichment from the north. - OCALA UPLIFT SALACHUA FOR m BONE VALLEY HAWTHORN FC MATION FORMATION IRMATION 0 I0 20 30 40 50 MILES Figure 2. Distribution of phosphate in Florida. These four geologic occurrences, the Hawthorn Formation, the Bone Valley Formation, the hardrock phosphate along the Ocala Uplift, and the Alachua Formation or residual Hawthorn Formation, as the case may be, account for the occurrence of commercial deposits of phosphate in Florida. Resources and Reserves Uranium is associated with the phosphorite and occurs in minerals of the Apatite group, Cal o(P04CO3)6(F,OH,CI)2. The structure of apatite is such that small quantities of V04, AsO4, and SO4 substitute for P04; Na, Sr, U, Th, and the rare earths may substitute for Ca (3). It is the uranium content of these phosphorites that we are interested in. The Florida land pebble marine phosphate deposits contain from 0.012 percent U308 and average 0.015 percent (4). As of this writing, we do not have extensive data on specific deposits. An assessment of this type is currently being conducted by a contractor to the Department of Energy to assess the reserve and resources of uranium by specific deposit. It is anticipated that the study will be completed in 1979. The phosphate deposits from the Hawthorn Formation of North Florida contain lesser amounts of uranium and average 0.006 percent. These deposits are probably too low grade to currently be considered for uranium extraction from wet-process phosphoric acid. For the purpose of this paper, we will consider only the phosphate from Central and South Florida as containing sufficient uranium oxide to be economically recoverable. Uranium oxide is recovered from Florida phosphates as a byproduct of wet-process phosphoric acid production. Therefore, to determine uranium oxide production potentials we should also look at the production capacity of wet-process phosphoric acid and the current trend to increase production of wet-process phosphoric acid. Table 1 lists those companies in Florida manufacturing wet-process phsophoric acid, with a forecast to 1980 (5). However, let's first look at the theoretical availability of uranium oxide from Florida phosphates in the Central and South Florida area. How much U308 is contained in the phosphate rock? We have established that the Central and South Florida phosphorites contain an average of 0.015 percent U308 or 0.3 pound/short ton (0.33 pound/metric ton) of phosphate rock. The current phosphate reserve figures for Central Florida are 1,499 million short tons (1,400 million metric tons) recoverable at $15 to $20 per short ton (6). In broad terms, 224,850 short tons (204,000 metric tons) of uranium oxide are contained in the Central and South Florida phosphate reserves. If we include the additional 1,253 million short tons (1,100 million metric tons) of identified subeconomic resources, this would add an additional 187,950 short tons (171,000 metric tons) of uranium oxide, for a total of 412,800 short tons (374,000 metric tons) theoretically available from the Central and South Florida phosphate deposits. By present technology and economics, however, only the uranium oxide contained in the phosphate rock that is processed into wet-process phosphoric acid is economically recoverable. Table 1 lists twelve (12) companies and their capacities to produce wet-process phosphoric acid in Florida and Louisiana. As a rule of thumb, for our purposes, a pound of U308 is recoverable per ton of P205 occurring in phosphates of the Central and South Florida area. Table 1 shows a capacity to produce wet-process phosphoric acid of 4,710,000 short tons (4,273,000 metric tons) P205s in 1978 less the North Florida capacity; therefore, 2,355 short tons (2,100 metric tons) of U30s would theoretically be available for recovery (excluding recovery loss). The Department of Energy estimates that approximately 115,000 short tons (104,000 metric tons) of U308 will be contained in the wet-process phosphoric acid processed through the year 2000 (7). This figure includes all the wet-process phosphoric acid plants in the county, whereas we estimate that approximately 54,000 short tons (49,000 metric tons) of U308 will be available from Florida through the year 2000 based on Table 1 production capacities. If the capacity to produce wet-process phosphoric acid increases in the period 1980-2000, then additional U308 would be available for recovery. There are indications that this will be the trend (8). Present Activity To date, byproduct uranium oxide production in the United States has been modest, amounting to less than 1,000 short tons (907 metric tons). With projected increasing demand for uranium and correspondingly higher prices, byproduct sources of uranium oxide, especially that from phosphates, are receiving increased attention, particularly in Florida. The recovery of uranium oxide from wet-process phosphoric acid has become more attractive as the price of uranium oxide increases and as technology improves. As we have pointed out, the Central and South Florida phosphate deposits contain more uranium oxide than other domestic phosphate rock; therefore, the wet-process phosphoric acid made from this phosphate rock is an attractive source of uranium oxide. The Uranium Recovery Corp. (URC) completed in 1976 an $8 million complex at Mulberry, Florida, to extract uranium using its own solvent extraction process from wet-process phosphoric acid. The URC concept is to split the process into two phases, with only the initial solvent extraction and stripping operation at the phosphoric acid plant site. The stripped uranium oxide solution from the first phase is transported by truck to a central processing plant where the second solvent extraction and stripping step produces specification-grade uranium oxide concentrate. This approach has the advantage of requiring simplified "modules" at phosphoric acid plants; the more complex but smaller scale downstream processing is accomplished at a single centrally located facility (2). The first shipment of 19 short tons (17.2 metric tons) of U308 was made in 1978, and URC plans to construct additional modules at other wet-process phosphoric acid plants. The present recovery capacity of URC from the W. R. Grace module is 300,000 pounds (136,000 kilograms) of U30s annually. During 1978, several additional companies announced plans to recover uranium from wet-process phosphoric acid and to build facilities. International Minerals and Chemicals Corp. (IMC) has received permits to build a uranium recovery facility at its New Wales chemical plant in Polk County and has started construction. The company announced that it plans to recover 625,000 pounds (284,000 kilograms) of uranium annually, with the plant going onstream in 1980. In addition, IMC will recover 1.2 million pounds (545,000 kilograms) of uranium annually from C. F. Industries' two wet-process phosphoric acid plants in Polk and Hillsborough counties in Florida. IMC will recover "crude yellow cake" from the wet-process phosphoric acid stream and ship it to its New Wales facility for refining into yellow cake. The two C. F. Industries' "feeder" plants, costing $20 million, are scheduled to go onstream in late 1980, about one year after IMC's New Wales plant will be completed. With the new feeder plants, IMC's production capacity of uranium yellow cake from Florida phosphate will be about 2 million pounds (909,000 kilograms) annually. The sales end has also been bright. IMC has entered into a long-term contract with Florida Power and Light Co. (FPL) to supply about one-third of its uranium fuel needs through 1992. IMC will recover the uranium as yellow cake from its New Wales chemical complex near Mulberry. The yellow cake will be refined to uranium hexafluoride by Kerr-McGee in Oklahoma and Allied Chemicals in Illinois. The FPL agreement with IMC calls for a minimum of 400,000 pounds (182,000 kilograms) of uranium oxide annually, worth over $200 million over the life of the contract. In addition, the Tennessee Valley