Directions for industrial use of aerosols

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Material Information

Title:
Directions for industrial use of aerosols
Physical Description:
4 p. : ; 27 cm.
Language:
English
Creator:
Yeomans, A. H ( Alfred Henry ), 1908-
United States -- Bureau of Entomology and Plant Quarantine
Publisher:
U.S. Dept. of Agriculture, Agricultural Research Administration, Bureau of Entomology and Plant Quarantine
Place of Publication:
Washington, D.C
Publication Date:
Edition:
Rev.

Subjects

Subjects / Keywords:
Aerosols -- Industrial applications   ( lcsh )
Insect pests -- Control   ( lcsh )
Genre:
federal government publication   ( marcgt )
non-fiction   ( marcgt )

Notes

General Note:
Caption title.
General Note:
"E-835, Revised."
General Note:
"October 1953."
Statement of Responsibility:
by A.H. Yeomans.

Record Information

Source Institution:
University of Florida
Rights Management:
All applicable rights reserved by the source institution and holding location.
Resource Identifier:
aleph - 030338464
oclc - 780534798
System ID:
AA00025238:00001

Full Text

October 1953 LIBRARY E-835, Revised
STATE PLANT BOARD

United States Department of Agriculture
Agricultural Research Administration
Bureau of Entomology and Plant Quarantine




DIRECTIONS FOR INDUSTRIAL USE OF AEROSOLS

By A. H. Yeomans
Division of Stored Product Insect Investigations



Aerosols are used in many industrial structures to control insects
by direct contact or by applying a light deposit of insecticide on the top
of exposed horizontal surfaces.
An aerosol is composed of a number of fine liquid particles suspended
in the air. It is considered that in an insecticidal aerosol all the particles
should be smaller than 50 microns in diameter and 80 percent (by weight)
of them should be less than 30 microns. Vapors or smokes composed
of particles less than 0.1 micron in diameter are not classed as insecti-
cidal aerosols because they exhibit slightly different characteristics.
Aerosols may be produced by liquefied-gas formulations released
through capillary or expansion-chamber nozzles, by steam or air
atomization of liquid, by spinning disks and rotors, by forcing liquid
under high pressure through atomizing nozzles, by heat vaporization,
or by a combination of these methods.
A wide range of particle sizes can be produced, and the size of the
particles has a great influence on the effectiveness of the aerosol. The
particle size determines the time the aerosol remains suspended in the
air and therefore the amount of dispersion by air currents throughout
the enclosure. The particle size is a critical factor influencing the
amount that collects on an insect as it flies through the aerosol. If the
particles are too small, they are deflected from the flying insect as
smoke is from a moving automobile, but they will settle out on the insect
while it is at rest if the exposure time is adequate. If they are too large,
they settle rapidly and their dispersion is poor; therefore their chance
of contacting the insect is also poor. When an insect does collide with
an oversized droplet, the excess insecticide is wasted.





-2-


Settling Rate and Dispersion

Aerosol particles tend to settle vertically at a rate related to their
size. The time required for oil particles to settle 10 feet is given
below.


Diameter
in microns Time

1 ------ 26 1/2 hours
5 ------ 72 minutes
10 ------ 19
15 ------ 15


Diameter
in microns


Time


20 ------ 5 minutes
30 ------ 2
50 ------ 45 seconds
100 ------ 11


Water droplets settle slightly faster. The lateral dispersion of
aerosols is accomplished by air currents after the small impetus from
the atomizer is expended. Aerosol particles will not be conveyed into
dead-end cracks or into materials through which air does not circulate.
As would be expected, small particles disperse laterally to greater
distances than do larger ones, as they are suspended in air for a longer
time. In unheated buildings air currents are at a minimum, but heating
sets up convection currents that are a great aid to dispersion. In some
cases it is necessary to aid dispersion with large-volume air blowers.
Table 1 shows the dispersion of aerosols of various particle sizes in an
unheated room with a ceiling height of 8 feet.

Table l.--LaLeral dispersion of aerosols of various particle
sizes released at the ceiling level in an unheated room
8 feet high


Percent of particles of indicated
Feet from mass median diameter
source --
5 microns 15 microns I 25 microns 45 microns

0 28 43 66 84
10 25 40 29 15
20 20 13 4 Trace
30 10 4 Trace
40 7 Trace
50 5
75 4
100 Trace





-3-


Deposit

About 95 percent of an aerosol settles on the top of horizontal sur-
faces, and the remaining 5 percent on the walls and ceilings. The
amount of deposit on a horizontal surface depends on the concentration
of the aerosol directly above that surface. Therefore, if the aerosol is
evenly dispersed throughout a room, the deposit will be proportional to
the distance of the surface from the ceiling. The deposit on walls and
ceiling is mainly on small protrusions, such as fibers, on rough sur-
faces which catch the particles as they go by on air currents or by
settling. Insects resting on the walls and ceiling will also be struck
by an occasional particle as it passes by. Surfaces colder than the air
temperature slightly attract very small particles.

Selecting Particle Size

No single particle-size range is suitable for all conditions where an
aerosol may be used. The particle-size range should be selected after
the factors involved in a proposed treatment have been evaluated. The
most important factor is time.
If the aerosol is to be applied to a structure or room that can be
closed for several hours, small particles will give the best dispersion
and penetration into small crevices. An aerosol with particles of about
5 microns mass median diameter was applied in a large warehouse.
A thermal generator was operated outside the building, introducing the
aerosol through an open door. The aerosol dispersed along the ceiling,
and by the time the proper amount had been applied it was well distrib-
uted throughout the warehouse by convection currents. The warehouse
was tren closed overnight and the aerosol allowed to settle. Uniform
distribution resulted.
When the treatment must be limited to a short time, larger particles
are necessary. A 15-minute exposure is sufficient with an aerosol having
particles with a mass median diameter of 15 microns, as most of the
particles will settle 10 feet within 5 to 15 minutes. Where flying insects
are to be controlled, this type of treatment is quite satisfactory. How-
ever, since lateral dispersion is restricted when particles of this size
are used, in large rooms or structures the aerosol must be released
from several points to give uniform dispersion.
Many types of application will fall between these two extremes. The
proper relation between time of exposure and particle size can be cal-
culated from the tabulation on page 2. The allowable settling time should
be based on the smallest particles. The approximate distances for
uniform dispersion can be determined from table 1. Better dispersion
can be obtained when heating sets up convection currents or when fans
are used.




UNIVERSITY OF FLORIDA
~~II I!I'I~I II II;I III! 1I
3 1262 09239 6349

After considering the foregoing factors, the operator can select the
most desirable particle size to meet his need, and then the type of gen-
erator that will produce the desired particle size and volume of aerosol.
If the available equipment will not produce the desired particle size,
then the time will have to be adjusted to the size that can be produced.
It has been demonstrated that particles above certain sizes, when
composed of some solvents and insecticides used in aerosol formula-
tions, will injure plant foliage. Persons treating greenhouses with
aerosols should keep this factor in mind when selecting the particle size.
Some structures may be too open for the successful use of aerosols
because of too much loss through the wall openings. In large open ware-
houses full of tobacco hogsheads, where an aerosol could not be con-
tained in the structures, it was found that a spray with particles of
abcut 50 microns mass median diameter, blown over the top of the
hogsheads by a mist blower, gave a uniform deposit of insecticide and
good insect control.

Formulations and Dosages

We have used the following formulations and dosages indoors:

1 pound of technical DDT dissolved in 7 1/2 pints of Sovacid 544C
(Socony Vacuum) to make 1 gallon, applied at the rate of 1 gallon
per 100,000 cubic feet.
1 1/4 pounds of technical DDT and 1/4 pound of lindane dissolved in
3 quarts of tetrachloroethylene plus 1 pint of SAE 50 motor oil
to make 1 gallon, applied at the rate of 2 quarts per 100,000
cubic feet.
1 quart of synergized pyrethrim (1-10 mixture of pyrethrins and
a synergist) plus 3 quarts of deodorized kerosene and 4 quarts
of tetrachloroethylene (proportions of last two materials can
be varied to regulate the particle size), applied at the rate of
1/2 to 3 gallons per 100,000 cubic feet, depending on the insects
involved.

To prevent explosion hazard, aerosols containing oils should not be
applied at rates that will give more than 2 gallons of these solvents per
100,000 cubic feet, and they should not be released near an open flame.
All work indoors should be done while wearing a proper respirator. The
pyrethrum formula is recommended for use around exposed foodstuffs.
Some formulations contain enough of a relatively nonvolatile oil to
maintain the desired particle size while it is suspended in the air.