Authority (TVA) signed two long-term contracts with IMC for about 10 percent of TVA's total uranium needs through 1992. The agreements involve about 850,000 pounds (386,325 kilograms) of uranium oxide annually, with a total value over $400 million. Wyoming Minerals Corp., a subsidiary of Westinghouse Electric Corp., has constructed a uranium oxide recovery facility at Farmland Industries' phosphoric acid complex near Bartow. Plans are to recover about 450,000 pounds (205,000 kilograms) of U3 08s. The plant went onstream in August 1978. Gardinier, Inc., announced plans to build its own uranium oxide recovery plant at its East Tampa operations. The $15 million plant will produce 425,000 pounds (193,000 kilograms) of uranium oxide annually and is scheduled to begin operations in March 1979. In addition, Freeport Chemical Co., which ships phosphate rock to its phosphoric acid facility in Louisiana, announced it will recover 690,000 pounds (313,605 kilograms) of uranium oxide annually at its Uncle Sam, La., facility. Agrico Chemical Co. also ships Florida phosphate rock to its wet-process phosphoric acid facility at Donaldsonville, La., and has entered into an agreement with Freeport Chemical Co. to make a primary uranium oxide extraction from the Donaldsonville facility and then ship it to its Uncle Sam, La., facility for secondary refining into yellow cake. About 400,000 pounds (182,000 kilograms) of uranium oxide will be recovered, and the recovery unit is expected to go onstream in 1980. Agrico is evaluating uranium oxide recovery technology at its South Pierce, Fla., facility and expects to make a decision in early 1979 as to recovery plans. Capacity of the facility is 300,000 short tons (272,000 metric tons) of P2 0s per year. The remaining uncommitted wet-process phosphoric acid operations are all evaluating uranium recovery technology and are expected to announce their commitments. To date, reserve and resource data on all uranium oxide from Florida phosphate have been based on published estimates of phosphate rock and the industry's capacity to produce wet-process phosphoric acid. In 1977-78, the Bureau of Mines, under its Minerals Availability System (MAS), contracted to develop data on each known phosphate deposit in Florida. This study for the first time has assembled reserve and/or resource data on 108 specific deposits. Table 2 presents the data developed under this program. Let's summarize what we have been talking about and assess Florida's potential as a uranium producer: 1) There are 1,499 million short tons (1,400 million metric tons) of phosphate reserves, which contain 224,850 short tons (204,000 metric tons) of U308. In addition, there are 1,253 million short tons (1,100 million metric tons) of identified resources containing 187,956 short tons (171,000 metric tons) of U30s for a total reserve and/or resource from Central and South Florida of 412,800 short tons (374,000 metric tons) of U30s theoretically available. Considering present technology, only the uranium oxide contained in the phosphate rock going into wet-process phosphoric acid will be available for recovery. 2) The Department of Energy estimates that 115,000 short tons (104,000 metric tons) of U308 will be contained in the wet-process phosphoric acid processed in the United States through the year 2000. Of this amount, it is estimated that 54,000 short tons (49,000 metric tons) will be available from Central and South Florida; much of the remainder will come from Florida phosphate ores processed at other locations. 3) We can estimate the annual potential availability of uranium oxide from Florida in two ways. First, let's look at the wet-process phosphoric acid production of 4,710,000 short tons (4,273,000 metric tons) P2Os in 1978 (Table 1); since we have established that 1 pound U30s/ton P20s was recoverable, 2355 tons (2,100 metric tons) of U38O is recoverable from wet-process phosphoric acid in Central and South Florida. Another approach would be to look at the phosphate rock going into wet-process phosphoric acid from Florida in 1977. This was 22.4 million tons (20.2 million metric tons). All of this rock was not processed in Florida, however; some went to Louisiana, where there is also uranium oxide extraction. Therefore, 3,360 short tons (3,000 metric tons) of U308 is available from Florida phosphate rock converted to wet-process phosphoric acid. Subtracting the phosphate rock used in North Florida, 2,355 short tons (2,100 metric tons) is available from Central and South Florida. We have now looked at availability in two ways in terms of the wet-process phosphoric acid production capacity and in terms of the amount of Florida phosphate rock going into wet-process phosphoric acid and have come up with the same figure 2,355 short tons (2,100 metric tons). We have been dealing in theoretical amounts. What we must look at is who is doing what or who plans to do what. Table 3 lists those companies that have announced their intentions to recover uranium oxide from wet-process phosphoric acid, either in Florida or outside Florida, but from Florida ores. We see that in the early 1980's Florida will be producing 1,593 short tons (1,400 metric tons) of uranium oxide, and if we include those ores going to Louisiana, a total of 2,137 short tons (1,900 metric tons) will be produced, leaving about 218 short tons (198 metric tons) available for recovery. If we assume that our national consumption of uranium oxide will be about 14,000 short tons (1,270 metric tons) in 1980, then Florida will supply over 11 percent of the national demand. If we look at the broader picture of the uranium recovered from Florida rock, then Florida would supply 15 percent, a significant contribution to our Nation's energy requirements. References 1. Cathcart, James B., and R. A. Gulbrandsen. United States Mineral Resources, Phosphate Deposits. Geol. Surv. Prof. Paper 820, 1973, pp. 515-525. 2. Finch, Warren I., Arthur P. Butler, Jr., Frank C. Armstrong, and Albert E. Weissenborn. United States Mineral Resources, Uranium. Geol. Surv. Prof. Paper 820, 1973, pp. 456-467. 3. Work cited in reference 2. 4. Woodmansee, Walter C. Minerals Facts and Problems, Uranium. BuMines Bulletin 667, 1975, pp. 1177-1199. 5. Harre, E. A., M. N. Goodson, and J. D. Bridges. Fertilizer Trends, 1976. Tennessee Valley Authority, Bull. Y-111, March 1977, 44 pp. 6. Zellars-Williams, Inc. Evaluation of the Phosphate Deposits of Florida Using the Minerals Availability System. BuMines Open File Report 112-78, June 1978, 196 pp. 7. U.S. Department of Energy. Statistical Data of the Uranium Industry. GJO-100 (78), January 1, 1978, 91 pp. 8. Stowasser, W. F. Phosphate Rock 1977. Mineral Industry Survey, March 15, 1978. TABLE 1.-Wet-process phosphoric acid production capacity (thousand metric tons P2 Os, followed by thousand short tons P2 Os) Agrico Chem-Williams Borden Chemical Co. C. F. Industries, Inc. Engelhard M&C-Con. Ser. Farmland Industries Freeport Minerals Gardinier Grace & USS Agri-Chem. W. R. Grace & Co. International Minerals Royster Co. USS Agri-Chem. Pierce, Fla. Donaldsonville, La. Piney Point, Fla. Bonnie, Fla. Plant City, Fla. Nichols, Fla. Pierce, Fla. Uncle Sam, La. Tampa, Fla. Bartow, Fla. Bartow, Fla. New Wales, Fla. Mulberry, Fla. Bartow, Fla. Fort Meade, Fla. Total Central Florida . . . . . . . . . . . T otal .. . .. ... .. .. .. .. .. .. .. .. .. .. . 1974 245 270 159 175 580 640 227 250 136 150 413 455 680 750 494 544 299 330 122 135 82 90 160 176 2,917 3,215 3,597 3,965 1975 272 300 363 400 159 175 580 640 567 625 136 150 413 455 680 750 494 544 299 330 680 750 122 135 82 90 160 176 3,964 4,370 5,008 5,520 1976 272 300 363 400 159 175 626 690 567 625 136 150 413 455 680 750 494 544 299 330 680 750 122 135 82 90 160 176 4,010 4,420 5,053 5,570 1977 272 300 363 400 159 175 626 690 567 625 136 150 413 455 680 750 494 544 345 380 299 330 680 750 122 135 160 176 4,273 4,710 5,316 5,860 1978 272 300 363 400 159 175 626 690 567 625 136 150 413 455 680 750 494 544 345 380 299 330 680 750 122 135 160 176 4,273 4,710 5,316 5,860 1979 272 300 363 400 159 175 626 690 567 625 136 150 413 455 680 750 494 544 345 380 299 330 680 750 122 135 160 176 4,273 4,710 5,316 5,860 1980 272 300 363 400 159 175 626 690 567 625 136 150 413 455 680 750 494 544 345 380 299 330 680 750 122 135 160 176 4,273 4,710 5,316 5,860 TABLE 2.-Total identified resources of phosphate rock in recoverable product tons by grade and cost (million metric tons, followed by million short tons) Location Northern Florida Cost per short/metric ton of product <$15 $15-$20 3.94 280.19 $20-$25 $25-$30 $30-$35 560.61 288.08 115.27 $35-$40 4 $40 12.70 7.26 Product Total grade, (million) percent BPL 1.268.05 4.o35 30U8.6 617.97 317.56 127.07 14.00 8.00 1,397.81 66.4 Central Florida Polk County 339.28 281.02 0.18 8.89 1.38 630.77 374.00 309.78 0.20 9.80 1.53 695.31 68.9 Hillsborough County 45.36 27.22 86.09 8.74 7.26 1.81 176.47 50.00 30.00 94.90 9.63 8.00 2.00 194.53 71.4 Sub-Total I 384.64 308.24 86.09 8.92 16.15 1.38 1.81 807.24 424.00 339.78 94.90 9.83 17.80 1.53 2.00 889.84 69.4 South Florida DeSoto, Manatee, & Sarasota Counties Hardee County Sub-Total II Total I + II Total Florida 406.78 448.40 260.36 287.00 667.14 735.40 384.64 975.38 424.00 1,075.18 388.59 1,255.57 428.35 1,384.04 162.96 214.09 179.60 236.00 167.82 183.70 185.00 202.50 330.74 397.79 364.60 438.50 416.83 406.71 459.50 448.33 977.45 694.89 1,077.47 765.89 54.43 60.00 73.87 81.45 128.30 141.45 144.46 159.25 259.73 286.32 70.03 - 77.20 - 21.77 73.48 24.00 81.00 91.80 73.48 101.20 81.00 93.18 75.29 102.73 83.00 105.88 82.55 116.73 91.00 908.26 1,001.20 781.03 860.95 1,689.30 1,862.15 2,496.54 2,751.99 3,764.59 4,149.80 1,268.05 TABLE 3.-Announced Uranium Recovery from Florida Ores Company Farmland Industries Gardinier International Minerals & Chemical Corp. C. F. Industries modules Uranium Recovery Corp. (W. R. Grace modules) Florida Subtotal: Agrico Chemical Co. (Donaldsonville, La.) Freeport Chemical (Uncle Sam, La.) Outside Florida Subtotal: Total from Florida Phosphate Rock: Announced U308 Production Capacity 450,000 lb 204,000 kg 425,000 lb 193,000 kg 750,000 lb 340,000 kg 1,260,000 lb 571,000 kg 300,000 lb 136,000 kg 3,185,000 lb (1,593 short tons) 1,444,000 kg (1,445 metric tons) 400,000 lb 181,000 kg 690,000 lb 313,000 kg 1,090,000 lb (545 short tons) 494,315 kg (494 metric tons) 4,275,000 lb (2,137 short tons) 1,939,000 kg (1,938 metric tons) Date Onstream Aug. 1978 Mar. 1979 1979 1980 1978 1982 1978 DEPARTMENT OF NATURAL RESOURCES BUREAU OF GEOLOGY This public document was promulgated at a total cost of $152.75 or a per copy cost of $.15 for the purpose of disseminating information on the development of the State's natural resources. IP Li-3'I.T'O a fl H,.S.I To - |
||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| MILLISECOND | CLASS.METHOD | MESSAGE |
|---|---|---|
| 0 | sobekcm_page_globals.constructor | |
| 0 | sobekcm_page_globals.constructor | Application State validated or built |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.constructor | Navigation Object created from URI query string |
| 0 | sobekcm_database.verify_item_lookup_object | |
| 0 | sobekcm_page_globals.display_item | Retrieving item or group information |
| 0 | sobekcm_page_globals.get_entire_collection_hierarchy | Retrieving hierarchy information |
| 0 | sobekcm_assistant.get_entire_collection_hierarchy | |
| 0 | cached_data_manager.retrieve_item_aggregation | |
| 0 | cached_data_manager.retrieve_item_aggregation | Found item aggregation on local cache |
| 0 | item_aggregation_builder.get_item_aggregation | Found 'all' item aggregation in cache |
| 0 | system.web.ui.page.page_load (ufdc.page_load) | |
| 0 | sobekcm_page_globals.constructor.on_page_load | |
| 0 | html_echo_mainwriter.add_style_references | Adding style references to HTML |
| 0 | html_echo_mainwriter.add_text_to_page | Reading the text from the file and echoing back to the output stream |
| 16 | html_echo_mainwriter.add_text_to_page | Finished reading and writing the file |